Carbon Cycle
Carbon Cycle
Carbon Cycle
Review
- Defining the Earth's temperature
- Rock Weathering
• Assume two types of rock exist (and approximate their chemical compositions):
1. Carbonate - CaCO3
2. Silicate - CaSiO3
• Carbonate Weathering
𝐶𝑎𝐶𝑂" + 𝐻! 𝐶𝑂" → 𝐶𝑎!# + 2𝐻𝐶𝑂"$
○ Consumes 1 unit of carbonic acid (derived from CO2).
○ Produces 2 units of bicarbonate.
• Silicate Weathering
𝐶𝑎𝑆𝑖𝑂" + 2𝐻! 𝐶𝑂" → 𝐶𝑎!# + 𝑆𝑖𝑂! + 2𝐻𝐶𝑂"$ + 𝐻! 𝑂
○ Consumes 2 units of carbonic acid (derived from CO2).
○ Produces 2 units of bicarbonate.
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- Carbonate Rocks
• Gigantic reservoir of carbon
• Small flux
• Long residence time - about 200 million years
• Accounts for about 80% of carbon removal over long amouts of time
• Only oxidized carbon
- Chemistry of Carbon
Most Oxidized Most Reduced
CO2 CO CH2Cl2 CH3Cl2 CH4
Carbonates
Organic Compounds
weathering rate
ycle
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- What effect does biology have on the carbon cycle?
• Conversion of CO2 to organic carbon (reduction)
• Decay of organic compounds can give you the production of CO2 from organic car
• Transport CO2 to soils/enhanced weathering
• Transport organic carbon to deep water
- Photosynthetic Organisms
• Anoxygenic Photosynthesis
○ Green and purple (sulfur and non-sulfur) bacteria and heliobacteria
• Oxygenic Photosynthesis
○ Cyanobacteria
- Pigments
• Light harvesting pigments
○ Bacteriochlorophyll (bchl) for anoxygenic photosynthesis
○ Chlorophyll for oxygenic photosynthesis
○ Different varieties that can absorb light at different wavelengths
- Carbon Fixation
1. Generate a high-energy electron (from chemicals or light)
2. Donate that electron to CO2 through a pathway
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- Organic carbon oxidation = heterotrophy
𝐶𝐻! 𝑂 + 𝑇𝐸𝐴 → 𝐶𝑂! + 𝑒𝑙𝑒𝑐𝑡𝑟𝑜𝑛𝑠
TEA = Terminal Electron Acceptor
- Proterozoic Era
• Large increase of flux of organic carbon into sediments
• More oxygen goes into the atmosphere and creates another step function change
- O2 cycle feedbacks
• Positive coupling between carbon burial and oxygen accumulation
• Negative coupling between oxygen accumulation and carbon oxidation
• Overall negative feedback loop
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