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MATERIAL SAFETY DATA SHEET

Product Trade Name: INITIATOR-EXTRA HIGH TEMP


Revision Date: 28-Mar-2011
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: INITIATOR-EXTRA HIGH TEMP


Synonyms: None
Chemical Family: Explosive
Application: Explosive Charge

Manufacturer/Supplier Halliburton Energy Services


P.O. Box 1431
Duncan, Oklahoma 73536-0431
Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance


Telephone: 1-580-251-4335
e-mail: [email protected]

2. COMPOSITION/INFORMATION ON INGREDIENTS

Substances CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA


Cyclotetramethylenetetranitramin 2691-41-0 0-10 Not applicable Not applicable
e (HMX)
2,6-Bis(picrylamino)-3,5-dinitro- 38082-89-2 5 - 10% Not applicable Not applicable
pyridine (PYX)

3. HAZARDS IDENTIFICATION
Hazard Overview Explosive. May cause eye, skin, and respiratory irritation. May cause headache,
dizziness, and other central nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably
mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water
for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treat symptomatically.

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5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined


Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (F): Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None. Do NOT fight fire. Isolate area and evacuate personnel to a safe area. Guard
against intruders. Allow fire to burn itself out.

Special Exposure Hazards May detonate with impact or on heating. May explode and throw fragments 1 mile or
more in fire. Evacuate all persons, including emergency responders.

Special Protective Equipment for Not applicable.


Fire-Fighters

NFPA Ratings: Health 1, Flammability 3, Reactivity 4


HMIS Ratings: Health 1, Flammability 3, Reactivity 4

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary Measures Use appropriate protective equipment. Use only competent persons for cleanup.

Environmental Precautionary Prevent from entering sewers, waterways, or low areas.


Measures

Procedure for Cleaning / Isolate area and remove sources of friction, impact, heat, low level electrical current,
Absorption and RF energy. Remove ignition sources and work with non-sparking tools.

7. HANDLING AND STORAGE

Handling Precautions Do NOT consume food, drink, or tobacco in contaminated areas. Avoid contact with
eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing before
reuse.

Storage Information Store only in ATF approved magazines. Keep away from friction, impact, and heat.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Cloth gloves.

Skin Protection Cotton coveralls, undergarments, and socks. Conductive soled shoes.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid


Color: Metallic
Odor: Odorless

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9. PHYSICAL AND CHEMICAL PROPERTIES
pH: Not Determined
Specific Gravity @ 20 C (Water=1): Not Determined
Density @ 20 C (lbs./gallon): Not Determined
Bulk Density @ 20 C (lbs/ft3): Not Determined
Boiling Point/Range (F): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (F): Not Determined
Freezing Point/Range (C): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Insoluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (lbs./gallon): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistrokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid May detonate with friction, impact, heat, and low level electrical current.

Incompatibility (Materials to Strong acids. Strong alkalis.


Avoid)

Hazardous Decomposition Shrapnel. Oxides of nitrogen. Metal oxides. Carbon monoxide and carbon dioxide.
Products

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation. Product does not present exposures health hazards
during normal handling and use. However, this product is an explosive material and
uncontrolled detonation may cause severe physical injury including death. All
explosives are dangerous and must be handles carefully and used following
approved safety procedures under the direction of competent, experience persons in
accordance with all applicable regulations and ordinances.

Inhalation May cause effects to the blood and blood system. May cause central nervous system
depression including headache, dizziness, drowsiness, incoordination, slowed
reaction time, slurred speech, giddiness and unconsciousness.
May cause damage to the nervous, urinary, and reproductive systems. Nitrogen
oxides generated during use are irritating to the respiratory system.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under
ingestion. Nitrogen oxides generated during use are skin irritants.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions None known.

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Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause blood forming system, nervous, urinary
tract and reproductive system damage. Prolonged or repeated exposure may cause
embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive / Not determined


Developmental Toxicity:

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not determined

Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Do NOT reuse container. Store only in ATF approved magazines.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN0455,Detonators, Non-Electric, 1.4S, II


EX-2009110143
NAERG 114

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Canadian TDG
Detonators, Non-Electric, 1.4S, UN0455, II
EX-2009110143

ADR

UN0455,Detonators, Non-Electric, 1.4S, II


EX-2009110143

Air Transportation
ICAO/IATA

UN0455,Detonators, Non-Electric, 1.4S, II


EX-2009110143

Sea Transportation
IMDG

UN0455,Detonators, Non-Electric, 1.4S, II


EX-2009110143
EmS F-B, S-X

Other Transportation Information


Labels: Explosive 1.4S

15. REGULATORY INFORMATION

US Regulations
US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely Not applicable


Hazardous Substances

EPA SARA (311,312) Hazard Acute Health Hazard


Class Fire Hazard
Sudden Release of Pressure Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the
reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:
Lead//7439-92-1
Copper//7440-50-8

EPA CERCLA/Superfund EPA Reportable Spill Quantity is 400 Pounds based on Lead (CAS: 7439-92-1).
Reportable Spill Quantity

EPA RCRA Hazardous Waste If product becomes a waste, it does meet the criteria of a hazardous waste as
Classification defined by the US EPA, because of:

Reactivity D003

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.


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NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law Does not apply.

Canadian Regulations
Canadian DSL Inventory All components listed on inventory or are exempt.

WHMIS Hazard Class F Dangerously Reactive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS
Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton
representative.

For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.

***END OF MSDS***

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