Class 12th Chemistry Worksheet

CHEMISTRY (Class XII)
Index
Chapters page
1. Solid State 01
2. Solutions 15
3. Electrochemistry 30
4. Chemical kinetics 46
5. Surface chemistry 62
6. General principles and processes of Isolation of Elements 77
7. p-Block Elements 88
8. d- and f- Block Elements 109
9. Coordination Compounds 117
10. Haloalkanes and Haloarenes 132
11. Alcohols Phenols and Ethers 150
12. Aldehydes Ketones and Carboxylic acids 167
13. Amines Organic Compounds containing Nitrogen 183
14. Biomolecules 202
15. Polymers 214
16. Chemistry in Everyday life 227

CLASS - XII CHEMISTRY (The Solid State)
Topic: Solids and their classification
1. What are fluids? Give examples. [1]
2. Solids are rigid why? [1]
3. How are solids classified? [1]
4. Define the term amorphous with example. [1]
5. The window panes of the old buildings are thick at the bottom. Why? [2]
6. The stability of a crystal is reflected in the magnitude of its melting

point. Explain [2]
7. Graphite is soft and good conductor of electricity. Explain.

[2]
8. Ionic solids are good conductors in molten state and in aqueous solutions
but not in solid state. Why? [2]
9. Differentiate between amorphous and crystalline solids with reference to

(1) Melting point
(2) Cleavage property
(3) Nature [3]
10. How are crystalline solids classified on the basis of nature of bonding?
Explain with examples. [3]
1
[ANSWERS]
Topic: Solids and their classification.
Ans 1: Substances which flow are fluids e.g. liquids and gases.
Ans 2: Rigidity in solids is due to fixed positions of the constituent particles and their
oscillations about their mean positions
Ans 3: Solids may be classified into two categories – crystalline and amorphous.
Ans 4: Amorphous means disordered and random arrangement of particles for example –
silica, plastic, rubber
Ans 5: Glass panes of old buildings are thicker at the bottom than at the top as from is an
amorphous solid and flows down very slowly and makes the bottom portion
thicker.
Ans 6: Melting point of a solid gives an idea about the intermolecular forces acting
between particles. When these forces are strong, the melting point is higher and
when these forces are weak, low melting point is observed. Higher is the melting
point, more stable the solid is.
Ans 7: Graphite is soft and good conductor due to its typical structure here carbon atoms
are arranged in different layers and each atom a covalently bonded to three of its
neighbouring atoms in the same layer. The fourth electron of each atom is free to
move about due to which it conducts electricity. Different layers can slide over the
other which makes it a soft solid.
Ans 8: In the solid state, the ions in the ionic solids are not free to move about due to their
rigid structure & strong electrostatic forces. Therefore they cannot conduct
electricity whereas in molten state and aqueous solution, the ions become free to
move about and they conduct electricity.
2
Ans 9:
Property Crystalline solids Amorphous solids
1. Melting point They have sharp melting They have a range of

point melting point.
2. Cleavage property They split into pieces of When cut with a sharp
plain and smooth edged tool, pieces of
surfaces when cut with a irregular surfaces are
sharp edged tool. obtained.
3. Nature They are true solids. They are pseudo solids or

super cooled liquids.
Ans 10: Classification of crystalline solids.
1. Molecular solids: The forces operating between molecules are dispersion or

London forces, dipole – dipole interactions, hydrogen
bounding e.g. CCl4, HCl, ice etc.
2. Ionic solids: The intermolecular forces are coulomibic or electrostatic forces,

e.g. NaCl, MgO etc.
3. Metallic solids: The forces operating is metallic bonding e.g. Fe, Cu, Ag etc.
4. Covalent or network solids: The attractive forces are covalent bonding e.g.
Diamond, Quartz etc.
3
Topic: Structures of crystals
1. Define the term: Crystal lattice [1]
2. What is a unit cell? [1]
3. What are the axial angles and edge length in a cubic crystal system? [1]
4. Give one example of each – Tetragonal and hexagonal crystal system. [1]
5. Name three types of cubic unit cells? [1]
6. How many atoms are there in a unit cell of a metal crystallizing in a: [2]
(a) FCC structure

(b) BCC structure
7. What is the contribution of an atom per unit cell if the atom is: [3]
(a) At the corner of the cube.

(b) On the face of the cube.
(c) In the centre of the cube.
8. A compound formed by A & B crystallizes in the cubic structure where ‘A’ are at
the corners of the cube and B are at the face centre. What is the formula of the
compound? [2]
9. Calculate the no. of atoms in a cubic based unit – cell having one atom on each
corner and two atoms on each body diagonal. [2]
10. What is the no. of octahedral and tetrahedral voids present in a lattice? [2]
4
[ANSWERS]
Topic: Structures of crystals
Ans 01: The three dimensional diagrammatic representation of constituent particles, in

which each particle is depicted as a point is called crystal lattice.
Ans 02: The smallest portion of a crystal lattice which, when, repeated in different
directions, generates the entire lattice, is called its unit cell.
Ans 03: Axial angles,       900 and edge lengths a = b = c.
Ans 04: Tetragonal crystal system – white tin, SnO2.

Hexagonal crystal system – Graphite, ZnO.
Ans 05: (a) Simple cubic (b) Face – centred cubic (c) Body centred cubic
Ans 06: (a) FCC = 4 (b) BCC = 2
Ans 07: (a) When atom is at the corner of the cube, the contribution is 1/8 atom.
(b) When the atom is on the face of the cube, its contribution is ½ atom.
(c) If the atom is in the centre of the cube, its contribution is 1 atom.
1
Ans 08: Contribution of atom A per unit cell =  8  1 atom
8
1
Contribution of atom B per unit cell =  6  3 atom
2
Ratio of A & B = 1:3 Formula = AB3.
1
Ans 09: No. of atoms contributed by 8 corners per unit cell =  8  1atom.
8
No. of atoms contributed by one diagonal = 2
No. of diagonal = 4
Total contribution by diagonal = 4  2 = 8
Total no. of atoms = 8 + 1 = 9 atoms
Ans 10: No. of octahedral voids present in a lattice is equal to the no. of close packed
particles and the number of tetrahedral voids is twice the no. of close packed
particles.
5
Topic – Packing in crystals
1. What is square close packing? [1]
2. What is the coordination number in :- [1]
(a) Square close packing (b) Hexagonal close packing.
3. Define – (a) void (b) coordination Number [2]
4. What is the packing efficiency in [3]
(a) hcp structure (b) BCC structure (c) Simple cubic structure
5. Give the relationship between density and edge length of a cubic crystal. [2]
6. Copper which crystallizes as a face – centred cubic lattice has a density of 8.93 [3]
g/cm3 at 20o C. calculate the length of the unit cell.
7. An element crystallizes in BCC structure. The edge of its unit cell is 288 pm. If the [3]
density is 7.2 glcm3, calculate the atomic mass of the element.
8. The compound CuCl has ZnS structure and the edge length of the unit cell in 500 [3]
pm. Calculate the density. (Atomic masses: Cu = 63, Cl = 35.5, Avogadro no = 6.02
 1023 mol-1)
9. In a compound, B ions form a close – packed structure & A ions occupy all the [2]
tetrahedral voids. What is the formula of the compound?
10. In crystalline solid, anions C are arranged in cubic close – packing, cations A [3]
occupy 50% of tetrahedral voids & cations B occupy 50% of octahedral voids.
What is the formula of solid?
6
[ANSWERS]
Topic – Packing in crystals
Ans 01: The close packing of spheres – atoms or ions, in which each sphere is in contact
with four of is neighbors, whose centres, if joined, form a square, is called square
close packing.
Ans 02: (a) in square close packing, the coordination no. is 4.

(b) In hexagonal close packing, the coordination no. is 12.
Ans 03 (a) void – the empty space left between close packed spheres are voids.
(b) Coordination number – the number of spheres or atoms surrounding a single
sphere or atom in a crystal is called coordination number.
Ans 04: (a) hcp packing efficiency is 74%.

(b) bcc packing efficiency is 68%.
(c) packing efficiency in simple cubic structure is 52.4%.
Ans 05: Density, d of a cubic cell is given by –

ZM
d  a3 N
A
Where Z = no. of atoms per unit cell

M = molar mass
NA = Avogadro number
a = edge length
Ans 06: 361.6 pm
Ans 07: 52 g/ mol
Ans 08: 5.22 g/cm3
Ans 09: Let the no. of B ions = 100

No. of A ions = no. of tetrahedral voids
= 2 no. of 3 = 2  100 = 200
Ratio of A & B = 200 : 100 = 2 : 1
Formula = A2B.
7
Ans 10: Suppose no. of anions, C = 100
50
Suppose no. of cations, A =  no. of tetrahedral voids
100
1
=  2  C 
2
50
No. of cations, B =  no. of octahedral voids
100
1
 C 
2
1
= 100  50
2
Ratio of ions A : B : C = 100 : 50 : 100
=2:1:2
Formula = A2BC2
8
Topic – imperfections in crystals
1. What is the meaning of term ‘defect’ with reference to crystal? [1]
2. Define two main types of defects. [2]
3. Name the types of point defect. [1]
4. (a) Identify the defect in figure below : [2]

(b) How does it affect the density of crystal?
(c) Give an example of crystal where this defect can be found.
(d) What is its effect on electrical neutrality of crystal?
5. Which defect is observed in a solid solution of CdCl2 and AgCl? Explain. [2]
6. Excess of lithium makes LiCl crystal pink. Explain. [2]
7. What are F centres? [1]
8. How does a crystal changes due to presence of F centre? [1]
9. Give an example which shows both frenkel and Schottky defect. [1]
10. Which type of ionic substances show? [2]

(a) Schottky defect
(b) Frenkel defect
9
[ANSWERS]
Topic – imperfections in crystals
Ans 01: The defects are irregularities in the arrangement of constituent particles in a
crystal.
Ans 02: Defects are of two types –

Point defects: - Irregularities or deviations from ideal arrangement around a
point or on atom in a crystal.
Line defect: - Irregularities or deviation from ideal arrangement in entire row of
lattice points.
Ans 03: point defects are of three types – stoichiometric defect, impurity defect & non –
stoichiometric defect.
Ans 04: (a) Schottky defect.

(b) It decreases the density of crystal.
(c) NaCl, KCl
(d) The crystal remains electrically neutral.
Ans 05: In a solid solution of CdCl2 and AgCl, impurity defect is observed. In the crystal of
AgCl, some of the sites of Ag+ are occupied by Cd2+, each Cd2+ replacing two Ag+. It
replaces the site of one ion and other site remains vacant.
10
Ans 06: When crystals of LiCl are heated in an atmosphere of Li vapour the Lithium
atoms are deposited on the surface of crystal. The Cl - ions diffuse to the surface of
crystal & combine with Li atoms to from LiCl which happens by loss of electrons
by Li atoms to form Li+ ions. These released elements diffuse into the crystal &
electrons get excited after absorbing light from visible region & emit pink colour.
Ans 07: F – centre is the position of an anion in an ionic crystal which is occupied by a
trapped electron
Ans 08: The crystal becomes paramagnetic and coloured due to presence of f – centre
Ans 09: AgBr.
Ans 10: (a) Schottky defect – ionic substances in which the cation and anion are of almost
similar sizes eg. NaCl, KCl, CrCl.
(b) Feenkel Defect – Ionic substances in which there is large difference in size of
ions eg. ZnS, AgCl, AgBr.
11
Topic – Electrical and magnetic Properties
1. Define the term – doping. [1]
2. What is the meaning of 13 – 15 compounds? [1]
3. Name an element which can be added to silicon to give a – [1]

(i) p – type semiconductor (ii) n – type semiconductor.
4. What is the difference between ferromagnetic and paramagnetic substances? [1]
5. In the fig – (i)
Fig. (i)
(a) Identify the magnetic behaviour of substance. [2]
(b) How are these substances different from diamagnetic substances?
6. Define the terms – Intrinsic semiconductor and extrinsic semiconductor. [2]
7. Classify solids on the basis of their conductivities. [2]
8. Explain conduction of electricity on the basis of band theory. [3]
9. Give two examples of each. [2]

(a) Ferromagnetic substances (b) Ferrimagnetic substances
10. Give two application of p – type and n – type semiconductors. [2]
12
[ANSWERS]
Topic – Electrical and magnetic Properties
Ans 01: Doping – The process of introduction of impurity atoms into an insulator to make
it a semiconductor is called doping.
Ans 02: A semiconductor formed by combination of 13 groups & 15 groups elements is 13

– 15 compound.
Ans 03: (i) For p – type semiconductor Borom can be added.

(ii) For n – type semiconductor, Phosphorous can be added.
Ans 04: A ferromagnetic substance has permanent magnetic behaviour whereas a

paramagnetic substance acts as a magnet only in the presence of an external
magnetic field.
Ans 05: (a) Antiferromagnetic field.

(b) In Antiferromagnetic substance the domain structure is similar to
ferromagnetic substance but the domains are oppositely oriented and cancel
out each others magnetic moment whereas in diamagnetic substance all
individual electron are paired which cancels the individual magnetic moments.
Ans 06: Intrinsic semiconductor – An insulator which conducts electricity when heated.
Extrinsic semiconductor – An insulator which conducts electricity on addition of
an impurity.
Ans 07: Solids can be classified into three types on the basis of their conductivities –
13
Solids Conductivities
1. Conductor 104 to 107  1m1
2. Insulators 10-20 to 10-10  1m1
3. Semi – conductor 10-6 to 104  1m1
Ans 08: The conductivity of metals depend upon the no. of valance electrons available per
atom. The atomic orbitals of metal atoms form molecular orbitals which are so
close in energy to each other as to form a band. If this band is partially filled &
overlaps with a higher energy unoccupied, conduction band, then electrons can
flow easily under an applied electric field & metal is a conductor. If the gap
between filled valance band and conduction band is large, electron cannot jump to
it & the substance is an insulator where as if the gap is small & on heating, can be
overcome, the substance acts as semiconductor
Ans 09: (i) Ferromagnetic substances –Fe, Co, Ni, CrO2, Gadolinium.
(ii) Ferrimagnetic substance – Fe3O4, Magnetite and Ferrites.
Ans 10: Application –

(i) A combination of both p – type and n – type semiconductors is used in diode
which is used as rectifiers.
(ii) npn & pnp types of transistors are used as amplifiers.
14
CLASS - XII CHEMISTRY (Solutions)
Topic: -Concentration of solutions
1. Define ‘solution’? [1]
2. Define the term ‘concentration? [1]
3. How does change in temperature changes the molarity and molality values? [1]
4. Calculate the volume of water which could be added to 20 ml of 0.65 m HCl to

dilute the solution to 0.2 m? [2]
5. A solution is prepared by dissolving 11g glucose in 200 cm 3 water at 300 C.

What is the mass Percentage of glucose in solution? The density of water
300C is 0.996 glcm3? [2]
6. Find the molality and molarity of a 15% solution of H2SO4 when its density
is 1.10 glcm3 & molar mass = 98 amu. [2]
7. Calculate the mole fraction of ethanol and water in a sample of rectified spirit
which contains 46% ethanol by mass? [2]
8. Calculate the % composition in terms of mass of a solution obtained by mixing

300g of a 25% & 400 g of a 40% solution by mass? [2]
9. One litre of sea water weight 1030g and contains about 6×10-3 g of dissolved 02.
Calculate the concentration of dissolved oxygen in ppm? [2]
10. The density of 85% phosphoric acid is 1.70 g/cm 3. What is the volume of a solution
that contains 17g of phosphoric acid? [2]
15
[ ANSWERS ]
Topic: -Concentration of solutions
1. Solutions are homogeneous mixtures of two or more than two components.
2. The relative amount of a substance in a solution is called its concentration.
3. As the temperature increases, volume increases and molarity decreases whereas molality
does not change with any change in temperature.
4. For dilution –
M1V1 = M2V2
MV 0.65M  20 ml
V2 = 1 1 = = 65 ml
M2 0.2M
Vol of water to be added to 20 ml =
= V2 – V1 = 65ml – 20ml = 45 ml.
mass
5. Density = = 0.996 g/cm3
volume
0.996 = mass
200cm3
Mass = 0.996×200 = 199.2 g
Mass% of glucose = mass of volume 100
mass of water  mass of glucose
11
= 100 = 5.23 %
199.2  11
6. Volume = mass/density
= 100 g/1.10 glcm3 = 90.9 cm3
no. of moles of H2SO4
Molarity =  1000
volume of solution
(15 / 98)
=  1000 = 1.68 m .
90.9
no. of moles of solute
Molality =
mass of solvent in kg
(15 / 98)
1000 = 1.8 M.
85g
16
7. Mass of ethanol = 46g
Mass of water = 100 – 46 = 54g
XA
Mole fraction of ethanol ,XA =
X A  XB
46
46 1 1
= = = = 0.25.
46 54 1 3 4

46 18
Mole fraction of water = 1-0.25 = 0.75
40
8. mass of solute in 400g of 40% =  400 = 160g
100
Total mass of solute = 160+75 = 235g
Total mass of solution = 400+300 = 700g
mass of solute
Mass% of solute = 100
Total mass of solution
235
= 100 = 33.57%
700
Mass % of solvent = 100 – 33.57 = 66.43%
9. mass of O2 = 6×10-3g
mass of o 2 6 103
ppm of O2 in 1030 g sea water = 10 6
= 106= 5.8 ppm.
mass of sea water 1030 
10. 85g phosphoric acid is present in 100g of solution.

100
17g of phosphoric acid is present in 17 = 20g of soution
85
mass
Volume of 17g of 85% acid =
density
20g
= = 11.8 cm3 .
1.70glcm3
17
Topic: - Solubility, vapour pressure and Raoult’s Law
1. Define the term – solubility? [1]
2. What is the effect of pressure on solubility of a gas? [1]
3. Carbon tetrachloride and water are immiscible whereas alcohol and water are
miscible. Explain on the basis of molecular structures of there compounds. [2]
4. State Henry’s Law. [1]
5. Why do mountaineers carry oxygen cylinder while climbing mountains? [2]
6. State Raoult’s Law. [1]
7. What are the factors on which vapour pressure depends? [1]
8. The vapour pressure of solvent gets lowered, when a non- volatile solute is
added to it. Why? [1]
9. Name two ways by which vapour pressure of a liquid can be lowered. [1]
10. Plot a graph between vapour pressure and mole fraction of a solution obeying
Raoult’s Law at constant temperature? [2]
18
[ ANSWERS ]
Topic: - Solubility , vapour pressure and Raoult’s Law
Ans 1. The maximum amount of a substance that can be dissolved in a specified amount
of solvent is called its solubility.
Ans 2. The solubility of a gas increases with increases of pressure.
Ans 3. Carbon tetrachloride is a non-polar compound whereas water is a polar compound.
They do not interact with each other and carbon tetrachloride cannot dissolve in
water whereas alcohol and water are completely miscible due to high polarity.
Ans 4. Henry’s Law states that the partial pressure of the gas in vapour phase is
proportional to the mole fraction of the gas in solution.
Ans 5. At high attitudes the partial pressure of oxygen is less than that of the ground level
which decreases the concentration of oxygen in blood and tissues. Low blood
oxygen causes climbers to become weak and unable to think clearly & they suffer
from anoxia. To avoid such situations, mountaineers carry oxygen cylinder while
climbing.
Ans 6. Raoult’s Law states that for a solution of volatile liquids, the partial vapour
pressure of each component in the solution is directly proportional to its mole
fraction.
Ans 7. The factors on which vapour pressure depends are –
1) Temperature of the liquid. 2) Nature of the liquid.

Ans 8. When a non-volatile solute is added to a solvent, the surface area for escape of
solvent molecules decreases and vapour pressure gets lowered.
Ans 9. The two ways by which vapour pressure can be lowered are –
1) By decreasing the temperature. 2) By adding a non- volatile solute.
Ans 10. P1
0
P
T ota l = P 1 + P2
P2
0
P 2
Vapour Press
P 1
X 2
X = 1
X 1 = 1 2
X = 0 X 1 = 0
2
19
Topic: - Ideal & non-ideal solutions, colligative properties relative

Lowering of vapour pressure
1. Define the term colligative properties? [1]
2. Name different colligative properties? [2]
3. Give the characteristics of ideal solution? [2]
4. A mixture of chlorobenzene and bromobenzene is a nearly an ideal solution
but a mixture of chloroform and acetone is not Explain? [2]
5. What are the possible deviations from ideal behaviors? [1]
6. Give one example of each deviation? [1]
7. Define the term azeotrope? [2]
8. Obtain a relationship between relative lowering of vapour pressure and mole
fraction of solute? [3]
9. The vapour pressure of CS2at 5000C is 854 mm Hg .A solution of 2.0g sulphur
in 100g of CS2 has a vapour pressure of 848.9 mm Hg .Calculate the formula
of sulphur molecule. [3]
10. At 4000C , the vapour pressure of water is 55.3 mm Hg .Calculate the vapour
pressure at the same temperature over 10% aqueous solution of urea [CO(NH2)2]? [3]
11. How much urea (molar mass 60 g/mol) should be dissolved in 50g of water so
that its vapour pressure at room temperature is reduced by 25%? [3]
12. Draw the graphs of both deviations from ideal behaviours? [2]
20
[ ANSWERS ]
Topic: - Ideal & non-ideal solutions, colligative properties relative

Lowering of vapour pressure
1. The property which depends upon amount of solute and not upon the nature of solute are
called colligative properties.
2. The colligative properties are –

a) Relative lowering of vapour pressure.
b) Elevation in boiling point.
c) Depression in freezing point
d) Osmotic pressure.
3. An ideal solution is formed from two liquids only when –

a) They obey Raoult’s Law
b) Δ Hmix = 0
c) Δ Vmix = 0
d) The various inter molecular forces are identical.
4. Chlorobezene & bromobenzene both have similar structure and polarity. Therefore the
various interactions (solute – solute, solvent – solvent & solute – solvent) are same
whereas in chloroform and acetone initially there is no hydrogen bonding but after
mixing solute solvent interactions (H –bond ) become stronger and solution deviates from
ideal behaviour.
5. There are two types of deviation from ideal behaviour – positive and negative deviations.
6. Positive deviation – ethanol and acetone.

Negative deviation – chloroform and acetone.
7. A solution at certain concentration when continues to boil at constant temperature

without change in its composition in solution & in vapour phase is called an azeotrope.
21
8. According to Raoult’s Law –
P1 = x1p10
ΔP = P10 – P = P10 – P10 X1
= ΔP1 = P10 (1-X1)
ΔP1 = P10 X2 (X1+X2 = 1)
P1
= X2
P10
P10 P 1
= = X2
P10
Relative lowering of vapour pressure.
9. PAo = 854 mm PA = 848. m , WB= 2.0g ,

WA = 100 g MB =?
MA = 12 + 2(32) = 76 g/mol /CS2)
P 0 P W W
A A
= XB = MB / A M
P0 A B A
= MB = WB × WA AP
0
M A PA  PA
= 2× 100  854
76 854  848.9
= 254.5 g/mol.
Let the formula = Sx

X×32 = 254.5 g/mol
254.5
X=
32
= 7.95
= 8.
= Formula = S8
10. 53.48 mm Hg.
11. 41.7 g .
22
12.
(b) Negative deviation
23
Topic : Elevation in boiling point, Depression in freezing point, osmotic pressure
1. Why is the boiling point elevated when a non – volatile solute is dissolved in a [1]
liquid?
2. How is boiling point changed when mass of solvent is doubled? [1]
3. 0.90g of a non – electrolyte was dissolved in 87.90g of benzene. This raised the [2]
boiling point of benzene by 0.250C. If the molecular mass of non – electrolyte
is 103.0 g/mol, calculate the molal elevation constant for benzene?
4. Show graphically the depression in freezing point on adding a non volatile [2]
solute?
5. Define cryoscopic constant? [1]
6. When 20g of a non – volatile solid is added to 250 ml of water, the freezing [2]
point of water becomes -0.90C. Calculate molecular mass of the solid if kf of
water is 1.860Ckg/mol.
7. What happens when red blood cells are placed in 0.1% NaCl solution? [1]
8. How is osmotic pressure of a solution related to its concentration? [1]
9. Calculate the osmotic pressure of 0.25 M solution of urea at 370C. R = 0.083 L [2]
bar/mol/k.
10. An aqueous solution of glucose, C6H12O6 has osmotic pressure of 2.72 atm at [2]
298k. How many moles of glucose were dissolved per litre of solution?
24
[ANSWERS]
Topic : Elevation in boiling point, Depression in freezing point , osmotic pressure
1. When a non – volatile solute is added the vapour pressure decreases and the solution is
heated to a higher temperature, increasing the boiling point.
2. ∆T = K Wsolute  1000
b b 
Wsolvent Msolute
= when the amount of solvent is doubled, ∆Tb is halved.
3. ∆T = K Wsolute  1000
b b 
Wsolvent Msolute
Wsolvent 1
K = ∆T × Msolute× 
b b
Wsolute 1000
87.90 1
= 103×0.25× 
0.90 1000
= 2.514 k kg/mol.
4.
5. When 1 mole of a solute (that neither dissociates nor associates) is dissolved in 1kg of
solvent, the depression in freezing point is called cryoscopic constant.
25
6. 250 ml = 250g as density of water = 1g/ml
Freezing pt of water = 273k
Freezing point of solution = - 0.90C+273 = 272.1k
∆Tf = 273 k – 272.1k = 0.9k
K W 1000
Msolute = f T solute
W
f solvent
1.86  26 1000
= = 165.3 g/mol .
0.9  250
7. Water from NaCl solution passes into cells &they swell. Finally they will burst.
8. Osmotic pressure, ̟ = CRT

C = concentration , R = gas constant.
T= temperature
9. T = 370C = 310k
n
T = CRT = RT
1
v
= 0.25×0.083×310 = 6.43 bar.
10. 0.111 mol.
26
Topics – Abnormal molecular mass
1. When does the measurement of colligative property leads to abnormal molecular

mass? [1]
2. Give various expressions for van’t Hoff factor? [2]
3. How are the various colligative properties modified after consideration of

van’t Hoff factor? [2]
4. The boiling point elevation of 0.6 g acetic acid in 100g benzene is

0.1265k. What conclusion can you draw about the state of solute
in solution? Molar elevation constant for benzene is 2.53 deg per molar? [2]
5. A weak electrolyte AB in 5% dissociated in aqueous solution? What is the

freezing point of a 0.10 molar aqueous solution of AB? Kf = 1.86 deg/molal? [2]
6. The osmotic pressure of a 0.0103 molar solution of an electrolyte is found to

be 0.70 atm at 2730C. Calculate van’t Hoff factor. R=0.082 L atm/1 mol/k? [2]
7. When is the value of i less then unity? [1]
8. The molecular mass of a solute is 120 g/mol and van’t Hoff factor is 4.
What is its abnormal molecular mass? [1]
27
[ANSWERS]
Topic: Abnormal Molecular Mass
1. When the solute undergoes either association or disassociation abnormal molar mass is
obtained.
2. Normal Molar mass

i=
Abnormal molar mass
Observed colligative property

=
Calculated colligative property
Total no. of moles of particles after association/dissociation

=
Total no. of moles of particles before association/dissociation
3. a) p1 - p1 = i X
0
2
p10
b)  Tb = i Kb .m
c) Tf = i Kf .m
d)  = i CRT
0.6 1000
4. Molality of acetic acid = 
60 100
= 0.10 m.
Tb = Kb  m
Tb 0.1265
M= = = 0.050 m
Kb 2.53
28
0.050
i= = 0.50
0.10
1
Since i = , acetic acid exist an dimer in solution.
2
5
5. Degree of dissociation × of AB = = 0.05 .
100
AB ----> A+ + B-
M 0 0
No. of moles dissolved
No. of moles after dissociations m(1-  ) m m 
0.1 (1 – 0.05) 0.1×0.05 0.1 × 0.05
Total moles = [0.1(1- 0.05)] + (0.1×0.05) + (.1× 0.05)

= 0.095 + 0.005 + 0.005 = 0.105m
Tf = Kf .m
= 1.86 × 0.105
= 0.1953 deg.
Tf = 00C- 0.1953 = 0.19530C
6. i = 2.76 The solute is dissociated in solution.
7. When the solute under goes association in solution , I is less then unity.
Normal moleculer mass

8. Abnormal molecular mass =
i
120
= = 30 g/mol .
4
29
CLASS - XII CHEMISTRY (Electrochemistry)
Topic: -Electrochemical Cells and Electrode Potential
1. Define the term – Electrode potential? [1]
2. Define the term – standard electrode potential? [1]
3. What is electromotive force of a cell? [1]
4. Can an electrochemical cell act as electrolytic cell? How? [2]
5. Single electrode potential cannot be determined. Why? [1]
6. What is SHE? What is its electrode potential? [1]
7. Explain construction and working of standard Hydrogen electrode? [3]
8. What does the positive value of standard electrode potential indicate? [1]
9. What is an electrochemical series? How does it predict the feasibility of a

certain redox reaction? [2]
10. Give some uses of electrochemical cells? [2]
30
[ANSWERS]
Topic: -Electrochemical Cells and Electrode Potential
1. A potential difference that develops between the electrode and the electrolyte is called
electrode potential.
2. When the concentration of all the species involved in a half-cell is unity, then the
electrode potential is called standard electrode potential.
3. Electromotive force of a cell is also called the cell potential .It is the difference
between the electrode potentials.
Ecell = Ecathode - Eanode
4. Yes, An electrochemical cell can be converted into electrolytic cell by applying an

external opposite potential greater than its own electrical potential.
5. A single half cell does not exist independently as reduction and oxidation occur
simultaneously therefore single electrode potential cannot be measured.
6. SHE stands for standard Hydrogen electrode. By convention, its electrode potential is
taken as 0 (zero).
7. Construction :
SHE consists of a platinum

electrode coated with platinum
black. The electrode is dipped in
an acidic solution and pure
Hydrogen gas is bubbled through
it. The concentration of both the
reduced and oxidized.
Forms of Hydrogen is maintained
at unity i.e) pressure of H2 gas is 1
bar and concentration of
Hydrogen ions in the solution is 1
molar.
31
1
Working – The reaction taking place in SHE is H+ (aq) + e- ---- H2 (g)
2
At 298 K , the emf of the cell constructed by taking SHE as anode and other half cell as
cathode ,gives the reduction potential of the other half cell where as for a cell
constructed by taking SHE as anode gives the oxidation potential of other half cell as
conventionally the electrode potential of SHE is zero.
8. The positive value of standard electrode potential indicates that the element gets
reduced more easily than H + ions and its reduced form is more stable than Hydrogen
gas.
9. The arrangement of metals and ions in increasing order of their electrode potential
values is known as electrochemical series.
The reduction half reaction for which the reduction potential is lower than the other
will act as anode and one with greater value will act as cathode .Reverse reaction will
not occur.
10. Electrochemical cells are used for determining the
a) pH of solutions
b) solubility product and equilibrium constant
c) in potentiometric titrations
32
Topic: -Nernst equation and its applications
1. A cell is represented by notation –

Cu (s) /cu2+ (aq) // Ag+ (aq) / Ag (s)
Calculate e.m.f of the cell if E0Cu2+/Cu = + 0.34V and E0 Ag+/Ag = 0.08V? [1]
2. What would happen if Nickel spatula is used to stir a solution of CuSO4?

E0Cu2+ / Cu = 0.34 V, E0N ; 2+ / Ni = -0.25V? [1]
3. State the factors that affect the value of electrode potential? [1]
4. Write Nernst equation for a Daniel cell? [1]
5. How is standard electrode potential of a cell related to :-

1) Equilibrium constant? [2]
2) Gibbs free energy change.
6. What is the half cell potential for Fe3+ /Fe electrode in which [Fe3+]= 0.1 m.
E0Fe3+ /Fe = + 0.771V [2]
7. Calculate pH of following half cell .

Pt , H2 / H2 SO4 , if its electrode potential is 0.03V. [2]
8. What is the cell potential for the cell at 250C

Cr / Cr3+ 10.1 m] //Fe2+ (0.01m) /Fe
E0cr+/cr = -0.74V ; E0 Fe2+/Fe = - 0.44V. [3]
33
9. Calculate  G0 for the reaction at 250C
Zn (s) 1 Zn2 + [0.0004m] 11 cd2+ (0.2m) 1 cd (s)
E0Zn2+/Zn = -0.763V , E0cd2+/cd = -0.403v , F=96500 C Mol-1 , R = 8.314 J/K. [3]
10. Calculate Equilibrium constant K for the reaction at 298K


Zn (s) + Cu2+ (aq)   Zn2+/aq) +Cu

E0Zn2+1Zn = -0.076v ; E0Cu2+/Cu = +0.34v. [3]
11. For what concentration of Ag+ (aq) will the emf of the given cell be zero at 250C
if the concentration of CU2+ (aq) is 0.1 M ? Cu (s) / Cu2+ (0.1M)// Ag+ (aq) / Ag(s)
E0 Ag+ /Ag = +0.80V; E0 Cu2+ /Cu = 0.34 V [3]
12. Calculate the standard free energy change for the cell- reaction.
Fe2+ (aq) + Ag+ (s) Fe3+ (aq) + Ag(s)
How is it related to the equilibrium constant of the reaction?
E0Fe3+/Fe2+ = + 0.77V , E0Ag+1/Ag = +0.08V F= 96500 C/mol. [3]
34
[ANSWERS]
Topic: -Nernst equation and its applications
1. E0cell =E0cathode – E0Anode

=E0Ag +/Ag – E0Cu2+/Cu
=0.80V – (+0.34V)
=+0.46V
2. From the reduction potential values, it is indicated that Nickel (more negative value)
is more reactive than copper and will, then displace copper from CuSO4
Ni (s) + Cu2+(aq) --- Ni2+ (aq) +Cu(s).
3. Factors affecting electrode potential values are –

a) Concentration of electrolyte
b) Temperature.
4. Daniel cell:
Zn(s) / Zn2 +(aq) //Cu2+(aq)/Cu(s)
Nernst equation – at 298 K
0.059 [Zn2 ]
Ecell = (E Cu +/Cu – E Zn +/Zn) -
0 2 0 2
log
2 [cu2 ]
5. (i) Standard electrode potential and equilibrium constant

2.303RT
E0cell = log kc
nF
Where E0cell = standard electrode potential of cell
R = Gas constant
T = temperature in Kelvin
n = no .of electrons.
F = Faraday’s constant and
Kc = Equilibrium constant
(ii) Standard electrode potential and Gibbs free energy change-

 G0 = - n F E0 cell
Where  G0 = Change in Gibbs’ free energy
n = No. of electrons
35
F = Faraday’s Constant
E cell = Standard electrode Potential of cell.
0
6. Fe3+ + 3e-  Fe
According to Nernst Equation –
0.059 1
E Fe 3+/ Fe = E0 Fe3+/Fe – log
n [Fe3 ]
0.059 1
= 0.771 V - log
3 0.1
= 0.771 V - 0.0197 V
= +0.7513V
7. PH = - Log [H+]
The cell reaction is –
H+ + e-  1 H2 (g)
2
According to Nearest Equation
0.059 1
E = E0 - log
n [H  ]
0.059 1
0.03V = 0 + (- log )
1 [H  ]
= 0 + 0.059 PH
0.03V
PH = = 5.07 V
0.059
8. The cell reaction is

2 Cr + 3 Fe2+ 6e-  2 Cr3+ + 3Fe
Nernst Equation –
2
Cr 3 
log 
0.059
Ecell = ( E0 Fe2+/ Fe- E0cr3+ /cr ) - 3
6  Fe 2 
0.059 0.10 2
=(-0.44v – (-0.74v) - log
 0.01
3
6
0.059
= 0.3V - log 104
6
= 0.3V – 0.0394V
= +0.2606 V
36
9. The half cell reactions are
Anode : Zn(s)  Zn2 + (aq) +2e-
Cathode : Cd2+ (aq) + 2e-  Cd (s)
Nernst Equation
0.059  Zn 2 
Ecell =(E0Cathode - E0anode)
- log 
n Cd 2 
0.059
= (- 0.403 – (-0.763) - log 0.0004
2 0.2
= 0.36V - 0.0798V = 0.4398V
G0 = - n F E0 cell
= -2mol  96500 C/mol × 0.4398V
= -8488 J mol-1
10. From the reaction, n =2

E0cell = E0cu2 +/cu - E0Zn2+/Zn
= + 0.34v - (-0.76v) = 1.10V
2.303RT
E0cell = log kc
nF
n
At 298k , E0cell × log kc
0.059
n
Log kc = E0cell ×
0.059
2
= 1.10  = 37.29
0.059
Kc = Antilog 37.29
= 1.95 ×1037
11. [Ag+] = 5.3 ×10-9 M
12. E0cell = 0.03V

G0 = -2895J
37
Topic: -Conductance, Equivalent – conductance and Molar conductance
1. Define the term – Resistivity? [1]
2. Give the unit of conductance? [1]
3. What do you understand by the term- conductivity? [1]
4. What are the factors on which conductivity of an electrolyte depend? [2]
5. How is molar conductance related to conductivity of an electrolyte ? [1]
6. Write an expression relating cell constant and conductivity? [1]
7. The conductivity of an aqueous solution of NaCl in a cell is 92  1 cm-1 the

resistance offered by this cell is 247.8  . Calculate the cell constant? [2]
8. The molar conductivity of 0.1M CH3COOH solution is 4.6 cm2 mol-1.

What is the conductivity and resistivity of the solution? [2]
9. The conductivity of metals decreases while that of electrolytes increases

with increases in temperature. Why? [2]
10. The measured resistance of a cell containing 7.5 x 10 -3 M solution of KCl at

250C was 1005  calculate
(a) Specific conductance and
(b) Molar conductance of the solution. Cell Constant = 1.25 cm-1 [2]
38
[ANSWERS]
Topic: - Conductance, Equivalent Conductance and Molar conductance
1. The resistively of a substance is its resistance when it is one meter long and its
area of cross Section is one m2 .
2. The SI unit of conductance is Siemens, denoted by the symbol, S & is equal to  -1.
3. Conductivity of a material in Sm-1 is its conductance when it is 1m long and its area
of cross - section is 1m2. It is represented by  .
4. The conductivity of an electrolyte depends upon

i) The nature of electrolyte added
ii) Size of the ions produced and their solvation
iii) Concentration of the electrolyte
iv) Temperature
5. Molar conductance,  m is related to conductively by the relation.

k
m=
c
Where  = conductivity in s/m.
C = concentration in mol/m3
6. Cell constant and conductivity are related by the expression-

G
= where G = Cell constant
R
 = conductivity
R = Resistance.
39
cell constant
7. Specific conductivity =
Resistance
Or cell constant = conductivity × Resistance
= 92  -1 cm-1  247.8 
= 22797.6 1



8. m =   1000 S cm2 mol
-1
C
1000 
=
M
m  M
=
1000
4.6 S cm2 / mol  0.1m
=
100
= 0.00046 s/cm
1
Resistivity =

 1
= = 2174  cm .
-1
0.00046 S cm
9. With increase in temperature, the K.E. of metal cation increases and obstructs the
free flow of electrons decreasing the conducts of metal while in case of
electrolytes, increased temperature increases the mobility of ions this increases
the conductance of ions.
10.  = 1.2 2/3 × 10-3  -1 cm-1

m = 165.7  -1 cm2 mol-1 .
40
Topic: - Kohlrausch Law & Electrolysis
1. What do you understand by strong and weak electrolytes? [1]

2. State kohlrausch’s Law? [1]
3. How is Limiting molar conductivity related to
i) degree of ionization and ii) dissociation constant [2]
4. In fig. (1), identify the nature
of electrolyte A& B. In which case
it is not possible to obtain value m
o A
of limiting molar conductance? B [2]

1 /2 1 /2
C ( m ol/ L)
5. At 298 K , the molar conductivities at infinite dilution of NH4Cl , NaOH and

NaCl are 129.8 , 217.4 and 108.9 scm2 mol -1 respectively .It molar conductivity
of 0.01M NH4OH solution is 9.33 scm2 mol-1 ,calculate the degree of dissociation
of NH4OH at this dilution? [2]
6. State Faraday’s Laws of electrolysis? [2]
7. What is meant by Faraday’s constant? [1]
8. How many faradays are needed to reduce 3g mole of Cu 2+ to Cu metal? [1]
9. How many g of chlorine can be produced by the electrolysis of molten
NaCl with a current of 1 amp. for 15 min? [2]
10. How many electrons flow when a current of 5 amps is passed through a
solution for 193 sec. Given f = 96500 C. NA=6.002 × 1023 mol-1? [2]
11. There are two possible reactions for cathode in the electrolysis of aqueous ZnCl2 : [2]
Zn2+ (aq) + 2e- Zn(s) E = -0.76v
2H2O (l) + 2e- H2 (g) + 2OH- (aq) E = - 0.83v
Which one will take place ?
12. Silver is deposited on a metallic vessel by passing a current of 0.2 amps.
for 3 hrs. Calculate the weight of silver deposited.
(At mass of silver = 108 amu, F = 96500 C? [2]
41
[ANSWERS]
Topic: -Kohlrausch Law & Electrolysis
1. An electrolyte that ionises completely in solution is a strong electrolyte eg. NaCl , CaCl 2
etc and an electrolyte that ionizes partially in solution is weak electrolyte eg CH 3
COOH , NH4OH etc.
2. Kohlrausch Law of independent migration states that limiting molar conductivity of an

electrolyte can be represented as the sum of the individual contributions of the anion
and cation of the electrolyte.
3. Relation between limiting molar conductance and degree of dissociation –

m
  where  = degree of dissociation
 om
m = molar conductance
m0 Limiting molar conductance
Relation between dissociation constant and limiting molar conductance –
C m2
Ka = where c = concentration
m0 (m0 - m)
4. A = strong Electrolyte
B = weak Electrolyte
In case of B , it is not possible to get an exact value of limiting molar conductance.
5.  0 (NH OH) =  o (Na Cl) +  o (NaOH)- o (NaCl)

m 4 m 4 m m
= 129.8 +217.4 – 108.9 = 237.3 5 cm2 /mol

2
m = 9.33 5 cm / mol
Degree of dissociation ,  =
m 0 237.3 5 cm / mol
2
= 0.039 or 3.9 %.
6. Faraday’s Laws of electrolysis
First Law: The amount of chemical reaction which occurs at any electrode during
electrolysis by a current is proportional to the quantity of electricity
passed through the electrolyte.
42
Second Law: The amount of different substances liberated by the same quantity of
electricity passing through the electrolytic solution is proportional to
their chemical equivalent weights.
7. Faraday’s constant is the quantity of electricity carried by one mole of electrons.

1 F = 96500 C/mol
8. Cu2+ + 2e-  Cu
Two faradays are needed to reduce 1g mole Cu 2+ 6 Faradays will be needed to
reduce 3g mole of Cu2+.
9. Q = It = 1× 15 × 60 = 900C
The reaction is 2Cl-  Cl2 + 2e-
2mol 1mol 2mol
 2F . produces 1 mol of Cl2
1mol of Cl2 = 71g
 2  96500 C produces 71g of Cl2
71
900 C will produce  900 g = 0.331 g of Cl2.
2 96500
10. Q = It = 5X 193 = 965 C

96500C = 1 mol of electrons = 6.022X1023 mol-1
 965
965 C = 6.022 X 1023
96500
= 6.022 × 1021 electrons.
11. Zn2+ has higher reduction potential (-0.76v) Than H2O (- 0.83v) and therefore Zn2+ is
reduced to Zn preferentially at cathode.
12. 2.417 g of silver.
43
Topic: - Batteries and corrosion.
1. What do you mean by primary and secondary battery? [2]
2. Name the cell used for low current devices like hearing aids, watches etc. Also give the
half cell reactions for such a cell? [2]
3. Give the reaction taking place in lead storage battery when it is on charging? [1]
4. A Leclanche cell is also called dry cell. Why? [1]
5. Why is the voltage of a mercury cell constant during its working? [1]
6. What are fuel cells? [1]
7. What do you understand by corrosion? [1]
8. Rusting of iron is quicker in saline water than in ordinary water .Explain? [2]
9. Name two metals than can be used for cathodic protection of iron? [1]
10. Enlist the factors affecting corrosion? [2]
44
[ANSWERS]
Topic: -Batteries and corrosion.
1. In the primary batteries, the reaction occurs only once and after the use over a period of
time battery becomes dead and cannot be reused again. A secondary battery , after used,
can be recharged by passing current through it in the opposite direction so that it can be
used again.
2. This cell is mercury cell – Half cell reactions are

Anode Zn (Hg) + 2OH-  ZnO + H2O + 2e- and Cathode HgO + H2O +2e-  Hg (e) +
2OH-
3. When the lead storage battery is on charging –

2 PbSO4 (s) + 2H2O (e)  Pb (s) + PbO2 (s) + 2H2SO4 (aq)
4. Leclanche cell consists of zinc anode (container) and carbon cathode. The electrolyte is
a moist paste of MnO2, ZnCl2, NH4Cl and carbon black. Because there is no free liquid in
the cell, it is called dry cell.
5. As all the products and reactants are either in solid or liquid state, their concentration
does not change with the use of the cell.
6. A fuel cell is a galvanic cell for converting the energy of a fuel directly into electrical
energy without use of a heat engine.
7. Corrosion is an electrochemical phenomenon in which metal gets decomposed in the

presence of air and water and forms compounds like oxides, sulphates, carbonates,
sulphides etc.
8. Saline water consists of greater no. of ions than normal water which increases the
electrochemical reaction. This increases rate of corrosion.
9. Names of the metals are – Zinc and Magnesium.
10. Factors affecting corrosion are -

1) Water and air 2) Presence of electrolytes in water. 3) Presence of gases like CO 2 ,
SO2.
45
CLASS - XII CHEMISTRY (Chemical Kinetics)
Topic: -Rate of reaction – Average and instantaneous rates
1. Define the term chemical kinetics? [1]
2. Define – Rate of reaction? [1]
3. What is average rate of a reaction? How is it determined? [2]
4. What are the units of rate of a reaction? [1]
5. What is instantaneous rate of a reaction? How is it determined? [2]
6. For the following reactions, write the rate of reaction expression in terms
of reactants and products? [2]
i) 4NH3 (g) + 5O2 (g)  4NO (g) + 6H2O (g)

ii) 2N2O5  2NO2 + O2
7. For the chemical decomposition of SO2Cl2, its initial concentration is

0.8420 mol/L and final concentration is 0.215 molL-1 in 2 hours.
What is the average rate of this reaction? [2]
8. In the expression of rate of reaction in terms of reactants, what is the

significance of negative sign? [2]
  O3 
9. 
For the reaction 2O3 (g)   3O2 (g), -
 was found to be 5.0 X 10-4 at m/s.
t
  O2 
Determine the value of in atm /s during this period of time? [2]
t
10. A chemical reaction 2A  4B+C in gas phase occurs in a closed vessel.

The concentration of B is found to be increased by 5 X 10 -3 mole L-1 in 10 second.
Calculate (i) the rate of appearance of B (ii) the rate of disappearance of A? [2]
46
[ANSWERS]
Topic: -Rate of reaction –Average and instantaneous rates.
1. The branch of chemistry that deals with the study of reaction rates and their mechanisms is
called chemical Kinetics.
2. Rate of reaction can be defined as the change in concentration of a reactant or product per
unit time.
3. Average rate of a reaction is defined as the change in concentration of a reactant or a

product per unit time. It can be determined by dividing the change in concentration of
reactant or product by the time interval
   A   B 
For the reaction: A  B R av = =
t t
4. The units of rate of a reaction are Mol /L /s
5. The rate of a reaction at a particular moment of time is called instantaneous rate of a

reaction.
For a reaction AB
R inst = d  A = d  B . Where dt = the smallest possible time interval (t  0)
dt dt
6. In terms of reactant In terms of products

1   NH 3  1 NO
i) R1 = 4 t R3 =
4 t

R2 = 1   O2  
R4 = 1   H 2 O 

5 t 6 t
1 1 1 1
R1 = R 2= R 3= R4
4 5 4 6
1   NH 3  = - 1   O2  1   NO  1   H 2 O 
 = = 
4 t 5 t 4 t 6 t
47
II ) In terms of reactant In terms of product
  N 2 O5    NO2 
R1 =  R2=
t t
  O2 
R3 = 
t
1 1   N 2 O5  1   NO2    O2 
R1 = R2 = R3 - = =
2 2 t 2 t t
7. change in concentration
Rate of reaction =
time interval
(0.8420  0.2105) mol/L = 0.6315 = 0.3158 mol /L/hr .

=
2hr 2
8. While writing the expression for rate of a reaction is terms of reactants, there is a negative
sign which indicates a decrease in concentration of reactants with time.
9. 
From the equation 2O3 (g)   3O2 (g)

1  O3  1   O2 
 =
2 t 3 t
  O2  3   O3  3
= =  (-5.0 10-4 atms-1 ) = 7.5104 atms-1
t 2 t 2
10. 2A  4B +C
1 d  A 1 d B= d C 
 =
2 dt 4 dt dt
i) Rate of disappearance3 of B
510 1 -4 -1 -1
= mol /L = 5  10 mol L s
10 5
 d  A 2 d B 1 d B
ii) = =
dt 4 dt 2 dt
1
=  5104 mol L-1 s-1 = 2.5 104 mol L-1 s-1
2
48
Topic: -Factors affecting rate of a reaction , order and molecularity of a reaction.
1. Is rate of reaction always constant? [1]
2. Enlist the factors affecting rate of a reaction? [1]
3. What do you understand by rate law expression? [2]
4. Is it possible to determine or predict the rate law theoretically by merely

looking at the equation? [1]
5. Define the terms – i) Order of a reaction [2]

ii) Molecularity of a reaction.
6. What are elementary and complex reactions? [2]
7. Differentiate between order and molecularity of a reaction? [2]
8. Determine the overall order of a reaction which has the rate law [2]
R = K [A]5/2 [B]3/2
9. What are the units of a rate constant of a [2]

a) First order reaction
b) nth order reaction.
10. For the reaction A+B  C+D, the rate of reaction doubles when the
concentration of A doubles, provided the concentration of B is constant.
To what order does A enter into the rate expression? [2]
49
[ANSWERS]
Topic: - Factors affecting rate of a reaction , order and molecularity of a reaction.
1. No. rate of a reaction is not always constant. It depends on many factors such as
concentration, temperature etc.
2. The factors affecting rate of a reaction are –

a) Concentration of reactants
b) Temperature
c) Catalyst
3. The rate law is the expression in which rate is given in terms of molar concentration
of reactants with each term raised to some power ,which may or may not be same as
the stoichiometric coefficient of the reacting species in a balanced chemical equation.
4. No, the rate law can not be predicted by merely looking at the balanced chemical
equation but must be determined experimentally.
5. i) Order of a reaction.
The sum of powers of the concentration of the reactants in the rate law expression is
called order of that reaction.
ii) Molecularity of a reaction.

The number of reacting species which must collide simultaneously in order to bring
about a chemical reaction is called molecularity of a reaction.
6. The reactions taking place in one step are called elementary reactions whereas when a
sequence of elementary reactions , called mechanism , gives us the product , it is called
complex reaction.
50
Order Molecularity
7.
i) it is an experimental parameter i) It can be predicted from equation
and cannot be predicted theoretically. theoretically
ii) It can be zero. ii) It cannot be zero.
iii) It can be a whole number as well as a iii) It cannot be a fraction. It can only be
fraction. a whole number.
8. Rate = k[A]x [B]y

Order = x +y
5 3
50 order = + = 4.
2 2
i. e; reaction is fourth order reaction.
9. i) First order reaction –

Units of rate constant , k = sec-1
ii) For nth order reaction

the units of rate constant, k = mol(1-n) (n-1)Ls-1
10. A+B  C+D

Rate  [A]x
Rate = 1 when [A] = 1 ---------- 1)
Rate = 2 when [A] = 2 -----------2)
Dividing equation 2) by 1)
2 2
x

1 1x
21  (2)x
x=1
The reaction is first order reaction.
51
Topic: -Determination of order of a reaction.
1. Identify the reaction order for from each of the following rate constant –
a) k = 2.3 ×10-5 L mol-1 s-1
b) k = 3.1 × 10-4 s-1 [1]
2. Consider the equation 2 NO (q) + 2H2 (g)  N2 (g) + 2H2O (g)

The rate law for this equation is first order with respect to H2 and second
order with respect to NO. write the rate law for this reaction. [1]
3. The rate Law for the reaction A+B  C is rate = K [A]2 [B] . What would the
reaction rate be when concentration of both A and B are doubled? [2]
4. Write the integrated rate equation for –

i) zero order reaction.
ii) first order reaction. [2]
5. From the graph below [2]

i) Identify the order of reaction.
ii) What will be the unit of rate constant?
52
6. The reaction 2N2O5 (g)  2NO2 (g) +O2 (g) was studied and the following data were
collected :
s.no [N2O5] mol L-1 Rate of disappearance of [N2O5]

(mol/L/min
1. 1.13×10-2 34×10-5
2. 0.84 ×10-2 25×10-5
3. 0.62×10-2 18×10-5
Determine
i) The order
ii) The rate law.
iii) Rate constant for the reaction. [3]
7. The following experimental data was collected for the reaction:

Cl2 (g) + 2NO (g)  2 NOCl(g)
Trial Intial conc. Of Cl2 (mol/L) [NO] mol/L Initial Rate,(mol/L/s)

1 0.10 0.010 1.2 X 10-4
2 0.10 0.030 10.8 X 10-4
3 0.20 0.030 21.6 X 10-4
Construct the rate equation for the reaction. [3]
8. Draw a graph for

a) Concentration of reactant against time for a zero order reaction.
b) Log [Ro]/ [R] against time for a first order reaction. [2]
9. What is the use of integrated rate equation? [2]
10. For first order reaction –

A B
Write (1) Differential rate law.
(2) Integrated rate law. [2]
53
[ANSWERS]
Topic: -Determination of order of a reaction
1. a) Since the units of rate constant are Lmol-1 s-1 The reactions is of second order.
b) Since the units of rate constant are s-1 , The reaction is of first order.
2. The rate law will be R = K [NO]2 [H2]
3. R1 = K [A]2 [B] -------------------------------------------------- 1)

R2 = K [2A]2 [2B] ----------------------------------------------- 2)
Dividing 2) by 1)
2
R2 = [2 A] [2B] 8 [A]2 [B] R2 = 8:1 or R = 8R
= = 2 1
R1 [ A]2 [B] [A]2 [B] R1
The rate of reaction increases eight times.
[R] 0[R]
4. i) Zero order reaction - K=
t
ii) First order reaction K = 2.303 log [R0 ]
t [R]
Where R0 is the initial concentration
R is concentration at time t.
5. From the graph

i) Reaction is first order reaction
ii) The unit of rate constant will be sec-1.
6. Let the order of reaction be x

Rate = K[N2O5]x
i) From the data -
34 ×10-5 = (1.13× 10-2)x--------------------------------------------- 1)
25×10-5 = (0.84× 10-2)x----------------------------------------------2)
54
18×10-5 = (0.62×10-2)x ----------------------------------------------- 3)
Dividing 1) by 2)
34 105 1.13102 x
=( )
25105 0.84 102
(1.36) = (1.35)x
X=1
The order of reaction with respect with respect to N2O5 is 1
ii) Rate law R = K [N2O5]
Rate 18105 mol/L/min
iii) Rate constant , K = = = 0.29 min-1
[N2O5 ] 0.62 102 mol/L
7. Order of NO is 2
Rate law = K [Cl2] [NO]2
8.
9. Use of integrated rate equation -

1. The value of rate constant can be known when concentration of reactant at different
times are known-
2. Order of a reaction can be determined by the knowledge of reaction concentration at

different times.
10. For the reaction A  B , if the order =1

d[ A]
(i) Differential rate law is = K [A]
dt
2.303 [R]o
(ii) Integrated rate law is t = log
K [R]
55
Topic: -Half life period Temperature dependence.
1. Give an example of pseudo – first order reaction ? [1]
2. Write the expression for half – life period of a first order reaction? [1]
3. A first order reaction is found to have a rate constant K = 5.5 × 10-14 sec -1.
Find half life of reaction? [1]
4. The time required to decompose SO2Cl2 to half of its initial amount is 60 min. If the
decomposition is a first order reaction, calculate the rate constant of the reaction? [2]
5. The rate constant for the first order decomposition of N2O5 at 250C is 3X10-2 min-1.
It the initial concentration of N2O5 is 2X10-3 mol/L, How long will it take to drop the
concentration to 5X10-4 mol /L ? [2]
6. Write Arrhenius equation. [1]
7. If the activation energy of a reaction is zero, will the rate of reaction still depend on
temperature? [2]
8. In general it is observed that the rate of a chemical reaction doubles with every 100
rise in temperature. If this generalization holds for a reaction in the temperature
range295K to 305K, what would be the activation energy for this reaction?
(R=8.314Jk-1 mol-1) [3]
9. The rate constant for a reaction is 1.5× 107 s-1 at 500C and 4.5× 107 s-1at 1000C.
Calculate the value of activation energy for the reaction R=8.314 JK-1 mol-1? [3]
10. Plot a graph showing variation of potential energy with reaction .coordinate? [1]
56
[ANSWERS]
Topic: - Half life period Temperature dependence.
1. Hydrolysis of ethyl acetate when concentration of water is very large , is an example of

pseudo first order reaction.
CH3COO C2H5 + H2O  CH3 COOH + C2H5OH.
2. For a first order reaction , the half life period is

0.693
T1/2 =
k
0.693
3. t1/2 =
k
0.693
= = 1.26 1013 s
5.51014 sec-1
4. 0.011 55 min-1
2.303 Ro
5. t= log
k R
2.303 2 103
= log
3102 min-1 5104
2.303
= log 4 (log 4 = 0.6021)
3102
= 46.22 min.
6. Arrhenius equation
K = A e –Ea/RT
Where K = rate constant , T = absolute temperature
Ea = Activation energy, R = gas constant.
7. K = A e-Ea/RT
When Ea = 0
K = A e -0/RT
57
= A. e0
K=A
Rate of reaction will not depend upon the temperature if activation energy is
zero.
8. T1 = 295K T2 = 305K
Ea = 2.303 R  T2T1  log k2 
T  T   k 
  
 2 1  1 
K2 = 2k1
 305 295 
Ea = 2.3038.314   2k1
 305  295  log k
  1
= 2.303 × 8.314 × 8997.5K log 2

= 51855.2 J/mol (log2 = 0.3010)
9. 22.0 KJ/mol.
10.
58
Topic: -Effect of catalyst, collision theory.
1. What is the effect of catalyst on rate constant? [1]

2. How is activation energy affected on adding a catalyst? [1]
3. What do you mean by the term- collision frequency? [2]
4. How does collision theory explain formation of products in a chemical reaction? [1]
5. What is the drawback of collision theory? [2]
6. How does the number of collisions change on increasing the temperature? [2]
7. There is no bar on the no. of collisions among the reaching species. Why most of the
reactions do not take place under normal conditions? [2]
8. From the fig. (1) [2]
(a) Calculate E for the reaction, activation
energy for forward reaction.
(b) Identify the curve for catalysed reaction.
(c) what is the energy of activation in the
presence of catalyst?
9. The activation energy of reaction is 75.2 KJ/mol in the absence of a catalyst and 50.14
KJ/Mol in the presence of a catalyst. How many times will the reaction grow in the
presence of a catalyst, if the reaction proceeds at 250C? [2]
10. The rate of a particular reaction quadruples when the temperature changes from 293 K to
313 K. Calculate activation energy for such a reaction. [2]
59
[ANSWERS]
Topic: -Rate of reaction – Effect of catalyst , collision theory.
1. A catalyst increases the rate constant value.
2. A catalyst lowers the activation energy by following a different path for the reaction.
3. The no. of collisions per second per unit volume of the reaction mixture is known as
collision frequency. It is denoted by Z.
4. According to collision theory, the reactant molecules are assumed to be hard spheres and
reaction occurs when these molecules collide with each other. The collisions in which
molecules collide with sufficient kinetic energy (called threshold energy) and proper
orientation, lead to formation of product. Here activation energy and proper orientation
of the molecules determine the criteria for effective collision & hence the rate of a
reaction.
5. The drawback of collision theory is that it considers the molecules to be hard spheres and
ignores their structural aspect.
6. The rate of reaction would increase on increasing the temperature as it will increase the
no. of collision as well as no. of effective collisions.
7. The reactions either do not have required energy or are not properly oriented, then the
reaction will not take place.
8. (a) From the figure-

Energy of reactions Er = 150KJ/Mol
Energy of products, Ep = 50Kj/Mol
Change in energy, E  EP  ER
= 50-150 = 100KJ/Mol
Threshold energy, Er = 350 KJ/Mol
60
Activation energy, Ea = Et – Er
= 350-150
= 200 KJ/Mol.
(b) The curve B is for catalysed reaction.
( C) In the presence of catalysts ,

Threshold energy Er = 250KJ/Mol
Activation energy, Ea = 250-150

= 100 KJ/Mol.
9. Let the rate constant in the absence of catalyst be K1, Let the rate constant in the presence
of catalyst be K2 Activation energy in the absence of catalyst, E1 = 75.2 KJ/Mol Activation
energy in the presence of catalyst, E2 = 50.14 KJ/Mol.
log 2 = E1  E2
K
K1 2.303RT
(75.2  50.14) 103 J / Mol

2.303 8.314J / K / mol  298K
= 4.391.
K2 
 Antilog 4.391
K1
K2 
 24604
K1
Or K2 = 24604 K1
10. 52.86 KJ/mol
61
CLASS - XII CHEMISTRY (Surface chemistry)
Topic: Adsorption – types and nature
1. What do you mean by the term –Adsorption ? [1]
2. Explain the terms – Adsorbate and Adsorbent ? [1]
3. Give some example of adsorbate and adsorbent ? [2]
4. Define the term – desorption? [2]
5. Give two differences between adsorption and absorption ? [1]
6. Why do finely divided solids act as good adsorbents ? [1]
7. Name the two types of adsorptions ? [2]
8. Write the four differences between physisorption and chemisorption? [2]
9. ‘Adsorption is an exothermic process ‘. Explain. [2]
10. Explain the Mechanism of adsorption. [1]
11. What is the sign of H , S and G when a gas is adsorbed by an adsorbent? [2]
12. (a) Which gas is adsorbed more readily on charcoal lump: ammonia or carbon
dioxide and why ?
(b) Which adsorbs more of carbon monoxide: charcoal lump or charcoal powder
& why? [2]
62
Topic: Adsorption – types and nature
ANSWERS
1. The accumulation of molecular species at the surface rather than in bulk of a solid liquid
is termed as Adsorption.
2. The molecular species which get concentrated or accumulated at the surface are
adsorbate and the material on the surface of which the adsorption takes place is
adsorbent.
3. Adsorbate examples O2, H2, CO, Cl2, NH3 etc.

Adsorbent examples – charcoal, silica gel, alumina gel, clay, colloid etc.
4. The process of removing an adsorbed substance from a surface on which it is adsorbed is

called desorption.
5. Adsorption Absorption
1. It occurs on the surface of the 1. The molecules of the substance are

Adsorbent. uniformly distributed throughout the body
of the solid or liquid.
2. Rate of adsorption decreases until 2. Rate of absorption is same throughout.
the equilibrium is reached .
6. Powdering of solids increase its surface and therefore it can adsorb a greater amount of
the adsorbate. Thus finely divided solids act as good adsorbents.
7. Two types of adsorptions are –

1. Physical adsorption or physisorption .
63
2. Chemical adsorption or chemisorption .
8. Physical Adsorption Chemical Adsorption

1. It is caused by Vander Waals forces. 1. It is caused by chemical bond formation.
2. It is not specific in nature. 2. It is highly specific in nature.
3. It is reversible in nature. 3. It is irreversible.
4. Enthalpy of adsorption is low. 4. Enthalpy of adsorption is high.
9. During adsorption, there is always a decrease in residual forces of the surface. Therefore
the surface energy decreases which appears as heat. Therefore adsorption is exothermic
process.
10. Adsorption arises due to presence of unbalanced forces or residual attractive forces on
the particles of the surface. These forces are responsible for attracting the adsorbate
particles on its surface and they cause the adsorption.
11. H is negative, S is negative and G is negative.
12. (a) Ammonia gets adsorbed more readily because it is polar molecule and easily
liquifiable.
(b) Charcoal powder adsorbs more of carbon monoxide because it has larger surface area
than charcoal lump.
64
Topic: Factors affecting adsorption, Application of adsorption , Homogeneous and

hetrogeneous catalysis
1. Name the factors which influence the extent of adsorption of a gas on solid. [2]
2. What is adsorption isotherm? [1]
3. H for chemisorption is high .why? [1]
4. Explain Freundlich adsorption isotherm. [2]
5. Give an equation showing variation of extent of adsorption with concentration

of a solution? [1]
6. Name the adsorbent used [3]

a) To remove coloured impurities from sugar solution.
b) In gas masks to remove chlorine.
c) To remove moisture from air.
7. Define the terms – catalysis and catalyst. [2]
8. What are positive and negative catalysts? [1]
9. What do you mean by the term promoter? Give an example. [1]
10. What are homogeneous and heterogeneous catalysis? Give example. [3]
65
Topic: Factors affecting adsorption, Application of adsorption, Homogeneous and

hetrogeneous catalysis
ANSWERS
1. Factors affecting extent of adsorption are –

(i) Nature of adsorbent and adsorbate.
(ii) Surface area of solid
(iii) Pressure of gas
(iv) Temperature
2. The variation in the amount of gas adsorbed by the adsorbent with pressure at constant
temperature can be expressed by means of a curve known as adsorption isotherm.
3. In chemisorption, chemical bonds are formed that evolves a large amount of energy.
Therefore H for chemisorption is high.
4. Freundlich adsorption isotherm gives an empirical relationship between the quantity of

gas adsorbed by unit mass of solid adsorbent and pressure at a particular temperature
x
The relationship is = K.P1/n (N> 1)
m
Where x is a mass of gas adsorbed on mass m

of adsorbent at pressure P, K &n are constant
that depend on the nature of adsorbent and
adsorbate – The relationship can be represented
by plotting curves between x/m and P. They show
that at a fix pressure, the physical adsorption
decreases with increase in temperature.
5. x/m = K C1/n (n > 1)

Where x/m is the extent of adsorption - k &n are constants and c is the concentration of
solution.
6. (a) Activated charcoal

(b) Activated charcoal
66
(c) Silica gel.
7. (a) The phenomenon in which a small quantity of a substance known as catalyst alters the
rate of a reaction is known as catalysis.
(b) The substance which alter the rate of a reaction and themselves remain chemically
and quantitatively unchanged after the reaction are known as catalysts.
8. A catalyst which increases the rate of a reaction is positive catalyst and which decrease
the rate is a negative catalyst.
9. Promoters are substances that enhance the activity of a catalyst e.g. molybdenum acts as a
promoter in Haber’s process.
10. Homogeneous catalysis –

When reactant and catalyst are in the same phase, the process is said to be homogeneous
catalysis.
Examples –
(1) Oxidation of sulphur dioxide in the presence of oxygen gas and nitric oxide gas as
catalyst.
2 SO2 (g) + O2(g) N  2 SO3 (g)
O (g )
(2) Hydrolysis of methyl acetate2 catalysed by H+ ions.

CH3COOCH3 (ℓ) +H 2 0 (ℓ)   4
 CH COOH(aq) + CH OH (aq)
H SO (ℓ0)
3 3
(3) Hydrolysis of sugar catalysed by H2S04.
Hetrogeneous Catalysis –
The catalytic process in which the reactant and catalyst are in different phases is known
as heterogeneous catalysis.
Examples:-
(1) Oxidation of sulphur dioxide in presence of platinum.
O2 (g) + 2SO (g )  
pt ( s )
 2SO (g)
2 3
(2) Preparation of ammonia by Haber’s process

N2 (g) + 3H2 (g) F 
e(S )
 2NH 3 (g)
(3) Oxidation of ammonia in Ostwald’s process.
4NH 3 (g ) + 5O 2 (g)   4NO(g) + 6H O (g)
Pt ( s )
2
67
Topic: Hetrogeneous catalysis, zeolites, enzyme catalysis
1. Explain modern theory of heterogeneous catalysis. [2]
2. What is meant by activity and selectivity of a catalyst? [2]
3. What is shape – selective catalysis? Give an example of shape selective catalyst. [2]
4. Give two examples of enzyme catalysed reaction. [2]
5. Write characteristics of enzyme catalysed reactions. [3]
6. Explain the mechanism of enzyme catalysis. [2]
7. Name some important industrial catalytic process and their catalysts. [3]
8. How do metal ions act as activators? [1]
9. What is the optimum temperature and pH for enzyme catalysed reactions? [1]
10. Give two examples of reactions catalysed by zeolites. [2]
68
Topic: Hetrogeneous catalysis, zeolites, enzyme catalysis
ANSWERS
Ans 1. According to modern theory of catalysis, the mechanism of heterogeneous catalysis

involves following steps –
(i) Diffusion of reactants on the surface of catalyst.
(ii) Adsorption of reactant molecules on the surface.
(iii) Occurrence of reaction on the catalysts surface through formation of an
intermediate.
(iv) Desorption of products from surface.
(v) Diffusion of products away from surface.
Ans 2. Activity of a catalyst is the extent to which a catalyst can increase the rate of reaction.
It depends upon the strength of chemisorption.
Selectivity of a catalyst is its ability to direct a reaction to yield a particular product.
The action of a catalyst is highly selective in nature.
Ans 3. The catalytic reaction that depends upon the pore structure of the catalyst and the size
of the reactant and product molecules is called shape selective catalysis. Zeolites are
good shape catalysts due to there honeycomb – like structure. The reactions taking
place in zeolites depends upon the size and the shape of reactant and product
molecules as well as upon the pores and cavities of the zeolites.
Ans 4. Examples of enzyme- catalysed reactions are –

(1) Inversion of cane sugar:
C H O (aq)  H O(ℓ) I 
nvertase
 C H O (aq) + C H O (aq)
12 22 11 2 6 12 6 6 12 6
2. Decomposition of urea into ammonia and carbon dioxide.

NH2CONH2 (aq)  H2O(ℓ)    2NH 3(g) +CO 2(g)
Urease
Ans 5. The characteristics of enzyme catalysed reactions are –

(1) They are highly efficient and specific in nature.
(2) They have maximum activity under specific temperature and pH.
(3) Their activity increases on adding activators and coenzymes while decreases in
the presence of poison or inhibitors.
69
Ans 6. Mechanism of enzyme catalysed reactions-
There are active centres or cavities on the surface of enzyme particles. The molecules
of the reaction or substrate which have complementary shape fit into these just like a
key
fits into a lock. This forms an activated complex which decomposes to yield products.
The reactions proceed in two steps –
Step 1: Binding of enzymes to substrate to form activated complex.
E+S ----- ES
Step 2 : Decomposition of complex to form products.
ES ----- E + P.
Ans 7. Process Catalyst

1. Haber’s process for preparation of ammonia. Iron , Molybdenum
2. Ostwald’s process for manufacture of nitric acid. Platinised asbestos.
3. Contact process for manufacture of sulphuric acid. Vanadium pentaoxide (V2O5).
Ans 8. The metal ions like Na+, Mn2+, Co2+, Cu2+ etc. can bind weakly to enzyme molecules.
This increases their catalytic activity and therefore metal ions can act as activators.
Ans 9. The optimum temperature is 298K – 310K and optimum pH is 5 – 7 for enzyme –
catalysed reactions.
Ans 10. Example of zeolite catalysed reactions are:

(a) Cracking of hydrocarbons in petroleum industries.
(b) Conversion of alcohols into gasoline.
70
Topic:-Colloids – classification and preparation
1. What are colloids? [1]
2. What is the range of particle size in colloids? [1]
3. What is dispersed phase and dispersion medium in [3]
(i) sol (ii) Aerosol (iii) Foam?
4. Give two examples of solid Sol and Gel? [1]
5. Differentiate between lyophobic and lyophillic sol? [3]
6. Colloid is a state not a substance. Explain? [1]
7. Give two examples of substances that form: – [2]
(a) Hydrophobic sol.
(b) Hydrophilic sol.
8. Differentiate between multimolucular and macromolecular colloid? [2]
9. What are associated colloids? Give an example? [1]
10. What is CMC and Kraft’s temperature? [1]
11. Write the equation for formation of [2]
(a) Sulphur sol.
(b) Ferric hydroxide sol.
12. Define the term peptization? [1]
71
[ANSWERS]
Topic:-Colloids – classification and preparation
Ans 1. A colloid is a heterogeneous system in which one substance is dispersed (dispersed

phase) as very fine particles in another substance called dispersion medium.
Ans 2. The range of diameter of colloidal particles is 1 to 1000 nm.
Ans 3. Dispersion medium Dispersed phase Colloid

(i) Solid Liquid Sol
(ii) Solid Gas Aerosol
(iii) Liquid Gas Aerosol
(iv) Gas Liquid Foam.
Ans 4. Solid sol – coloured glass, pumice stone.

Gel – Cheese, Butter.
Ans 5. Lyophobic sol Lyophillic sol.
1. It is relatively unstable due to 1. It is relatively more stable due to

Repulsion between dispersion med- attraction between dispersion medium
ium and dispersed phase. and dispersed Phase.
2. It is irreversible. 2. It is reversible.
3. It cannot be easily peptised. 3. It can be easily peptised.
4. Small quantities of electrolyte cause 4. Small quantities of electrolyte has no
precipitation. effect larger concentration causes
precipitation.
Ans 6. Every solute can be converted into the particle size of a colloid which is 1-1000 nm.
Therefore every solute can act as a colloidal particle under suitable conditions.
72
Ans 7. (a) hydrophobic sol : Gold, platinum
(b) hydrophilic sol : starch, proteins in water.
Ans 8. Macromolecular colloid Multimolecular colloid

1. It consist of aggregates of atoms or 1. They are themselves Large.
molecules with diameter less then 10-9m.
2. The atoms or molecules are held tog- 2. Since the molecules are flexible. They
ether by weak Vander Waal’s forces . can take Various shapes.
3. Example - Gold sol, sulphur sol. 3. Example – starch, proteins.
Ans 9. The substances, which at low concentration behave as normal electrolyte but at higher
concentration exhibit colloidal behavior due to formation of aggregates, are called
associated colloids. For example – soaps and detergents. They are also called micelle.
Ans.10 CMC or critical micelle concentration and Kraft’s temperature are the concentration
and temperature above which micelle formation or associated colloid formation takes
place.
Ans.11 (a) SO2 + 2H2S  O 

xidation
 3S + 2H 2 O
(Sol)
(b) FeCl3 + 3H2O  H 
yd r olysi s
 Fe(OH)3 + 3HCl
(Sol)
Ans.12 The process of converting a precipitate into colloidal sol by shaking it with dispersion
medium in the presence of small amount of electrolyte is called peptisation.
73
Topic:- Properties and applications of colloids, Emulsions.
1. How is a colloidal solution purified by dialysis? [2]
2. What is observed when light is passed through a colloidal solution? [1]
3. Define the terms – (a) Brownian movement (b) Electrophoresis? [2]
4. State Hardy- Schulze rule? [1]
5. What is a protective colloid? [1]
6. What is flocculation? [1]
7. Alum is used for purification of water. Why? [1]
8. Give three applications of colloidal solutions? [3]
9. What are the two types of emulsions? [1]
10. How does an emulsifying agent work? Give an example of emulsifying agent. [2]
74
[Answers]
Topic:- Properties and applications of colloids, Emulsions
Ans.1 Dialysis is a process of removing a dissolved substance from a colloidal solution by means
of diffusion through a suitable membrane. A bag of suitable membrane containing the
colloidal solution is suspended in a vessel through which fresh water is continuously
flowing. The molecules and ions diffuse through membrane into outer water and pure
colloidal solution is left behind
Ans 2. When light is passed through a colloidal solution, the path of light gets illuminated and a
bright cone of light is observed due to scattering of light in all direction. This is called
Tyndal effect.
Ans. 3 (a) Brownian movement:-
The continuous zig-zag movement of particles in a colloidal solution is called Brownian

movement.
(b) Electrophoresis:-
The movement of particles under an applied electric potential is called electrophoresis.
Ans.4 According to Hardy- Schulze rule-
The greater the valence of the flocculating ion added, the greater is its power to cause
precipitation.
Ans.5 A lyophillic colloid which is used to protect lyophobic colloid from electrolyte and from
getting coagulated is called protective colloid.
75
Ans.6 When a colloid precipitates and floats on the solvent, it is called flocculation.
Ans. 7 The dirty water contains electrically charged impurities which get coagulated on
adding alum which contains Al3+ ion. These impurities settle down after coagulation
and are then filtered.
Ans.8 Application of colloids-
1. Colloidal antimony is used in curing kalaazar.
2. Paints, synthetic plastics, rubber etc. all are colloidal solutions.
3. Rubber is obtained by coagulation of latex.
Ans.9 The two types of emulsions are-
(a) Oil dispersed in water (o/w type)
(b) Water dispersed in oil (w/o type)
Ans 10. An emulsifying agent is added to emulsions for its stabilization. It forms an interfacial film
between suspended particles and the medium eg. For o/w emulsions, Proteins, gums soaps
etc. can be used an emulsifying agent whereas for w/o long chain alcohols lamp black etc.
can be used.
76
CLASS - XII CHEMISTRY (General principles and processes of isolation of elements)
Topic :- Occurrence of metals, concentration methods
1. Define the term - metallurgy? [1]
2. What is gangue? [1]
3. Give some important ores of Aluminum, Iron, Copper and Zinc? [2]
4. Name the most abundant and second most abundant metal in earth’s crust. [1]
5. What do you understand by benefaction of ore? [1]
6. What is the basis of hydraulic washing? For which type of ores is it used? [2]
7. When is magnetic separation used? [1]
8. Explain froth floatation method. [2]
9. What is the role of a depressant in the floatation process? Give an example? [2]
10. What is used as collectors and froth stabilizers in froth floatation process?
What is their role in the process? [2]
11. What is leaching? Explain with an example. [2]
12. Which reagent is used for leaching of Gold or silver?

Write the equations involved. [2]
77
[Answers]
Topic: - Occurrence of metals, concentration methods
Ans.1 The scientific and technological process used for isolation of the metal from its ores is known
as metallurgy.
Ans. 2 The earthly or undesired materials which contaminate ore are called gangue.
Ans. 3 Metal Ore
Aluminum Bauxite
Iron Hematite, Magnetite
Copper Copper pyrite, Copper glance
Zinc Zinc blende, Calamine
Ans.4 The most abundant metal is Aluminum & second most abundant metal is iron.
Ans.5 Benefaction, concentration or dressing of ore means removal of unwanted materials from
the ore.
Ans.6 Hydraulic washing is based on the differences in the gravities of the ore and the gangue
particles. It is used when ore is heavy and impurities are lighter.
Ans. 7 If either of the ore or gangue is capable of being attracted by a magnetic field e.g. in
case of iron ores, magnetic separation is used for its concentration.
Ans. 8 Froth floatation is used for removing
gangue from sulphide ores. Here a
suspension of the powdered ore is mixed
with water. To it collectors and froth
stabilizer are added. A rotating paddle
agitates the mixture and draws air in it.
As a result froth is formed. The mineral
particles become wet by froth (oil) and gangue particles by water. The froth is skimmed off
and dried for the recovery of ore.
78
Ans.9 Depressant adjusts the proportion of oil and water so as to separate two sulphide ores. e.g. in
case of an ore containing ZnS and PbS, NaCN is used an depressant which selectively
prevents ZnS from coming to the froth.
Ans 10. Pine oil, fatty acids or xanthate can be used as collectors to enhance the non- wettability of
mineral particles whereas cresols or aniline can be used as froth stabilizer to stabilize the
froth in froth floatation process.
Ans 11. Leaching is used if the ore is soluble in suitable solvent. e.g. Aluminum is leached from
bauxite by using a conc. solution of NaOH at 473-523 K and 35-36 bar pressure. Al2O3 is
leached out an sodium aluminates leaving behind impurities-
Al2O3 (S) + 2NaOH(aq)+3H2O  2Na[Al(OH)4 ]
The aluminate solution is centralised by passing CO2 gas & hydrated Al2O3 is precipitated
which is filtered, dried and heated to give pure Al2 O3.
2Na[ Al(OH )4 ] + CO 2  Al2O3.xH2O(s)+2NaHCO3 (aq)
Al 2O3.xH 2O(S ) 1  Al 2O 3(s) + xH 2O (g)

470 K
Ans.12 A dil. Solution of NaCN or KCN in the presence of air is used as reagent for leaching of
silver and gold. The equations are-
4M (s)  8CN  (aq)  2H O(aq)  O (g)  4[M(CN) ] (aq)+4OH (aq)

2 2 2
(Where M= Ag or Au)
2[M (CN )2 ] (aq)  Zn(s)  [Zn(CN ) 4 ]2 (aq)  2M (s)
79
Topic:- Extraction of crude metal from concentrated ore, Thermodynamic principles of

metallurgy
1. Sulphide and carbonate ores are converted to oxide before reduction. Why? [1]
2. What is calcinations and roasting? Give one example of each? [2]
3. What is slag? Give an example. [1]
4. How does a reducing agent helps in reduction? [1]
5. Write the relationship between Gibbs free energy, enthalpy change
and change in entropy? [1]
6. What is the condition for a reduction reaction to occur in terms of free
energy change? How can it be achieved? [2]
7. What are Ellingham diagrams? [1]
8. State one limitation of Ellingham diagrams. [1]
80
[Answers]
Topic:- Extraction of crude metal from concentrated ore, Thermodynamic principles of

metallurgy
Ans 1. Since the reduction of oxide ores involves a decrease in Gibb’s free energy making  G
value more negative, it is easier to reduce oxides therefore suphide and carbonate ores
are converted to oxides before reduction.
Ans 2. Calcination:- It is the process of heating carbonate ore in the absence of air when
volatile matter escape leaving behind metal oxide . e.g.
Zn CO3 (s) 
 ZnO (s) + CO2 (g)
CaCO3 - Mg CO3 
 CaO (s) + MgO (s) + 2CO 2 (g)
Roasting :- Here ore is heated in a regular supply of air at a temperature below the
melting point of metal e.g.
2ZnS + 3O2  2ZnO + 2SO2
2PbS + 3O2  2PbO + 2SO2
Ans 3. Slag is the substance obtained after flux reacts with impurity.
Flux + Impurity Slag.
For example silica is added as flux to remove iron oxide during extraction of copper as
ferrous silicate.
FeO + SiO2  FeSiO3 (slag)
Impurity flux
Ans 4. During the reduction of the metal oxide, the reducing agent combines with oxygen of
metal oxide and gets itself oxidized.
Mx Oy  y C  x M  y CO Here carbon is reducing agent.
81
Ans 5. When  S is entropy change ,  H is enthalpy change , than at temperature T, the
change is Gibbs free energy is given by
 G =  H – T  S.
Ans 6. When the value of  G is negative , the reduction reaction is said to be spontaneous
1) It  S is positive , on increasing the temperature, the value of T  S would increase
&  G will become negative.
2) For a process which is otherwise having  G positive & is non- spontaneous, , it can
be coupled with a reaction having highly negative  G value so that the overall  G
is negative and the process can take place.
Ans.7. Ellingham diagrams are graphical representation of variation of  G vs T for the

formation of oxides of elements i.e., for the reaction
2xM (S )  O2 (g)  2MxO(gs)
Ans.8 Ellingham diagrams only tell us about the feasibility of a reaction. They do not tell
anything about the reaction kinetics.
82
Topic:- Extraction of iron, copper and Aluminum
1. What is pig iron? [1]
2. What is cast iron? [1]
3. What is wrought iron? [1]
4. What is added as flux in extraction of iron? [1]
5. Explain the extraction of copper? [2]
6. What is Blister copper? [1]
7. Write the equation for reduction of zinc oxide? [1]
8. What is the basis of reduction of a molten metal salt? Explain [2]
9. Why is cryolite used during extraction of Aluminum? [1]
10. How is copper extracted from low grade ores? [1]
83
[Answers]
Topic:- Extraction of iron, copper and Aluminum
Ans 1. The iron which is obtained from blast furnace and contains about 4% carbon and
many other impurities in smaller amounts like S, P, Si, Mn etc, is called pig iron.
Ans 2. Iron obtained by melting pig iron with scrap iron and coke using hot air blast is cast
iron.
Ans 3. Wrought iron and malleable iron is the purest form of commercial iron which is
prepared from cast iron by oxidizing impurities in a reverberatory furnace lined
with heamatite.
Ans 4. Limestone is used as flux in extraction of iron.
Ans 5. The sulphide ores of copper are roasted to give oxides:
2Cu2 S  3O2  2Cu2O + 2SO2
The oxide can then be easily reduced to metallic copper using coke.
Cu2O  C  2Cu+CO
The impurities like iron oxide are removed as slag by reacting with SiO2, added as
flux.
FeO  SiO2  FeSiO3
Ans 6. The solidified copper obtained after extraction has blistered appearance due to
evolution of SO2 is called blister copper.
The reduction of zinc-oxide is done using coke. ZnO  C    Zn+ CO

COKE ,673 K
Ans.7.
Ans.8 In the reduction of molten metal salt, electrolysis is done which is based on
electrochemical principles following equation G  nFE0
Here n is the number of electrons and E0 is the electrode potential of redox couple.
More reactive metals have large negative values of the electrode potential and are
difficult to reduce.
Ans.9 Cryolite is used to lower the melting point of alumina and increase conductivity.
Ans10. Copper is extracted by hydrometallurgy from low grade ores. It is leached out using
acid or bacteria.
84
Topic:- Oxidation –Reduction; Refining.
1. Give an example of extraction based on oxidation reduction. [1]
2. How are gold and silver extracted? [2]
3. Give two examples of metal refined by [3]

a) Distillation
b) Liquation
c) Electrolytic refining
4. Explain electrolytic refining of copper. [2]
5. Which method is used for refining of silicon or gallium? [1]
6. What is the principle behind zone refining? [1]
7. Give the requirements for vapour phase refining? [2]
8. Write a short note on Mond’s process. [2]
9. Which method is used for refining of zirconium? Explain. [2]
10. What is the principle behind chromatography?

Name some types of chromatographic techniques. [2]
85
[Answers]
Topic:- Oxidation –Reduction; Refining
Ans 1. An example based on extraction by oxidation is extraction of chlorine from brine.
Ans 2. Gold and silver are extracted by leaching the metal with CN-. The metal is later
recovered by displacement method in which zinc acts as reducing agent.
4 Au(s)  8CN   2H O(aq)  O (g)  4[Au(CN) ] (aq)+4OH (aq)
2 2 2
2[ Au(CN )2 ]  Zn(s)  2 Au(s) [Zn(CN )4 ]2


Ans 3. a) Distillation – Zinc and Mercury
b) Liquation – Tin and Antimony
c) Electrolytic refining – Copper and Zinc
Ans 4. Electrolytic refining of copper-
In this method impure copper acts as anode and a strip of the same metal in the pure
form is used as cathode. The electrolyte is acidified solution of copper sulphate. The
net result is the transfer of copper in pure form from the anode to cathode.
Anode : Cu  Cu2+ + 2e-

Cathode : Cu 2+ + 2e-  Cu
Impurities from the blister copper like antimony, selenium, tellurium, silver, gold and
platinum deposit as anode mud.
Ans 5. The refining of Silicon or gallium is done by Zone refining.
Ans 6. The principle of zone refining is that impurities are more soluble in the melt then in
the solid state of the metal.
86
Ans.7. The two requirements of vapour phase refining are :-
1) The metal should from a volatile compound with an available reagent,
2) The volatile compound should be easily decomposable so that recovery is easy.
Ans.8 Mond’s Process-
In this process, nickel is heated in a stream of carbon monoxide to give a volatile

complex, nickel tetra carbonyl.
Ni  4CO   [Ni(CO) ]
330 K
350 K 4
The carbonyl is heated to higher temperature
[Ni(CO) 4 ] 4   Ni+4CO

50 470 K
Ans.9 Zirconium and Titanium are refined by van Ankle process, Here the crude metal is
heated in an evacuated vessel with iodine.
Zr  2I2  Zr I4
The metal iodide is decomposed on a tungsten filament, electrically heated to about

1800K and pure metal is deposited on the filament.
ZrI4  Zr +2I2
Ans10. The principle behind chromatography is that different components of a mixture are
differently adsorbed on an adsorbent. Some of the chromatographic techniques are
paper chromatography, column chromatography, gas chromatography etc.
87
CLASS - XII CHEMISTRY (P – block elements)
Topic:- 15th Group elements : Atomic properties , Oxidation states.
1. Write the elements of group 15? [1]
2. Write chemical name & formulae of

a) Chile saltpetre
b) Indian saltpetre [1]
3. What is special about the valence configuration of Group 15? [1]
4. The atomic radii increases considerably from N to P but very little increase is
observed from As to Bi. why? [1]
5. Give reason for the following- the first ionization enthalpy of 15th group
elements is higher than 16th group elements ? [1]
6. How does metallic character vary down the 15 group & why? [1]
7. What are the common oxidation states of this group? [1]
8. What is the maximum covalence shown by N? [1]
9. Bi (v) is a stronger oxidizing agent than Bi(III). Why? [1]
10. Give an example showing disproportionation of oxidation state of nitrogen? [1]
88
[Answers]
Topic:- 15th Group elements : Atomic properties ,
Oxidation states.
Ans.1 The elements of group 15 are

Nitrogen (N), Phosphorous (P) , Arsenic (As) , Antimony (Sb) and Bismuth (Bi).
Ans 2. (a) Chile saltpetre – Sodiumritrate – NaNO3
(b) Indian saltpetre – Potasium nitrate – KNO3
Ans 3. The valence configuration of 15 group is ns2np3 the s-orbital is completely filled and p-
orbital is half filled . This half filled orbital gives extra stability to elements of this
group.
Ans 4. There is a considerable increase in size from N to P as expected but due to the
presence of completely filled d- orbitals which have very poor shielding effects, the
increases in size is very little from As to Bi.
Ans 5. Due to extra stability of half filled configuration, the first Ionisation enthalpy of 15 th
group elements is higher than 16th group configuration ns2np4)
Ans 6. The metallic character increases down the group due to decrease in ionization
enthalpy and increase in size of atom.
Ans 7. The common oxidation states of the group are-
-3 , +3 & +5.
Ans 8. Nitrogen shows a maximum covalence of +4 because only four orbitals, one S and three
P- orbitals are available for bonding in Nitrogen.
Ans 9. Bi is more stable in +3 oxidation state in comparison to +5 due to inert pair effect
therefore Bi (v) has a strong tendency to act as oxidizing agent.
Ans 10. 3HNO2 HNO3 + H2O + 2NO

+3 +5 +2
Here Nitrogen is getting oxidized to a higher oxidation state as well as reduced to a
lower oxidation state.
89
Topic:- Group 15 elements : Chemical Properties, Dinitrogen
1. Give reasons for the following? [1X5=5]
(a) Nitrogen does not show catenation.
(b) PCl5 exists but NCl5 does not.
(c) The stability of Hydrides follows the order-
NH3  PH3  Ar5 H3  SbH3
(d) PH3 is a weaker base than NH3.
(e) Molecular nitrogen is chemically inert.
2. Complete and balance- [1x5=5]
(a) NH 4Cl(aq)  NaNO2 (aq) 


(b) Ba(N3 )2 

(c) 3Mg  N2 

(d) N2  O2  H 
eat


(e) 2NaN3 

3. What are the two isotopes of nitrogen? [1]
4. Write two uses of dinitrogen. [2]
90
[Answers]
Topic:- Group 15 elements : Chemical Properties,
Dinitrogen
Ans.1 (a) Nitrogen being small in size has high electron density. Due to strong inter electronic
repulsions, N-N single bond is weak & nitrogen does not undergo catenation.
(b) Due to absence of d-orbitals, nitrogen cannot expand its oxidation state to +5 and
NCl5 does not exist whereas in P due to presence of empty 3d orbital +5 oxidation
state is attained.
(c) As we move down the group 15, atomic radii increases making the bond of element
with Hydrogen weaker this decreases the stability of hydrides of heavier elements.
Therefore the order of stability is.
NH3  PH3  AsH3  SbH3
(d) As Phosphorous atom is larger than N- atom, the lone pair of electrons is distributed
over a large surface area of P-atom than N-atom. Therefore the tendency of P to
donate the lone pair of electrons is less.
(e) Molecular nitrogen (N2) is inert because N  N bond energy is very high due to
small size of N- atom and presence of multiple bond.
Ans 2. a. NH4 Cl(aq)  NaNO2 (aq)  N2 (g)  2H2 O(ℓ)  NaCl(aq)

b. Ba(N3 )2  Ba + 3N2
c. 3Mg  N2  Mg3 N 2
d. N 2  O2 H 
eat
 2NO(g)
e. 2NaN3  2Na+3N2
Ans 3. The two isotopes of nitrogen are 14 N and 15 N .

Ans 4. Dinitrogen is used
(a) In the manufacture of ammonia.
(b) As a refrigerant to preserve biological material, food items.
(c) In cryosurgery.
91
Topic:- 15th Group elements : Ammonia , Nitric acid , phosphorous – allotropes ,

phosphine.
1. Complete and balance - 1 10=10

(i) (NH4)2SO4+ 2NaOH 
(ii) 2FeCl3 (aq) +3NH4OH (aq) 
(iii) AgCl(s) + 2NH3(aq) 
(iv) NaNO3 + H2SO4 
(v) 3NO2 (g) + H2O(l) 
(vi) Cu + 4HNO3(conc) 
(vii) 4Zn+ 10HNO3(dil) 
(viii) [Fe(H2O)6]2 + + NO 
(ix) I2 + 10HNO3 
(x) S8 + 48HNO3(conc) 
2. What are the optimum conditions for maximum yield of ammonia?

[1]
3. Ammonia is a Lewis base. Why? [1]
4. Ammonia has higher boiling and melting points than expected .Why? [1]
5. Explain the chemistry behind brown ring test for detection of nitrate ions. [2]
6. Write three differences between white and red phosphorous. [3]
92
[ANSWER]
Topic:- 15th Group elements : Ammonia , Nitric acid , phosphorous – allotropes ,

phosphine.
Ans 1. (i) (NH4)2SO4+ 2NaOH  2NH3 + 2H2O + Na2SO4

(ii) 2FeCl3 (aq) +3NH4OH (aq)  Fe2O3. xH2O(s) + 3NH4Cl (aq)
(iii) AgCl(s) + 2NH3(aq)  [Ag(NH3)2]Cl (aq)
(iv) NaNO3 + H2SO4  NaHSO4+HNO3
(v) 3NO2 (g) + H2O(l)  2HNO3(aq) + NO(g)
(vi) Cu + 4HNO3(conc)  Cu (NO3)2+2NO2 +2H2O
(vii) 4Zn+ 10HNO3(dil)  4Zn(NO3)2 +5H2O + N2O
(viii) [Fe(H2O)6]2+ + NO  [Fe (H2O)5 (NO)]2+ + H2O
(ix) I2 + 10HNO3  2HIO3 + 10NO2 + 4H2O
(x) S8 + 48HNO3(conc)  8H2SO4 +48NO2 + 16H2O
Ans 2. The optimum conditions for the production of ammonia are-
200  105 Pa or 200 atm pressure, 700K temperature , and presence of catalyst such as
iron oxide with K2O and Al2O3 as promoters.
Ans 3. Due to the presence of lone pairs on nitrogen atom of ammonia, it can donate electron
pair and acts as a lewis base.
Ans 4. In solid and liquid states, ammonia molecules are associated by intermolecular
hydrogen bonding. There fore ammonia has higher boiling and melting points.
Ans 5. The brown ring test for nitrate ions depends on the ability of Fe2+ to reduce nitrates to
nitric oxide, which reacts with Fe2+ to form a brown coloured complex.
NO3- + 3Fe2+ + 4H+  NO + 3Fe3+ + 2H2O
[Fe (H2O)6]2+ +NO  [Fe(H2O)5NO]2+ + H2O
Ans 6. White phosphorous Red phosphorous

1. It is translucent waxy solid 1. It has iron grey Lustre.
2. It is poisonous and glows in dark 2. It is non poisonous and does not glow in
dark.
3. It is less stable and more reactive. 3. It is more stable and less reactive.
93
Topic:- 15th Group : phosphorous halides, oxoacids of 15 group elements, structures.
1. Complete and Balance-
a) P4 + 8SOCl2 
b) 3CH3COOH + PCl3 
c) P4 + 10SO2 Cl2 
d) POCl3 + 3H2O 
e) Sn + PCl5 
f) 4AgNO3 + 2H2O + H3PO2 




2. All five bonds in PCl5 are not equal. Give an equation in support of this statement.
3. Draw the structure of following :-
(i) NO
(ii) N2O4
(iii) HNO3
(iv) PCl5
(v) (H3PO3)3
(vi) H3 PO2
(vii) H3PO3
94
[ANSWER]
Topic:- 15th Group : phosphorous halides, oxoacids of 15 group elements, structures.
Ans. 1. Complete and Balance-

a) P4 + 8SOCl2  4PCl3 + 4SO2 + 2S2Cl2
b) 3CH3COOH + PCl3  3CH3COCl + H3PO3
c) P4 + 10SO2 Cl2  4PCl5 + 10SO2
d) POCl3 + 3H2O  H3PO4 + 3HCl
e) Sn + PCl5 SnCl 4 + 2 PCl3
f) 4AgNO3 + 2H2O + H3PO2  4Ag + 4HNO3 + H3PO4
Ans 2. When heated , PCl5 loses a chlorine molecule this shows that two P- CL bonds are
weaker and hence longer than others.
PCl5 H 
eat
 PCl3 + Cl2
Ans 3. (i)
= = 



(ii)
95
(iii)
(iv)
(v)
(vi) (vii)
96
Topic:- Group 16: general properties , Dioxygen , oxides.
1. Write the members of 16 Group. [1]

2. Give the general electronic configuration of 16 Group. [1]
3. Give reasons :- [5]
(a) Oxygen molecule is diatomic where as sulphur molecule is polyatomic.
(b) The most common oxidation state of oxygen is -2.
(c) H2O is liquid whereas H2S is gas at room temperature.
(d) The increasing order of acidic character in 16 th group hydrides is H2O< H2Se<H2Te.
(e) SF6 is exceptionally stable, SH6 does not exist.
4. Discuss the geometry of SF4. [2]
5. Complete and balance-
(a) 2 Ag2O(s) 
(b) 2H2O2 (aq) 
(c ) 2Zns  3O2 
(d) 4HCl  O2 C 

ucl2

(e) Al2O3 (s)  6HCl(aq)  9H2O(l) 
(f) Al2O3 (s)  6NaOH (aq)  3H2O(l) 
6. Discuss the different types of oxides. [2]

7. Enlist some uses of dioxygen. [2]
8. Write different isotopes of oxygen. [1]
97
[ANSWERS]
Topic:- Group 16: general properties , Dioxygen, oxides..
Ans. 1. The elements of group 16 are.

Oxygen(O), Sulphur (S), Selenium (Se), Tellurium (Te) and Polonium (Po)
Ans 2. The general electronic configuration of 16 group is ns2np4.
Ans 3. (a) Oxygen being small in size forms effective and strong P  -P  bonds with other
oxygen atom. Therefore oxygen molecule is diatomic and discrete whereas
Sulphur due to its larger size, its orbitals cannot overlap effectively to form
P  -P  bonds & completes valency by forming  bonds with many sulphur
atom. Therefore sulphur molecule is polyatomic solid.
(b) Since oxygen is highly electronegative, it has little tendency to give electrons.
Therefore its most common oxidation state is -2.
(c) H2O is liquid at room temperature due to presence of intermolecular Hydrogen

bonding which is absent in H2S.
(d) As we move down the group, the size of atom increases this make the bond of
the element with hydrogen weak. Due to weaker bonds, the bond dissociation
enthalpy decreases making the molecule more acidic. Therefore the order of
acidic strength is.
H2O < H2S < H2Se < H2Te
(e) SF6 is exceptionally stable due to steric reasons. Hydrogen being

electropositive or less electronegative than fluorine cannot make the s-
electrons of sulphur to participate in bonding. Therefore SH6 does not exist.
F
Ans 4. In SF4 the hybridisation of sulphur is F

sp3d. The structure is trigonal bi-pyramidal
in which one of the equatorial positions is
S :
occupied by a one pair of electrons. The
geometry is called see-saw geometry.
F
98
Ans 5. (a) 2 Ag2O(s)  4 Ag(s)  O2 (g)
(b) 2H2O2 (aq)  2H2 O(l)  O2 (g)
(c ) 2Zns  3O2  2ZnO  2SO2
(d) 4 HCl  O 2 C   2Cl +2H O

uCl2
2 2
(e) Al O (s)  6HCl(aq)  9H O(l)  2[Al(H O) ]3+ (aq)+6Cl-

2 3 2 2 6
(f) Al2O3 (s)  6NaOH (aq)  3H2O(l)  2Na3[Al(OH)6 ](aq)
Ans 6. A binary compound of oxygen with another element is called oxide. Oxides can be
simple or mixed . Simple oxides can be classified as acidic, basic Amphoteric or
neutral.
An oxide that combines with water to give an acid is termed acidic oxide e.g. CO 2, SO2
etc.
An oxide that combines with water to give a base is called basic oxide e.g. Na 2O, CaO,
BaO etc.
An oxide that shows characteristics of both acids and bases is Amphoteric oxide e.g.
Al2O3 .
An oxide that shows characteristic of neither acid nor base is called neutral oxide e.g.
CO, NO and N2O.
Ans.7 Oxygen is used-

(a) In oxyacetylene welding.
(b) In manufacture of steel.
(c) In hospitals and mountaineering as oxygen cylinders.
Ans.8 The isotopes of oxygen are 16O, 17

O, 18 O .
99
Topic:- Ozone,Sulphur, Sulphur dioxide & oxoacids, Sulphuric acid.
1. Write the characteristics of pure Ozone? [1]
2. At what concentration ozone is harmful? [1]
3. Draw the resonating structures of ozone? [1]
4. Explain the oxidizing action of ozone? [1]
5. How is ozone estimated quantitatively? [1]
6. Complete and balance:- [6x1=6]
(i) PbS (s) + 4O3(g) 
(ii) NO(g) + O3(g) 
(iii) 4FeS2 (s) + 11O2(g) 
(iv) 2NaOH + SO2 
(v) 2Fe3+ + SO2 + 2H2O 
(vi) Cu + 2H2SO4 (conc) 
7. Give a test to detect the presence of SO2 gas? [2]
8. Give the structures of
(i) sulphurous acid and
(ii) Peroxodisulphurous acid? [1]
9. Write the various steps for preparation of sulphuric acid by contact process?
[2]
10. Name different sulphates formed by sulphuric acid? [1]
100
[ANSWER]
Topic:- Ozone,Sulphur, Sulphur dioxide & oxoacids, Sulphuric acid.
Ans. 1 Pure ozone is pale blue gas, dark blue liquid and violet black solid.
Ans. 2 If the concentration of ozone increases above 100 ppm, breathing becomes
uncomfortable resulting in headache and nausea and it becomes harmful.
Ans. 3
Ans. 4 Ozone has a very strong tendency to liberate nascent oxygen according to the
equation:-
O3 O2 + O
Therefore it acts as a strong oxidizing agent.
Ans. 5 When ozone reacts with an excess of potassium iodide solution buffered with a
borate buffer (PH = 9.2) iodine is liberated. This iodine can be titrated against a
standard solution of sodium thiosulphate to estimate the amount of ozone.
2I – (aq) + H2O + O3  2OH- (aq) + I2(s) + O2(g)
Ans. 6 (i) PbS (s) + 4O3(g) PbSO 4(s) + 4O2(g)

(ii) NO(g) + O3(g)  NO2(g) + O2(g)
(iii) 4FeS2 (s) + 11O2(g)  2Fe2O3(s) + 8SO2(g)
(iv) 2NaOH + SO2 Na2SO3 +H2O
(v) 2Fe3+ + SO2 + 2H2O  2Fe2+ +SO42- + 4H+
(vi) Cu + 2H2SO4 (conc)  CuSO4 + SO2 + 2H2O.
101
Ans. 7 When SO2 (g) is passed through a violet coloured acidified potassium
permanganate solution , it gets decolourised.
5SO2 + 2MnO4- + 2H2O  5SO42- + 4H+ + 2Mn2+
Ans. 8 (i) Sulphurous acid
(ii) Peroxodisulphuric acid
Ans. 9 Contact process for sulphuric acid:-

Step 1: Burning of sulphur in air to give SO2.
S + O2 SO2
Step 2: Conversion of SO2 to SO3 by reacting it with oxygen in presence of V2O5.
2SO2 + O2 V 
2O5
 2SO 3
Step 3: Absorption of SO3 in H2SO4 to give of oleum (H2S2O7)
SO3 + H2SO4  H2S2O7 (oleum)
Step 4: Dilution of oleum with water to get H2SO4 of desired concentration
H2S2O7 +H2O  2H2SO4
Ans. 10 The two type of sulphates are –

i) Normal sulphate eg. Na2SO4 , CuSO4
ii) acid sulphate eg. NaHSO4.
102
Topic:- Group 17
1. Give reasons- 6x1=6
a) Halogens have smallest atomic radii in their periods
b) The negative election gain enthalpy of fluorine is less than that of chlorine.
c) All halogens are coloured.
d) The only possible oxidation state of fluorine -1.
e) Fluorine forms only one oxoacid.
f) The stability of hydrides follows the order HF>HCl>HBr>HI.
2. Complete and balance- 5x1=5
(i) 2F2(g) + 2H2O (l) 
(ii) 4NaCl + MnO2 + 4H2SO4 



(iii) 4HCl + O2  C 
uCl 2


(iv) C10H16 + 8Cl2 
(v) 6NaOH + 3Cl2 




3. Chlorine water on standing loses its yellow colour. Why? [1]
4. Explain the bleaching action of chlorine? [1]
5. Write two uses of chlorine? [2]
103
[ANSWER]
Topic:- Group 17
Ans. 1(a) Due to maximum effective nuclear charge, halogens have smallest atomic radii.
(b) Due to small size of fluorine atom, there are strong inter electronic repulsions in
the small 2p orbital of fluorine and thus incoming electron does not experience
much attraction and fluorine has less negative electron gain enthalpy than that of
chlorine.
(c) Halogens absorb radiation in visible region which results in oxidation of electrons
to higher energy level by absorbing different quanta of radiation, they show
different colours.
(d) Since fluorine is most electronegative element and is short of only one electron for
completing octet, it shows the only oxidation state of -1.
(e) Due to small size and high electro-negativity , Fluorine forms only one hypohalous
acid.
(f) As the size of element increases down the group, the bond dissociation enthalpy for
HX bond decreases making the bond weaker and weaker therefore the order of
thermal stability is HI < HBr < HCl < HF.
Ans 2. (i) 2F2(g) + 2H2O (l)  4H+(aq) + 4F- + O2 (g)

(ii) 4NaCl + MnO2 + 4H2SO4  MnCl2 + 4NaHSO4 + 2H2O + Cl2
(iii) 4HCl + O 2 C 

uCl2
 2Cl2 + 2H2O
(iv) C10H16 + 8Cl2  16HCl + 10C
(v) 6NaOH + 3Cl2  5NaCl + NaClO3 + 3H2O
Ans. 3 On standing chlorine water forms HCl and Hypochlorous acid (HOCl) due to which
it loses its colour. Cl2 + H2O  HCl + HOCl
Ans. 4 The bleaching action of chlorine is due to its tendency to give nascent oxygen so
that the substance gets oxidixed. Cl2 + H2O  2HCl + [O]
Coloured substances + [O]  colourless substance.
Ans. 5 Culorine is used for
a) Bleaching wood pulp, cotton and textiles
b) Manufacturing dyes, drugs, refrigerants etc.
c) Sterilizing drinking water.
104
Topic:- Hydrochloric acid, Interhalogen compounds, Group 18.
1. Complete and balance 1x10=10
a. NaHSO4 + NaCl  8
23 k

b. Au + NO3- + 4H+ +4Cl- 
c. Na2 CO3 + 2HCl 
d. Na2SO3 + 2HCl 

e. Cl2 + 3F2  5
73 k

f. Br2 + 5F2 
g. XeF4+ O2F2 
h. XeF2 + PF5 
i. XeF6 + 3H2O 
j. XeF6 + 2H2O 


2. Draw the structures of following: 1x6=6
(i) HOClO (ii) HClO4 (iii) BrF3 (iv) XeO3
(v) XeF4 (vi) XeF2
3. What are interhalogen compounds? Why are they more reactive than halogens? [2]
4. Noble gases have very low melting and boiling points. Why? [1]
5. Name a gas used [2]
a) In gas – cooled nuclear reactors
b) In fluorescent bulbs
c) For filling electrical bulbs
d) As cryogenic agent.
105
[ANSWER]
Topic:- Hydrochloric acid, Interhalogen compounds, Group 18.
Ans. 1 a. NaHSO4 + NaCl 8

23k
 Na2SO4 + HCl
b. Au + NO3- + 4H+ + 4Cl -  AuCl-4 + NO + 2H2O
c. Na2 CO3 + 2HCl  2NaCl + H2O + CO2
d. Na2SO3 + 2HCl  2NaCl + H2O + SO2
e. Cl2 + 3F2 5
73k
 2ClF3
f. Br2 + 5F2  2Br F5
g. XeF4+ O2F2  XeF6 + O2
h. XeF2 + PF5  [XeF] + [PF6]-
i. XeF6 + 3H2O  XeO3 + 6HF
j. XeF6 + 2H2O  XeO2F2 + 4HF.
Ans. 2 i) HOClO
ii) HClO4
106
v) XeF4
iii) BrF3
iv) XeO3
vi) XeF2
Ans. 3 When two different halogens react with each other, inter-halogen compounds are
formed e.g.
Cl2 + F2 4
37 k
 2ClF
They are more reactive than halogens due weak bond between different halogens and
high electronic repulsion.
Ans. 4 In noble gases, the only types of inter-atomic forces are weak dispersion forces which
results in very low melting and boiling points.
Ans. 5
(a) Helium (c) Argon
(b) Neon (d) Helium.
107
CLASS - XII CHEMISTRY (The d– & f- block elements)
Topic:- General properties of transition metals.
1. Zinc, cadmium and mercury are not considered as transition metals. Why? [1]
2. Write the general configuration of d- block elements. [1]
3. Give reasons- [5]
(i) Transition metals have high melting points.
(ii) Second and third transition series have similar radii.
(iii) Second ionization is difficult from Cu and Cr whereas it is easy for Zn.
(iv) Most of the transition elements are paramagnetic.
(v) Transition elements form alloys.
4. What are the factors that decide the ionization potential? [1]
5. Transition metals generally form coloured ions. Why? [2]
Which of the following will be colored? [2]
Sc3+, V2+, Mn2+ , Cu+, Ni2+.
6. Give an explanation for the catalytic properties shown by transition metals. [2]
7. Write some characteristics of interstitial compounds. [2]
108
[ANSWER]
Topic:- General properties of transition metals.
Ans. 1. Zinc, cadmium and mercury have fully filled d10 configuration. Therefore they are
not considered as transition metal.
Ans 2. General electronic configuration of d- block elements is (n-1)d1-10 ns 1-2.
Ans 3. (i) In transition metals besides ns electrons, (n-1)d electrons can also participate
in bonding making stronger metallic bonds. This increases their melting points.
(ii) Due to lanthanoid contraction, there is a decrease in size of 5d series. This

makes their sizes same as sizes of elements of 4d series.
(iii) In Cr the electronic configuration is 3d5 4s1 and for Cu, it is 3d10 4s1. In these
after first ionization, which removes the electron from 4s , second ionization
requires disturbance in half filled or fully filled configuration which requires
high enthalpy whereas the configuration of Zn is 3d104s2. Here after second
ionization, the configuration of Zn is completely filled. Therefore second
ionization is easier for Zn but difficult for Cr and Cu.
(iv) Para magnetism in transition elements arises due to presence of one or more
unpaired electrons in atomic orbitals.
(v) Due to similarity in their sizes, transition metals can take each others position
in their crystal lattice. Therefore they are able to form alloys.
Ans 4. The ionization potential values are governed by various ionization enthalpy
values, bond enthalpy values and hydration enthalpy values.
109
Ans 5. Transition metals form coloured ions due to d-d transition. Coloured ions will be
those which have unpaired electrons
Sc3+ 3d0 Colourless

V2+ 3d3 Coloured
Mn2+ 3d5 Coloured
Cu+ 3d10 Colourless
Ni2+ 3d8 Coloured.
Ans 6. Catalytic properties shown by transition metals can be explained due to

(i) Presence of variable valency and ability of elements to form complexes.
(ii) Surface of metals where the reaction can occur.
Ans 7. Some characteristics of interstitial compounds are

(i) They have high melting points.
(ii) They are very hard.
(iii) They retain metallic lusture.
(iv) They are chemically inert.
110
Topic:- potassium dichromate , potassium permanganate.
1. What is the ore of K2Cr2O7 and KMnO4 ? [1]
2. Explain the steps of preparation of potassium dichromate? [3]
3. What is the effect of adding a base to potassium dichromate? [1]
4. Draw the structure of chromate and dichromate ions? [2]
5. Describe the steps of preparation of KMnO4? [2]
6. Give some of the uses of KMnO4? [2]
7. Draw the structure of manganate and permanganate ions? [2]
8. Complete and balance:- [6  1=6]
1. 5Fe2+ + MnO4- + 8H+ 
2. 5NO2- + 2MnO4- +6H+ 
3. 2MnO4- +H2O + I- 
4. 8MnO4- +3S2O8 2- +H2O 
5. Cr2O72 + 14H+ + 6Fe2+ 
6. Cr2O72- + Sn2+ + 14H+ 
















111
[ANSWER]
Topic:- potassium dichromate , potassium permanganate
Ans. 1 Potassium dichromate  chromite ore (FeCr2O4) Potassium Permanganate MnO 2

pyrolusite.
Ans. 2 Preparation of potassium dichromate takes place in three steps.
Step 1 : Fusion of chromite ore with sodium or potassium carbonate in free

excess of air.
4FeCr2O4  8Na2CO3  7O2  8Na2CrO4  2Fe2O3  8CO2
Step 2 : Conversion of Sodium Chromate to Sodium Dichromate by acidifying it.

2Na CrO  2H   Na Cr O +H O + 2Na +
2 4 2 2 7 2
Step 3: Conversion of sodium dichromate to potassium dichromate by reaching

it with KCl.
Na2Cr2O7  KCl  K2Cr2O7  NaCl
Ans.3 When a base is added to orange coloured potassium dichromate its colour changes
to yellow due to formation of potassium chromate.
Cr2O7 2  2OH   2CrO 42  H O
2
Ans.4
112
Ans 5. Potassium Permanganate is prepared in two steps:
Step 1: Fusion of MnO2 with KOH and oxidizing agent to give dark green K2MnO4.
2MnO2  4KOH  O2  2K2 MnO4  2H2O
Step 2: Disproportionation of manganate ions to give permanganate ions.

3MnO 2  4H   2MnO   MnO  2H O
4 4 2 2
Ans6. Uses of potassium permanganate –

(a) As an oxidizing agent.
(b) For bleaching of wool, cotton & silk.
(c) For decolourisation of oils.
Ans.7
Ans 8 1. 5Fe2+ + MnO4- + 8H+  Mn2+ +4H2O + 5Fe3+

2. 5NO2- + 2MnO4- +6H+  2Mn2+ +5NO3- +3H2O
3. 2MnO4- +H2O + I-  2MnO2 +2OH- +IO3-
4. 8MnO4- +3S2O3 2- +H2O  8MnO2 + 6SO42- +2OH-
5. Cr2O72 + 14H+ + 6Fe2+  2Cr3+ + 6Fe3+ + 7H2O
6. Cr2O72- + Sn2 + 14H+ Sn4+ + 2Cr3+ +7H2O
113
Topic:- f-block elements: Lanthanoids and Actinoids.
1. Name the two series of f-block. [1]
2. The chemistry of actionoids is more complicated than lanthanoids. Why? [1]
3. What is the general valance configuration of f-block elements? [1]
4. What is the lanthanoid contraction? What are its causes and consequences? [3]
5. What is the most common oxidation state of lanthanoids and actionoids? [1]
6. Actionoid contraction is more than lanthanoid contraction. Give reason. [1]
7. What is the composition of mischmetall? Give its one use. [2]
8. Actionoids show larger number of oxidation states than lanthanoids. Why? [1]
9. What happens when [2]

(a) A lanthonoid reacts with dil- acid
(b) A lanthonoid reacts with water.
114
[ANSWER]
Topic:- f-block elements: Lanthanoids and Actinoids.
Ans. 1 The two series are-

i) 4f series or Lanthanoids ii) 5f series or actinoids.
Ans. 2 The complications in the actinoid series is due to

i) Existence of a wide range of oxidation states. ii) Their radioactivity.
Ans. 3 The general electronic configuration of f-block elements is (n-2) f 1-14 (n-1) d 0-1 ns2
Ans. 4 Lanthanoid contractions – The cumulative effect of the regular decrease in size or
radii of Lanthanoid with increase in atomic number is called Lanthanoid
contraction.
Causes - The shape of f orbitals is diffused. They have poor shielding effect due to
which the effective nuclear charge increase with increase in atomic number. This
causes a decrease in atomic radii
Consequences – Due to Lanthanoid contraction-
1. Radii of the members of the third transition series is similar to those of second
transition series.
2. It becomes difficult to separate Lanthanoids.
Ans. 5 The common oxidation states of

(1) 4f series is +3 (2) 5f series is +3, +4, +5, +6 & +7
Ans. 6 The actinoid contraction is more than Lanthanoid contraction as the shielding
Power of 5f orbitals is poorer than 4f orbitals.
Ans. 7 Mischmetall is an alloy of a Lanthanoid metal and iron and traces of S, C, Ca &
Al. It is used in Magnesium based alloy to produce bullets, shell and lighter Flint.
Ans. 8 Actinoids can show many oxidation states as in actinoids 5f orbitals are filled
which are not as buried as Lanthnoids and can also participate in bonding to a
greater extent besides 6d and 7s electrons.
Ans. 9 (i) When a Lanthanoid reacts with dil- acid, it liberate hydrogen gas.
Ln + dil.HCl  Ln Cl3 + H2
(ii) When a Lanthanoid reacts with water, it forms hydroxide.
Ln + H2O  Ln (OH)3 +H2
115
CLASS - XII CHEMISTRY (coordination compounds)
Topic:- Werner’s theory, some definitions
1. What are complex compounds? [1]
2. Give some examples of coordination compounds. [1]
3. What were the two valences given by Werner for coordination compounds? [1]
4. Enlist the common shapes of Werner’s complexes. [1]
5. What is the difference between a double salt and a complex?
Explain with an example. [2]
6. What are ligands? Explain different types of ligands. [3]
7. What do you understand by the term coordination number? [1]
8. What are the different shapes or coordination polyhedra in the complexes? [2]
9. Define oxidation state of a metal. [1]
10. Distinguish between homoleptic and hetroleptic ligands. [1]
116
[ANSWER]
Topic:- Werner’s theory, come definitions
Ans.1 Complex compounds or coordination compounds are those compounds in which the
metal atoms are bound to a number of anions or neutral molecules.
Ans.2 Examples of coordination compounds are chlorophyll, haemoglobin and vitamin B 12.
Ans.3 Werner gave the concept of two valences-
a) Primary or ionisable valences.
b) Secondary or non ionisable valences.
Ans.4 The common shapes given by Werner were – octahedeal, tetrahedral and square planar.
Ans.5 Double salts dissociate completely into simple ions when dissolved in water e.g., Mohr
salt, FeSO4 (NH4)2 SO4, 6H2O will dissolve in water and give ferrous, ammonium and
sulphate ions. On the other hand, the complex ions do not completely dissociate into all
constituent ions e.g. K4 [Fe(CN)6] will dissociate to give potassium ions and [Fe(CN) 6]4-
ions only.
Ans.6 The ions or molecules bound to central atom or ion in the coordination entity are ligands
e.g [Fe(CN)6]4- has six CN- ligands.
Types:-
(1) On the basis of charges on them ligands con be negative (e.g. Cl-, OH-, CN- etc.),
positive (e.g. H3O+, NH4+ etc.) or neutral (e.g. CO, NH3, H2O).
(2) On the basis of their donor atoms ligands can be monodentate or unidentate (one
donor atom) e.g- H2O, NH3, Cl- etc, or didentate (two donor atoms) H2N CH2 CH2
2- 4-
NH2 or C2O4 etc. or polydentate (several donor atoms) e.g [EDTA] is a
hexadentate ligand.
117
(3) Ligands which can ligate through two different atoms are called ambidentate ligands
eg. NO2- and SCN- ions. Whereas when a di- or polydentate ligand uses its two or
more donor atoms to bind a single metal ion, it is called chelate ligand.
Ans7. The total number of ligand donor atoms to which a metal is directly bonded is called its
coordination number e.g. in complex [PtCl4]2- , the coordination number of dt is 4.
Ans8. The various coordination polyhedra are –
Ans9. The oxidation number of a metal is the charge it would carry if all the ligands are
removed along with the electron pairs that are shared with the metal atom or ion.
Ans.10 Homoleptic complexes are those in which only one type of ligand or donor group is
present e.g. [Pt(NH306]3+ has only NH3 as ligand. Whereas hetroleptic complexes are
those in which different types of ligands are present eg. [Pt(NH3)4 Cl2]+ has two type of
ligands- NH3 and Cl-.
118
Topic:- Nomenclature of coordination compounds.
1. What IUPAC names of following complexes?

1. [Co (NH3)6]3+
2. [Fe (C2O4)3]3-
3. [Ni (CN)4]2-
4. [Pt(NH3)4 Cl2]2+
5. [NiCl4]2-
6. [Co(NH3)5 ONO]2+
7. [Co (NH3)5Cl]Cl2
8. [Cr (CN) (H2O)5]2+
9. [Co (NO2)6]3-
10. [Co (en)3]Cl3
2. Write formula for the following compounds.

1. Hexammineplatinum (VI) Chloride
2. Potassium hexacyanoferrate (III) ion
3. diamminedichloridoplatinum (III) ion
4. Tetramminedichloridocobalt (III) ion
5. Annine chlorobis (elhylenediamine) cobalt (III) ion.
6. Hexaamminechromium (III) hexacyanocobaltate (III)
7. Pentramminenitro –N- Cobalt (III) Chloride.
8. Pentramminebromidoocobalt (III) sulphate
9. triamminediaquachlorocobalt (III) Chloride
10. Tetramminedichloridooplatinum (IV) Bromide
119
[ANSWERS]
Topic:- Nomenclature of coordination compounds.
Ans1. Hexamminecobalt (III)ion

Ans2 Trioxalatoferrate (III) ion
Ans3 Tetracyanonickelate (II) ion
Ans4 Tetraamminedichlidooroplatinum (IV) ion
Ans5 Tetrachloridoonickelate (II) ion
Ans6 Pentamminenitrito –O-cobalt (III) ion
Ans7 Pentamminechloridoo cobalt (III) Chloride
Ans8. Pentaquacyano chromium (III) ion
Ans9 Hexanitrito –N-cobaltate (III) ion
Ans10 Tris (ethylenediamine) Cobalt (III) Chloride
Ans1. [Pt (NH3)6] Cl6

Ans2. K3 [Fe (CN)6]
Ans3. [Pt (Cl2) (NH3)2]+
Ans4. [Co (NH3)4 Cl2]+
Ans5. [Co Cl (en)2 (NH3)]2+
Ans6. [Cr (NH3)6] [CO(CN)6]
Ans7. [Co (NH3)5 NO2] Cl2
Ans8. [Co (NH3)5 Br ] SO4
Ans9. [Co (NH3)3 (H2O)2 Cl ] Cl2
Ans10. [Pt Cl2 (NH3) 4 ] Br2
120
Topic:- Isomerism in coordination compounds
1. Define – isomerism. [1]
2. What is geometric isomerism? When can a compound show. [2]
(1) Cis – Trans isomerism
(2) Fac and Mer isomerism.
3. How do optical isomer differ from each other? [1]
4. Make the cis and trans forms of the complex [2]
[ Cr Cl2 (en)2]+ . Which one of these will be optically active?
5. Which isomerism is shown by a compound having ambidentate ligand? Give example. [2]
6. What is ionization isomerism? Give an example. [1]
7. How do solvate isomers differ from each other? [1]
8. Draw the geometrical isomers of [Cr (NH3 )2 (CN)4)- ? [1]
9. Indicate the types of isomerisms shown by the complex – K [ Fe (H2O)2 (en)2 Cl2] ? [1]
10. Give an example of coordination isomerism? [1]
121
[ANSWER]
Topic:- Isomerism in coordination compounds
Ans1. Isomerism is the phenomenon of existence of two or more compounds with same
chemical formula but a different arrangement of atoms.
Ans2. The isomerism that arises in hetroleptic complexes due to different possible
geometric arrangements of the ligands is called geometric isomerism.
1) Cis and Trans isomerism can occur in square planar complexes of formula [MX 2
L2] ( X&L are unidentate ligands) , square planar complexes of formula MAB X L
& octahedral complexes of formula MX 2 L4 .
2) Fac and mer isomerism can occur in octahedral complexes of formula Ma3b3.
Ans3. Optical isomers differ in the direction in which they rotate the plane of polarized
light in a polarimeter.
Ans4. [Cr Cl2 (en)2 ]+
Cis and trans forms.
122
The cis form will be optically active.
mirror
Ans5. A complex having ambident ligand will show linkage isomerism e.g [Cr (NH 3)5
(NO2) ] Cl2 has NO-2 as ambident Ligand and its Linkage isomer will be [Cr (NH 3)5
(ONO) ]Cl2.
Ans6. Ionisation isomerism arises when the counter ion in a complex salt is itself a
potential Ligand and can displace a Ligand which can then become counter ion e.g.
[CO (NH3)5 SO4] Br and [CO (NH3)5 Br] SO4 are ionization isomer.
Ans7. The solvate isomers differ by wether or not a solvent molecule is directly bonded to
the metal ion or is merely present on free solvent molecules in the crystal.
Ans8. Geometrical isomers
Ans9. Both geometrical and optical isomerisms will be present.
Ans10. Example of coordination isomerism is
[Cr (NH3)6] [Co (CN)6] and [Co (NH3)6] [Cr (CN)6]
123
Topic:- Valence bond theory and crystal field theory
1. State the postulates of valence bond theory. [2]
2. Explain that the complex [Co (NH3)6]3+ is diamagnetic on the basis of valence
bond theory. [2]
3. [Ni(CO)4]2+ is square planar whereas [NiBr4]2- is tetrahedral . Explain. [2]
4. Enlist the limitations of valence bond theory. [2]
5. State crystal field theory. [2]
6. What is crystal field splitting? [1]
7. How does the magnitude of o and P decide the actual configuration of d4 in
the presence of octahedral field? [2]
8. Show with diagram, the crystal field splitting of d- orbital in an octahedral field. [2]
9. Why are complexes coloured? [1]
10. When is a coordination compound colourlese? [1]
124
[ANSWER]
Topic: - Valence bond theory and crystal field theory.
Ans1. According to valence bond theory:-
(a) In the presence of ligands, the metal ion uses its ns,(n-1)d, np or ns, np, nd orbitals
for hybridization.
(b) These hybrid orbitals are of equivalent energy.
(c) The hybrid orbitals have definite geometry such as octahedral, tetrahedral, square
planar etc.
(d) The hybrid orbitals overlap with ligand orbitals which can donate electrons to make
bond.
Ans2. In [Co(NH3)6]3+
Orbitals of Co3+ ion

    
(ground state) 3d 4S 4P
Excited state configuration   
3d 4S 4P
d2SP3 hybridised orbitals         
Six electron pairs from ligands
Since there is no unpaired electron, the complex is diamagnetic.
Ans3. [Ni (CO)4]2+
Orbitals of Ni2+     

3d 4S 4P
(ground state)
125
    4S 4P
Excited state configuration
3d
   
    dsp2 4P
dsp2 hybridization
Since the hybridization of Ni here is dsp2 the complex has square planar geometry.
[NiBr4]2-
    

Orbitals of Ni2+
( ground state) 3d 4s 4p
Excited state configuration     
        

Sp3 hybrid orbitals
SP3
Since the hybridsation of Ni in this complex is Sp3, it has tetrahedral geometry.
Ans4. Limitations of valence bond theory-

1. It involves a number of assumptions.
2. It does not give quantitative interpretation of magnetic data and kinetic stabilities of
complexes.
3. It does not explain the colour of complexes.
4. It does not distinguish between strong field and weak field ligands.
Ans5. According to crystal field theory-

1. The metal ligand bond is ionic.
2. Ligands are point charges in case of anions or dipoles in case of neutral molecules
3. When the asymmetrical negative field of ligands surrounds the metal atom or ion,
the degeneracy of its d- orbiltals is lifted and they split into two sets.
4. The pattern of splitting depends on the nature of crystal field.
5. In general ligands can be arranged in a series in the order of increasing field strength
called spectrochemical series-
I   Br  SCN  Cl  S2  F  OH  C O 

2 4  H 2O  NCS  edta  NH
2 4 
3  en  CN  CO
126
Ans6 The splitting of otherwise degenerate d- orbitals into two sets in the effect of asymmetrical
negative field of ligands is called crystal field splitting.
Ans7. When the crystal field splitting energy, o  pairing energy ,P, then the fourth electron of
d4 configuration gets paired and the actual configuration becomes t 24geg0
When 0  P , the fourth electron of d4 configuraion goes to higher eg level and the actual
configuration becomes t 2g3 eg1
Ans8.
Crystal field splitting in an octahedral field.
Ans9. The colours of complexes are due to d – d transitions.
Ans10. The substance will be colourless if
a. There is no splitting of orbitals.
b. The configuration of metal ion or atom in d10 or d0
127
Topic: - Bonding in metal carboyl, stability of complex, applications of coordination

compounds
1. What is the shape of [Fe (CO)5]? [1]
2. Explain the synergic bonding in metal carbonyls. [2]
3. What do you understand by stability of a complex and instability constant of
coordination compounds? [2]
4. How is EDTA used in estimation of hardness of water? [1]
5. Explain the role of complexes in metallurgy with an example. [1]
6. Give some example showing importance of complexes in biological system? [2]
7. How is excess of copper and iron removed from body? [1]
8. Give examples of complexes in [2]
a) Chemical analysis
b) Industrics
128
[ANSWER]
Topic:- Bonding in metal carboyl , stability of complex , applications of coordination
compounds
Ans. 1 [Fe (CO)5]

Geomectry = Trigonal bipyramidal
Ans. 2 The metal – carbon bond in metal carbonyls has both s & P- character. The M – C 
bond is formed by donation of lone pair of electrons of carbonyl carbon into a
vacant orbital of metal. The M – C  bond is formed by the donation of a pair of
electron from a filled d- orbital of metal to the vacant  orbital of carbon monoxide.
The metal to ligand bonding creates a synergic effect that strengthens the bond.
Ans. 3 The stability of a complex in solution is the degree of association between the two
species involved in the state of equilibrium. The instability constant is reciprocal of
the formation constant. It is also called dissociation constant.
Ans.4. Hard water is titrated with Na2 –EDTA complex for estimation of its hardness.
During the process, the Ca2+ and Mg 2+ ions form complex with EDTA replacing Na+.
The method is based on the difference in the stability constant of calcium and
magnesium complexes.
129
Ans.5 Some extraction processes make use of complex formation e.g. during metallurgy of
Gold, it combines with cyanide in the presence of oxygen and water to form the
complex [Au (CN)2]- in aqueous solution by addition of zinc.
Ans. 6 Examples of complexes in biological system.-

1. Chlorophyll is a complex of Mg.
2. Haemoglobin is a complex of iron.
3. Cyanocobalamine , Vit B12, is a complex of cobalt.
Ans. 7 Excess of copper and iron are removed by chelating Ligands D – penicillamine and
desferrioxime B through the formation of coordination compounds.
Ans. 8 (a) Chemical analysis –

Qualitative and Quantitative analysis methods involve use of Ligands like EDTA,
DMG etc.
(b) Industries.
Hydrogenation of alkenes is done by using a sodium complex called Wilkinson
catalyst. In black and white photography, silver complexes are used.
130
CLASS - XII CHEMISTRY (Haloalkanes and Haloarenes)
Topic:- Nomenclature
(1). Give IUPAC names of following compounds 1x10=10
1.
CH3 CH CH2 CH2 Br
Br
CH3 CH CH2 Cl
2.
OH
CH3
3. C CH CH2 Cl
CH3 CH2
Br Br
Cl
4. CH3 C CH CH2 CH3
CH3 CH2 CH3
5. C6H5CH2CH2Cl
6. C6H5
CH3 CH
Cl
7. C6H6Cl6
131
8. CH
CCl3
9.
Br Br
Br
10. CH C CH2 CH2 Br
3
CH3
(2). Give the structures of following.: 1x10=10
1. 1,3-Dichloro -2-(bromomethyl) propane
2. Isobutylchloride
3. Ortho bromotoluene
4. 1 – Bromo – 4 – chlorobutane
5. 3 – Bromo – 5 – chloro – 3,5 – dimethyloctane
6. 2,3 – Dibromo – 1 – chloro -3- methylpentane
7. 2 – Chloro – 3 – ethyl -1, 4- pentadieme
8. 2,3 – Dibromo – 1 – chloro -3- methylpentane
9. 2 – Chloro – 1 – phemylpropane
10. Tert – butylchloride
132
[ANSWERS]
Topic: - Nomenclature
Ans1. 1, 3- Dibromobutane
Ans2. 1- Cholopropan-2-ol
Ans3. 2, 3 – Dibromo-1-chloro-3-methylpentane
Ans4. 2-Choloro-3-ethyl-2-methyl pentane
Ans5. 1-Chloro-2-phenylethane
Ans6. 1-Chloro-1-phenyl ethane
Ans7. 1, 2, 3, 4, 5, 6- hexachlorocyclohexane
Ans8. 2, 2- Dihexyl 1, 1, 1-Trichloro ethane
Ans9. 4, 4-dibromobiphenyl
Ans10. 1, 3-Dibromo -3- methyl butane
CH2
Ans1. CH2 CH CH2
Ans2. CH3 CH CH2 Cl
CH3
CH3
Ans3.
Ans4. Br CH2 CH2 CH2 CH2 Cl
133
CH3 CH3
Ans5. CH3 CH2 CH2 CH2 CH2 CH3
CH3
Ans6. CH3 CH2 C CH CH2Cl
Br Br
Ans7. H2C = CH CH C = CH2
C2H5 Cl
CH3
Ans8. CH3 CH2 C CH CH2 Cl
Br Br
Ans9. CH2 CH CH3
Cl
CH3
Ans10. CH3 C Cl
CH3
134
Topic:- Reasoning Questions
Explain giving reasons:- (each question carries 2 marks)
1. Thionyl chloride is preferred for converting alcohol to haloalkane.
2. Phenol cannot be converted to chlorobenzene by reacting with HCl.
3. HNO3 is added during iodination of benzene.
4. p- dichlorobenzene has higher melting point than meta – dichlorobenzene.
5. The boiling points of isomeric haloalkenes decrease with increase in branching.
6. Hydrolysis of optically active 2- bromobutane forms optically inactive butan - 2 - ol.
7. Chlorobenzene is less reactive towards nucleophilic substitution reaction.
8. Chloroform is stored in dark coloured bottles.
9. The order of boiling points is RCl < RBr < RI.
10. Vinyl chloride is less reactive than allyl chloride.
135
[ANSWERS]
Topic:- Reasoning Questions
Ans.1 Thionyl chloride is preferred for converting alcohol to haloalkane because the bi-
products formed are all gases which escape into the atmosphere.
R  OH  SOCl2  RCl +SO2 +HCl
Ans.2 In phenol, due to resonance, the carbon –oxygen bond has a partial double bond
character and is difficult to break being stronger than a single bond. Therefore it can
not be converted to chlorobenzene by reacting with HCl.
Ans.3 When benzene is reacted with iodine, the reaction is reversible in nature. It leads to
the formation of reactants back. Therefore and oxidizing agent like HNO3 oxidizes the
HI formed in the reaction and keeps the reaction in forward direction.
Ans.4
m – dichlorobenzene p - dichlorobenzene
p- dichlorebenzene is having symmetrical structure therefore it can fit better into the
crystal cattie which increases its melting point.
Ans.5 The boiling points of isomeric haloakanes decreases with branching due to decrease
in surface areas with branching .As branching increasing the structure becomes more
spherical and the surface area decreases. e.g. the boiling points of isomers of C 4H9 Br
follows the order.
136
Ans.6 CH3 CH CH2 CH3 2 - Bromo butane
Br
The compound undergoes hydrolysis by SN1 mechanism via the formation of
carbocation which is planar.
The attack of nucleophile can result in product which is a mixture of compounds both
with same configuration and inverted configuration.
Therefore it results in the formation of racemic mixture which is optically inactive.
Ans.7 Chlorobenzene is less reactive towards nucleophillic substitution due to –

1. resonance , C- Cl bond acquires a double bond character
and becomes stronger than a single bond.
2. SP2 hybridisation in C of C-X bond, the carbon becomes more electronegative and
holds the electron pair of C-X bond more tightly decreasing the bond length .
137
3. Instability of phenyl cation.
4. Repulsion for incoming nucleophile from electron rich ring.
Ans.8 Chloroform gets oxidsed slowly by air in the presence of light to an extremely
poisonous gas phosgene. Therefore to avoid any exposure to air and sunlight, it is kept
in dark coloured bottles.
2CHCl3 +O2 light
  2COCl2 + 2HCl
Ans.9 The boiling points of alkyl halides depends on dipole and van-der-waal’s interaction.
These attractions get stronger as the molecules get bigger in size and have more
electrons. As the size of halogens increases in the order –
C l  Br  I
The boiling points also follow the order
RCl < RBr <RI
Ans.10 Due to resonance C- Cl bond gets double bond character and becomes stronger than a
single bond, making vinyl chloride less reactive than allyl chloride.
138
Topic:- Conversions
Convert
1. 1 - Butene to 1 — chlorobutane.
2. Ethene to ethanol.
3. Chlorobenzene to phenol.
4. Methyl bromide to acetic acid.
5. 2- chlorobutane to sec- butyl ethyl ether.
6. Chlorobenzene to benzyl chloride.
7. Chlorobenzene to Benzene.
8. Methane to Ethane.
9. Benzene to o- chlorotoluene.
10. 1- chloropropane to 2- iodopropane.
139
[ANSWER]
Topic:- Conversions
HBr CH3 -- CH 2 - CH 2 -- CH 2 Br
Ans.1 CH3 -- CH2 -- CH = CH2
Peroxide
1 - Butane aq. KOH
CH 3 CH2 CH 2 CH2 Cl SOCl 2

CH3 -- CH2 - CH 2 -- CH2 OH
1 - Chlorobutane
H2SO4
Ans.2 CH2 = CH CH3 CH2 OH
2
HO
2
ethene ethanol
Cl ONa OH
Ans.3 623K, 300 atm HCl

+ NaOH
Dow's Process -- NaCl
chlorobenzene Phenol
H2O
KCN
CH3Br CH3CN CH3COOH
Ans.4
methyl bromide Acetic acid
CH3
Cl CH2
CH3 CH CH2CH3 + CH3 CH2 ONa CH3 CH O CH2CH3

Ans.5 Sec - butyl ethyl ether
2 -- chlorobutane
140
Ans.6
Cl CH3 CH2Cl CH2OH
dry ether Cl2

+ CH3 Cl + 2Na aq. KOH
Fe dark
Chlorobenzene
benzyl alcohol
Ans.7
Cl ONa OH
+
623K, 300 atm H Zn
+ NaOH
Benzene
Chlorobenzene
Cl2 UV Light
Ans.8 CH4 CH3Cl
Methane
2 CH3 Cl + 2Na CH3CH3

Ethane
Cl Cl
Ans.9 Fe CH3 Cl
+ Cl2
dark anhyd AlCl 3
CH3
Benzene
O - Chlorobolunene
Ans.10
CH CH CH CH alc. KOH CH CH = CH HBr CH CH CH

3 2 3 3 2 3 3
1 -- chloropropane Br
Nal
CH3 CH CH3
I
2 -- lodopropane
141
Topic:- Identification Question
1. CH 3 CH 2 CH 2 Br  a 
lc K OH
  X   H/ H
O
  Y   P
2 Cl
  Z 
 5
2. An organic compound ‘A’ having molecular formula C3H6 on treatment with aqueous H2SO4
given’ B’ which on treatment with Lucas reagent gives ‘C’. The compound ‘C’ on treatment
with ethanolic KOH gives back on compound ‘A’. Identify A, B, & C.
3. An organic compound ‘A’ on heating with NH3 and cuprous oxide at high pressure gives
compound ‘B’. The compound ‘B’ on treatment with ice cold solution of NaNO 2 and HCl gives
‘C” , which on heating with copper turning and HCl gives ‘A’ again. Identify A, B & C.
compound
HBr alc HBr peroxide

4. CH3 CH CH3 X Y Z
KOH
OH
5. alc KOH Br2

C2 H5 Br A B
6. CuBr
NaNO2
C6 H5 NH2 A B
HCl
Cl
+
7. NaOH H , H2O
A B
623K1 Pressure
8. A compound ‘A’ contains carbon and hydrogen only and has molecular mass of 72. Its photo
chlorination gives a mixture containing only one monochloro and two dichloro hydrocarbons.
Deduce the structure of A and chlorinated products.
142
[ANSWERS]
Ans1. X= CH3 CH = CH2
Y= CH3 CH CH3
OH
Z= CH3 CH CH3
Cl
A(C H ) aq.H2SO4 ZnCl2 HCl alc

Ans2. B C A
3 6
KOH
A = CH3 CH = CH2 B = CH3 CH CH3 C = CH3 CH CH3
OH Cl
The equations are
aq.H2SO4 ZnCl2 HCl
CH3 CH = CH2 CH3 CH CH3 CH3 CH CH3
OH Cl
alc KOH
CH3 CH = CH2
NH3 NaNO2 Cu/HCl

B C A
Ans3. A Cu O HCl
2
Cl
A=
143
NH2 N2Cl
B= Aniline C= Bengene diazonium chloride
The reactions are
Cl NH2 N2Cl Cl
NH3 NaNO2, HCl Cu/HCl

Cu2O
Ans4. HBr alc

CH3 CH CH3 CH3 CH CH3 CH3 CH =CH2
KOH
OH Br (Y)
(X) HBr peroxide
CH3CH2 CH2 Br
(Z)
Ans5. alc KOH Br2
C2 H5 Br CH2 = CH2 CH2 CH2
Br Br
(A)
(B)
N2Cl Br
Ans6. NaNO CuBr
2
C6 H5 NH2 B
HCl
(A) (B)
144
Cl ONa OH
Ans7. +
NaOH H , H2O
623K1 Pressure
(A) (B)
Ans8. A is C5H12 (mol. Wt. 72)

Since its gives one mono chloro and two dichloro derivatives on photochemical
chlorination, it is
CH3
CH3 C CH3
CH3
The reactions are
CH3
CH3 C CH3 + Cl2

CH3
(A)
Cl2 hr
CH3 CH2 - Cl CH3
CH3 C
CH2 - CH - 2 Cl + HCl CH3 C CH - Cl +
2
CH3 C CHCl2
CH3 CH3 CH3
Dichloro - compounds
145
Topic:- Miscellaneous Questions
1. What is lucas reagent? [1]
2. Which of the following will show optical is omerism
1 – bromobutane or 2 – bromobutane? [1]
3. Arrange CH3 CH2 CH2 CH2 Br , (CH3) 3 C Br, CH3 CH (CH3) CH2 Br
in order of increasing boiling points. [1]
4. Give an example of [2]
(a) Fittig reaction
(b) Finkelstein reaction.
5. What happens when [2]
a) Thionyl chloride acts upon I - propanol.
b) Ethanol reacts with PBr3
6. How many aromatic isomers are possible for the formula C7 H7 Cl ?
Write the structure and names. [2]
7. How is chlorobenzene prepared by [2]
(a) direct chlorination
b) diazotization method?
8. How can we distinguish between an alkyl halide and aryl halide? [2]
146
[ANSWER]

Ans1. A mixture of HCl and anhydrous ZnCl2 is known as Lucas reagent.
Ans 2. CH 3CH 2CH 2CH 2Br CH3CH CH2CH3
Br
1 -- bromobutane
2 -- bromobutane
2- bromobutane will be optically active as it has one chiral carbon (C 2).
Ans3. The order of increasing boiling points is
(CH3)3 C Br < CH3 CH CH2 Br < CH3 CH2 CH2 CH2 Br
CH3
Boiling point decreases with increase in branching as it reduces the surface area.
Ans 4. (a) Fittig reaction
Cl Cl
dry
+ Na +
ether
diphenyl
Chlorobenzene
(b) Finkelstein reaction CH3CH2Cl + Nal CH3CH2 l + NaCl
chloroethane lodoethane
Ans5. (a) When thionyl chloride acts upon 1- propanol chloropropane is formed .
CH3CH2CH2OH + SOCl2  CH3CH2CH2Cl+SO2 +HCl
(b) When ethanol reacts with PBr3, bromoethane is formed.
3CH3CH2OH  PBr3  3CH3CH2 Br  H3 PO3
147
Ans6. C7H7Cl - Three aromatic isomers are possible.
CH3
2 - m e t h y lc h o lo r o b e n z e n e
Cl
CH3
Cl 3 - m e t h y lc h o lo r o b e n z e n e
CH3
4 - m e t h y lc h o lo r o b e n z e n e
Cl
Cl
Ans7 (a) by direct chlorination- Fe

+ Cl2
dark
Benzene Chlorobenzene
(b) by diazotization method.
NH2 N2Cl N2Cl
e
Aniline + NaNO2 + HCl + N2 + NaCl
diazotization
Diazoniumsalt
Cu2Cl2/HCl
Cl
Chlorobenzen
Ans8. Alkyl halide e.g. C2 H5X, C6H5CH2X etc. can be distinguished from aryl halide, C6H5X,
by AgNO3 test.
HNO 3
Alkyl halide + aqKOH + AgNO3 AgX
ppt.
HNO
3
Alylk halide + aqKOH + AgNO 3 NO ppt.
148
CLASS - XII CHEMISTRY (Alcohols, phenols and Ethers)
Topic:- Nomenclature.
1. Write IUPAC names of :-

ix.
i. CH3--CH2--CH--CH--CH2--CH2--CH2--CH3
OH CH3
C H 3 --C H --C H 2 --C l

ii. x.
OH
iii. CH3--CH--CH--CH2--CH2--OH
OH OH 2. Write structural formula and give

IUPAC names :-
iv. (CH3)3COH
i. Benzyl Alcohol
v. Br--CH2--CH--CH--Br ii. Ethylene Glycol
OH CH2Cl iii. Glycerol

Cl
iv. m- cresol
vi. CH3-----C-----CH-----CH2-----CH2-----CH2 --------- OH
CH3 CH2----- CH3

v.
vii. vi. Ethylphenylether
vii. Methylpropylether
viii. Anisole
viii.
ix. Isopropyl methylether
x. Phenetole
149
Topic:- Nomenclature.
[ANSWERS]
Ans 1 (i) 4 – Methyloctan-3-ol

Ans 1 (ii) 1-Chloro propan-2-ol
Ans 1 (iii) Pentan – 1,3,4 – triol
Ans 1 (iv) 2 – Methylpropan -2-ol
Ans 1 (v) 1,3 – Dibromo – 4- chloro – 2- butanol
Ans 1 (vi) 4 – Chloro – 3 – ethyl – 4- methyl hexanol.
Ans 1 (vii) 2 – Phenyl ethanol
Ans 1 (viii) 2- Methyl phenol.
Ans 1 (ix) 4- Bromo -3, 3,5 – trimethyl – hex -1-ene- 2,5- diol
Ans 1 (x) 2,3 – Dimethylbutan – 2,3 –diol
CH2 OH
Ans 2 (i)
1- Phenyl methanol
CH2 OH
Ans 2 (ii) Ethane - 1,2 - diol
CH2 OH
CH2 CH CH2
Ans 2 (iii)
Propane - 1,2,3 - triol
OH OH OH
150
OH
Ans 2 (iv) 3- Methyl phenol
CH3
CH3 CH CH2 CH2 OH

Ans 2 (v)
3 - Bromobutanol
Br
Ans 2 (vi) O CH2 CH3

Ethoxybenzene
Ans 2 (vii)
O CH3
Ans 2 (viii) Methoxybenzene
CH3
Ans 2 (ix) CH O CH3 2 - Methoxy propane
CH3
O CH2 CH3
Ans 2 (x)
Ethoxybenzene
151
Topic:-Reasoning Questions
Give Reasons for the followings :-
1. Phenol is acidic in nature.
2. Phenol has a smaller dipole moment than methanol.
3. o- nitrophenol has lower boiling point ( is more volatile ) than p – nitrophenol.
4. Methanol is miscible with water while iodomethane is not.
5. Alcohols have higher boiling points than isomeric ethers.
6. Ethers are soluble in water alkanes are not.
7. The order of acidic strength in alcohols is R CH2OH > R2 CHOH > R3 COH
8. During preparation of ester from alcohol and acid, water has to be removed as soon as it is
formed.
9. Ethers can not be prepared by dehydration of secondary or tertiary alcohols.
10. Reaction of anisole with HI gives methyl iodide and phenol.
152
Topic:-Reasoning Questions
[ANSWERS]
1. Phenol is acidic in nature because
a) phenol , due to resonance, the positive charge rests on oxygen making the shared
pair of electrons more towards oxygen and hydrogen as H+
b) The carbon attached to OH is SP2 hybridize and is more electronegative, this decreases
the electron density on oxygen, increasing the polarity of O-H bond and ionization of
phenol.
c) The phenoxide ion formed by loss of H+ is more resonance stabilized than phenol itself.
2. In phenol due to electron rich benzene ring the C-O bond is less polar whereas in
methanol the C-O bond is highly polar. Therefore the dipole moment of methanol is higher
than phenol.
3. P- nitrophenol has intermolecular hydrogen bonding which increases the boiling point
while in o- nitro phenol due to presence of intra molecular hydrogen bonding, there is a
decrease in boiling point and increase in volatility.
153
4. Methanol can form intermolecular hydrogen
bonding with water but there is no hydrogen
bonding in iodomethane and water. Therefore
methanol in miscible in water.
5. Alcohols can form intermolecular hydrogen bonds due to their high polarity whereas,
ether cannot. Therefore alcohols have higher boiling points than isomeric ethers.
6. Ethers can form H- bonding with water molecule whereas alkenes cannot. Therefore
ethers are soluble in water and alkanes are not.
7. In alcohols, the acidic strength is due to polar nature of O-H bond. An electron releasing group
e.g., alkyl groups, increases electron density on oxygen tending to decrease the polarity of O-H
bond. This decreases the acid strength. Therefore the order of acid strength is
8. The reaction between alcohol and carboxylic acid is reversible and goes in backward
direction if water is not removed as soon as it is formed.
H
ROH  RCOOH ———⇀ RCOOR' +H O
↽—— 2
154
9. For secondary and tertiary alcohols, elimination competes over substitution and alkenes
are formed on acidic dehydration as the reaction follows Sn1 mechanism. Therefore the
acidic dehydration of secondary or tertiary alcohols does not give ethers.

10. In case of anisole, methyl phenyl oxonium ion, C 6 H5  O  CH 3 is formed by protonation
H
of ethers during reaction with HI. The bond between O- CH3 is weaker than the bond
between O-C6H5 because carbon of phenyl group is SP2 hybridised and there is a partial
double bond character. Therefore the attack by I- ion breaks O-CH3 bond to form CH3I.
C6 H5 OCH3  HI  C 6 H5OH + CH3I
155
Topic:- Conversions
Do the following conversions :-
1. Ethene to 1,2 -ethanediol
2. Phenol to Salicyldehyde
3. Butanol to Butanoic acid
4. Ethanol to propanone
5. Phenol to salicylic acid
6. Methanol to Ethanol
7. Ethanol to propanol
8. Phenol to Benzyl Alcohol
9. Ethanal to propan -2- ol
10. l – propanol to 2 – bromo propane
156
Topic:- Conversions.
Ans 1.
Ans 2.
Ans 3.
Ans 4.
Ans 5.
157
Ans 6.
Ans 7.
Ans 8.
Ans 9.
C C
=
A10.
158
1. An organic compound ‘ A ‘ having molecular formula C3 H6 on treatment with aq. H2SO4 [3]
give ‘B’ which on treatment with Lucas reagent gives ‘C’. The compound ‘C’ on treatment
with ethanolic KOH gives back ‘ A’ .Identify A, B , C .
2. An organic compound A (C H O) gives a characteristic colour with aq. FeCl solution. (A) [3]
6 6 3
On reacting with CO2 and NaOH at 400k under pressure gives (B) which on acidification
gives a compound (C) .The compound (C) reacts with acetyl chloride to give (D) which is
a popular pain killer. Deduce the structure of A,B,C & D.
3. An organic compound (X) when dissolved in ether and treated with magnesium metal [3]
forms a compound Y. The compound, Y, on treatment with acetaldehyde and the product
on acid hydrolysis gives isopropyl alcohol. Identify the compound X. What is the general
name of the compounds of the type Y.
4. A compound ‘A’ with molecular formula C4H10O on oxidation forms compound ‘B’ gives [3]
positive iodoform test and on reaction with CH3MgBr followed by hydrolysis gives (c).
Identify A, B & C.
5. An aromatic compound (A) having molecular formula C6H6O on treatment with CHCl3 [3]
and KOH gives a mixture two isomers ‘B’ and ‘C’ both of ‘B’ & ‘C’ give same product ‘D’
when distilled with Zn dust. Oxidation of ‘D’ gives ‘E’ of formula C 7H6O2. The sodium salt
of ‘E’ on heating with soda lime gives ‘F’ which may also be obtained by distilling ‘A’ with
zinc dust. Identify compounds ‘A’ to ‘F’ giving sequence of reactions.
6. Compound ‘A’ of molecular formula C5H11Br gives a compound ‘B’ of molecular formula [3]
C5H12O when treated with aq. NaOH. On oxidation the compound yields a mixture of
acetic acid & propionic acid. Deduce the structure of A, B & C.
7. [3]
8. [3]
159
Topic:- Identification Question.

[ANSWERS]
Ans 1.
Ans 2.
Ans 3. The compound X is CH3Br and Y is CH3MgBr The compounds of the type ‘Y’ are called
Grignard reagent.
Ans 4. The compound ‘B’ is obtained by oxidation of C4H10O and gives positive iodoform test
and also reacts with CH3MgBr , it must be methyl Ketone , it must be methyl ketone
having four carbon atoms i.e, CH3COCH2CH3 .
160
This can be obtained by oxidation of 2 – butanol i.e , CH3 CH CH2 CH3 Therefore , the
reactions are. OH
Ans 5.
The aromatic compound having molecular formula C6H6O and which gives a mixture of
two isomers on reacting with CHCl3 and KOH is phenol i.e.
161
Ans 6.
Since acetic acid & propionic acid are the products of oxidation of C which is a ketone, C is
CH3 CH2 CH2CO CH3. Since it is the oxidation product of B, therefore
The reactions are
Ans 7.
Ans 8.
162
Topic:- Miscellaneous Question.
1. What is denatured alcohol? [1]
2. Mention two important uses of methanol. [1]
3. Arrange C6H5OH, C2H5OH & H2O in the increasing order of acid strength. [1]
4. Give the structure of main product of action of excess of Br2 on phenol. [1]
5. How is the presence of peroxides in ethers detected? How are peroxides removed [2]
from Ethers?
6. Explain a chemical test to distinguish between primary, secondary and tertiary [2]
alcohols.
7. What is Lucas test? [2]
8. What is Picric acid? How is it prepared from phenol? [1]
9. What is wood sprit? Why is it so called? [1]
10. Give equations for preparation of ethanol by fermentation. [2]
163
[ANSWERS]
Topic:- Miscellaneous Question
1. Industrial alcohol (ethyl alcohol) is made unfit for drinking purpose by addition of a small
quantity of poisonous substance, methanol. This is called denatured alcohol. For denaturation,
copper sulphate or pyridine can also be added.
2. Uses of methanol:-
i) It is used for denaturing alcohol.
ii) It is used as a solvent for paints & varnishes.
3. The order is C2H5OH< H2O <C6H5OH.
4. The main product will be 2,4,6-tribromophenol.
5. Presence of peroxides in ethers is detected by addition of freshly prepared FeSO4 and KCNS.
Appearance of blood red colour confirms the presence of peroxide. They can be removed by
shaking ethers well with FeSO4 solution.
6. Primary tertiary and secondary alcohols can be distinguished by oxidation reaction.

Primary alcohols give aldehyde with CrO3
R C H 2 O H  C 
rO 3
 R C H O
Secondary alcohols give ketone with CrO3.
R 2 C H O H  C
rO3
 R CO
2
164
Tertiary alcohol do not get oxidized with CrO3
R3COH C 
rO3
 No reaction
7. Lucas test is used for distinguishing between primary secondary and tertiary alcohols. When a
tertiary alcohol is dissolved in Lucas reagent (Conc. HCl + ZnCl2) it produces turbidity
immediately where as secondary alcohols produce turbidity after some time and primary
alcohols do not react at all and no turbidity is product.
8. Picric acid is 2,4,6 – trinitrophenol
It is prepared from phenol by nitration with conc. HNO3.
9. Wood spirit is methanol. It is so called because earlier it was obtained from destructive
distillation of wood only.
10. Ethanol can be prepared by fermentation of sugar –
C H O + H O  I 
nvertase
 C 6 H 12 O 6 +C 6 H 12 O 6
12 22 11 2 enzymes
Sugar Glucose fructose
C H O   2 C H O H + 2 C O
Z ym a se
6 12 6 enzymes 2 5 2
Ehanol
165
CLASS - XII CHEMISTRY (Aldehydes, Ketones and carboxylic acids)
CH2 CHO
1. Give IUPAC names of following (viii)
(i) CH3CO - CH - CH CH Cl
2 2
C2H5 Br
CH2 CHO
(ii) (ix) HOOC – CH = CH – COOH
Br
CHO
(iii) CH CHO (x)
CH3
OCH3
(iv)
CH3 CO CH CH2 CH2 Cl
2. Draw the structure of the following –
CH3
(v) CH3 CH (OH) CH2 CO CH3 (i) 4- Methoxybenzaldehyde

(ii) 5- Bromo -3- Chloro -2- iodobenzoic acid
CH3 (iii) 3,3 – Dimethyl -1- Chlorobutane
CH3 CO CH
(vi) (iv) 2,3- Dihydroxy -4-methylpentanal
CH3
(v) 3- Hydroxy-2-methyl -propanal
(vi) 2,4 –Dimethyl -3- pentanone
CH3 (vii) 1,2 –Ethaneodioc acid
(vii) C2H5 C C2H5 (viii) 3- Pentene -2-one
(ix) 1,3 – Propane –dioic acid
COOH
166
[Answer]
Ans1(i). 5-Chloro -3- ethylpentan -2-one.
Ans1(ii). 2 –(1-bromophenyl) ethanal
Ans1(iii). 2- Phenylpropanal
Ans1(iv). 5- Chloro -3- methyl pentan -2-one
Ans1(v). 4- Hydroxypentan -2- one
Ans1(vi). 3- Methylbutan -2-one
Ans1(vii). 2- Ethyl -2- methylbutanoic acid
Ans1(viii). 2- (1- Bromophenyl) ethanal
Ans1(ix). But-2- en -1,4 –dioic acid
Ans1(x). 4- Methoxybenzaldehyde
CHO
Ans 2(i).
OCH3
COOH
Ans 2(ii). I
Cl
Br
167
CH3
Ans 2(iii). CH3 C CH2 CH2 Cl
CH3
Ans 2(iv). CH3 CH CH CH CHO
CH3 OH OH
Ans 2(v). HO CH2CH CHO
CH3
Ans 2(vi). CH3 CH CO CH CH3
CH3 CH3
COOH
Ans 2(vii).
COOH
CH3 C CH = CH CH3
Ans 2(viii).
O
Ans 2(ix). COOH CH2 COOH
168
Topic:- Reasoning Questions.
Q. Give Reasons :-
1. Carboxylic acid is stronger acid than phenol.
2. Ethanol is more soluble in water than ethyl chloride
3. Aldehydes are more reactive than Ketones towards nucleophilic additions.
4. Carboxylic acids has higher boiling points than alcohols of same no. of carbon
atoms.
5. Ethanoic acid has molar mass of 120 in vapour state.
6. Carboxylic acids do not give characteristic reactions of carbonyl group.
7. Formal dehyde does not undergo aldol condensation.
8. Floro acetic acid is a stronger acid than acetic acid.
169

[ANSWERS]
1. Carboxylic acid on dissociation form carboylate ion which is stabilized by two equivalent
resonance structure in which negative charge is at the more electronegative oxygen
atom, whereas the conjugate base of phenol, phenoxide ion, has non – equivalent
resonance structures in which negative charge is at the less electronegative carbon
atom. Therefore resonance is not as important as it is in carboxylate ion. Moreover the
negative charge is delocalized over two more electronegative oxygen atoms in
carboxylate ion whereas it is less effectively delocalized over one oxygen atom and one
carbon atom in phenoxide ion. Therefore the carboxylate ion is more stabilized than
phenoxide ion and carboxylic acids are stronger acids than phenol.
2. Ethanol can form intermolecular Hydrogen bonding with water molecules, ethyl chloride
can not. Therefore ethanol is soluble in water and ethyl chloride is not.
3. Aldehydes are more reactive than Ketones due to steric and electronic reasons. In
Ketones due to presence of two relatively large alkyl groups, the approach of nucleophile
is more hindered than in aldehydes having only one such substitute. More over the +I
effect of alkyl groups reduces the electophilicity of carbonyl group more in Ketone than
in aldehydes.
4. Carboxylic acids have more extensive association of molecules through intermolecular
hydrogen bonding than alcohols. Moreover their boiling points are higher than alcohols
of same carbon atoms.
5. Ethanoic acid exists as dimer in vapour state in which two molecules remain together by
hydrogen bonding. This increases the effective molecular mass to 120.
6. In carboxylic acids due to presence of resonance, the C=O group is not a pure carbonyl
group & therefore they do not show characteristic reactions of carbonyl group.
7. Formaldehyde does not have any  - hydrogen and therefore it can not show aldol
condensation.
8. In fluoroacetic acid, Fluorine being electron withdrawing group stabilizes the conjugate
base through delocalization of the negative charge
O
F C
O
Therefore fluoroacetic acid is a stronger acid than acetic acid.
170
Topic:- Conversions
1. Toluene to benzaldehyde
2. Acetaldehyde to Acetamide
3. Methanol to acetic acid
4. Methanol to Ethanol
5. Acetic acid to Propionic acid
6. Ethyl alcohol to acetone
7. Acetone to tert butyl alcohol
8. Toluene to m- nitrobenzoic acid
9. Phenol to acetophenone
10. Acetaldehyde to Acetone
171
[ANSWER]
Topic:- Conversions
OCO CH3
CH3 CH CHO
Ans1.
OCO CH3
CrO3 H+/H2O
(CH3 CO)2 O
Toluene Benzaldehyde
Ans2. (O) NH3

CH CHO CH COOH CH COO NH CH3CONH2
3 3 3 4
KMnO4
Acetaldehyde Acetamide
KCN
Ans3. CH OH + SOCl CH Cl CH CN CH COOH
3 2 3 3 + 3
H2O/H
Methanol Acetic acid
H+/H2O
Ans.4 H C = O CH3MgBr CH3 CH2 OMgBr CH3 CH2 OH
Cu/573K
CH3CHO
H Etanol
Methanol
LiAIH4 12 Red P KCN

CH3COOH CH3 CH2 OH CH CH2 I C CH2 CN
Ans5. (H) 3 3
+
Acetic acid H2O
H
CH3 CH2 COOH
Propionic acid
172
Ans6.
- CH3 CO DRY
CH CH OH (O) CH COOH slaked lime Ca(OH) CaCO distillation CH C CH
2
3 2 3 Ca 3 3 3
KMnO4
acetic acid CH3 CO C
Ketone
Ans7.
O CH3 CH3 OH
H+
CH3 C CH3 + CH3 Br Mg CH3 C O Mg Br CH3 C OH + Mg
H2O
CH CH Br
3 3
Acetone
test butlyalcohol
CH3 COOH COOH

Ans8.
(O) Conc. HNO3 + H2SO4
Alk.KMnO4
NO2
Tulene
m - nitro benzoic acid
OH COCH3
Ans9.
Zn CH3 COCl
dust anhyd. AlCl3
phenol
Acetophenone
- CH3 COO CH3

(O) Ca(OH)
Ans10. 2
Ca distill
CH3 CHO CH3COOH C=O + CaCO3
KMnO4
CH3 COO CH3
173
1. A compound ‘A’ with formula C5H10O gives a positive 2, 4 –DNP test but a negative Tollen’s
test It can be oxidizing to carboxylic acid ‘B’ of molecular formula C3H6O2, when treated
with alk. KMnO4 under vigorous conditions. The salt of ‘B’ gives a hydrocarbon ‘C’ on
Kolbes’ electrolytic decarboxylation. Identify A,B.C & write chemical equations.
2. Acompound A with molecular formula C5H12O on oxidation forms compound B with

molecular formula C5H10O. The compound B gives iodoform test but does not reduce
ammoniacal silver nitrate. The compound B on reduction with Zn – Hg/ HCl gives compound
C with molecular formula C5H12. Identify A,B.C & give the chemical reactions involved.
3. An organic compound A, which has a characteristic odour, on treatment with NaOH forms two
compound B and C. Compound B has molecular formula C7H8O which on oxidation gives
back A. Compound C is the sodium salt of an acid. C, when heated with soda lime yields an
aromatic hydrocarbon D. deduce the structures of A to D.
C l2 / r e d P a lc . N H
4. CH 3
C O OH ( A) 3
( B)
Br2/KOH NaNO2/HCl
5. C6H5 CONH2 A B C
K2Cr2O7/H2SO4
+
KCN H2O/H PCl5
6. CH3Cl A B C
7. CH3COOH C 
a(OH )2
 (A) d 
ry distribution
 (B) I 
2 / NaOH
(C)
8. CH 3 COCH 3  L  X  S
iAlH 4

OCl 2
 Y  a 
lc. KO H
 Z
9. HC  CH H  
3O / Hg SO4
 A O
 B C 
o (O H ) 2
 C
10. Two moles of compound (A) on treatment with a strong base gives two compounds (B) and
(C). The compound (B) on dehydrogenation with Cu gives (A) while acidification of (C) gives
carboxylic acid (D) having molecular formula CH2 O2. Identify (A) to (D).
174
[Answers]
Ans1. 2, 4 - DNP
A (C5H10 O) Positive
Negative
A alk. KMnO4
B (C3H6 2O )
Kolbe's
C3H6O2 - Na C
decarboxylation
As the compound A gives a positive 2, 4-DNP test but negative Tollen’s test, it is a ketone. Since
on oxidation, it gives an acid B, of molecular formula C3H6O2, it is CH3CH2COCH2CH3 and B is
CH3CH2COOH. As C is obtained by Kolbes decarboxylation of B, C is CH 3CH2 CH2 CH3.
Therefore A = Pentan -3 one, CH3 CH2 CO CH2 CH3
B = Propanoic acid CH3 CH2 COOH
And C = Butane CH3 CH2 CH2 CH3
The sequence of reactions is
NO2
NO2
CH3 - CH 2CO -H2O
CH3CH2
H 2N - NH NO2
C = NNH NO2
CH 3 CH2 CH3CH2
CH 3 CH 2 CO CH 2 CH 3 a 
lk .kmNo4
 CH 3CH 2COOH  CH COOH
3
kolbe 's 
CH CH COOK
3 2     CH 3 CH 2 CH 2 CH 3 +CO 2 +KOH +H 2
decarboxylation
175
Ans2.
(O)
A (C5H12O) B (C5H10O)
Iodoform test
x 

Zn - Hg
B C (C5H12)
HCl
Since B gives a negative Tollen’s test but positive Iodoform test, it is methyl ketone, i.e, CH 3CO
CH2 CH2 CH3. Also it is formed by oxidation of A.
CH 3 C H CH 2 CH 2 CH 2 CH3
Therefore A is secondary alcohol i.e, | on reduction B gives pentane
OH
with Zn –Hg/ HCl.
Therefore C is CH3 CH2 CH2 CH2 CH3
Therefore
A = CH3 CHOH CH2 CH2 CH3

B = CH3 CO CH2 CH2 CH3
C= CH3 CH2 CH2 CH2 CH2 CH3
Reactions:-
(O) (H)
CH3 CH CH2 CH2 CH3 CH3 C CH2 CH2 CH3 CH3 CH2 CH2 CH2 CH3
-H2O Zn - Hg/HCl
(B) (C)
OH (A) O
I2/NaOH
CH3 C CH2 CH2 CH3 CHI3+ CH -3 CH - 2CH - COONa
2
+ Nal + H O 2
176
Ans3.
NaOH
A B + C (Sodium salt of acid)
(C7H8O)
NaOH + CaO
(O)
D (aromatic)
A
The molecular formula of (B) and characteristic odour of (A) suggests that (A) is an aromatic
aldehyde, C6H5 CHO and (B) is alcohol, C6H5CH2OH. As (C) is a sodium salt of an acid & gives
hydrocarbon (D) on heating with soda lime, (C) is sodium benzoate and (D) is benzene.
Therefore:-
CH O
A = b e n z a ld e h y d e , , B = b e n z y la lc o h o l
CH 2
OH COONa
, = S o d iu m b e n z o a te ,
C
D = ben zen e T h e r e a c t io n a r e
CHO C H 2O H COONa
Conc.NaOH
+
(b ) (C )
NaOH +
(O)
Ca O
CH O
(A)
177
Ans4. A = CH2 COOH , B = CH2 COOH
Cl NH2
Ans5. (A) = C6 H5CH2NH2
N2Cl
(B) =
(C) =
O
Ans6. (A) = CH3CN
(B) = CH3COOH
(C) = CH3COCl
Ans7. (A) = (CH3 COO)2 Ca

(B) = CH3 COCH3
(C) = CHI3
Ans8. X = CH3 CH CH3
OH
Y = CH3 CHCH 3
Cl
Z = CH3-CH = CH2
178
Ans9. A = CH3 CHO
B = CH3 COOH
C = CH3 CO CH3
Strong Base
Ans10. 2 A B + c
NaOH
+
573K Cu H
A CH2O2 D
Since (D) is a carboxylic acid with one carbon only, it is HCOOH. As it is obtained from (C)
acidification, (C) COONa and (A) is HCHO which on treatment with strong base (NaOH) gives
CH3OH & HCOONa (cannizaro’s reaction).
NaOH
The reactions are :- 2H CHO CH3OH + H COONa
B c
+
Cu573K H
HCHO HCOOH
179
1. Give one use of Formalin. [1]
2. What is the chemical name of Tollen’s reagent and Fehling’s solution [2]
3. Write the structure of alkenes that on ozonolysis will give ketone only. [1]
4. What is the function of BaSO4 in rosenmund reaction? [1]
5. Name the isomers with molecular formula C3H6O.
Which one will have high boiling point? [1]
6. Write a chemical test to distinguish between aldehyde and ketone. [1]
7. What happens when acetaldehyde is kept with a trace of sulphuric acid?
Write the structure of product. [1]
8. What is the Hofmann bromamide reaction? Illustrate with one example. [1]
180
[ANSWERS]
Topic:- Miscellaneous Question
Ans.1 Formalin is used as a disinfectant, preservative for biological specimens and in leather industry.
Ans.2 Tollen’s reagent = Ammoniacal Silver Nitrate

Fehlings solution = Sodium Potassium Tartarate.
Ans.3 CH3 C= C CH3 2, 3 - dimethyl but - 2 - ene
CH3 CH3
Ans.4 BaSO4 acts as a catalytic poison which prevents further reduction of aldehyde to alcohol.
Ans.5 The two isomers are CH3COCH3 and CH3 CH2CHO. Acetone boils at higher temperature due
to presence of two electron donating alkyl groups.
Ans.6 Aldehydes and ketones can be distinguished by Tollen’s test. Aldehydes give a silver mirror on
reacting with Tollen’s reagent whereas ketones will not react.
Ans.7 A trimer of acetaldehyde, called paraldchyde is formed.

CH3
CH
O O
CH3 CH CH CH3
Ans.8 Hoffman bromamide reaction is a reaction in which amides are converted to amines of one
carbon less than the starting amide. It is a very important step – down reaction.
RCONH2 + Br2 + KOH RNH2 + KBr + K2CO3 + H2O
181
CLASS - XII CHEMISTRY (Amines)
1. Give IUPAC name of 1X 10=10
C H 3 -- N -- C H 3 (vii) C6 H5 CH2 CH CH3

(i) NH2
(ii) m- NC C6H4NH2 (viii) O – (NH2)2 C6 H4
(iii) CH3 CH – CH2 CH2 N H – CH3 (ix)

NO2
CH3
(iv) CH3 CH2 CH2 N
CH3 (x)
(v) CH3 NH C – CH3
CH3
CH 3
(vi) C N H2
C H3
C H3
2. Write structure of following 1x10=10
(i) Aminobut -2- ene (v) N, N- Dimethyl methanamine

(ii) N- Methyl –N- ethylaniline (vi) N- Phemylaniline
(iii) N- Ethyl -2- pentanamine (vii) 3-Phenyl propanamine
(iv) 2,4,6 – Tribromoaniline (viii) Benzylamine
182
[ANSWERS]
1 (i) N, N–dimethylaniline
CN
3-aminobenzonitrile
1 (ii)
NH2
1 (iii) N- methyl -3 – nitro -1- butanamine
1 (iv) N, N – dimethylpropanamine
1 (v) N- methyl -2- aminopropanamine
1 (vi) 2- Methyl propane
1 (vii) CH2 CH CH3

1-phenyl-2-propanamine
NH3
NH2
NH2 1, 2-benzenediamine
1 (viii)
1 (ix) N – Ethyl pentan-2-amine
1 (x) N, N – Dimethyl-4-nitro aniline
183
2 (i) NH2 CH2 CH = CH CH3
CH 3
N
C 2
H 5
2 (ii)
2 (iii) CH3 CH2 CH2 CH CH3
NH CH2 CH3
NH2
2 (iv) Br Br
Br
2 (v) CH3 – N – CH3

CH3
HN--C6 H5
2 (vi)
2 (vii) CH2 CH2 CH2 NH2
C6H5
CH2 NH2
2 (viii) IUPAC name - 1- Phemylmethamine
184
Give Reasons
1. It is difficult to prepare pure amines by ammonolysis of alkylhalides. [2]
2. Amines have higher boiling points than hydrocarbons of similar molecular mass. [2]
[2]
3. Aniline is weaker base than cyclohexylamine.
4. [2]
Methylamine is a stronger base than aniline.
[2]
5. Before nitration, aniline is converted to acetanilide.
[2]
6. It is easier to brominate aniline as compared to benzene.
[2]
7. Reduction of nitro compound to aniline using iron scrap and HCl is preferred.
[2]
8. Aromatic amines cannot be prepared by Gabriel Phthalimide synthesis.
9. [2]
During acylation of amines, pyridine is added.
[2]
10. Aniline does not undergo Friedel – Craft’s reaction.
185
[ANSWERS]
1. The process of ammonolysis yields a mixture of primary, secondary, tertiary amines

and quaternary salts. The separation of this amines is a very complicated process and
difficult. Therefore it is difficult to prepare pure amines by ammonolysis of alkyl
halides.
2. Amines have higher boiling points than hydrocarbons of comparable molecular mass
due to the presence of intermolecular hydrogen bond in amines which is absent in
hydrocarbons. Therefore, amines exist as associated molecules and have higher
boiling points.
In alcohols and carboxylic acids, the electro- negativity of oxygen is more than
nitrogen of amines. Therefore the hydrogen bonds of alcohols and acids are stronger
than in amines and alcohols & carboxylic acids have higher boiling points.
3. As a result of resonance in aniline; the lone pair on nitrogen delocalized over the
benzene ring and is less available for protonation than in cyclohexyl amine which
does not undergo resonance.
Resonating structure of aniline –
186
4. Due to electron donating nature of CH3, NH2
group, electron pair. Availability at N- atom
in methyl amine is much higher than that in CH3 NH2
aniline; in aniline the benzene ring
decreases the electron density at N- atom in Methylamine
aniline. Thus CH3NH2 is a stronger base
than aniline. Aniline
5. Aniline is very much susceptible to nitration and nitric acid is a strong oxidizing agent.
Therefore to avoid oxidation of aniline, -NH2 group is protected by its acetylation to
acetanilide which undergo nitration smoothly without any oxidation.
NH2
6. In aniline, due to +R effect of –NH2 group the benzene
ring gets activated to a large extent and it becomes easier
to brominates aniline as compared to benzene.
Anili ne B enzene
7. For reduction of nitro compounds to aniline, iron scrap and HCl is preferred because
FeCl2 formed gets hydrolysed to release HCl during the reaction & therefore only a
small amount of HCl is required to initiate the reaction.
8. Aromatic amines cannot be prepared by Gabriel pythalimide synthesis as aryl halides

do not undergo nucleophilic substitution with the anion formed by pythalimide.
9. Acylation of amines is carried out in presence of pyridine or another base stronger

than amines as it removes HCl so formed and shifts the equilibrium in forward
direction.
10. During Fridel Craft’s reaction, aniline forms salt with aluminum chloride, the catalyst
of reaction due to which nitrogen acquires a positive charge and acts as a strong
deactivating group for further reaction.
187
Topic:- Identification Question.
Each question carries 3 marks

1.
2. A compound (X) having formula C3H7 NO reacts with Br2 in the presence of NaOH to give
another compound (Y). Compound (Y) reacts with HNO2 to form ethanol and N2 gas . Identify
(X) and (Y) . Write the reaction involved.
3. An organic compound A (C3H5N) on boiling with alkali gives NH3 and sodium salt of an acid B
(C3H6O2). The compound A on reduction gives C (C3H9N) which on treatment with nitrous acid
gives an alcohol D (C3H8O). Identify A to D
4.
5.
188
6.
7.
8.
9.
10.
189
[ANSWERS]
Ans 1.
Ans 2.
Since Y gives ethanol and N2 gas with HNO2, therefore it is CH3 CH2 NH2.
Ethan amine (Y) is formed on reacting (X) with Br2 and NaOH;
Therefore X is CH3 CH2 CO NH2.
Therefore
X= CH3 CH2 CONH2
Y = CH3 CH2 NH2
The reactions are –
190
Ans 3.
Since the compound (A) gives sodium salt and ammonia, (A) is cyanide. The compound (C)
is a primary amine as it reacts with HNO2 and forms an alcohol (D) Therefore
A= CH3 CH2 CN , B= CH3 CH2 COOH,
C= CH3 CH2 CH2 NH2 , D= CH3 CH2 CH2 OH
Equations are-
Ans 4.
191
Ans 5.
Ans 6.
Ans 7.
Ans 8.
192
Ans 9.
Ans 10.
193
Topic:- Conversions
1. Aniline to N- phenylethanamide
2. Aniline to P- aminoazobenzene
3. Benzene to Aniline
4. Nitrobenzene to bromobenzene
5. Benzene to m- bromoaniline
6. Aniline to benzoic acid
7. Aniline to p- nitro aniline
8. Methylamine to ethylamine
9. Nitroethane to Nitro methane
10. Benzene to 1,3,5 – tribromobenzene
194
Topic:- Conversions
Ans1. NH2 NHCOCH3
base
+ CH3COCl + HCl
Aniline N - phenylethanamide
NH2
Ans2.
+
+ ice cold H NH2

Cl - N = N N=N
Aniline benzene diazonium

chloride P - aminoazobenzene
NO2 NH2
Ans3. HNO3+ Sn/HCl

H2SO4
Benzene AniLine
Benzene
NO2 NH2 N2Br Br

Ans4.
Sn/HCl NaNO2/ CuBr
HBr Sandmeyer reaction
Nitrobenzene Bromobenzen
195
Ans5. NO2 NO2 NH2
HNO3/H2SO4 Br2/Fe
Sn/HCl
Benzene Br Br
m - bromoaniline
NH2 N2Cl CN COOH

Ans6.
+
NaNO2/HCl CuCN H3O
Aniline Benzoic acid
NH2 NHCOCH3 NHCOCH3 NH2

Ans7.
+
HNO3/H2SO4 H2O/H
+ CH3COCl
Aniline
NO2 NO2
p - nitroaniline
Ans8. CH NH HONO CH OH Red P/l2 CH l KCN CH CN H2/Nl

3 2 3 3 CH3CH2NH2
-N2 3
Ethylamine
Methylamine
196
Ans9.
Ans10.
197
1. For an amine RNH2, write an expression to indicate its basic strength [1]
2. Give one use of quaternary ammonium salts. [1]
3. Give one example of Hoffmann – Bromamide reaction [1]
4. Distinguish between ethylamine and aniline. [1]
5. The IUPAC name of secondary amine having lowest molecular mass is . [1]
6. Give an example of diazotization [1]
7. Write one use of diazonium salt [1]
8. How can the reactivity of aromatic amines be controlled? [1]
9. Give one use of tertiary amines. [1]
10. Name a reagent which can distinguish between primary, secondary and
tertiary amines [1]
198
[ANSWERS]
1.
RNH2 + H2O ⇌ RNH3 + OH

+ -
[RNH 3 ] [OH- ]
Kb =
[RNH2 ]
2. Quaternary ammonium salts are widely used for manufacture of synthetic detergents.
3. In Hoffmann – Bromamide reaction an acid amide is reacted with Bromine in presence

of a base to give a primary amine having one carbon less than the starting amide.
RCONH2 + Br2 + 4 NaOH  RNH2 + Na 2 CO3 + 2 NaBr + 2 H2O
4. Ethylamine and aniline can be distinguished by azodye test. On treating aniline with
benzene diazonium salt, orange or red coloured azodye is formed which is not formed
with ethyl amine.
5. N- Methylmethanamine.
199
6. During diazotization benzene diazonium chloride is prepared by the reaction of aniline
with nitrous acid at 273 – 278 K
7. Diazonium salts are used in preparation of substituted aromatic compounds.
8. The reactivity of aromatic amines can be controlled by acylation.
9. Tertiary amines like trimethylamine are used as insect attractants.
10. P- Toluenesulphonyl chloride Hinsberg reagent can be used as a distinguishing reagent

for primary, secondary and tertiary amines.
200
CLASS - XII CHEMISTRY (Bimolecules)
Topic:- Carbohydrates and their classification
1. Give some examples of bimolecules [1]
2. What are carbohydrates? [1]
3. Give one example of each- Monosaccharide, disaccharide and polysaccharides. [1]
4. Which disaccharides are non – reducing sugars? [1]
5. Classify the following as monosaccharides disaccharides and polysaccharides- [1]
Glucose, Sucrose, maltose, ribose, glycogen, lactose, fructose.
6. What is the meaning of statement- Glucose is an aldohexose. [1]
7. Why are polysaccharides considered non- sugars? [1]
8. Give two examples of reducing sugars [1]
9. Which sugar is present in milk? [1]
10. Name the reagents used to check the reducing nature of carbohydrates. [1]
201

[ANSWERS]
Ans1. Examples of biomolecules –
carbohydrates, proteins, Nucleic acids, Lipids, enzymes etc.
Ans2. Carbohydrates are optically active polyhydroxy aldehydes or ketones or the compounds
which produce such units on hydrolysis.
Ann3. Monosaccharide – Glucose, Fructose etc.
Disaccharide – Sucrose, maltose etc.
Polysaccharide – Cellulose, starch etc.
Ans4. In disaccharides, if the reducing groups of monosaccharides, i.e. aldehydic or ketonic

groups are bonded eg. In sucrose, these are non- reducing.
Ans5
Monosaccharide Disaccharides Polysaccharides
Glucose Sucrose Glycogen
Fructose Maltose
Ribose Lactose
Ans6. Glucose is an aldohexose means that it contains six carbon atoms and aldehyde group.
Ans7. Polysaccharides are not sweet in taste & hence are called non – sugars.
Ans8. Examples of reducing sugars –
Maltose and Lactose.
Ans9. In milk, lactose is present.
Ans10. Tollen’s reagent and Fehlings solution can be used to check reducing nature of sugars.
202
1. How is glucose obtained from starch? [1]
2. Give a reaction to prove that –
(a) Glucose has carbonyl group
(b) The six carbons in glucose are arranged in a straight chain [2]
3. What is the significance of ‘D’ and ‘+’ before the name of glucose in D (+) – glucose? [2]
4. Which reaction of glucose cannot be explained by its cyelic structure? [2]
5. What are anomers? Name the two anomers of glucose. [2]
6. Give the structures of  and  forms of glucose. [2]
7. What are the expected products of hydrolysis of
(a) Sucrose
(b) Galactose [2]
8. What is animal starch ? Where is it found? [2]
9. Give two examples of polysaccharides. [1]
10. Name any Hexose other than glucose [1]
203
[ANSWERS]
Topic: - Carbohydrates and their classification
Ans1. Glucose can be obtained from sucrose by boiling sucrose with dil – HCl in alcoholic
medium.
C12 H 22 O11  H 2 O  H  C 6 H 12 O 6 + C 6 H 12 O 6

Sucrose Ghuose Fructose
Ans2. (a) Glucose molecule reacts with hydroxylamine to form an oxime and adds a
molecule of HCN to form cyanohydrin . These reactions prove that a carboxyl
group is present in glucose
CHO CH = N - OH
NH2OH
(CHOH)4 (CHOH)4
CH2OH CH2OH
Oxime
CN
CHO CH
OH
HCN (CHO H)4
(CHOH) 4
CH2OH CH2OH
cyanohydrin
(b) When glucose in heated with HI, it forms n- hexane. This shows that 6 carbons
of glucose are arranged in a straight chain.
CHO
HI,
(CHOH)4 CH3 - CH2 - CH2 - CH2 - CH2 - CH3
CH2OH
204
Ans3. The letter ‘D’ written before the name of glucose represents its relative
configuration whereas (+) represents dextrorotatory nature of the molecule.
Ans4. The penchant structure of glucose cannot explain that glucose despite having
aldehyde group –
(a) does not give 2,4- DNP test, schiffs test and does not react eith NaHSO3 .
(b) Its penta acetate does not react with hydroxyl – amine indicating the absence of
free CHO group.
Ans5. Anomers are a pair of diasteomers of adoses or ketoses which differ in
configuration about C-l, C-2 carbon atom.
The two anomers of glucose are  - glucose and  - glucose.
Ans6.   D  ()  glucopranose   D  ()  glucopyranose
Ans7. Products of hydrolysis of

i. Sucrose =  - D- Glucose &  - D- Fructose
ii. Lactose =  - D- Galactose &  - D- Glucose
Ans8. Animal starch is glycogen. It is present in liver, muscles and brain.
Ans9. Examples of polysaccharides = starch, glycogen and cellulose.
Ans10. Other Hexoses = Fructose, Galactose.
205
Topic:- Proteins
1. What is the basic unit of proteins? [1]
2. How are amino acids classified? [2]
3. Give an example of zwitter ion? [1]
4. Write the name of bond between the two  - amino acids. [1]
5. Differentiate between fibrous and globular proteins. [1]
6. What is the information given by primary structure of proteins? [1]
7. Differentiate between  - helical and  - pleated sheet structure. [2]
8. What do you understand by secondary structure of proteins? [2]
9. Name the forces responsible for secondary and tertiary structure. [1]
10. What is denaturation of proteins? Explain with examples. [1]
206
Topic:- Proteins
[ANSWERS]
Ans1. The basic unit of all proteins in  - amino acids.
Ans2. Amino acids are classified as essential and non – essential amino acids.
The amino acids which can be synthesized in the body are known on non – essential
amino acids e.g. Asparetic acid, Glycine etc.
The amino acids which cannot be synthesized in the body and must be obtained
through diet are known as essential amino acids. E.g. Histidine, lysine.
O
Ans3.
R CH C O Zwitter ion
+
NH3
Ans4.  - amino acids are connected by peptide linkage.
Ans5.
Fibrous Proteins Globular Proteins
1. Their molecules have long thread 1. They have folded ball – like structure
like structure.
2. they have helical or sheet 2. They may have three dimensional Shapes.
structures
3. They are in soluble in water but 3. They are soluble in water, acids and
soluble in strong acids and bases. Bases and salts.
e.g. Keratin, fibroin etc. e.g. Egg albumin, casein insulin.
207
Ans6. Primary structure of proteins tells about the sequence in which various amino acids
are linked with each other.
Ans7.  - helical structure  - pleated sheet structure

1. In this structure, formation of 1. In this structure, the long peptide
hydrogen Bonding between amide chains lie side by side in a zig-zag
groups within the same chain manner to form a flat sheet. Each
causes the peptide chains to chain is held to the two
coil up into a spiral structure like a neighboring Chains by hydrogen
right handed screw. bonds. These sheets can slide upon
one another in three dimensional
e.g.  - keratin, skin, wool etc.
structures.
e.g. fibroin present in silk etc.
Ans8. The secondary structure of protein refers to the shape in which a long polypeptide
chain can exist arising due to regular folding of the backbone of poly peptide chain
due to hydrogen bonding between > C = O and , - N –H group of poly peptide chain.
Ans9. The forces which are responsible for tertiary structure of proteins are hydrogen
bonds, disulphide linkage, vanderwalls and electrostatic forces of attraction.
Ans10. Disruption of the native conformation of a protein by changing its environment like
PH value, temperature etc. resulting into loss of its biological activity is called
dehaturation of proteins. During denaturation, secondary and tertiary structures get
destroyed while primary structure remains same e.g., coagulation of egg albumin by
boiling.
208
Topic:- Enzymes and Vitamins
1. What are enzymes? [1]
2. How are enzymes named? Give an example. [2]
3. Give an example of enzyme catalysed reaction. [1]
4. What are vitamins? Give two examples. [1]
5. How are vitamins classified? [2]
6. Which vitamins cannot be stored in our body? [1]
7. Where are fat soluble vitamins like A, D, E, and K stored in our body? [1]
8. Write the disease caused by deficiency of vitamins A, B2 , B6 , B12, C, D E and K. [4]
209
[ANSWERS]
Topic:- Enzymes and Vitamins
Ans1. Enzymes are biocatalyst which are very specific for a particular reaction and a
particular substrate. Almost all enzymes are globular proteins.
Ans2. Enzymes are generally named after the compound upon which they work. e.g.
enzyme that catalyses the hydrolysis of maltose into glucose is named maltase.
Some times enzymes are named after the reaction where they are used. e.g. the
enzymes which catalyze reduction of other is called oxidoreductase.
Ans3. Example of enzyme catalysed reaction –
C H O M  2 C H
altase
O
12 22 11 6 12 6
Maltose Glucose
Ans4. Vitamins are organic compounds required in the diet in small amounts to perform
specific biological functions for normal maintenance of optimum growth and health
of the organism. e.g. vitamins A, B, C, D etc.
Ans5. Vitamins are classified into two groups depending upon their solubilities-
(i) Fat soluble vitamins – which are soluble in fats and oils. e.g. vitamins A, D, E & K.
(ii) Water soluble vitamins – which are soluble in water e.g. vitamins B& C.
Ans6. Water soluble vitamins cannot be stored in our body as they are excreted in urine.
Ans7. Water soluble vitamins are stored in liver and adipose (fat storing) tissues in our
body.
Ans8. Vitamin Deficiency disease
A Xerophthalmia, Night blindness
B2 digestive disorders
B6 Convulsions
B12 Pernicious anaemia
C Scurvy
D Rickets
E Muscular weakness
K Increased blood clotting time.
210
Topic: - Nucleic Acids
1. Name the different types of RNA molecules found in the cells of organisms [1]
2. What are the three components of nucleic acids? [1]
3. Name different bases present an (i) DNA (ii) RNA [2]
4. What is nucleoside? [1]
5. What type of bonding occurs between two nucleotides? [1]
6. Write the sequence of bases in the complementary strand of the given strand - [1]
AGGCTTAACCT
7. Name the various sugars present in RNA & DNA. [1]
8. Write functional differences between [2]
RNA & DNA.
211
[ANSWERS]
Topic:- Nucleic Acids
Ans1. The different types of RNA molecules are transfer RNA (+ RNA), messenger RNA
(m–RNA), ribosomal RNA (r- RNA)
Ans2. The three components of nucleic acid are base, sugar and phosphate group.
Ans3. Bases present in DNA – Thyamine (T), Adenine (A), Guanine (G), Cytosin (C) and in
RNA are uracil (U), Adenine (A), Cytosine (C) and Guanine (G).
Ans4. The molecules in which one of the organic base is combined with sugar are called
nucleosides.
Ans5. The two nucleotides are joined by phopho- diester linkage.
Ans6. The sequence of bases in the complementary sequence is –

TCCGAATTGGA
Ans7. The various sugars present in nucleic acids are Ribose in RNA and deoxyribose in
DNA.
Ans8. DNA is very important for passing of hereditary information from one generation
to other.
In RNA protein synthesis takes place.
212
CLASS - XII CHEMISTRY (Polymers)
Topic:-Classification of polymers
1. Define polymers. [1]
2. Write various uses of polymers. [3]
3. On what basis are polymers classified? [2]
4. What is the difference between a homopolymer and a copolymer? [1]
5. Classify the following substances as natural, semi – synthetic and synthetic polymers [3]
6. Give two examples of each (i) linear polymer (ii) Network polymer. [2]
7. How are addition polymers different from condensation polymers? [2]
8. What is the basic difference between following pairs: [2]
(a) Elastomers and fibres
(b) Thermo setting polymer & thermo plastic polymers.
213
[ANSWERS]
Topic: - Classification of polymers
Ans1: Polymer are defined a very large molecules having high molecular mass which are
formed by joining of repeating structural units on a large scale.
Ans2: Polymers are used in manufacture of plastic buckets, cups and saucers, children’s toys,
packaging bags, synthetic clothing materials, automobile tyres, insulating materials etc.
polymers are the back bone of five major industries – plastics, elastomers, fibres, paints &
varnishes.
Ans3: Polymers are classified on the basis of

(a) Source
(b) Structure
(c) Mode of polymerisation
(d) Molecular forces
Ans4:
Homopolymer Copolymer
The addition polymers formed by The polymers made by addition
polymerisation of a single monomeric polymerisation from two different
species are known an homopolymers monomers are known as
e.g. – polythene copolymers e.g. Buna – S
Ans5: Natural polymers : Cellulose, Starch, And Protein

Semisynthetic : Rayon
Synthetic : Plastic, Nylon
214
Ans6: Linear polymers : Polythene, Polyvinylchloride
Network polymers : Bakelite, Melamine
Ans7: Addition Polymers: - They are formed by the repeated addition of monomer molecules
possessing double or triple bonds e.g. polythene
Condensation polymer:- They are formed by repeated condensation reaction between two
different bifunctional or trifunctional monomeric unit, with elimination of small
molecules such as water e.g. Nylon – 6, 6.
Ans8:(a)
Elastomers Fibres
1. These are rubber like solids with 1. There are thread forming solids with
elastic properties high tensile strength
2. The polymer chains are held together 2. The polymer chains are closely packed
by weakest intermolecular forces due to strong intermolecular forces
e.g. Buna – S like Hydrogen bond e.g. Nylon – 6, 6
(b) Thermoplastic Thermosetting polymers

1. They are linear or slightly branched 1. They are cross – linked or heavily
molecules. branched molecules.
2. They are capable of repeatedly 2. They undergo extensive cross linking
softening on heating and hardening on heating & can not be reversed e.g.
on cooling e.g. PVC. bakelite.
215
Topic:-Types of polymerisation Reactions
1. Name the two types of polymeristion. [1]
2. Name some initiators. [1]
3. Explain the mechanism of polymerisation of ethene. [2]
4. Name the two type of polyethene. [1]
5. Differentiate between LDP and HDP. [2]
6. Write the monomer of Teflon. [1]
7. Give preparation of polyacrylonitrile. [1]
8. Write one use of each – Teflon and polyacrylonitrile. [2]
216
[ANSWERS]
Topic: - Types of polymerisation Reactions
Ans1: The two types of polymerisation are

(a) Addition polymerisation and
(b) Condensation polymerisation.
Ans2: Examples of initiator are –

Benzoyl peroxide, acetyl peroxide, tert – butyl peroxide etc.
Ans3: Polymerisation of ethene takes place by free radical mechanism. It follows a three step
mechanism:-
Step I: chain initiating step formation of phenyl free radical.
Step II:
Step III: Chain termination step
Ans4: Polyethene is of two types –

1) Low Density Polyethene 2) High Density Polythene
217
Ans5:
(LDP) Low Density Polythene (HDP) High Density Polythene

1. It is obtained by polymerisation of ethane 1. It is formed when polymerisation takes
under pressure of 1000 to 2000 atm. & place in a hydrocarbon solvent in
temperature of 350K to 570K. presence of a catalyst e.g. Ziegter-natta
2. It is prepared in the presence of dioxygen or a catalyst at 333K-343K and 6-7atm
peroxide initiator. pressure.
3. It has highly branched structure. 2. It requires Ziegler – Natta catalyst.
4. It is chemically inert, tough and flexible. 3. It has a linear structure.
5. It is a poor conductor of electricity. 4. It in more tougher and harder.
6. It is used in toys, flexible pipes etc. 5. It is used for making buckets, dustbins,
pipes etc.
Ans6: Teflon
Monomer = Tetrafluoroethene
CF2  CF2
Ans7: Polyacrylonitrite
Ans8: Uses:
(1) Teflon is used in making oil seals & for non – stick surface coated utensils.
(2) Polyacrytonitrile is used for wool in making commercial fibres an orlon or acrilan.
218
Topic:-condensation Polymerisation
1. What is condensation polymerisation? [1]
2. Why is condensation polymerisation also called on step – growth polymerisation? [1]
3. Write some examples of condensation polymers. [1]
4. Give monomers and preparation of Nylon – 6, 6 and Dacron. [3]
5. How is Nylon – 6, 6 different from Nylon -6? [1]
6. What are Bakelite and Melamine? Give their structures. [2]
7. Write uses of bakelite and melamine. [2]
8. Give the formula of monomer of Nylon – 6. [1]
9. What is copolymerisation? [1]
10. Give the monomer and preparation of Buna – S. [2]
219
[ANSWERS]
Topic: - Condensation Polymerisation
Ans1: Condensation polymerisation involves a repetitive condensation reaction between two

bifunctional monomers which results in the loss of simple molecules of water, alcohol
etc.
Ans2: Condensation polymerisation produces a distinct functionalized species and is

independent of each other. Therefore it is also called step growth polymerisation.
Ans3: Examples of condensation polymers are Nylon-6, 6, Dacron, Nylon 6 etc.
Ans4: Preparation
(i) Nylon – 6, 6
Monomers: Hexamethylene diamine Adipic acid.
(ii) Dacron
Monomers: Ethylene Glycol
Terephthalic acid
Ans5: Nylon – 6, 6 is made of two bifunctional monomers, each having 6 carbon atoms whereas
Nylon – 6 is made from heating only one monomer having 6 carbon atoms.
220
Ans6 Bakelite – It is phenol – formaldehyde polymer.
Melamine – It is melamine – formaldehyde polymer
Ans7: Bakelite is used for making combs, phonograph records, electrical switches, handles.
Melamine is used in manufacture of unbreakable crockery.
Ans8: Monomer of Nylon -6 is caprolactum
Ans9: The reaction in which a mixture of more than one monomeric species is allowed to
polymerise & form a copolymer is called copolymerisation e.g. Buna -S.
Ans10: Preparation of Buna – S
221
Topic:-Rubber, Biodegradable Polymers
1. What is the monomer of natural rubber? [1]
2. How are the characteristics of natural rubber modified? [1]
3. Give two examples of synthetic rubber. [1]
4. How are neoprene & Buna – N prepared? Which one is a copolymer? [2]
5. Give one example of biodegradable polymer. [2]
6. Classify following on Homopolymer and copolymer- [2]
PVC, Polystyrene, Buna – S, Neoprene, Buna – N, Teflon.
7. Classify following an addition and condensation polymer- [2]
Bakelite, Polythene, Nylon – 6, 6, Polyacrylonitrile
8. Write monomers of polystyrene and PVC. [2]
222
[ANSWERS]
Topic: - Rubber, Biodegradable Polymers
Ans1: Monomer of national rubber is isoprene or 2 – methyl – 1, 3 – butadiene.
Ans2: Natural rubber is soft at high temperatures and brittle at low temperatures. It is soluble in
non – polar solvents and non – resistant to oxidizing agents. These properties can be
modified by mixing raw rubber with sulphur. & an appropriate additive at a temperature
373K to 415K. This is called venlcanisation.
Ans3: Example of synthetic rubber –

Neoprene, Buna – N etc.
Ans4: Preparation of Neoprene-
Preparation of Buna – N.
Ans5: Biodegradable polymer: PHVB, Nylon – 2 – Nylon -6.
223
Ans6: Homopolymer Copolymer
PVC Buna – S
Polystyrene Buna – N
Neoprene
Teflon
Ans7: Addition polymer condensation polymers

Polythene Dacron
Polyacrylonitrite Nylon – 6, 6, Bakelite
Ans8: Polymer Monomer
1. Polystyrene Styrene,
2. PVC Vinyl Chloride,
224
CBSE TEST PAPER-01
CLASS - XII CHEMISTRY (Chemistry in Everyday Life)
Topic:-Drugs
1. Define Drugs. [1]
2. Define chemo therapy. [1]
3. What are the various basis of classification of drugs? [2]
4. Give some examples of drug targets. [1]
5. Explain drug – enzyme interaction. [2]
6. What are antagonists and agonists? [1]
7. Metal – hydroxides are used an antacids instead of metal hydrogen carbonates. Why? [1]
8. What are antihistamines? Give two examples. [2]
225
[ANSWERS]
Topic: - Drugs
Ans1: Drugs are chemicals of low molecular masses which interact with macromolecular targets
and produce a biological response.
Ans2: The use of chemicals for therapeutic use is called chemotherapy.
Ans3: Drugs are classified on the basis of

(a) Pharmacological effect
(b) Drug action
(c) Chemical structure
(d) Molecular targets
Ans4: Examples of drug targets – Enzymes, Receptors, Lipids, Carbohydrates etc.
Ans5: Drug – Enzyme interaction –
Drugs can block the binding site of the enzyme and prevent the binding of substrate or
can inhibit the catalytic activity of enzyme acting as enzyme inhibitors. Drugs inhibit the
attachment of substrate on active site of enzyme in two different ways –
(i) They compete with the natural substrate for their attachment on the active site of enzyme
acting as competitive inhibitors.
226
(ii) Some drugs bind to a different site, called allosteric site so as to change the shape of
active site in such a way that substrate cannot recognise it.
If the bond formed between an enzyme & an inhibitor is a strong covalent bond, the
enzyme is blocked permanently & is degraded by the body.
Ans6: Drugs that bind to the receptor site & inhibit its natural action are called antagonists
whereas the drugs that mimic the natural messenger by switching on the receptor are
agonists.
Ans7: Excessive hydrogen carbonates can make the stomach alkaline and trigger the production
of even more acid. Therefore metal hydroxides are better antacids as they are insoluble &
do not increase pH above neutrality.
Ans8: Antihistamines prevent the interaction of histamine with the receptors present in the
stomach wall e.g. Rantidine, Soldane etc.
227
Topic:-Drugs
1. What are tranquilizers? [1]
2. How does an antidepressant work? Explain with example. [2]
3. Give two examples of barbiturates. [1]
4. What are analgesics? [1]
5. Explain the types of analgesics with example. [2]
6. What are antibiotics? [1]
7. How are antibiotics classified? Explain with example. [3]
8. What in the difference between antiseptics & disinfectants? [2]
9. Give two examples of drugs used as antiseptics and disinfectants. [1]
10. Give two examples of antifertility drugs. [1]
228
[ANSWERS]
Topic: - Drugs
Ans1: Tranquilizers are neurologically active drugs which are used for the treatment of stress
and mild or even severe mental diseases.
Ans2: Antidepressants are used in case of a person suffering from depression e.g. noradrenalin
is a neurotransmitter that plays a role in mood change. If the level of noradrenaline is low,
the person suffers from depression. An antidepressants inhibits the enzyme which
catalyses the degradation of noradrenalin. If the enzyme is inhibits, the neurotransmitter is
slowly metabolized & can activate the receptor for longer time & counteracts the effect of
depression.
Ans3: Examples of barbiturates –

Veronal, amytal, Nebutal, Liminal & Seconal.
Ans4: Analgesics reduce or cure pain without causing impairment of consciousness, mental
confusion, incoordiantion or paralysis or some other problem of nervous system.
Ans5: Analgesics are classified an

(i) Non narcotic analgesics – These drugs are effective in reliving skeletal pain & are non
– addictive. They may have many other effects like reducing fever and preventing
platelet coagulation. e.g. Aspirin & Paracetamol.
(ii) Narcotic analgesics – These are habit forming or addictive drugs e.g. morphine & its
homologues. They, when administered in medicinal doses relieve pain & produce
sleep but in poisonous doses, they can produce coma, convulsions & even death.
229
Ans6: Antibiotics are the drugs used to treat infections because of their low toxicity for humans
& animals. They are the substances produced wholly or partly by chemical synthesis,
which in low concentration inhibit the growth or destroys the microorganisms by
intervening in their metabolic processes.
Ans7: Antibiotics are classified on the basis of –

(1) Their cidal (killing) or. Static (inhibitory) effect. They can be Bactericidal (inhibits
the actinty) e.g. penicillin in bactericidal white Tetracycline is bactereostatic.
(2) Their spectrum of action i.e. the range of bacteria or other microorganisms that are
affected by them. Antibiotics which are effective against a wide range of Gram –
positive are broad spectrum antibiotics, those effective mainly against Gram –
positive or gram negative bacteria are narrow spectrum antibiotics wherever those
effective against only a single bacteria are limited spectrum antibiotics. e.g.
Penicillin G is narrow spectrum while Arnpicillin in broad spectrum antibiotic.
Ans8: Antiseptics are those antimicrobials which are applied to the living tissues such an
wounds cuts, ulcers and diseased skin surfaces e.g. sofracmicine etc. these are not
ingested like antibiotics. Disinfectants are applied to inanimate objects such as floors,
drainage system instruments etc. e.g. phenol.
Ans9: Drugs used antiseptics on well on disinfectants –

(1) 0.2% solution of phenol is an antiseptic while its one % solution disinfectant.
(2) Dettol.
Ans10: Antifertility drugs –

1. Norethindrone
2. Novestcof (ethrynylestrediol)
230
Topic:-Artificial Sweeteners, soaps and detergents
1. Give some examples of artificial sweeteners. [1]
2. Which artificial sweetener is preferred for diabetes and why? [2]
3. What are the limitations of aspartame and alitame? [2]
4. Name two food preservatives. [1]
5. How are floating soaps made? [1]
6. Why soaps do not work in hard water? [1]
7. How are detergents classified? [3]
8. How is the problem of non – biodegradable detergents solved? [1]
231
[ANSWERS]
Topic: - Artificial Sweeteners, soaps and detergents
Ans1: Examples of artificial sweeteners are Aspartame, Saccharin, Alitame, Sucrolse etc
Ans2: Saccharin is preferred for diabetic persons as it is excreted from body in urine unchanged.
It is entirely inert and harmless when taken.
Ans3: Aspartame is of limited use because it in unstable at cooking temperature & is used in
cold foods & soft drinks.
Alitame is a high potency sweetener & its sweetness cannot be controlled.
Ans4: Two food preservatives are table salt, sodium benzoate etc.
Ans5: Floating soaps are made by beating tiny air bubbles before the hardening of soap.
Ans6: Hard water contains calcium and magnesium ions, which form insoluble calcium or
magnesium soaps when soap is dissolved in hard water. They separate as scum in water
and are useless as cleaning agents. Therefore soaps do not work in hard water.
Ans7: Synthetic detergents are classified as –
(a) Anionic detergents – these are sodium salts of sulphonated long chain alcohols or
hydrocarbon. Here the anionic part of the molecule is involved in the cleansing action.
e.g. sodium laurylsulphate.
(b) Cationic detergents – these are quaternary ammonium salts of amines with acetates,
chlorides or bromides anions. e.g. cetyletrimethyl – ammonium bromide.
(c) Non – ionic detergents – these detergents do not contain any ion in their constitution.
e.g. CH3 (CH 2 )16 COO(CH2CH2O)n CH2CH2OH
Ans8: The detergents having highly branched hydrocarbon part is non – biodegradable & causes
water pollution. This problem can be overcome if the branching of hydrocarbon chain is
controlled & kept to minimum – unbranched detergents are biodegradable and cause less
pollution.
232
FIRST UNIT TEST PAPER 01
CLASS - XII CHEMISTRY
Time: 11/2 hours Maximum Marks: 40

Note: Attempt all questions:
1. Person suffering form high blood pressure should take less common salt. Explain why? [1]
2. Write the Nernst equation for the electrode reaction. [1]
Mn+ + ne-  M(s)
3. Define ‘anisotropy’. [1]
4. Why is boiling point elevated when a non – volatile solute is added to the solvent? [1]
5. Write the order of the reaction from the graph.
6. The molality of an aqueous solution is 1.002m. Determine the mole fraction of the solute. [2]
7. Differentiate order and molelcularity of a reaction. [2]
8. If KCl is doped with 10 -3 mol% of CdCl. What is the concentration of cation vacancies?
9. 87.5% of the substance disintegrated n 45min. (First order reaction).
What is the its half – life? [2]
10. Zinc rod dipped in 0.1M solution of znSo4, the salt is 85% dissociated at the dilution at 298 k
calculate its electrode potential (Given E 0Zn 2
/ Zn
 0.76v ) [2]
11. State Rauolt’s law. Explain the cause of positive and negative deviation from Rauolt’s law with
suitable examples. [3]
12. Consider a certain reaction A  Products with K = 2.0  10-2 sec-1. Calculate the concentration
of ‘A’ remaining after 100 seconds, if initial concentration of ‘A’ is 1.0 Mol L -1.
13. Write the Mechanism of rusting of iron. [3]
14. Define Molar conductivity. Explain the variation of Molar conductivity with concentration of
weak & strong electrolytes. [3]
233
15. An element crystallises in FCC unit cell with edge length of 200 pm. Calculate its density if
200g. Of this element contains 24  1023 atoms. [3]
16. A reaction is first order in A and second order in B
(i) Write differential rate equation.
(ii) How is rate affected if the conc. Of B is tripled?
(iii) How is rate affected when the conc. Of both A & B is doubled?
17. (a) Classify each of the following as being either a P – type or n – type semiconductor. [5]
(i) Ge doped with In
(ii) B doped with Si
(b) Write the possible value of van‘t’ Hoff’s for solute undergoing
(i) Association,
(ii) Dissociation and
(iii) No association or dissociation.
234
CLASS - XII (CHEMISTRY)
Time : 1.5 Hours M.M.40
1. In corundum Oxide ions are arranged in hexagonal close packing and Aluminium
ions occupy two-third of the Octahedral voids. What is the formula of corundum?
2. Differentiate between Molarity and Molality. (1)
3. Silver forms fcc unit cell and X-ray studies of its crystals show that the nearest
neighbour distance is 288.96pm Calculate the density of silver (Atomic mass =
107.9u)
4. Zinc Oxide is white but it turns yellow on heating, Explain. (2)
5. When a non volatile solute is added to a solvent, the B. pt of solution gets elevated.
Explain with the help of diagram. (2)
6. the depression in Freezing point of water observed for the same amount of acetic
acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above.
Explain briefly. (2)
7. Silver is electrolysed/electrodeposited on a metallic vessel of total surface area
900cm2 by using a current of 0.5 amp for two hours. Calculate the thickness of silver
deposited. Density of silver=10.5g/cm 3 (Atomic mass of silver =108 amu, F =
96500Cmol-1)
8. The following reaction was studied in a closed vessel.
2N2O5 K 4NO2(g)+O2(g)
It was found that the concentration of NO2 increases by 2.0x10-2molL-1 in five
seconds. Calculate. (3)
i. the rate of reaction
ii. the rate of change of concentration of N2O5.
9. The emf of the following cell is found to be 0.20V at 298K
Cd/Cd2+ (g) ll Ni2+ (2.0M)/Ni
What is the molar concentration of Cd2+ ions in the solution of
(Eo Cd2+/Cd=-0.40V,EoNi2+/Ni=-0.25Y (3)
10. A colloidal solution of Agl is prepared by two different methods given below
i. What is the charge on Agl colloidal particles in the two tubes (A) and (B)?
ii. Give reason for the origin of charge. (3)
235
11. The time required for 10% completion of a first order reaction at 298K is equal to that
required for its 25% completion at 308K. If the pre-exponential factor for the reaction is
3.56x109s-1 calculate its rate constant at 318K and also the energy of activation. (3)
12 a. Differenciate b/w order and molecularity of a reaction.
b. The half – life period of a first order reaction is 60 minutes. What percentage
will be left after 240 minutes? (5)
13 a. Write the cell reaction involved in
i. fuel Cell
ii. Mercury cell
iii. Dry Cell
b. In each of the following pairs which will allow greater conduction of electricity
and why?
i. Silver wire at 20oC, same silver wire at 50oC
ii. NaCl solution at 20o, same NaCl solution at 50o C
14. a. 1M NaNO3(aq) solution having density 1.1g/cm3 calculate its freezing point and
boiling point of solution. (Kb=0.52K/m,Kf = 1.86v/m).
B.pt of water = 373.15K
F.pt of water = 273.15k
b. Derive the relationship between relative lowering of vapour pressure and mole
fraction of the volatile liquid (5)
236
CLASS - XII (CHEMISTRY)
Time : 1.5 Hours M.M.40
Attempt all the questions.
1. In what type of the defect the density of ionic crystal increases? [1]
2. What deviation is observed when NH4 Cl mixed with water? [1]
3. The conductivity and Molar conductivity of which is more between 0 .1M CH3 [1]
COOH & 0.01M CH3 COOH?
4. What will be value of Vant’s Hoff factor [1]

i. for solution of K4 Fe (CN)6
5. The rate of reaction is 3.102x10-3 mole/It/sec. What is the order of the [2]
reaction?
6 Define schottky defect and Frankel’s defect. [2]
7. Atomic radius of gold is 0.144nm crystalises in a FCC Unit cell what is the [2]
length of side of cell?
8. Show graphically that freezing point of a liquid will depressed when a non [2]
volatile solute is dissolved in it.
9. Give the mechanism of rusting of iron. [2]
10. Predict the product of electrolysis in the following. [2]

i. An aqueous solution of AgNO3 with silver electrode.
ii. A dilute solution of H2SO4 wit Pt electrode.
11. Conductivity of 0.00241M acetic acid is 7.896x10 -5 Scm. Calculate molar [3]
conductivity if  0m for CH3 COOH is 390.5Scm2/mole. What is its dissociation
constant?
12. Write the Cathode, Anode and overall cell reaction in oxygen hydrogen fuel [3]
237
cell.
13. What is semi conductor. Describe the two main types of semiconductor and [3]
contrast their conduction mechanism.
14. Analysis shows that iron oxide has formula Fe0.95 O1.00. What fractions of iron [3]
exist at Fe2+ & Fe3+ ion?
15. N2 gas bubbled through water at 293K How many milli moles of N 2 gas would [3]
dissolve in 1 litre of water? Assume that N2 excerts a partial pressure of 0.987
bar. Henry’s constant for N2 for 293K is 76.4K bar.
16. 19.5gm of CH2 FCOOH is dissolved in 500gm of water its depression in [5]
freezing point of water is observed 1 0C. Calculate Vantt’s Hoff factor &
dissociation constant of CH2FCOOH.
17. The following result have been obtained during kinetic studies of the reaction
[5]
2 A+B  C+D Experiment
[A]/mol-1 [B]/mol L-1 [initial rate of formation of D/mol L-1 min
I 0.1 0.1 6.0x10-3
II 0.3 0.2 7.2x10-2
III 0.3 0.4 2.88x10-1
IV 0.4 0.1 2.40x10-2
OR
The electrical resistance of a column of 0.05 mol L -1 Na OH solution of
diameter and length 50 cm is 5.55x10 3  (ohm). Calculate its resistivity,
conductivity and molar conductivity.
238
CLASS XII (CHEMISTRY)
Time 3 Hrs. M. M. 70
General Instructions
1. All questions are compulsory.
2. Marks of each question are indicated against of it.
3. Q. No. 1 to 8 are very short answer questions and carry 1 mark each.
4. Q. No. 9 to 18 are short answer questions and carry 2 marks each.
5. Q. No. 19 to 27 are also short answer questions and carry 3 marks each.
6. Q. No. 28 to 30 are long answer questions and carry 5 marks each.
7. Use Log tables if necessary. Use of calculators is not allowed.
1. Name the element with which silicon is doped to give p type semi conductors. [1]
2. Give the example of a compound in which hydrogen bonding results in the [1]
formation of a dinner.
3. State any one condition (with example) in which a bimolecular reaction may be [1]
of first order.
4. Zinc but not copper is used for the recovery of Ag from the comple [Ag (CN) 2]- [1]
Why?
5. What is mend process for purification of Nickel? Give reactions only. [1]
6. Which form of sulphur is pacamagnetic? [1]
7. Name the first compound of Xenon formation of which established the [1]
reactivity of Xenon.
8. Name the oxometal anion of first transition series in which the oxidation [1]
number of the element is equal to group number.
9. Explain with suitable example – [2]

1. Ferromagnetism
2. F – Centres.
10. a. Show graphically the depression in freezing point of a solution, containing [2]
non volatile solute.
b. Why does the vapor pressure of a solution having non – volatile solute is
239
lower than the vapour of pure solvent.
11. Aluminium crystallizes in the (ccp) structure. It’s metallic radius is 125 pm. [2]
1. What is the length of the side of the unit cell.
2. How many unit cell are there in 1.00 cm3 of Aluminium.
12. What role does the molecular interaction play in the solution of alcohol and [2]
water?
13. Write the chemistry of recharging the lead storage battery. [2]
OR
A solution of Ni (NO3)2 is electrolyred between platinum electrodes using a
current of 5 amperes for 20 minutes. What mass of Ni deposited at the cathode.
(Ni = 59)
14. The decomposition of Ammonia on platinum surface is zero order reaction. [2]
What are the rates of formation of N2 and H2 (K = 2.5 x 10-4 mol L-1 S-1)
15. Define order of reaction. How will you prove that a chemical reaction is of first [2]
order?
16. 1. What is the maximum oxidation state that transition element may exhibit. [2]
2. Cu has 3d10 configuration still it is transition element Why?
17. How do you account for the reducing character and basicity of H 3 PO3 on the [2]
basis of their structure.
18. Account for – [2]

1. Interhalogen compounds are reactive than individual molecules.
2. White phosphorus is more reactive than red phosphorus.
19. 1. Write the reactions involved in blast furnace in the extraction of lron [3]
from its ore.
2. What criterion is followed for the selection of stationary phase in
Chromatography.
20. Define the following terms with example. [3]

1. Associated Colloid.
240
2. Peptisation.
21. The rate constant for the decomposition of hydrocarbon is 2.418 x 10 -5 at 546 [3]
K. If the activation energy is 179.9 KJ/mol, what will be the value of pre –
exponential factor.
OR
For a first order reaction, show that time required for the completion of 99% is
twice the time required for the completion of 90% of a reaction.
22. Give reasons – [3]

1. Ester hydrolysis slow in the beginning and becomes fast after some
time.
2. Why is it necessary to remove CO when NH3 prepared by Haber’s
process?
3. Adsorption always exothermic.
23. An element has a body – contered (bcc) structure with a cell edge of 288 pm. [3]
The density of the element is 7.2 g/cm3. how many atoms are present in 208 g
of the element.
24. Explain – [3]

1. PCl3 fumes in nature.
2. H2 Te is more acidic than H2S
3. HF is less acidic than Hl
25. What help of a graph explain why it is not easy to determine Rm for a weak [3]
electrolyte by extra ploting the concentration molar conductance curve for the
strong electrolyte.
26. What happen when – [3]

1. Concentrated H2 SO4 is added to Calcium Fluoride.
2. White Phosphorous reacts with Sodium hydroxide in inert
atmosphere.
3. Chlorine reacts with hot and concentrated Sodium Hydroxide.
241
27. Explain giving reasons – [3]
1. Transition metals and many of their compound show paramagnetic
behaviour.
2. Transition elements form coloured compounds.
3. Variation in oxidation states of transition metals is different from p-
block element.
28. State Henry’s law. If the solubility product of CuS is 6 x 10 -16 calculate the [5]
maximum molarity of CuS in aqueous solution
OR
a The depression in freezing point of water, observed for the same molar
concentration of CH3COOH, CCl3COOH and CF3COOH increases in the order as
stated above.
b. Calculate the depression in freezing point of water when 10 g of
CH3CH2CHCl COOH is added to 500 g of water. Ka = 1.4 x 10-3 and kf = 1.86 K kg
mol-1.
29. a Represent the cell in which the following reaction takes place – [5]
Mg (s) + 2Ag(0.00 1M)  Mg2+ (0.13M) + 2Ag
Calculate it Ecell if Ecell = 3.17 V.
b The standard electrode potential for Daniell cell is 1.1 V. Calculate the
Gibb’s energy for the reaction –
Zn(s) + Cn2 + (aq)  Zn2 (aq) + Cu(s)
(F = 96487 C)
OR
a The cell potential of mercury cell remains constant during its life why?
b. Predict the products on electrolysis of an aqueous solution of AgNO 3 using
Platinum electrodes.
c. The electrical resistance of a coloumn of 0.05 mol L-1 NaOH solution of
diameter 1 cm and lengh 50 cm is 5.55 x 103 ohm. Calculate its resistivity
conductivity and molar conductivity.
30. a Draw the structure and also state the hybridization of central atom.
242
1 H4 P2 O7
2 XeOF4
b Complete the following reaction –
Cu + HNO3 (con.) 
l2 + H2 O + Cl2 
c Give one use of ClF3.
OR
a Give one use of liquid Sulphur Dioxide
b Draw the structure and also state the hybridization of central atom.
1 H2 SO5
2 XeO3
c Complete the following –
l2 + HNO3 (con) 
Al + O2 
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243

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CHEMISTRY (Class XII)

6. General principles and processes of Isolation of Elements 77

8. d- and f- Block Elements 109

9. Coordination Compounds 117

10. Haloalkanes and Haloarenes 132

11. Alcohols Phenols and Ethers 150

12. Aldehydes Ketones and Carboxylic acids 167

13. Amines Organic Compounds containing Nitrogen 183

14. Biomolecules 202

15. Polymers 214

16. Chemistry in Everyday life 227

1. What are fluids? Give examples. [1]

2. Solids are rigid why? [1]

3. How are solids classified? [1]

4. Define the term amorphous with example. [1]

6. The stability of a crystal is reflected in the magnitude of its melting

7. Graphite is soft and good conductor of electricity. Explain.

9. Differentiate between amorphous and crystalline solids with reference to

Topic: Solids and their classification.

Property Crystalline solids Amorphous solids

1. Melting point They have sharp melting They have a range of

3. Nature They are true solids. They are pseudo solids or

Ans 10: Classification of crystalline solids.

1. Molecular solids: The forces operating between molecules are dispersion or

2. Ionic solids: The intermolecular forces are coulomibic or electrostatic forces,

Topic: Structures of crystals

1. Define the term: Crystal lattice [1]

2. What is a unit cell? [1]

5. Name three types of cubic unit cells? [1]

(a) FCC structure

(a) At the corner of the cube.

Topic: Structures of crystals

Ans 01: The three dimensional diagrammatic representation of constituent particles, in

Ans 03: Axial angles,       900 and edge lengths a = b = c.

Ans 04: Tetragonal crystal system – white tin, SnO2.

Ans 06: (a) FCC = 4 (b) BCC = 2

Topic – Packing in crystals

1. What is square close packing? [1]

2. What is the coordination number in :- [1]

(a) Square close packing (b) Hexagonal close packing.

3. Define – (a) void (b) coordination Number [2]

4. What is the packing efficiency in [3]

g/cm3 at 20o C. calculate the length of the unit cell.

density is 7.2 glcm3, calculate the atomic mass of the element.

tetrahedral voids. What is the formula of the compound?

What is the formula of solid?

Ans 02: (a) in square close packing, the coordination no. is 4.

Ans 04: (a) hcp packing efficiency is 74%.

Ans 05: Density, d of a cubic cell is given by –

Where Z = no. of atoms per unit cell

Ans 06: 361.6 pm

Ans 07: 52 g/ mol

Ans 08: 5.22 g/cm3

Ans 09: Let the no. of B ions = 100

Topic – imperfections in crystals

1. What is the meaning of term ‘defect’ with reference to crystal? [1]

2. Define two main types of defects. [2]

3. Name the types of point defect. [1]

4. (a) Identify the defect in figure below : [2]

6. Excess of lithium makes LiCl crystal pink. Explain. [2]