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    Matrix Science Academy: Chemistry MHT CET L2 2022-23 Hints and Solutions

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    This document provides a chemistry test with 50 multiple choice questions and their solutions. The test covers topics including organic chemistry reactions, acid-base chemistry, transition metal complexes, and IUPAC naming conventions. It is intended as a practice exam to help students prepare for the MHT CET Level 2 chemistry exam.

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    Matrix Science Academy: Chemistry MHT CET L2 2022-23 Hints and Solutions

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    Light May
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    This document provides a chemistry test with 50 multiple choice questions and their solutions. The test covers topics including organic chemistry reactions, acid-base chemistry, transition metal complexes, and IUPAC naming conventions. It is intended as a practice exam to help students prepare for the MHT CET Level 2 chemistry exam.

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    This document provides a chemistry test with 50 multiple choice questions and their solutions. The test covers topics including organic chemistry reactions, acid-base chemistry, transition metal complexes, and IUPAC naming conventions. It is intended as a practice exam to help students prepare for the MHT CET Level 2 chemistry exam.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    30 views3 pages

    Matrix Science Academy: Chemistry MHT CET L2 2022-23 Hints and Solutions

    Uploaded by

    Light May
    This document provides a chemistry test with 50 multiple choice questions and their solutions. The test covers topics including organic chemistry reactions, acid-base chemistry, transition metal complexes, and IUPAC naming conventions. It is intended as a practice exam to help students prepare for the MHT CET Level 2 chemistry exam.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    MATRIX SCIENCE ACADEMY

    Chemistry MHT CET L2 2022-23


    Time : 60 Min Chem : Groupwise Paper Marks : 50
    Hints and Solutions

    01) Ans: D) both (a) and (b) therefore, it is paramagnetic in nature.


    Sol: Carbinol is CH3OH. Hence, ethanol
    CH3  CH2  OH is called methyl carbinol

    02) Ans: D)  7
    Sol: Since the solution is acidic, pH < 7. This is 2
    For the complex ion Ni  CN4  , In the complex
    because [H ] from H2O [107 ] cannot be
    2
    neglected in comparison to 1012 M. ion Ni  CN4  , there are four CN ligands
    which are strong field ligands.
    03) Ans: A) C2O24 Ni is in + 2 oxidation state.
    Sol: C2O24 Ni28  4s2 3d8  Ni2  3d8 .
    The hybridisation involved is dsp3 and the
    04) Ans: A) Ammoniacal silver nitrate complex ion is square planar with no unpaired
    electrons therefore it is diamagnetic in nature.
    05) Ans: A) neutral Figure
    06) Ans: D) one secondary and two primary OH 12) Ans: C) CsOH
    groups. Sol: C5OH is strong base undergoes complete
    CH2  OH
    ionization.
    |
    Sol: C H  OH
    | 13) Ans: A) Current
    CH2  OH Sol: Current has no effect the degree of ionization.
    i.e. one secondary and two primary alcoholic
    14) Ans: C) C2H5OH
    groups.
    Sol: C2H5OH
    07) Ans: B) salicylic acid.
    15) Ans: D) anomeric carbon
    2
     c
    08) Ans: C) K a  16) Ans: B) 1.0 m
    1 
    Sol: This is the mathematical form of Ostwald's [salt]
    Sol: pOH  pKa  log
    dilution law. [Acid]
    [Salt] [salt]
    09) Ans: B) acetic acid. 5.5  4.5  log  log  5.5  4.5  1
    K Cr O 0.1 0.1
    Sol: CH3CH2OH 
    2 2 7
     CH3COOH
    [salt]
    i.e.  antilog 1  10  [salt]  1
    0.1
    10) Ans: B) B2H6 and alkaline H2O2
    Sol: Hydroboration oxidation i.e. industrial 17) Ans: C) primary alcohol.
    preparation of alcohol is as Sol:
    1 Dry
    3CH3CH  CH2  B2H6   (CH3CH2CH3 )3 B
    2 ether
    HO
    (CH3CH2CH3 )3 B 
    2 2
     3CH3CH2CH2  OH

    11) Ans: B) 2,0


    Sol: In the complex ion NiCl4 
    2
    , the oxidation 18) Ans: C) 4
    state of Ni is + 2.
    19) Ans: B) amminepentachloroplatinate (IV) ion
    Ni28  4s2 3d8  Ni2  3d8
    The hybridisation involved is sp3 and the complex 20) Ans: A) Water
    ion is tetrahedral. It has two unpaired electrons,

    JEE-MAIN, MHT-CET, NEET/AIPMT, MHT-CET-XI - New Syllabus (MH)


    MATRIX SCIENCE ACADEMY

    Sol: H2O  H  OH 34) Ans: D) K4 Ni  CN2 (Ox)2 


    Acid
    [Acid because of donation of proton] Sol: K4 Ni  CN2 (Ox)2  by IUPAC rule.
    H2O H  H3O
    Base
    35) Ans: B) glucosidic linkage
    [Basic because of gaining of proton]
    36) Ans: C) sp3
    21) Ans: C) sp3d2
    Sol: sp3
    Sol: [CoF6 ]3 is an outer complex containing
    sp3d2 hybridisation. 37) Ans: D) 4  105
    Sol: c = 0.1,   0.02
    22) Ans: D) CH3CHOHCH3
    Kb  2.c  0.1  4  104  4  105
    Sol: CH3CHOHCH3


    38) Ans: B) 8  103
    23) Ans: B) H2SO4 , HSO4
    Sol: HgSO4 of Ksp  S2  S  Ksp

    Sol: Here, H2SO4 H  HSO4
    i.e. S  6.4  105  8  103 m/l
    24) Ans: A) dyes.
    Sol: 
    39) Ans: B)  Ag  CN2 
    Sol: EAN rule states that for a stable complex the
    EAN - atomic number of noble gas. If not so, the
    complex does not follow EAN rule. The EAN values
    for the given four complex ions are as follows.
    4
    (a) Fe  CN6  : Fe26 ,Fe2  24 electrons, 6CN
    25) Ans: A) triammine diaquachloro cobalt (III)
    chloride. ligands contributing 6  2  12 electrons
    Sol: From IUPAC rule.  EAN = 24 + 12 = 36 (At. No. of Kr).

    (b)  Ag  CN2  : Ag 47 , Ag   46 electrons. 2CN
    26) Ans: B) basic   a mino acid
    Sol: Out of two lone pairs of electrons on two ligands contributing 2  2  4 electrons
    nitrogen atoms, one is involved in Resonance and  EAN = 46 + 4 = 50 (Not At. No. of any noble gas).
    the other is available for protonation therefore  Does not follow EAN rule
    Histidine is a basic   a mino acid. 3
    (c) Co  NH3 6  : Co27 ,Co3  24 electrons 6NH3

    27) Ans: B) 6.3  103 ligands contributing 6  2  12 electrons


     EAN = 24 + 12 36 (At. No. of Kr
    Sol: Here, Ksp  4s3 2
    (d) ). PtCl6  : Pt78 ,Pt4  74 electrons. 6Cl
    Ksp 6
    1.0  10
    S  3 3  S  6.3  103 ligands contributing 6  2  12 electrons.
    4 4  EAN = 74 + 12 = 86 (At. No. of Rn).
    28) Ans: D) 13 40) Ans: B) Secondary alcohol
    Sol: [OH ]  101M , so pOH  1
    3
    We know, pH  pOH  14  p H  1 4 1 1 3 41) Ans: C) CO  H2O6 
    3 3
    29) Ans: D) quinol Sol: Fe  CN6  and Co  NH3 6  are low-spin

    30) Ans: B) cellulose complexes involving d2sp3 hybridisation, while


    3

    31) Ans: D) NO3 


     Co  H O 
    2 6
     is a high-spin complex involving

    Sol: Those compounds which accept H are sp3d2 hybridisation (outer orbital complex).
    known as Bronsted base, NO3 accepts H and
    form HNO3 . So it is a base. 42) Ans: D) BF3
    Sol: BF3
    32) Ans: D) lysine
    43) Ans: D) 1, 4
    33) Ans: C) aldehydic and alcoholic.
    44) Ans: B) intra-molecular hydrogen bonding

    JEE-MAIN, MHT-CET, NEET/AIPMT, MHT-CET-XI - New Syllabus (MH)


    MATRIX SCIENCE ACADEMY

    Sol:

    45) Ans: D) sp3 to dsp2


    Sol: In the complex ion NiCl4 
    2
    , the
    3
    hybridisation involved is sp and the molecular
    geometry is tetrahedral. When the weak-field
    ligands Cl , change to strong-field ligands CN ,
    2
    the complex ion formed is Ni  CN 4  which

    involves dsp2 hybridisation and the molecular


    geometry is square planar.

    46) Ans: D) B2H6 .H2O2  NaOH


    Sol: In this reaction addition of H2O has taken
    place according to Anti-Markownikoff rule; hence,
    the reaction must be B2H6 reaction.

    47) Ans: C) coordination number

    48) Ans: B) 3.0


    Sol: Here, [H ]  103 M,  pH   log[103 ] i.e. pH  3

    49) Ans: B) Cr  H2O4 Cl2  Cl

    Sol: Cr  H2O4 Cl2  Cl

    50) Ans: A) Myoglobin

    JEE-MAIN, MHT-CET, NEET/AIPMT, MHT-CET-XI - New Syllabus (MH)

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