17.

o~naotk pressure (it)

nv - 11sRT
1tV ~ ~
M X RXT M - WB X RX T
B ' ,, - ~
n
n .,,, ll rrxv
. . v XR>< r
Osmot1~ p~essfrure is related to the rela . or ,r - C'RTwh\.TC ·c .
depression m eezing points . hve low . ts molarity.
according etln2 of v
to the foUo ..~ apour pre-s~u .
" ,, mg rclatio . rt, clevatJon in bo ·1· .
P _ . nr;. 11ng poun and
1t ~ .t /J I I
(
P,.
~ Ix J ~
d><R.xr

1t ::: AT,, X d X RX T B

~,,
it ~ AT/ X cl X RX T

where di~ the den~ity of solut'

~I
IOI} at (CUln,,
...,... raturc ·r
18. Molal elt:vation constnnt, K1i _ !!_ x M,1 x <r;~
IOOOx A"~P H
19. Molal <lt:pression constant K _ R x M,, x (T1") 2
'f -:-:-::---~-
IOOO X6 luc fl

PilUNUM® ®WW•it'FI
Choose and write the correct option in ti, r. II .
. of amalgam of mercu e.Jo owrng 'Jllestious ·
n
I. /\. so lutio h
Solute · S ry Wat sociiu 111 contains
o 1vent .
(a)Solid Sol' 1 Solute Solvent
(h) Solid
ic
(c) Licp1icl Solid Li<p1id
. . (d) Liquid L" .d
2. One kdo~ram of sea water sample c r . iqui
. 1~ . .• on aans 6 mg of di~s0 J . •d O Th
ppm m I 1c s,1mplc 1s · ,c t· . c conc.:cnlr.tlion of o in
(n) 0.06 (b) tiO ~
(r) 6 (d) 0.6
3. Mole fr.adion of lhc solute in a 1.0 mol·al ., . . . • •
- - • • (jllCOllS so1Uhun ls:
(n) 0.1 / 10 (h) 0.0 1ii (r) 0.0:,-1-1
(d) 1.7700
4. /\I wlial co11c.:c11lra1io11 llol':-. lite :-.olu1iu 11 uf' ell 1 I. . I . I .
" ) cue ~ ) t.:u u:-.ct..l a:-. au ,111l1frcc1.c?
(n) J:>'; i w,h1m<' by ,·olnmc (b) " >'t I I
. . ,>, ,< lllrl~~ >y \ 'O llllll'
(() :,59t mass by mass td,1 35 ppm

~DU)<TRUM £;!_~ ICO 371-373 3rd FLOOR SECTOR 34-A CHANDIUIUI

~:b~i1::(SPECTRUM ~---_E=- 11: 11111-1ms. 7111M2717 ~
25
 Wllll'r al room hm11>l'rallll'll soluli.1111 fl•cls l'cml lu loud1· ll nc1l"r Wh'
5. On clissolvinu· :-. in
:-. su.,11r
tht' li11l11win~ l'IISt•s dissolution 111' sug-nr will be mosl. rnpad? [N<:F.n1· F. Pl•ch
• . • ··"'«'111
(11) S11~11r rr~·~rals in cnlcl 1l';lfc•1: (h) S11gnr rr\'srnl, 111 hor wntt'r. "'
(1') Pnwclt-rt'd sngnr in cnld wnrcr. (d) Pnwckrc' rl s11gnr in hor ,rnrf:r.
6. At l'quilibrium 1hc r11lll of diswlution of :1 solid solute in a vul:1lill' lh1uid
, . .
.
SO1V~nt
IN<.f.HJ' f.\-""'/'l
(b} grt'illt'I' Lli.111 lilt' l'illt' of l'l'\'sl ·il)i',. , fir
(11) b,~ 1ha11 the rntt' ol't'l'~·s1allisa1iu11 . • ~· 1111.111
(cl) :tern
(fl l'qual Ill lhl' rate of crys1alli~a1icJ11
7. The valut' of llt•nry's conslnnl KH is______ . . INl.'f.'Jff f :.t,•mpl
(a) g-n•att•r for ~-ases with hig-he1· solubilit )', (b} grt'aler tor 1,;<ISl:'S w11h lowt'r solubilitl'. Qrj
(t·) t'(>nslnl\l for all gast•s, (rl) 1w1 l'dn ltid 10 IIH' sol11hili1)' of g:•~c-~. ·

8. I.ow concentrntion of oxy~cn in the blood and tissues of people livin~ al hi~h."!'i_ludc is due
-----· INU:Rr 1,;.te111ptar1
(a) low lt'mpc;-rall11·c;-
(b) low ntmospht'ric prt'sstrrt'
(c) high atmospheric pressure
(d) both low te mpera! ure and high al 111ospheric press11rt'
9. 50 ml. of nn aqueous solution of glucose C 11 II 1~06 (Molar mass: 180 g/mol) contains 6.02 )( 10 ,
molecules. The concentration of the solution ";11 be l<:JlSE 2020 (56/2/IJI
(a) 0.11\·I (b) 0.2 ;,\·I (c) 1.0 :\,f (d) 2.01\·f
l 0. A solution of chloroform in dicthy lether
(a) obeys Rao uli's law. (b) shows a posi tive dc·\·iar ion from R;iouh's law,
(c) s hows II negati,·e dcYiation from Rno11lt'l> law.(d) b<"h,wes like' a near ideal solution.
I I. Considering the fol'lnntion , breaking nnd strength of h ydrogen bond, predict which of tlit
following- mixltm:s will show a positive dl•viation fr~m Ra_o ult 's law? [NCERT Exemplar]
(a) .Methanol aud acetone. (b) C.hlol'Olunu aud acetone.
(c} ;\'itl'ic acid and wa ler. (cl) Pht'nol and aniline.

12. The system thnt forms maximum boiling azcolropes is:

(n) ctln·I alcohol-water (b) hcnzcnc-tolt1cn c
(c ) aCl'ltllll'•Chloroform (,/) <:.11·1.>011 disulphidc:-ac:etom:
13. At n given temperature, osmotic p1·ess11re of a concentrated solution of a 1mbstance
IN<.'ERT E.1;11111plarJ
~
(a) is hig h <'r than 1.hal ofa dih11e solution .
is lower rhan tlrnr. of;-i dil11tc snl111io n.
(h)
(c) is snmt· as that of a dilute rnlutio n.
(d) c.muot be compared with os111olit· prt'ssure oftlilutt' solution. ]
14. An unripe mango plact"d in a concentrated salt solution to pl'epare pickle, shri\'els becm
[NCERT faemplor)
(t1) il g,1ius water due lo osmosis. (b) it lost·s w,ller due to re\·crse osmosis.
(c) it gain!! Wnt<'r clue to revcr!le osmosis. (d) it loses water <lue to osmosis.
15. lf we place lhe blood cells in a solution conlaining less llrnn 0.9~f (m/V) sodium chloride, Thef
would swell. This is because
2
(11) tht- sol111io11 is hypotonic (b) tht'. snl111ion is isoronic
(c) th.- solution is hypcrronk (d) norll' of thcsc
2
16. Which of the following colligath·e property is used to calculate the molar mass ofbiomolecu
(n) Relativt'. lowt-ring ofvi1po11r press11ri- (b) F.lerntio 11 in hoiliug point
(c) l>f'prcssion in frc<-zing point (d) Osmotic prcssmc

ICO 371-373 3rd FLOOR SECTOR 34-A

11111117-13325, 7811M2797
 ls is false ? [Nr:F.RT F.wmJ,lu r)
17. \Vhich of 1he l'ollowin ~ s lalemen pt t'ssu n.· a n .· lhl' silm t·.
(a) l "uit s o filtlll osphtTic pn·s-, u1·t· aud
0 M110 1ic
(Ii) In n •Vt'l"St' n~llll >!> i~. ~n! Vt' lll ntolc--nil t'!> mo,·c-- 1_'11·0 111-{h_ a !'lt"lllipt"1·11
1t"a h~t" lllt"lllhra1 1t' h-0 111 a
n •gin n nf ln w <'r ,n11n ' 11trnrio11 ofsnlilf <' ro a r<'g10 11 of lugh <' r ~n nc<' nrrnrin n .
(c) Thc vn l11 c o f m o lnl d <' prcssin n ,nn st.n nt de- pends c,n n nrurc of ~n l\'C' nt.
(cl) Rd a tin· lowe ri11g uf ,·;1p<.H1 r p rt'!>'>ll l"I:' , is a d i111t'11'>i u 11less l(lH1111JLy.
and boiling
Molal e lentlio n c ons tant is c alculate d from th e e nthalpy of v a pourisat ion (,\ .,..,H)
18.
poinl of 1he pun· s ol\'enl (1.,) using the rdalion:
ti ,~,11 H . 1 (HIil ,w.1·,.,,'!
M H'f°t I 000 ff/' 'I. •
( c) J.:.. = 'I. (d ) K 1, = I\ llli~
(a ) ;;,, = 100(; 6. 11 ({J) A1, = M ti 11 " I 000 AJ.-1 R 'J"'' ~ ,•11/• ~
•~ A •~

· 1· JI · 1 • f'· l · :> [NCERT. Exempla. r]

. .
19. \-Vhid1 ot the o owmg s lalcmen s as ,1 sc. t solvents will ha, e the
(a) ·1\\'O differ ent solution s of sucrose of same molality prepare d m differen
. .
same d e pn·ssiou iu freezin g p o iut.
(b) ll1e osm o tic (ll"t-ssu1·e a sol111io 11 i.s g iven b y the e qual.io n 7t = CRT ( where C is the molant y of
or
the solmio n).
(c) D eneasi11 g o rcl t- r o f osm o t ic press111·t- fo r 0 .0 1 M a q11t-ou s solu1ion s of
barium chlo rid e, p o ta ssium chlo rid e, acetic a c id and su crose is
l:h 1C I,, > K C I > C l L1C OO H > s11crose-.
a s olution
(d) Acco;.cli11 g t o R ao11l~ 's law, tht' vapo ur press11re e xe rLe d by a volatile compon e nt of
is dircc.rly p rop o rtio n;i l to irs mole frac.ti o n in th e solution .
20. W'hcn KCI is dissolve d in water, the
(a) boiling po int of rh c solution <kcreases
(b) boiling point of the solution increases
(c) boiling point o f th e solution 1·e mains unclrnnge d
(d) none of th e a bove
21. Compare d lo Puri, lhc vapour pressure of watt..-r at Delhi is
(a) eqnnl (h) more (r.) less (d) none of th e se
The ppm of
22. A sample of' hard waler was found lo contain 40 mg of MgS0-1 in 10 kg of' sample.
MgSO.1 in the sampl e will b e
(a) 2 ppm (b) 1 pp111 (c) 8 ppm (d) l!i ppm
23. If the m ()lari1y of a solution ()f s ulphuric add is 1.35 .M, then its molality wilJ be
(The density of' the acid solulion is 1.02 g cm-:")
(a) '.L43 m (b) 1.80 m (r) 1.5 2 m (d) 2.39 m

• IfMolariLy of dilute solulion is doubled , lhc valu e of' mola) depressi on conslant (Ki) will
be
{a) halved (b} tripled (c) unchang ed (cl) douuled

• When dry grapes or raisins arc placed in waler, lhcy swclJ due to
(c,) osmosis (b) diffusion (c) surface Lension (d) absorpti on
. The mixture lhnl forms minimum bc,iling azcolrop c is
(o) ~frtlurno l-acctk acid (h) Chlornfo nn-hen7. r.nc
(r.) Water-ni tric add (rl) 11-hcxan c-acct.on c
When nn egg is placed in conccntr nlcd solution of' sodium chloride , it shrinks due lo
(o) cxosmosi11 (b) cndosmn sis (c) diffosion (d) surface rcnsion

When a non-vulu lifo solute in dissolve d in w.itcr

(a) The boiling point increases (b) The vapour pressure decrease s
(e) The frec:r.ing pnint dt'c-rt"nsC'.s (r/} .\II of the nbovc

ICO 171-173 3nl FLOOR Sl!CTOR 34-A CHANDIGARH

IMR==JJit=. 11111117•13321, 7181M 2717 www.eduxtrum.com
. RUMa 27
 • term is not affected by the temperature?
• conccntrauor1
29. Which of the fo IIowuig . . . (c) .Molalil)' (d) ..!!:.'h
. (b) ;\onna 111~ · 1•
(a) Mol,1nlv· . . .. ff, ·iccl b)' 1hc 1cu1pcriilurc, ,:>

30 \Vhid1of1hcfoIJowing1s,1 _1.:t: 1· , (r) .!!.!.(fr. (rl) All of th .

• . (h) ;\on11a 11\ 1,

I'd in liquid does ,wt dep~n d upon

(a) Molan1v
. .'. .
31, The solubtl1ty of so 1 . .
3 (b) lt'lllpt'rat 11re
. . of'~oh1te aud so, 1 t'lll .
(al 11,•1 t111t' · (d) ,ill ol r.hc above
(d p rcss11 re •
. . d' , ,ct in 90 g of water, then the 111nlc-fractt011 of solute i~
32. If 5 ·85 g of NaCl is ,sso 1\C ..
(h) o.2 (r)U.0I (r/)0.01%.
(a) 0.1
u ·r· point of water in a pressure cooker is
33, oOI uig 00"(' ( ) l l l OO"C (d) uoue of ti
(a) below 1000c (b) above 1 . c. equa u .
34, The molarity of water is
r-: r-: - (c) 80 (d.> ,19,9
(a) 18 (b) ,)::,,;:,
35, Which one of the following is a colligative property?
(a) The lwlflife ofa radioactive elemenr (b) The conductance of solutiou
(1:) Tht> s11rfoce tensioll of solu1.io11 (d) The osmotic prt'.ssure of sol111io11
36. The relative lowering of vapour pressure is equal to the mole fraction of solute.
known as
(b) Rauuh's law
(a) Hem')'°s law
(c) Ostwald's clilutiou law (d) Van't Iloff law

37. Isotonic solutions have the same

(a) Yisrosily (b) molar co11cen1 ration (c) boiling pni11t (d) density
38, Ir 18 ~ glucose is present in IO00 g ofa solvent, the solulion will be
(a) I 111ul.1r (b) 0 . I 1110/.11· (c) O,j 111Ulal (ti) 0. I 111ufal
39. Al constant temperature, the osmotic pressure of a so)ulion is
(a) clirt'clly proporlional 10 1he co11ce111ra1io11.
(b) i11verselr proportional 10 rile conce111ra1ion.
(c) direcll)' propor1io11al 10 1he sciw11·e. o f 1he conc:enrrnrion.
(d) iudcpcudeut of co11cemratio11.
40. When a non-volatile solute is dissolved in a pure soJvcnl
(a) frl'l'Zing point of the sol11tio11 is lkcn~<1:\erl.
(/, ) freezing point of the sol11tio11 is increased.
(c) boiling point oft.he sol111io11 is clecrt'asecl.
(d) Both (a) H ncl (c).
41. Which 0~1c of the _following is not a colligali,·c property?
(a) Relauve . lowenng" uh·a1Jo111· 1J1·-, .ss111·~
• , (b) 0 SIIIOtlC
. . fJl't'SSlll 't'
(c) Elevation ofboilino-
o rooint· (d). 1,onc-
,.. o f t. I1ese
42. Osmotic • pressure
• or a ·sugar s·ol u 1·10n at 240C 1s
. 2.5 aim. The c.:onccntration or the i,c,lu
m0 Ics/1 lire IS
(a) 10.25
. (b ) l.025 (c) 1025 (d) 0. 1023
43. Elcvahon of boiling poinl w·is 0 52
100 g of M ' ·
h oc f
w en 6 g o a c.:ompound X was d'1sSOI
wa Ier. o 1ccular weigh I of X . , (K - 0 52 K. -I
(a) 120 kg,'mol b '· •s b - • m .)
44 N ( ) GO kg/mo! (c) 180 kg/mo! (d) 3·12 kg/mo!
• umber of moles of the soluti .
(a) molality · on per litre of the solution is
45 (b) nwlarit v ( ) . (d,l fonuality
• The boiling point r . · c normahtr

rii ) o a solution cont· . .

JI! m~:1::;·:;='=e
(a) d ep1-essed (b c1mmg a non-volatile solulc is
elevaLt·d . f 1 ese
I fi= ac:a. o 11

--- -~,.!..~a__ _ 13= •· .....,...uu. 7IIIM27ff

• An aqueo us solutio. n of metha nol in w·11er
'
h·.as• v.apou
. r pressu re
• > t'Cjlli-1 10 that ol 11ietlt;rn ol
{a) t>(jllal to 1ha1 of walt'r (I)
(r) morr than th,H of w;it<:r
c-ss . Irnn r rnr ot. ,,..HN
(d) I ti I ·
.
• 5 ml. N I--IC:I , 20 .. • . 3 ' . ' ogci,c , an<llh cvolum c ;, m•dc
ml. '.'ll / 2H,)S0 .1 and 30 ml. N HNO arc mixc t t I
to om· htn.·. 1 hl' norm;a hty of the n·sullin J.t solutio n is
tn I ':',/S (bl ':',/ IO (c) r,;/~IJ tdJ ':',/111
• • .
500111 Lofana t1ueo1 1ssuh1 1ionot '~l11co 22 1
secont ains6X t0 molecu le~" Tliu••<
" ,,i·cen l '" ,on
· o I' l I"

so Iut1on 1s (c) 1.0 yf (d_) 2.0 M

(b) 0.2 \ •l
(a) 0.1 "M
• If NaCl is added lo ice, then the meltin g point of ice will
(a) increas e (b) <.kcrcase
(<') remain s uucba uged (rl) firs< increas e then tleaeas e

O. A solutio n is a (b) homogeneous mixtur e

(a) hetero geneou s mLxture
(d) g el
(c) colloid al sol
I. t\n ideal solutio n is the one which obeys (d) None of Lhese
(c) Bolh (a) and (b)
(a) R.ioult 's law (b) He1ll")'·s Jaw
2. Real solutio n shows deviat ion from R.aoult 's law (d) none of these
(a) positive (b) negativ e (cl both (a) and (b)
3. If llBC is placed in 0.91 % NaCl solutio n then it will
(a.) shrink (b) sweJl
(d) either shrink or swell
(c) neithe r shrink uor s,,·ell
4, Chloro ben:,;e
(u) ;,lea ne-broa
I solutio n noben: ,;ene system is an examp le of al ,oh, Iion with po,;t i,., ,1,-,;, tio u
(b) nou-;de

(<) non-id eal solutio n with negativ e deviati on (di none of these
5. The numbe r of moles of each of the followi ng in 20 g will be
(;j c,H.,o , (;;1 cH,OH (;;;1 cH, COOH
(" l O· l l l , 0·333. 0·625 (b) 0· 333. 0·625. O· ll 1 (cl O· I 11, 0·625, 0· 333 id) 0·62 >. 0·333, O· I JI
Increa se of ten1pe rature of an aqueou s solutio n will cause
(u J d ec,·ea,e ;u ,uulality (b) dec,·ea se in n,uladt )'
(c) d,c,·ea ,e in mole fractio n (di dcm•as e iu % (" -/\\')
In cold co,udd e>, •Jycul i, added W watc, in ca,
,ad;,.tn<> dn,;ng w;nte,. It ,.,u It> ;n
(al towe dng in hoiling poin<- (bl reducin g the viscosity.
(<) reducin g the ,pccific heat. (di lowerin g in frccziu g point.
, The conccn t..,,tion of, cnnc-, ,.,~, ,oh•tio n which i, ;,oto"k with 0,86'
/4 ,olntio n of u,ea

(mol, wl. = 60 g/mol) is

(al 4.9'l (b) 3% 1'1 5.8% (d)
Pa,dal P''"'" "' of a ,utut;o n """pnn cnt ;, di,ectl y p,opod iunol lo it,8.1%
mole f,actin n, This
statem (d) Os1.walcl's clil111io11 law
ent is
(a) Henry' known as (b) Raoult.
s law 's law (c) Dist rihutio u Jaw
At high altitud e, the boiling point of water is lower becaus e
(a) 1mosphec-.-ic l'ressur e is low (b) tt:mper nture is low
(c) 11aunosp hedc prt'.ss1ire is high (d) 11o i1t•
0 lt'.St"
r,1 .
}or an . uqucou !I !lolutio
. {KI= 1,86"Cn.moi-
freezin
' kgg,nd
point is -0.186° (.'" E"Ie,
.,. ·
.., pi,on u K, = 0.512'( ' 1-t c1hon
k ..
of the boil . o f the smnc
mg poml
l
(a) 0.186"C
:a====- (b) 0.0512"C
)
(,· 'mo..
I .SG C g) (d) !U2"C
~---.1JJ':S4--- SCO 371-37
3 3rd FLOOR SECTOR 34-A
¾TR IM
• _MCTRUM J====I.:.i== •= 98887-13325, 78892-42797 www.ecluxt
CHANrum.comH
DIGAR
29
 • l'lhuw 111•1it11tivc d~vl111iun whvn
I\. " "·
•,tun • of A"". 'I Il\,,11~(
.
'\llllp tllll 11 1111
•' '1' I
h;1t1 .. ..... •
\ .\ -
11 ul 1\--1\ 111lt'1·,1t·1ton
' •
\ I\ 1111r1,1, •m111 I!\!\ 1 nnd
. '
,., 1 · . .\
. . , •., ...... 1h1lll · '
- ·\ l\- 1\ 11111 •nw11 011
/11 . \ I\ Ulh'f,1•' 11011 I!\ \\l'
' \ . " >0
-. (I, ,\S,,.
l
l• , ""' • > 0
, ,' , ·
1,,1. ""' • (). .,s,..., · I c 1111 1·, 1ti\
• t'
. ntrn su 1011 w,' ti1 n 0 .1,u oln
ti.'I . ::!.'\,111 ol 11 ,.., 11 ,·u ,n ,,f bni·a
• I um 1' · . . I
f •l!'i I Tiu· 11 wln nly 1· b , • r so Utio
o 11r111m h)·ch ·oxic l,, sul
:add i:.an• II till'\' ,uhu • o •• m .•
(fl (l.~8
I' n of Ii
_ (M tl. I I . ll IOJl Will bu
,,,1 11.0 , · (fl) ll '\"
. . form 1111 i<kn l ,-olu lwn, . I .• "
6-1. If l11111ul, 111 ( ,,.
,-\ :an_< . . , .
1,i I c111 halp ,· of 1111:-.:111~ is 7<'1 <>
(bl , •1111 " ' '·' 0 f 1••1' 11•-• I' 1.1'1 ll
Ill .. " . .

l
,·I fr,·,· <'ll<' t~,- of mixi ng as 1.,· ro
id) fr<'<' t'll<' ti ,· 11,.. w<'II us llw 1· . • .
<'Ill ropy o llllXI III{ 1s z1•1·0 .
. \\'hil -h vm· ,1f 1bc follo wing s lall' nwn ls
65 is folse ?
I) Rfln uh 's l;rn· suu,· s rhrat llw
(( vr-ap our prc-s surc· of~ rom pon t·nt o,•c-r
• . • •• fl sol .
it:> 1110 k lra<.·11011. t \II 101) i~ 1> • •
1
(bl Tht> osm otic pn:•s:>un~ (1t) or a solu Opol 'tio
liou is ~ive n by Lhe equa Lion n =
111c> l:ll'il\· or
tht' sohl li on.
lrl n,c con- eel orde r of osm o tic pres
sure for 0.0 l .M aqu
BaC J:! > KC l > C: Il:1C:OO11 > s u cros e. eou s solu tion of ,. ·I
e,,c l co111pou
(d) Two SIICl'()St' solu 1ion s or s ; 1111t'
111olali1y prt'p t1rt' d
fn·N ing poin t clt-prc-s~ion . in difft 'rt' tll soln ~nts will l .
Ii\\:(' th('
66. Etru imol .tr solu tion s in Che sam e sol\ 'cnl
will h:l\' c
(a) diffe re nt boil ing and diff creu l fn:c Ling
poin ts.
(bl sn 111t· boil ing a nd s11m c trc-c zing poin
ts.
(t') s11mc free- zing poin t but diffr
r<'n t boil ing poin t.
(rf) s:un ,• boil ing poin t but diflc-rcn t
fr<'c zing poin 1.
67. The g luco se solu tion lo be inje
cted into the bloo d s trea m and I he blo<.
sam e. 1d itsel f shou ld ba
(n) , -i~cnc ity (h) Y,q>n 11r prc-s s11rc- (c) m ohu ·ity ld ) osm otic pressm-e
68. TlH· mo~t L'om mon ly u sed arlil iL·ia
l ~,:m i•pL ·rme ablc mem bran e is chem
(<1) pota ssiu m ferr ocya nide
ical ly
lb) n •1-'1-'.:.-1 :,ulp hm.:.-
(,·) rop pc-r krri cyaniclc-
lei) copp t:T ft·no cyau idl'
69. A mix lurc nf ethy l ako hol and prop
yl ah:o hol has a Ya pou r pres s ure of 290
The w1p onr pre:c.snre of prop yl alco mm Hg at
hol is 200 mm Hg. If the mol e frac tion
0.6, its vap our p1·c ssur c (in mm Hg) of ethy l al
al the sam e l<.•m p,•ra tun• will bl'
(a ) 3 60 (h) !\.:)0 (r) '."100 (d) iOO
70. At 80° C, the \'ap our pres sure of
pur e liqu id A is 520 mm II~ ancl Chai
ol' purl \ lit1u B
mm II~. If a mix lurc solu tion uf A and
n boil s at 80° C and I atm pres sure , the nmoidunt
the mix ture is
(a) 52 mot p<.'l'CL'llt (b) :H mo! perc enl (c) ,18 mol pcrn .•nt
71. The vap our pres sure of wat er nt 20°C
is 17.5 mm Hg. If 18 g of gluc o~e (C1S
178. 2 g of wat er at 20°C:, the vap our H1:10,) i5
pres sure of the resu ltin g solu tion will
(ll) 0. 1,:, mm Hg be
(h) Ji .~\2:'l mm Hg (t') 0. 1.'\7 mm Hg (d) 16.8 3mm
72. A 5.2 mol al .iqu\ 'Olls solu tion of m<.•
lhyl ako hol, C:Il;\011, is sup plie d. The
met hyl alco hol in the :,1oh11ion will be
(n) 0 . 100 (h) 0. I 00 (t) 0.08 li

EDutrnuM e=====Ci!.: :. ICO 371-373 3rd PLOOll •CTOll

f3~"r:: !SPECTRUM ~====-r;-== ■: 11117-13321, 7aa n-a TIT
L
 . Camphor is1·1oft en use d in mo1ccu tnr ...
. . rea< 1 Y ava ilah ].. ·••ll ss det e .... . nat ·
(a ) 1t 1s ' • ••ll ion of naP h tha lcn b
· (/,·1 ii I1.1
. . . Iat1·1C ' ~ " Vt"1·v I11· c Y~ s t
(r.) It IS \0 'it-,:>pic:- ~ct hod ~;i US c
it is solv t'i ,· 1. Kh ci·yo
a (m ol. ma ss g _1 (d)
. t "'""1·,,
• A sol uti on of ure 56 n101 ) bo ·1
' or or
ga11 1r lillh!it;i . II
K,, for wnoler nre 1.8 6 and 0,5 12 Kl,.. _,
Is at 100 .1s oc
• at the at • nr".,,
~ Dlo l 1l'. • • eric pr
•- •
'
;\-l" C- spc chv cty , lht' :1b lllo sph
(a) 0.b:)-l (. (b) - O.c-i
(r) () "> . ·. • ovt ' sol uti on".·1 c~s urc . l( I( :\J\d
. . ~1 lrc.•e~c.• .,1 f
of two litt uid s p , d c· ·• 4 C. (d)
- '1 )4"C
5. Th e vap . our prl •ss urc ,tn ~ are 80 un 60 tor~ re . d . " ·
. h}' mix inu 3 mo e of p . d I chv cl" Tl1
pre ssu re ol sol uti on obt ain ed · ~ 111
• spt"
2 tno lor Qw oul db.. l'lu t:,1 ,ap c,u r
.. (b) 1-l Oto n (· . ' e
(a) 12 tor r <) G8 tun
3 l (d) 20 l<,n ·
tai nin g IO g per dm of ure a (mo
1 60
6. A sol uti on con ar ma ss - g mo l- ) it1 ·aso ton.,c "·it h •
I
. r I ah
· 1c sol ute . Th e nu, lcc ul• ecu of the· -
soIut1 on o a non -vo ar ma, .,. a:,•~
l r1 (c) ~i° n-v ola tilc 11olutc: it1
mo r {b) 2jQ g mo 300
(a) 200 g g mo l (d) 3"0 - 1
. (m ola r ma ss 250 g m r•) . · :.> g n1ol
-el ect rol yte sol ute
77. 1.00 g of a non g of benzene.
sio n con sta nt, Kl of bcn 1.cncois S.~ ;~d ~'is ol:e11 in 51.2
If the frcc 1.in g poi nt dep res gm , the freezing point of
bcn:tl'ne wil l be low ere d by
(b) 0.4 K (r.) o.:, K (d) 0.5 K
tn ) 0.2 K
e in eth ano l
78. A sol uti on of ace ton
(a.) obe ys Rao ult" s law.
n fro m Ra oul t's law.
{b) sho ws a neg a tive d evi atio
m Ra oul t's law.
(c) shows a positiv e dc\ 'int ion fro
sol11tio11.
(d) bch a\·c s like a n ear ide al
,~:r,,
s
79. Th e fac tor Kb rep res ent
(c) for ma lity (d) mo hui ty
(a) mo lali t)'
(b) uor ma lit\·
tha n eith er of the m wh en it
otr opi c sol uti on of two liqu ids has boi ling poi nt low er
80. An aze
fro m Ra o ult"s law
(n) sho ws neg ativ e de\ 'iat ion
ult' s l,rw
(b) sho ws no d evi atio n fro m Rao
fro m Rao ult' s Im,·
[ (c) sho ws pos itive d evi atio n
(d) is sat ura ted
s. ilo w of wa ter thr ou~ h a sem ipe rm eab le me
mb ran e is
81. Du rin ~ osm osi

I
con ce ntr atio n onl y
(a ) fro m sol utio n hav ing low er
<.:uu cen tra tio u onl y
(/,) fro m sol uti on ha\ 'ing hig her
flow rat es
1eable m c mbrn11e wit h equ al
(c) fro m bot h sid es of se111ipen1 l flow rate s.
t 300
(rl) fro m bot h '$ ides of st·m ipe
rru eable rue mb rnu e wit h une qua
sid es of the
glu cos e and 0.1 M sol uti on of ure a are pla ced on two
If 0.1 M sol uti on of tha t
c me mb ran e lu equ al hci ghl .8, the n it wil l be cor rec t to say
liem ipc rme abl
nt ,icr oss the mc mb nrn c.
{a) the re will be no ne t mo ,·c rnc
a sol utio n.
(b) glu cos e will flow tow arc ls ure
(c) ure a will How low ard s glu
cos e sol utio n.
(d) wat<>r will flow fro lll Lll 't>it
sol utio n to glu cos e.
re at 273 K wh en 10 g glu cos
e (1t 1), 10 g urea (n, ),
ip bel wc cn osm oli c pre ssu
Th e rel atio nsh
250 mL of wn ler is
10 g suc rus t• (it:1) arc dis sol ved in (d) n, > ff 1 > ~
(b) n > n, > 1t (c) n 1 > Jte > 7t:,
(a) Jte > 1t1 > n, 2 1
pressure
sol u lion ol' a pro tei n con tain s 1.2 6 g or protein. Th e osmotic
20_0 mL o~· an a<1ucous ss of pro tein will be
uho n at 300 K is fou nd to be 2.5 7 X I o-3 bar. Th e mo lar ma
thai; sol
1 1
(R = 0.083 I. bar n10 i- K- ) 1 (d) 610 39 g mn1-
1
5 1022 g mo l 1 (b) 122 0•1l g mo r
1 (c) 3] O11 g mo r
(a)

1-173 3n l PLOOR IICTOll M A

RUM i;! ===~Jl~== ICO 3711
_JTR~~~ u • 11 7-1me, 7I N M lff l
 :),
.... .., 200 )
. . •d (111111, WCIJ!O
s nf cl1b 11s u: n~·1 N i.!I
85. Th e num bt.• r uf g1·11111• • • ,.t,·••iw1h l•l O. I (,· ) J g • l I_
. t l • ,..
ntfl lt't. lllS so I 1111011 0 !,:'I\ !52~ c.i f3i ,cu fan on -
1,11 tog
<h i!.! ~
oo.
I r w111cr == 0.6( I) 20 ·• •
. I 00' '( ') bl·t .·Ol lll'S : is (K1, or -1
of \\U ll'r ( ' . f luh
f l •'•U g lUo J•I
S6. Th l' b,,ili111: pl• inl Th •· mn lt-n 1l1 1r w•· •gh l u :,,o ( 1·) l!! ,'.!U i; wu I I .
in 200 I.: ol: w11f••r. I 1
., u e Iii di1111of
1 / • I"
1.>.· - 1110
f 1101 1-v ol.a l1 e HO 2 r.:3 K kg lllo J•I"ed
• (,) ) • ·
(") I 7 '1 l g lllt> I 1· Wh enJ J'LB !f g" en e .:>
.. ~ J(b (be nz JS •
bt•1 1zc 11e i .~ 35 j.2 3 ,. ,.
Si. Ho ilin ~ po int of · r,us - , I 10 354. .J
, · c:c
· ~ pl:>1·111 rs
· 11c, bo1·l111
. bt.•11zt.• _
-1 (d) ,,· c> g lllo J·t
.,t ,t
1 l • s.,,b- ~,
.I 1H •n- vu1•.1,·1 ·ull ·c 1 s ,·) I J (5 g 1110 1
mo h•n da r 11111ss l• f Jlg . \¥h en 15 g of a no n.
(hl I !.!O g ,nn l ( d VoJati'IV-
(11 l !'iS g 11101- • ,. ooc• . . 121 · 8 nu•n·su u
re is clc crc asc lo 12 0.2 01 ... ••• or
ll
of bcu .tc nc . ;11 .,• ·, •. is
66. \i1p o11 r p1- ..•s.sur c f b t.•n.tt.'llC: • J s • V'IJ )UII J' prc :s
. .
1s d1 sso h•t•cl 111 25 0 g
v (d) !502.7
lul c is c) 1 :12 .81--' g
mo lt~ cuJ ur we igh t oft lw so . .
(l>) 3.H .8 g (
Hg . If o.5 g of a no n-v ola t1l e :riolui
(al :l!U i7 g . 3
e
C:C l. at 25° C: ,s I 4 numl n I 1e va po ur pr ess ur e oft h
S9 . Th e va po ur pre ssu re of
_, •
1
. , • . CC l. 1, I e SOhw
• ec1 111 100
. we ,g- ht 65 ~ mo l ) JS
= d,s soh
H (d) g
(11 10I . g3 4 3
be (D en sit yo fC :C l.1 = 1.5 8g cm -")11111 Hg (£)
14 1. • 111111 g · - 9111t11f-Jg
(h) 1-13 .991 wh en a 00 ll•Volatif
(a) 19 9:1 -lm m Tig . db }' Jo mm of me rcu ry
h I . .
de cre ase . ull on 11; O 2 Jf e
ur pre ssu re of a soh ·en t ,s f the soJ utc 1n t c so . • • lhc d
90 . Th e va po r. • O . (a
l. l he mo le ira clJ- OD.. ·u ry the n the mo le fra ch on of th C soIVent
• .
wHs ad de d to the soh 'cn. 1 re (b)
. 1:-; lo be 2 0 nu n o · me
1n the l7i po ur pre ssu re (c) U.6
(d) 0.2
(b) o.o (c)
(a) 0 .--l. 27 3 K i1'
s olu tio n co nta ini ng 0.3 mo l of so lut e pe r lil rc at (rl)
re of a
91 . TI1 c o s mo tic pre ssu 3 at111 27 n
(b) 0.3 X 2 X 0.0 82 I X
. . o.:J 27 :i
1
(a)
(a) - - x O. O,'-iil a111 (c)
(d) 0 \ x 0.0 82 1 x 27:~ atm 06. WI!
0/ x 0.0 82 1 x 273 atm
(c)
it fre eze s at ap
bo iJs al l 00 .55 °C ; d1 en
(a)
lut ion of a su bs lan cc p
JaJ nq ue ou s so 1
92 . If I.0 mo 1
an d K,. = J .86 °C kg mo r )
(c)
(K6 = 0.5 J °C kg· mo r
(,:) ;, i :"> K (d) 27 4 K A5
271 K (h)
(a) 27 2 K wi ll be moJ
cli on ofs olu lc in its on e mo lal aq ue ou s so lut ion gc,J
le fra
93 . Th e mo
(a) 0.1 08
(b ) 0.0 18
(c) 0.0 08
bs lan ce s ha vin g strcngth4
.5 (a) I
cti on of sol 111 e in an :up 1co 11s sol u lio n of a su As,
fra
94 . Th e mo le- 0.0 7:'5 (c) 0.4 5
(d) 0.0 45 hyd
(aJ 0.i 5
(h)
us e the va po ur pr of p
on of J.0 0 mo Jal in KI . "W hic h ch an ge wiJ I ca
sol uti (a) f
95. An :up 1eo us
sol uti on lo inc rea se? (b ) Ad cli lio n of N a 2 SO,1
(a i Adclic ion of Na Cl
(cl) .-\.dclition of wa ter l. (c)
(c) Ad dit ion of 1.0 0 mo lal Kl 1
34 2 g mo l- ) ha s be
en prepared by
se (m ofo r ma ss = 9. (d)
96. A sol uti on of su cm ter . Th e fre ez ing po int
of the sol uti on obtai 7. (b)
cro se in J 00 0 g of wa
68. 5 g of su 1
mo l- 5. (a)
(Kr for wa ter = 1.8 6°( ; kg
)

(b) - 0.5 20 ''C (c) + 0.3 72 °C a. (b)

(a) - 0.372 "C an d B, re~ pc cm
va po ur pr es su re of pu re liq uid co mp on en ts, A 1. (d)
97. P..1 an d Po are the on en t A, the total
uti on . If ;ct rep res en ts th<.' mo le fr~action of co mp • (h)
bin ary sol • (d)
sol uti on will be
/>,1 + 7_., (/1.1 - f>o) (r:) Po + X.-1 (JJn - j>_-,.) • (d)
(a) P.1 + X.-1 <Po - ,
JJ.-) (h)
(h)

,.

I I
IC O 371-373 3rd FLOOR •CTO
R MA
•= IIU7-13321, '78IDG7l7
 li.-1t·~n-l _(_l ',~l-l {_'_I
Vapour pn.·ss~u ~rc~' ~o~f~<~:h~l-o_r _o ~ . . ._a;;;;;:::::::::::=:=::::========-••■■-
dichloroan c.•lh· 1111d
Ir~ and 41.5 mm II~ rcspcx·iiv clv '\'· ' :,)
d . . . . ,tpour press . •Ille (l"ll ("J
'H. 'I ;f,, at the sa111e t . . urc ol lhc so1t11·1c1 . I~ . 2) Ill 2Gol.
(. (. :Ian 40g· of CH ,,(
• • , empe,·att . . no >h'11 • 11rc 200
-
and molccula i· mas1' of C:ll~CI,,
•
11
= 81> u)
be (Mnlecnl • .' •cd by n,ixin~
e Will
n, IIIU!'ls ot' ( 'H .
llltn
25 .5 II: or
...,
(a) I ,,,.DJ mm llg (l>) GL:i.08 111111 Ilg . . · <.i:s = 119.&
.. \ ( ) 90. li·1 1111 II 11 u .
' • f

I he number ot grams ot concentr ated nitric acid ti la t s Iinuld begus d (d) 28r,.:,2 111111 1I ~
IINl)., so I u hon
. . (l'. · e to prepare 2S0 inl.of2 OM
1s ,1vc.·n c.·u11c.·1.·nlr11kcl IH:id is 701•· I IN<) . ~)? ,c
_) . . •
(") 1l.Ogcn1 1 c. H:\O.1 (bl 5-l.0gcon c. Hi\'O,.I (r) -11• • o g.·,one-. H No!l (rl) ~)0.0
• • M

g c:nnc.. H:'-!o,
• • • • •

lVh1d1 of the.~Jollowm~ 1s not sallshccl by an ideal solution?

(n) •\mx I '= () (/,) /\ l ' :;t:()
11\IX

(f) Oheyanc r ro Ranult's I.aw (d) L\,,,;, H = ()

Whid1 of th~ following mixhm: will form maximum boiling azculropc ?
(a) cone. ll:\O 3 a11cl \\'ater (b) i\ceto11e ancl benzene:
c) Ethyl alrohol a11cl watt'r (d) Acelo11t' and C:S 2
of
r1olal dq>n•ssi ou _conshml . for waler is 1.86 °C/m. The frcl·zing point of a 0.05 mohil solulion
a non•cfoc trolvlc m water 1s
t")-l.86" C . (b) -0.93" C (c) -0.09~)'' C (d) 0.9~, 0 c

pie Henry's law is applicab le only when

/a) the gas undergoes ,1ssociation or dissocilltion in t.he solution.
~) tl1e gas undergo es any chemical change.
b the press11 re of the gas is not too high a11d te mperatm ·e is 1101. 100 low.
~) All of rhe aboYe
fhe ·rnpour pressure of a li<Juid in a closed vessel depends upon
~) surface area of the vessel. (b) amount of liquid.
J,) tempera ture. . none of . the a I)ove.
(d)
1
fbic_h of the followin g ~iqu~d pairs shows a posilivc d eviation from RaouJt's law?
) \-\'ater - hydroch lonc acid (b) Benzene - methano l
) Wate.1· - nitri c acid · (rf.) An~tone - c.hlorofo rm
solution of a substanc e is isotonic with a 1.5% sol.ution of urea (molar mass = 60
f5.25%
lor 1
) in the same solvent. If the densities of both the solutions are assumed
to be equal to
cm ....:\ molar mass o f the substanc e will be
210.0 g mol ... 1 (b) 90.0 g 11101- 1 (r) 1 L"U) g mol 1 (d) 105.0 g moi- 1

solution has a I :4 mole ratio of pcntanc to hexane. The vapour pressure s of the
tdrocarbo ns at 20°C: arc 440 nnu Ilg- for pcnlillll! and J 20 mm Ilg· for hexane. The mole fntj
entane in the vapour phase is
0.200 (b) 0.5·19 (t:) 0. 786 (d) 0.178

2. (c) 3. (b) 4, (a) 5. (d) 6. (c) 7. (b)

10. (r.) I I. (a) 12. (d) 13. (a) 14. (d) 15. (a)

18. (a) J 9. (ll) 20. (b) 2 I. (c) 22. (b) 23. (c)
26, (d) 27, (a) 28, (d) 29. (c) 30. (d) 31. (c)
34. (b) 35. (d) 36. (b) 37. (b) 38. (d) 39. (o)
42. (d) 43. (h) 44. (h) 45. (b) 46.(c) 47.(d)
50. (b) 5 I. (a) 52, (t:) 53. (c) 54. (a) 55. (c)
8. (a) 59. (b) 60. (h) 61. (b) 62. (a) 63. (o)
• (b) 67. (d) 68. (d) 69. (b) 70. (d) 71. (a)
• (d) 75. (a) 76, (c) 77. (b) 78. (c) 79. (a)

ICO 371-373 3rd FLOOR IICTOR 34-A

:6 ■118887-13325, 78892-42797 www.
-
n of nRphlhnlcnc b Y It" 8 \ method bccau" '
I

.
73, (.aJllP ho•· is often used
. in 1nolccuhu· n1oss
,,) ii is n•adily ;t\'illlilh)t"
. . . I ,. ,
dctcrminntio
(l) • 1
, ~· . '.as il ~:•·r .
.'"_Kh ( ' 1')'<.>SC'opi.- ,·on~1,u11
(d) 11 1s ,;nl\, 111 to, orl(i'llllC' Mth!lli'II\C-
C

( • ~:,,
) r ,s , o n , 1<
(r 1 • f tn•cn (mol. mass 56 g mol- 1) boils nt l 0O. l 8°C at the ntmo1,pheric prcHure. u K 1 nnd
74 A solulJ0ll O l cl 0 512 K k~ 11101- 1 rc..-spectivcly , lhc..- above solulion will l'n•czc ·al
• Kb (or• w:, 1cr •·,re • 86 an . l • O frH''C · (r) 6 .."S4'· C (rl) - () ..'H" C •
: 1 .
fl' .- I ' . uids p and Q arc 80 :111d 60 torr. rcspccuvcly . . The lolul v;,puur
(a) 061-n
· ·
, ,,;sure o h\'O.
Ill
lb 'xinu· 3 1110Jeof'Pancl 2 11111 o
1 r Q won Id be
Thcvapourp •t:-
• 1 obt ·unec
7!S, nr.. s..;ure o(. so 1u 11111 • 0 )' 1111. .~ (c·) GLS lOIT (d) 20 loIT
r .... , .. (b) H wn: t· . ( nolecular mass =
60 g mol
.
-• ) .as 1soto111c . with. a 5'/4
(a) 7 2 toll 1
. . IO g ner dnt o u1 ea • . I .
u1
A olution contarn111g r
1ccu 1ar n,a ... .s of the non-"olat1lc so ulc 1 l
76, , ~ S I ·1 lute The n1<> (d) 350 g mo -
•olution of a non-VO nh C so . 1- • (c) 300 g 1uor•
s
(a) 200 g mo1-• - g UlO
(b) 950 . ss r') was dissolved in 51.2 ~ of benzene.
I 00 g of a uou-electrol yte •~lute (molar
250
"t . 1110
f bcn;cnc is 5 . 12 K kg ,nol-'' the r,.,.,,ing point of
77, Jfthe freezing point depression constant, lo
•nzcnc will be towered by ( ) 0 ~• K (d) 0.5 K
bC 9 ' (b) 0.4 K C ••,

(a-) 0.- K
A solution of acetone in ethanol
_ 78, . .
(a.) obeys R;ioult's Jaw.
(b) shows a neg-1tive devia~ion _fro m Raoul~ s ta,,.
(c) shows a positive dc\'i;iuon fr01~1 Raoult slaw.
(d) bcha\'CS like a near idet1l solu110n.
~T,,
The foctor - represents (d) n10h11ity
79, Kb
. . (b) uonnalitv (c} fonnalit)'
(a)u10a1t}· · • fl J ·1
I I
n azeotropic solution of two liquids has boiling point lower than either o t ,ern w ien I

80, A
(a) shows negative deviation froru Rao ulr's law
(h) shows no d eviation from Rc1o ult"s l;iw
(c) shows positive deviation from Raoull's la,,·

(d) is salllt'ate d
1. During osinosis. How of water through a ~cmipermea ble membrane is
8 (a) froin solution having towel' concent rauon 0 111 )'
(b) frolll solution having hig her co11ceutra tiou only _
(c) frolll both sides of seu1ipenuea ble llll'lllUntllt' with equal flow rates
(d ) from bolh sides of semipenuea bk rucmbrnue with unequal flow rates.
82- If o. 1 M solut;on of glucose and O. I M sol ut;on of u re• are placed on two s ;des of I he
scmipcrmc.1 ble membrane tu c<1uaJ heights, then it will be correct to sny that
(a) r.herc will be no n et 1110,·ement ;icross rh e membrane.
(b) glm:ose will fl ow towanls un~a solutio n .
(c) urea will Hovi towa rds glucose solution.
(d) wa1er will flow from lll"t'cl solution to glucose. 2
1
83, The relationship between osmotic pressure at 273 K when 10 g glucose (n ). 10 g u1·ca (rt ), und
10 g s ucrose (rr 3 ) arc dissolved in 250 mL of w;11Cr is (d) 1t5 > 1t1 > 1t~
(a) 1t2 > n, > n:; (h) n~ > 7ts > 7t1 (c) n, > 7t2 > 1t:1

84. 20_0 mL o!' an :u1ucous solution of a protein co~tains 1.26 g of protein. The osn1otic pressure of
Uus solutmn at 300 K is found to be 2.57 X I 0-3 bar. The molar mass of protein will be
1 1 1
(R = 0.083 L bar mo1- K- ) {d) 6101m g nwr
1 {c) 3)011 g 11101 - I
_ (a) 5 I 022 g mot 1 (b) I 22O,J l g 11101 -

I • SCO 371-373 3rd FLOOR SECTOR M-A CHANDIG ARH

M: 11887-133 25, 78892-427 97 www.eduxtrum.com
3
 85, (r ) 86. (11 ) 87. (fl )
81. (ii) 82. (o) 83. (11 1 84, (r/) Ill\•II,,
93. //J) 94. (b) 95. (d )
89. (< I 90. (/1) 91. (fl 92. //1) 96.,,,,
{01. (a l 102 . ({ l 103 . (l'J
97. (d \ 98. l l .I 99. {( 1 100. (/11 104
"' )
105 . (b l 106. (a) 107. (dl

1f£i IWW3 •X•\1fii M:~t J

I . R eacI t h l' pass a~e . . . b •low ·mcl answ er Ihc. fo Jlow in~ qu es tion s :
~1, c n c • .
• . , , .. m ge of co u u r 11illua 111.
\Vh c u a sulu lio 11 d o n 1101 obey •. Jaw on· r cum <: ' . ,JJ1, rJi, ...
. Rao u 11 ~ ' . . S()]t1 b~Oll is t·ith c r h ighe
· '- ll 1111
.
u o n-1d c al sol111 1011 . The va p o . . ·s11H· o 1 s ue 1J r o r low er tl·· !,
. lll pi es. • . •
1LI 1J011 ex
. hib its po.rn1v e dev1•a1tiou . •011'
pn:·d1cl ed b~· Rao ult .s [al\.. r1· 11 . 15. . I . ,her the so . .
. ug ' .. . < 111
. .
lowe r. 11 c xlub11.s neg a ti.ve c1eviat · · f1·om Rao u1t s 1,rn,. T h e c;w sc o f th e se dc:vi,11j 111( . 1
.1on 0 11 ~ 111- .
.
natu re of i11te rnn i o11s at rh e molecul • c:ase of p nsin ii·I' d e,·i.n timn from Ra0 u 1r·~la .' 11
ar lr ,.el. 111 ·' • • B B · e che in ccrm
inte ractions are ,,·eaker than those I \ A 01 - 1
• · ·•
oli:>c 1. . ' \\,.1,
)etwcen ' - k . . t!l (>se he twc:-e ri ti, - 11ta1 aur
fo rces bet wee n tlw sol11t t'-SO IYe 11t · wra fl t 11,lll al(,
111 0 Iec u Ies ' 1
l' f · · · t' S() 1Lil (' 1
a nd so l\'<' ll t-so ln~111 molec ules. .I. . · snch
. I I I
so Int.i nns, t w mo c, 11 f•s of :\/nr -sc,
• . his mca m t 1Hit 111 · ll
hnd rr .
easi e r t o csc:;1pc rlrnn 111 pure st.ill<' . Tl115 · ,ill increase th e Yap ou r p ress J,
' \ ure· resn1 t·
pos1· 11ve
· rt e v1,1 • 1.1•o n .
111 case o f ncgatn · .c devi,ations from Rao ult s law. rlie
· . . . . .. in?
forc es betll' eeu A-,\ and B-B mre mw lenr lar atrr• .
are weaker than those be1w ee11 · 111
A-D a ucl lead s to der:rt:.1.1t
,·ap our press ure resu lting neg u1 ative deviations.

/11 these quesli011s (Q.

No (i) to (iv)j , a slate111e11t of assertio
reason is give 11. Choose the correct answ n foll owe d hy a slat ement
er out of the f o/lowi11g choices. 1
(a) Asserl·ion a11d reason both are
correct statements and reason is corr
ecl e}.'J)/a11alio11 for asserti,~
(b) Assertion and reason both art:
correct statements but reason is no/
assertion. correct explarrati,m fi
(c) Assertion is correct statement but
reason is wrong statement.
(d) Assertion is wrong statement but
reaso11 is correct stalenumt.
(i) A ss erti on (A) : A s~lu lion
fo r111r d by adding carbon disu lph
d e v1atw11 fn 1111 Rao uh \ lall'. ide l o ace tOll t" '>111:, 1, '> posilr,•
Rea son (H): T hc dipo lar
i11t crn r 1io11s h r lll'<'<' ll s >I . I
• .
th an th e I es p ecl!•ve 111ter
• • 1
ac110 11 s amo ,· IIti t -~o n ·111 111nlcn1ks <1 rr s1ro
•<
. I 11gft
molecul es. 11
g ie so lit e-so lut e a ud sol\'ellt
-soh-er.
(ii ) Ass erlio n (A) : A 1ni x1.11re
or ph e11ol and ..i niliiw .1 . . .
(R): Tht> i111 en11olenilar H-1 r s iows p os1tl\•1• clr ,·iari
. . Oil f1'0 111 R,1 011 It 's Ia11
on nitr oge n atom of aniliionc ing lwtwt> r n i i .
llc 1·s ' t. . I 1t•1tol1c pro 1011 ;111d Joni> 11a1.,
I-1-b oucling betwee11 si111ihr . ,• 1., I.ongc-r ti I
' 11 11. ecu1es. ian I. le rcsp ccti\'e inr c rmo lcculM
OR
Th e ,·a pou r pressure inrreasrs ·
.. , . . ..
I I
' "••:_in r rm o l'fll arar tran ivc. for . 111 pos1 1;v e dcviati 1·
I
~ O il ro111 Rao111t·s l;nr.
• an rhosc between rhe sol ccs lerw c I
· .en t le soln t<'-solv
1-hr xan c a11 I I
· lltc- s0 1
111 ·· <'tH mo 1e c:11 1cs~ re
11
· ' < -1cptane · c
. and sol\'
1 • • is an ideal cnr-solY c nr molecules.
~ 1 arrrnrt1w : forr r · solu tion .
.
·,I S 1
to th os<: be111· .
)Cl\\' ('
en th e
ceu solu , . . solv c:-1lt-so lve nt ;:ind
t -solven1. sol111r·