XI (PQRS) CHEMISTRY REVIEW TEST-4

Q.1 A packet of an aritifical sweetner contains 45.75 mg of saccharin which has the structural formula

How many moles & molecules of saccharin are contained in 45.75 mg of saccharin? How many hydrogen
atoms? [3]
[Ans. 2.5 × 10 , 1.505 × 10 , 7.528 × 1020]
–4 20

[Sol. Molar mass of saccharin = 183

45.75  10 3
No. of mole of saccharin = = 25 × 10–3 = 2.5 × 10–4
183
No. of molecules = 25 × 10–3 × NA  1.505 × 1020
No. of atoms = 1.505 × 1020 × 5 7.528 × 1020 ]

Q.2 Calculate  (ratio of Cp & Cv) for

(a) Triatomic nonlinear gas at low temperature.
(b) Triatomic linear gas at high temperature; assume that the contribution of vibrational degree of freedom is 50%.
[3]
[Ans. (a) 1.333, (b) 1.222]
[Sol.(a) Vibrational degree inactive at low temperature
for triatomic nonlinear gas
3 3
Cv = R + R  3R
2 2
Cp = 4 R
Cp 4
= = = 1.333
Cv 3
3 2 1 9
(b) Cv = R + R + 4R × = R
2 2 2 2
9 11
Cp = R+R=
2 2
Cp 11
= = 1.222 ]
Cv 9
Q.3 The subshell that arises after f sub-shell is called g sub-shell.
(a) How many g orbitals are present in the g sub-shell
(b) In what principal electronic shell (n) would the g sub-shell first occur and what is the total number of
orbitals in the shell. [3]
[Ans. (a) 9, (b) 5, 25]
[Sol. For f subshell l = 3
 g subshell l = 4
(a)  total g orbitals in g-subshells = 2l +1
=2×4+1=9
(b) for principal shell, l = 4,  = n–1  n = 5
total no. of orbitals in shell = n2 = 52 = 25 ]

2  105
Q.4 For a real gas (mol. mass = 30) if density at critical point is 0.40 g/cm3 and its T
c= K, then
821
calculate Vander Waal's constant a (in atm L2mol–2). [3]
[Ans. 1.6875 ]
30
[Sol. Vc =  75 cm3mol–1
0.40
Vc
b=  25 cm3mol–1  0.025 Lmol–1
3
8a
Q Tc =
27 Rb
2  105 8 a
=  a = 1.6875 ]
821 27  0.0821  0.025

Q.5 The percentage by volume of C3H8 in a gaseous mixture of C3H8, CH4 and CO is 39. When 100 ml of
the mixture is burnt in excess of O2. Find volume (in ml) of CO2 produced. [3]
[Ans. 178 ml]
[Sol. 100 ml gaseous mixture contain 39 ml C3H8
So, mixing volume of CH4 & CO = (100–39) = 61 ml
1
C3H8 + 5O2 — 3CO2 + 4H2O; CH4 + 2O2 —CO2 + 2H2O; CO + O —CO2
2 2
61 ml (CH4 & CO) will produce 61 ml CO2; C3H8 will produce = 3 × 39 = 117 ml
Total CO2 produce = 117 + 61 = 178 ml ]
Q.6 The angular momentum of an electron in a Bohr's orbit of H-atom is 3.1652×10–34 kg-m2/sec. Calculate
the wavenumber in terms of Rydberg constant (R) of the spectral line emitted when an electron falls from
this level to the ground state.[Use h = 6.626 × 10–34 Js] [3]
8
[Ans. R   ]
9
nh
[Sol. Angular Momentum mvr =
2
n  6.626  10 34
3.1652×10–34 =
2
n=3
 1 
  1 
  = R. Z2.  n2 n2 
 1 2

1 1  8
 = R. 12  2  2   R   Ans.]
1 3  9

Q.7 For the reaction 2NH3(g) — N2(g) + 3H2(g). What is the % of NH3 converted if the mixture diffuses
twice as fast as that of SO2 under similar conditions [3]
[Ans. 6.25]

rmix M SO 64
 2 2
[Sol. rSO M avg  = M avg ; Mavg = 16
2
1
Let the initial moles be one
2NH3  N2 + 3H2
1–2x x 3x
Total wt. 17 1 1
Mavg = Total moles ; 16 = ; x= ; moles dissociated =
1  2x 32 16
(1 16)
% dissociation =  100 = 6.25% ]
1

Q.8 If Pd v/s P (where P denotes pressure in atm and d denotes density in gm/L) is plotted for H2 gas (ideal
d 
gas) at a particular temperature. If  dP ( Pd )  = 10, then find the temperature in °C. [3]
  P 8.21atm
[Ans. 40 K]
[Sol. PM = dRT
2 M  d ( Pd ) 2PM 2  8.21 2
Pd = P   ; =  10 ; = 10
 RT  dP RT 0.0821 T
T = 40 K ]
Q.9 Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain alkali metal
(work function = 2.0 eV). Calculate maximum kinetic energy (in eV) of the photoelectrons. [3]
[Ans. 0.55]
13.6 13.6 13.6
[Sol. En = – eV; E = – ; E = – eV/atom
n2 2
22 4
42
E = E4 – E2 = 2.55 eV
Absorbed energy = work function of metal + KE
2.55 = 2 + KE
KE = 0.55 eV Ans. ]

Q.10 Use the Heisenberg's Uncertainity Principle to calculate the uncertainity (in meters) in the position of a
honeybee weighing 0.70 g and travelling at a velocity of 0.85 m/s. Assume the uncertainity in the velocity
is 0.1 m/s.[Use h = 6.626 × 10–34 Js] [3]
[Ans. 7.53 × 10 m]–31

h 6.626 1034
[Sol. x = 4 mV = = 7.53 × 10–31 m ]
4  3.14  0.7 103  0.1

Q.11(a) What is the shortest wavelength line (in nanometers) in the Lyman series of He+ spectrum
[use R = 1.097 × 10–2 nm–1]
(b) Which is denser at the same temperature and pressure, dry air or air saturated with water vapour? Justify
in brief. [2+2]
[Ans. (a) 22.79 nm, (b) dry air]
1 1 1 
[Sol. (a) = RZ2  2  2 
 1  
1
=R×4

1 100
= 
4R 1.097  4
 = 22.79 nm
(b) Dry air is denser ; it has a large average molecular mass
Air satuarted with water vapour (molar mass = 18) ]
Q.12 Urea (H2N–CO–NH2) is manufactured on large scale by passing CO2(g) through ammonia solution
followed by crystallization. CO2 for the above reaction is prepared by combustion of hydrocarbon. If
combustion of 236.11 kg of a saturated hydrocarbon (CnH2n+2) produces as much CO2 as required for
production of 1000 kg urea, deduce molecular formula of hydrocarbon. [4]
[Ans. C12H26]
[Sol. 2NH3 + CO2  NH2 – CO – NH2 + H2O
1000  103
Moles of Urea = = 16.66 × 103
60
 moles of CO2 = 16.66 × 103
CnH2n+2 + O2  nCO2 + H2O
16.66  103
× [12n + (2n+2)] = 236.11 × 103
n
n  12
 Molecular formula of hydrocarbon  C12H26 ]

Q.13 2.5 g of a sample containing Na2CO3, NaHCO3 and some non-volatile impurity on gentle heating loses
12.4 % of its weight. Residue is dissolved in 100 ml water and its 10 ml portion required 15 ml of 0.1 M
aqueous solution of BaCl2 for complete precipitation of carbonates. Determine mass % of Na2CO3 in
the original sample. [5]
[Ans. 42.4% , Na2CO3]
[Sol. Na2CO3 – x gm
NaHCO3 – ygm
12.4
× 2.5 = 0.31 gm
100
weight in loss due to formation of H2O & CO2
2NaHCO3  Na2CO3 + CO2 + H2O
y y y
84 2  84 2  84
y y
×4+ × 18 = 0.31
2  84 2  84
0.26 y + 0.107 y = 0.31
y = 0.84
mole of NaHCO3 = 0.01
0.01
Na2CO3 from NaHCO3 = = 0.005 = 0.5 × 10–2
2
mole of BaCl2 + Na2CO3  BaCO3 + 2NaCl
moles of BaCl2 = moles of Na2CO3  15 × 10–3 × 0.1
mole present in 100 ml = 10 × 1.5 × 10–3  1.5 × 10–2
Initial moles of Na2CO3 = 1.5 × 10–2 – 0.5 × 10–2 = 10–2
10 2  106
Mass percentage of Na2CO3 in sample = × 100 = 42.4% Ans.]
2 .5
Q.14(a) Arrange the correct order of increasing wavenumber of the following radiations
I.R., U.V., radiowaves, X-rays and visible light
(b) Match the column
Column I Column II
(A) Lyman series (P) Visible region
(B) Humphrey series (Q) Ultraviolet region
(C) Paschen series (R) Infrared region
(D) Balmer series (S) Far infrared region
(c) Two flasks A and B of equal volumes maintained at temperature 300 K and 600 K contain equal mass
of H2 and CH4 respectively. Calculate the ratio of total translational kinetic energy of gas in flask A to
that of flask B. [2+2+2]
[Ans. 4 ]
[Sol.(a) X-rays > U.V. > visible light > I.R. > radiowaves
(b) AQ, BS, CR, DP
m/2
(c) moles ratio = nA/nB = =8
m / 16
TA/TB = 300/600
n A TA 1
Ratio = = ×8=4 ]
n BTB 2

Q.15(a) At 273 K and 8 atm pressure, the comprassibility factor for a gas is 0.8. Calculate the volume of
1 milli moles of gas at this temperature and pressure.
(b) If velocity of electron moving in nth Bohr’s orbit of H-atom is ‘vn’, what is the velocity of a hypothetical
particle of charge same as electron and mass two times to that of electron revolving in the same orbit.
Assume the nucleus to be non stationary.[Given : 1840 me = mp] [2+4]
1841
[Ans. (a) 2.24 ml, (b) vn × ]
1842
P.V
[Sol.(a) = 0.80
nRT
V  22.4   273 
  = 0.8 ×    = 2.24 L / mol.
n  273   8 
Volume of one millimoles of gas = 10–3 × 2.24 = 2.24 × 10–3litre
= 2.24 ml.
(b) Taking movement of nucleus and applying concept of reduced mass
 n 2h 2 
Rn =  2

2
 z 4  me 

nh  zk 2e 2   
ve = 2Rm  ve =  nh  m 
e   e 
 1840 m e
for electron m = 1841 m
e e

 1840
for hypo particle 2m =
e 1842
 v 'n 1840 1841 1841
vn = × = Ans.
1842 1840 1842
1841
v'n = vn × ]
1842

Q.16 Given the sub shells 1s, 2s, 2p, 3p and 3d. Identify those meet the following descriptions
(a) Has l(azimuthal quantum no.) = 2
(b) Can have m (magnetic quantum no.) = –1
(c) Is empty in a nitrogen atom
(d) Is full in a carbon atom
(e) Can contain two electrons, both with spin ms = +1/2
(f) Contains the outermost shell electrons in oxygen atom [6]
[Sol. (a) 3d (b) 2p, 3p, 3d (c) 3s, 3p and 3d (d) 1s & 2s
(e) 3p, 3p and 3d (f) 2p ]

Q.17(a) Calculate the ratio of time periods in first and third orbits of hydrogen atom.
(b) The electron in the first excited state (n1 = 2) of H-atom absorbs a photon and is further excited (n2).The
Debroglie wavelength of the electron in this excited state is 1340 pm. Find the value of n2. [3+3]
[Ans.(a) 1/27, (b) 4]
2rn
[Sol.(a) Time periods =
vn

n3
T
Z2
T1 1 13
 T = 3 =
3 3 27

150
(b) = Å
V

150
 1340 ×10–2 =  V = 0.835 volt
V
 13.6 
Energy = 0.835 eV i.e. n = 4  2  0.85 
 4 
or
h
=
mv

6.62 1034
v=
13.4 1010  9.11031
 v = 5.43 × 105 m/s
z
2.18 × 106 × = vn
n
1
2.18 × 106 × = 5.43 × 105
n
n=4 ; n =2 first excited state Ans.]

Q.18 The apparatus shown consists of three temperature jacketed 1 litre bulbs connected by stop cocks.
Bulb A contains a mixture of H2O(g), CO2(g) and N2(g) at 27°C and a total pressure of 547.2 mm Hg.
Bulb B is empty and is held at a temperature –23°C. Bulb C is also empty and is held at a temperature
of –173°C. The stopcocks are closed and the volumes of lines connecting the bulbs is zero.
Given: CO2(g) converted into CO2(s) at –78°, N2(g) converted into N2(s) at –196°C & H2O(g)
converted into H2O(s) at 0°C.
[Use R = 0.08 atm-litre/mole·K]

(a) The stopcock between A & B is opened and the system is allowed to come to equilibrium. The pressure
in A & B is now 228 mmHg. What do bulbs A & B contain?
(b) How many moles of H2O are in system?
(c) Both stopcocks are opened and the system is again allowed to equilibrium. The pressure throughout the
system is 45.6 mmHg. What do bulbs A, B and C contain?
(d) How many moles of N2 are in the system? [8]
 547.5 
  1
 760  0.72  1
[Sol. Total initial no. of moles in bulb A = ntotal = = = 0.03
0.08  300 0.08  300
After opening the cock:
In bulb A
 228 
  1
n(N  760 
2  CO 2 )
= = 0.0125
24

 228 
  1
n(N  760  0 .3
I bulb B 2  CO 2 )
= = = 0.015
0.08  250 0.08  250
nH = 0.03 – (0.0125 + 0.015) = 0.0025
2O

Ans.(a) Bulb A : N2(g), CO2(g)

Bulb B: N2(g), CO2(g), H2O(s)
Ans.(b) No. of mole of H2 = 0.0025
45.6
1
After opening C  n N in A = 760 = 0.0025
2
0.08  300
 45.6
1
n N in B nN 760
= = 0.003
2 2
0.08  250
45.6
1
0.06
n N in C n N = 760 = = 0.0075
2 2
0.08 100 0.08 100
Ans.(c) Bulb A : N2(g)
Bulb B : N2(g), H2O(s)
Bulb C : N2(g), CO2(s)
Ans. (d) Total no. of mole of N2 in system = 0.013 ]