Arfken MMCH 7 S 2 e 13
Arfken MMCH 7 S 2 e 13
Arfken MMCH 7 S 2 e 13
13 Page 1 of 3
Exercise 7.2.13
Radioactive nuclei decay according to the law
dN
= −λN,
dt
N being the concentration of a given nuclide and λ, the particular decay constant. In a
radioactive series of two different nuclides, with concentrations N1 (t) and N2 (t), we have
dN1
= −λ1 N1 ,
dt
dN2
= λ1 N1 − λ2 N2 .
dt
Find N2 (t) for the conditions N1 (0) = N0 and N2 (0) = 0.
Solution
ln N1 = −λ1 t + C1
So then
N1 (t) = N0 e−λ1 t .
Substitute this formula for N1 into the second ODE involving N2 .
dN2
= λ1 N1 − λ2 N2
dt
dN2
= λ1 N0 e−λ1 t − λ2 N2
dt
Bring λ2 N2 to the left side.
dN2
+ λ2 N2 = λ1 N0 e−λ1 t
dt
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Arfken Mathematical Methods 7e: Section 7.2 - Exercise 7.2.13 Page 2 of 3
This is a first-order linear ODE, so it can be solved by multiplying both sides by an integrating
factor I. ˆ t
I = exp λ2 ds = eλ2 t
λ1
N2 (0) = N0 e−λ1 (0) + C2 e−λ2 (0)
λ2 − λ1
λ1
0 = N0 + C2
λ2 − λ1
λ1
C2 = −N0
λ2 − λ1
Plug this back into the general solution for N2 (t).
λ1 λ1
N2 (t) = N0 e−λ1 t − N0 e−λ2 t
λ2 − λ1 λ2 − λ1
λ1
= N0 (e−λ1 t − e−λ2 t ), λ1 6= λ2
λ2 − λ1
Suppose secondly that λ1 = λ2 . Then equation (1) becomes
d λ2 t
(e N2 ) = N0 λ2 .
dt
Integrate both sides with respect to t.
eλ2 t N2 = N0 λ2 t + C3
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Arfken Mathematical Methods 7e: Section 7.2 - Exercise 7.2.13 Page 3 of 3
N2 (0) = C3 = 0
So then
N2 (t) = N0 λ2 te−λ2 t , λ1 = λ2 .
Therefore,
N1 (t) = N0 e−λ1 t
λ1
N0
(e−λ1 t − e−λ2 t ) if λ1 =
6 λ2
N2 (t) = λ2 − λ 1 .
N0 λ2 te 2−λ t if λ1 = λ2
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