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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier
Commercial Product Name : Methanol
REACH Registration Number : 01-2119433307-44-0031 (EU) ; 01-2119433307-44-0030 (UK)
EC No : 200-659-6
CAS No. : 67-56-1
1.2. Relevant identified uses of the substance or mixture and uses advised against
Specific use(s) : Solvent
Industrial
1.3. Details of the supplier of the safety data sheet
Company : Methanex Europe S.A.
Waterloo Office Park - Building N - Drève Richelle 161 - box 31
B-1410
Waterloo, Belgium

Tel.:(32) 2 352 03 70
Fax:(32) 2 352 06 99

1.4. Emergency telephone number

Emergency telephone : +32 14 58 45 45
Brandweer informatiecentrum voor gevaarlijke stoffen (B.I.G.)
Technische Schoolstraat 43 A, B-2440 Geel (7d/24h)

Country Official advisory body Address Emergency number

IRELAND (REPUBLIC National Poisons Information Centre Beaumont Hospital +353 1 8379964
OF) Beaumont Hospital Beaumont Road
9Dublin
UNITED KINGDOM National Poisons Information Service Dudley Road 0870 600 6266 (UK only)
(Birmingham Centre) B18 7QHBirmingham
City Hospital

2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
2.1.1. Classification according to Regulation (EU) 1272/2008
CLP-Classification : The product is classified as hazardous in accordance with Directive
1272/2008/EEC.
Acute Tox. 3 (Inhalation:vapour) H331
Acute Tox. 3 (Dermal) H311
Acute Tox. 3 (Oral) H301
STOT SE 1 H370
Flam. Liq. 2 H225

Full text of H-phrases: see section 16.

2.1.2. Classification according to EU Directives 67/548/EEC or 1999/45/EC

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Classification : The product is classified as dangerous in accordance with Directive

67/548/EEC.
F; R11
T; R23/24/25
T; R39/23/24/25

Full text of R-phrases: see section 16.

2.2 Label elements

2.2.1. Labelling according to Regulation (EU) 1272/2008
CLP pictograms :

GHS02 GHS06 GHS08

Signal word : Danger
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H301 - Toxic if swallowed.
H311 - Toxic in contact with skin.
H331 - Toxic if inhaled.
H370 - Causes damage to organs
Precautionary statements (CLP) : P270 - Do no eat, drink or smoke when using this product
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 - If swallowed, immediately call a doctor.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P307+P311 - IF exposed: Call a POISON CENTER or doctor/physician
P405 - Store locked up
2.2.2. Labelling according to Directives (67/548/EEC - 1999/45/EC)
Not relevant

2.3. Other hazards

other hazards which do not result in :
classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
Substance name Product identifier % Classification according to
Directive 67/548/EEC
methanol (CAS No.) 67-56-1 <= 99,85 F; R11
(EC No) 200-659-6 T; R23/24/25-39/23/24/25
(EC Index) 603-001-00-X
Substance name Product identifier % Classification according to
Regulation (EC) No.
1272/2008 [CLP]
methanol (CAS No.) 67-56-1 <= 99,85 Flam. Liq. 2, H225
(EC No) 200-659-6 Acute Tox. 3 (Dermal), H311
(EC Index) 603-001-00-X Acute Tox. 3 (Inhalation), H331
Acute Tox. 3 (Oral), H301
STOT SE 1, H370

Full text of R-, H- and EUH-phrases: see section 16.

3.2. Mixtures
Not applicable
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4. FIRST AID MEASURES

4.1. Description of first aid measures
First aid measures : Immediate medical attention is required.
Inhalation : Keep at rest.
Move to fresh air.
Oxygen or artificial respiration if needed.
Call a physician immediately.
Skin contact : After contact with skin, wash immediately with plenty of soap and water.
Take off contaminated clothing and shoes immediately.
Wash contaminated clothing before re-use.
Obtain medical attention.
Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes.
Consult a physician.
Ingestion : Drink plenty of water.
Call a physician immediately.
Additional advice : Never give anything by mouth to an unconscious person.
Show this safety data sheet to the doctor in attendance.
Treat symptomatically.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation : Toxic by inhalation. Possible effects include headache, dizziness, cramp,
unconsciousness and death. Nausea Vomiting Blindness Toxic: danger
of very serious irreversible effects through inhalation.
Skin contact : Toxic in contact with skin. Toxic: danger of very serious irreversible
effects in contact with skin.
Eye contact : May be irritating.
Ingestion : Toxic if swallowed. Possible effects include headache, dizziness, cramp,
unconsciousness and death. Nausea Vomiting Blindness Toxic: danger
of very serious irreversible effects if swallowed.

4.3. Indication of immediate medical attention and special treatment needed

Treatment : Contact a poison control centre.

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media : Use dry chemical, CO2, water spray or alcohol resistant foam.
Extinguishing media which shall not be used : High volume water jet
for safety reasons
5.2. Special hazards arising from the substance or mixture
Fire Hazard : Highly flammable.
Specific hazards : Vapours may form explosive mixtures with air. Evacuate personnel to safe
areas. Burning produces noxious and toxic fumes. Possible
decomposition products are: Formaldehyde Carbon oxides Vapours are
heavier than air and may spread along floors. Flash back possible over
considerable distance. The pressure in sealed containers can increase
under the influence of heat. Cool containers / tanks with water spray. Fire
residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
5.3. Advice for firefighters
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Special protective equipment for fire-fighters : Wear personal protective equipment. In the event of fire, wear self-
contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel : Wear personal protective equipment. See also section 8. Evacuate
personnel to safe areas. Avoid contact with skin, eyes and clothing. Do not
breathe vapours or spray mist. Ensure adequate ventilation. Keep away from
open flames, hot surfaces and sources of ignition. Ensure all equipment is
electrically grounded before beginning transfer operations. Do not smoke.

6.2. Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.
6.3. Methods and materials for containment and cleaning up
Methods for cleaning up : Remove all sources of ignition. Do not use sparking tools. Prevent further
leakage or spillage if safe to do so. Dam up. Soak up with inert absorbent
material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep
up and shovel into suitable containers for disposal. Dispose of in accordance
with local regulations.
6.4. Reference to other sections

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
Handling : Wear personal protective equipment. See also section 8. Avoid contact with
skin, eyes and clothing. Do not breathe vapours or spray mist. Do not burn,
or use a cutting torch on, the empty drum. Ensure all equipment is
electrically grounded before beginning transfer operations. Always replace
cap after use. Keep away from open flames, hot surfaces and sources of
ignition. Do not smoke. Ensure adequate ventilation. Do not puncture or
incinerate. Use only explosion-proof equipment.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Eye
wash bottle with pure water Use only in an area equipped with a safety
shower. Wash hands before breaks and immediately after handling the
product.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Do not store near or with any of the incompatible materials listed in section
10. Keep away from open flames, hot surfaces and sources of ignition. Keep
containers tightly closed in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
Specific use(s) : Solvent Industrial

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Component : methanol (67-56-1)

TLV-TWA (ppm) : 200 (PT)
TLV-TWA (mg/m³) : 260 (DK, LV, LU, SK, SI, CH, NL, FR, AT, LT, EL, HU, HR, EE, SE); 266 (BE, ES,
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UK); 50 (BU); 250 (CZ); 270 (DE, FI); 100 (PL); 130 (NO); 133 (NL)
TLV-STEL (ppm) : 250 (PT)
TLV-STEL (mg/m³) : 325 (EL) ; 330 (FI) ; 333 (BE, UK); 350 (SE, EE); 520 (NL); 1040 (CH, AT); 1000 (CZ);
1300 (FR); 300 (PL) ; 1040 (HU); 1080 (DE)

DNEL : 40 mg/kg bw/day Dermal exposure

260 mg/m³ Inhalation exposure
Workers
8 mg/kg bw/day Dermal exposure
50 mg/m³ Inhalation exposure
Consumers
PNEC : 570,4 mg/kg Sediment
23,5 mg/kg Soil
100 mg/l STP
154 mg/l Fresh water
15,4 mg/l Marine water
8.2. Exposure controls
Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment.
Respirator with a half face mask (EN 140) Full face mask (EN 136)
Recommended Filter type: (A - EN 141)
Hand protection : Nitrile rubber , Polyvinyl alcohol , Neoprene gloves . ( EN374 ) The selection
of specific gloves for a specific application and time of use in a working area,
should also take into account other factors on the working space, such as
(but not limited to): other chemicals that are possibly used, physical
requirements (protection against cutting/drilling, skill, thermal protection),
and the instructions/specification of the supplier of gloves.
Eye protection : Safety glasses with side-shields , Goggles . ( EN 166 )
Skin and body protection : Overalls, apron and boots recommended.
Engineering measures : Ensure adequate ventilation. Use with local exhaust ventilation.
Environmental exposure controls : Do not flush into surface water or sanitary sewer system.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Appearance : liquid
Colour : colourless
Odour : characteristic
pH : No data available
Melting point/range : -97,8 °C
Boiling point/boiling range : 64,7 °C
Flash point : 11 °C (1013 hPa)
Evaporation rate : No data available
Explosion limits :
Vapour pressure : 169,27 hPa (25°C)
Vapour density : No data available
Density : ca 0,792 g/cm³ (20°C)
Relative density : 0,79- 0,8
Water solubility : Miscible
Partition coefficient: n-octanol/water : -0,77
Autoignition temperature : 455 °C (1013 hPa)
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Decomposition temperature : Not applicable

Viscosity : 0,544- 0,59 (25 °C)
Explosive properties : not applicable
Oxidizing properties : Not applicable

9.2. Other information

Molecular Weight : 32

10. STABILITY AND REACTIVITY

10.1. Reactivity
Reactivity : Flammable liquid
See also section 10.5
10.2. Chemical stability
Stability : Stable under normal conditions.
10.3. Possibility of hazardous reactions
No data available
10.4. Conditions to avoid
Conditions to avoid : Heat, flames and sparks.
10.5. Incompatible materials
Incompatible materials : Incompatible with strong acids and oxidizing agents.
10.6. Hazardous decomposition products
Hazardous decomposition products : Burning produces noxious and toxic fumes. Carbon oxides Formaldehyde

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity : Toxic if inhaled. Toxic in contact with skin. Toxic if swallowed.
Methanol(67-56-1)
ATE (oral) 100,000 mg/kg
ATE (dermal) 300,000 mg/kg

methanol (67-56-1)
LD50/oral/rat 1187- 2769 mg/kg
LD50/dermal/rabbit 17000 mg/kg
LC50/inhalation/4h/rat 128,2 mg/l/4h

Skin corrosion/irritation : Not classified (Not classified due to data which are conclusive although insufficient
for classification.)
pH: No data available

Serious eye damage/irritation : Not classified (Not classified due to data which are conclusive although insufficient
for classification.)
pH: No data available

Respiratory or skin sensitisation : Not classified (Not classified due to data which are conclusive although insufficient
for classification.)
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Germ cell mutagenicity : Not classified (Not classified due to data which are conclusive although insufficient
for classification.)

Carcinogenicity : Not classified (Not classified due to data which are conclusive although insufficient
for classification.)

Reproductive toxicity : Not classified (Not classified due to data which are conclusive although insufficient
for classification.)

Specific target organ toxicity (single : Causes damage to organs.

exposure)

Specific target organ toxicity (repeated : Not classified (Not classified due to data which are conclusive although insufficient
exposure) for classification.)

Aspiration hazard : Not classified (Not classified due to data which are conclusive although insufficient
for classification.)

Further information

12. ECOLOGICAL INFORMATION

12.1. Toxicity
Component : methanol (67-56-1)
LC50/96h/fish : 15400 -29400 mg/l
EC50/48h/daphnia : > 10000 mg/l
IC50/72h/algae : ca. 22000 mg/l Selenastrum carpricornutum (Pseudokichnerela subcapitata)

12.2. Persistence and degradability

Persistence and degradability : Readily biodegradable
12.3. Bioaccumulative potential
Bioaccumulation : Does not bioaccumulate
Partition coefficient: n-octanol/water : -0,77

12.4. Mobility in soil

Mobility : Mobile in soils
12.5.Results of PBT and vPvB assessment
PBT/vPvB : This substance is not considered to be persistent, bioaccumulating nor toxic
(PBT).,This substance is not considered to be very persistent nor very
bioaccumulating (vPvB).
12.6. Other adverse effects
Further information : Do not flush into surface water or sanitary sewer system.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Waste from residues / unused products : Dispose of in accordance with local regulations.
Additional ecological information : Do not flush into surface water or sanitary sewer system.
Codes of waste (2001/573/EC, 75/442/EEC, : The following Waste Codes are only suggestions: 07 01 04* - other
91/689/EEC) organic solvents, washing liquids and mother liquors 15 01 10* -
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packaging containing residues of or contaminated by dangerous

substances Waste codes should be assigned by the user based on
the application for which the product was used.

14. TRANSPORT INFORMATION

14.1. UN Number
UN-No. : 1230

14.2. UN proper shipping name

Proper shipping name : METHANOL

Proper shipping name IATA/IMDG : METHANOL

14.3. Transport hazard class(es)
14.3.1. Overland transport
Class : 3-0
Hazard identification number (Kemler No.) : 336
Classification code : FT1
ADR/RID-Labels : 3 - Flammable liquid
6.1 - Toxic substance

Orange plates :

Tunnel restriction code : D/E

Limited quantities (ADR) : LQ00
Excepted quantities (ADR) : E2

14.3.2. Inland waterway transport (ADN/ADNR)

Class (ADNR) : 3

14.3.3. Transport by sea

Class : 3
Limited quantities (IMDG) : 1L
EmS : F-E, S-D

14.3.4. Air transport

Class : 3
Subsidiary Class : 6.1

14.4. Packing group

Packing group : II

14.5. Environmental hazards

Other information : No supplementary information available.

14.6. Special precautions for users

No data available
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No data available

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No data available
15.1.2. National regulations
WGK : 1

15.2. Chemical Safety Assessment

Chemical Safety Assessment : A Chemical Safety Assessment has been carried out for this substance.

16. OTHER INFORMATION

Text of R phrases mentioned in Section 3 : R11 -Highly flammable.
R23/24/25 -Toxic by inhalation, in contact with skin and if
swallowed.
R39/23/24/25 -Toxic: danger of very serious irreversible
effects through inhalation, in contact with skin and if
swallowed.

Full text of H-Statements referred to under sections 2 and : H225 -Highly flammable liquid and vapour.
3. H301 -Toxic if swallowed.
H311 -Toxic in contact with skin.
H331 -Toxic if inhaled.
H370 -Causes damage to organs

Sources of key data used to compile the datasheet : http://ecb.jrc.it

Chemical Safety Report

Abbreviations and acronyms : CSR = Chemical Safety Report

DNEL = Derived No Effect Level
LD50 = Median lethal dose
N.O.S. = Not Otherwise Specified
PNEC = Predicted No Effect Concentration
STEL = Short term exposure limit
TLV = Threshold limits
TWA = time weighted average
ADNR = Accord Européen relatif au Transport International des
Marchandises Dangereuses par voie de Navigation du Rhin
ADR = Accord européen relatif au transport international des marchandises
Dangereuses par Route
CLP = Classification, Labelling and Packaging Regulation according to
1272/2008/EC
IATA = International Air Transport Association
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IMDG = International Maritime Dangerous Goods Code

LEL = Lower Explosive Limit/Lower Explosion Limit
UEL = Upper Explosion Limit/Upper Explosive Limit
REACH = Registration, Evaluation, Authorisation and Restriction of
Chemicals
PBT = Persistent Bioaccumulative Toxic
vPvB = very Persistent and very Bioaccumulative

The contents and format of this SDS are in accordance with EEC Commission Directive 1999/45/EC, 67/548/EC,
1272/2008/EC and EEC Commission Regulation 1907/2006/EC (REACH) Annex II.

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only
for this product. If the product is used as a component in another product, this SDS information may not be applicable.