Demeton

SAFETY DATA SHEET
1. PRODUCT
1.1 Product identifiers

Name: Demeton S
CAS-No.: 126-75-0
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Synthesis of substances
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Acute toxicity, Oral (Category 2), H300
Acute toxicity, Dermal (Category 1), H310
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram
Signal word Danger

Hazard H300 + H310 Fatal if swallowed or in contact with skin
statement(s)
Precautionary P262 Do not get in eyes, on skin, or on clothing.
statement(s) P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water.
P310 Immediately call a POISON CENTER/doctor.
P322 Specific measures (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P361 Remove/Take off immediately all contaminated clothing.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS

No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Molecular weight: 258.36 g/mol
CAS-No.: 126-75-0
EC-No.: 204-801-8
Hazardous components
Component Classification Concentration

Demeton-S
Acute Tox. 2; Acute Tox. 1; H300 + H310 <= 100 %
1
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Move out of dangerous area.Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.2 Indication of any immediate medical attention and special treatment needed
No data available
5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture

No data available
5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information

No data available
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel
to safe areas.
For personal protection see section 8.
6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections

For disposal see section 13.
2
7. HANDLING AND STORAGE
7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Components with workplace control parameters

Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Personal protective equipment

Eye/face Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
protection government standards such as NIOSH (US) or EN 166(EU).
Skin Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
protection touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Complete suit protecting against chemicals, The type of protective equipment must be selected according to
Protection the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-
protection purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
environmen
tal
exposure
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties

Appearance Form: liquid
Odour unpleasant
Odour Threshold No data available
pH No data available
Melting point/freezing point No data available
Initial boiling point and boiling range No data available
Flash point No data available
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability or explosive limits Upper explosion limit: 5.3 %(V)
Lower explosion limit: 1 %(V)
Vapour pressure No data available
Vapour density No data available
Relative density 1.132 g/cm3
Water solubility insoluble
3
Partition coefficient: n-octanol/water No data available
Auto-ignition temperature No data available
Decomposition temperature No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available
9.2 Other safety information
No data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents, Strong bases
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Sulphur oxides, Oxides of
phosphorus
Other decomposition products - No data available
In the event of fire: see section 5
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
LD50 Dermal - Rabbit - 24 mg/kg
LD50 Intraperitoneal - Rat - 1.500 mg/kg
Remarks: Biochemical:Enzyme inhibition, induction, or change in blood or tissue levelsTrue cholinesterase.
LD50 Intraperitoneal - Mouse - 0.174 mg/kg
Remarks: Peripheral Nerve and Sensation:Flaccid paralysis without anesthesia (usually neuromuscular blockage).
LD50 Intravenous - Rat - 1.700 mg/kg
Remarks: Biochemical:Enzyme inhibition, induction, or change in blood or tissue levelsTrue cholinesterase.
LD50 Subcutaneous - Mouse - 6 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
4
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: TF3130000
bradycardia, bronchospasm, restlessness, To the best of our knowledge, the chemical, physical, and toxicological
properties have not been thoroughly investigated.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
No data available
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and
non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)
UN number: 3278 Class: 6.1 Packing group: I
Proper shipping name: Organophosphorus compound, liquid, toxic, n.o.s. (Demeton-S)
5
Reportable Quantity (RQ):
Poison Inhalation Hazard: No
IMDG
UN number: 3278 Class: 6.1 Packing group: I EMS-No: F-A, S-A
Proper shipping name: ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. (Demeton-S)
IATA
UN number: 3278 Class: 6.1 Packing group: I
Proper shipping name: Organophosphorus compound, liquid, toxic, n.o.s. (Demeton-S)
15. REGULATORY INFORMATION
SARA 302 Components

No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components

This material does not contain any chemical components with known CAS numbers that exceed the threshold (De
Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards

Acute Health Hazard
California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.

Acute Tox. Acute toxicity
H300 Fatal if swallowed.
H300 + H310 Fatal if swallowed or in contact with skin
H310 Fatal in contact with skin.
HMIS Rating
Health hazard: 3
Chronic Health Hazard:
Flammability: 0
Physical Hazard 0
NFPA Rating
Health hazard: 4
Fire Hazard: 0
Reactivity Hazard: 0

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SAFETY DATA SHEET

1.1 Product identifiers

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Acute toxicity, Dermal (Category 1), H310

2.2 GHS Label elements, including precautionary statements

Signal word Danger

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS

Component Classification Concentration

4. FIRST AID MEASURES

4.1 Description of first aid measures

5.1 Extinguishing media

Suitable extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

5.4 Further information

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

For personal protection see section 8.

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

7.1 Precautions for safe handling

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

8.2 Exposure controls

Appropriate engineering controls

Personal protective equipment

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

9.2 Other safety information

10. STABILITY AND REACTIVITY

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

10.5 Incompatible materials

Strong oxidizing agents, Strong bases

10.6 Hazardous decomposition products

Other decomposition products - No data available

In the event of fire: see section 5

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

12. ECOLOGICAL INFORMATION

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Other adverse effects

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

14. TRANSPORT INFORMATION

Proper shipping name: Organophosphorus compound, liquid, toxic, n.o.s. (Demeton-S)

Poison Inhalation Hazard: No