@ ERA Reference Material AWitnetoapend « Certificate of Analysis = Product: Wat™ Pollution Total Cyanide Catalog Number: 502 Lot No. 280-502 ari ts oe tid spt Certificate Issue Date: July 18, 2018 separately rom ths Corcate of Analysis. Please Expiration Date: February 28, 2021 Em, Revision Number: Original CERTIFICATION Certified QC Performance PT Performance Parameter Value? Uncertainty? Acceptance Limits? Acceptance Limits* mit * mat mot Phenol 0.868 0.408 0.651 - 1.08 : Cyanide, total 0.852 4.38 0.652 - 1.04 0.554 - 1.15 ‘Amenable Cyanide 0.410 40.1 0.232 - 0.631 0.266 - 0.554 ANALYTICAL VERIFICATION Certified Parameter Value" Proficiency Testing Study NIST Traceability Mean Recovery’ n © SRMNumber Recovery mot mot * * Phenol 0.868 - : - : : Cyanide, total 0.852 0.850 99.8 26 - : ‘Amenable Cyanide 0.410 0.400 976 5 : : Page 1 of 2 Lot: P280-502 800.372.0122 + 303.431.8454» www.eragc.com 16341 Table Mountain Pkwy « Golden, CO 80403 +Reference Material * Certificate of Analysis = 1. The Certitied Values ae the actual "made-o" concontrations confirmed by ERA analytical verification, The certhied values are monitored and purchasers il be noted of any signfcant changes resulng in recertification or wihdraval of his catfied reference material Guring tne period o vay of tis corteate 2. The Uncertainty is the otal propagated uncertainty atthe 95% confidence interval. The uncertainty is based on the reparation and intemal analytical \vorteation ofthe product by ERA, multiplied by a coverage factor. The uncertainty apples to the product supplied and does not take into account any quired or optional dluton and/or preparations the laboratory may perform while sing this produc. 3. The QC Performance Acceptance Limits (QC PALS are based on actual historical data collected in ERAS Proficiency Testing program. The QC PALS™ reflect any inherent biases inthe metnods usod o establish the limits and closely aporoximata a 95% confidence Inirva of the performance that ‘experiences laboratories should achieve using accepted environmental methods. Use the GC PAL™ to realstealy evaluate your performance agaist YOU" peers 4. Tha PT Performance Acceptance Limits (PT PALs™) are calclatd using the regression equations and fixed acceptance eeriaspecied inthe INELAC proficiency testing requirements. Use the PT PALS™ when analyzing this GC standard alongsige USEPA and NELAC compliant PT standards Please note that many PT study acceptance limits are concentration dependent (some non-inealy and, therefore, the acceptance imi of tis GC Standard and ary PT standard may der relative to their diference in concentrations, 5. The PT Data/Traceabilty data include the mean value, porcant recovery and number af datapoints reported by the laboratories in our Proficiency ‘Testing study compared the Certified Values. in additon, where NIST Standard Reference Materials (SAMs) are avaiable, each analyte ras beer analytcaly vaced 'o the NST SRM Isted. This products traceable tothe lt numbers ofits staring materials. All gravmetrc and volumetre measurements relatad tos manulactue ae vaceable to NIST through an unbroken chain of comparisons, ‘Traceability Recovery (%) = [(% rocovery cart standera)(%e recovery NIST SAM))"100 ‘The raceabity data show: were compiled by analyzing the ERA standards or ther associated stock solutions against the applicable NIST SAMs. 6. For adcitonal nformaten on tis preduct suchas intended use, instructions for provided Instueion Sheet level of homogeneity, and safety information, please reler othe If you have any questions or need technical assistance, please call ERA technical assistance at 1-800-372-0122 or send an email to [email protected]. Certitying Officer Quality Officer Brian Miller Matthew Seebeck Beinn Molla Jud hie Page 2 of 2 Lot: P280-502 16341 Table Mountain Pkwy + Golden, CO 80403 + T: 800.372.0122 + 303.431.8454 + www.eragc.comERA @ ‘AWaters Company Instructions for Catalog # 502 Cyanide & Phenol Revision 030512 Description: «This standard is packaged in a 15 mL screw-top vial cont ing approximately 14 mL of standard concentrate. ‘This concentrate is preserved with approximately 0.2% (w/v) sodium hydroxide. ‘+ The concentrate can be stored at room temperature. © This product is intended to be used as a quality control check of the entire analytical process for the analytes/matrix included in the standard. + The cilution instructions below represent the minimum suggested sample size for this product. Using a smaller sample size may invalidate the assigned value and/or uncertainty shown on the certificate of analysis. Helpful Hints: This standard has been prepared as a concentrate and must be diluted prior to analysis © As the USEPA Criteria Document requires that cyanide be present in a complex form, the diluted standard mustbe analyzed for total eyanide. * This standard should be analyzed as soon as possible after the concentrate is diluted. Instructions: 1, Add 100-200 mL of deionized water and approximately 1 to 2 mL of 50% sodium hydroxide to a clean 1000 mL class A volumetric flask. 2. Shake the Cyanide & Phenol vial prior to opening 3. Using a clean, dry, class A pipet, volumetrically pipet 5.0 mL of the concentrate into the 1000 mL volumetric flask. 4, Dilute the flask to final volume with deionized water. 5. Cap the flask and mix well 6. Immediately analyze the diluted sample by your normal procedures. 7. Report your results as mg/L for the diluted sample, Safety: ERA products may be hazardous and are intended for use by professional laboratory personnel trained in the competent handling of such materials. Responsibility for the safe use of these products rests entirely with the ‘buyer and/or user, Material Safety Data Sheets (MSDS) for all ERA products are available by calling 1-800-372- 0122.@ ERA SAFETY DATA SHEET Issuing Date 12-0ct-2015 Revision Date 12-Oct-2015 Rovision Number 1 1, IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Number 502 Product Name Cyanide & Phenol, WastoWatR™ ‘Synonyms: None Recommended use of the chemical and restrictions on use. Recommended Use ‘Laboratory use only Uses advised against [No information available Dotails of the supplier of the safety data shoot ERA a Waters Company ‘Address 116341 Table Mountain Parkway, Golden, CO 80403 USA srgency Telephone Number +1-303-431-8454 ‘Supplier Email ‘[email protected] Emergency telephone number. Company Emergency Phone In case of EMERGENCY call CHEMTREC Day or Night Number Within USA and Canada: 800-424-9300 International Call Collect: +1-703-527-3887 ___ 2. HAZARDS IDENTIFICATION Classification ‘This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). [Skin corrosionimntation [Category 1 [Serious eye damage/eye iritation [Category SHS Label elements, including precautionary statements Emergency Overview signal word Danger lazard Statements uses severe skin bums and eye damage Appearance Clear, coloress Physical state Liquid->Liquic Odor Odorie Precautionary Statements - Prevention Do not breathe dustifume!gas/mistvapors/spray Wash face, hands and any exposed skin thoroughiy after handling ‘Wear protective gloves/protective ciothingleye protection/face protection Precautionary Statements - Response Immediately calla POISON CENTER or doctor/physician Speeific treatment (see supplemental fist aid instructions on this label) Page 1/9502- Cyanide & Phenol, WasteWatR™ Revision Date 12.00.2015 Eyes IF IN EYES: Rirse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately cal a POISON CENTER or doctor/physician Skin IF ON SKIN (orhair): Remove/Take off immediately all contaminated clothing. Rinse skin with waterishower ‘Wash contaminated clothing before reuse Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately cal a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Rinse mouth. DO NOT induce vomiting Precautionary Statements - Storage. Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity (0% of the mixture consists of ingredients) of unknown toxicity, Other informaton No information available interactions with Other Chemicals 'No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS. "Note: ony the components contributing to the products GHS hazard classification are listed inthis section ‘The product cortains no substances which at their given concentration, are considered to be hazardous to health [Chemical Name. CAS-No. Percent dium Hydroxide 1310-73-2 02, FIRST AID MEASURES | First ald measures: General Advice Immediate medical attention is required. Show this safely data sheet to the doctor in attendance. Eye contact, Rinse immediately wit plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention/advice. Skin contact ‘Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek immediate medical attention/advice. Inhalation Remove to fresh ar. If breathing has slopped, give artifical respiration. Get medical attention immediately. Do not use mouth-fo-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way ‘valve or other proper respiratory medical device. If breathing is ciicul, (rained personnel should) give oxygen. Delayed pulmonary edema may occur. Get medical attention immediately if symptoms occur. Ingestion Do NOT induce vomiting. Rinse mouth immediately and drink plenty of waler. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Self-protection ofthe first alder _Ensuro that medical personnel are aware of the materil(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing (see section 8), Page 2/9502- Cyanide & Phenol, WasteWatR™ Revision Date 12-Oct-2015 cls, both acute and del Most important Symptoms and Burning sensation, Effects indication of any immediate medical attention and special treatment needed Notes to Physician Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give ‘chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. 5. FIRE-FIGHTING MEASURES. ‘Suitable Extinguishing Media Use extinguishng measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extir CAUTION: Use of water spray when fighting fire may be inefficient. ‘Specific hazards arising from the chemical ‘The product causes bums of eyes, skin and mucous membranes. Thermal decomposition can lead to release of iitating gases and vapors. Uniform Fire Code Corrosive: Other-Liquid Hazardous Combustion Products Carbon oxides Explosi Sensitivity to Mechanical Impact No, Sensitivity to Static Discharge No, Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHAINIOSH (approved or equivalent) and full protective gear. ACCIDENTAL RELEASE MEASURES. Personal precaution: m mergency procedures Personal precautions ‘Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spillleak. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental precautions. Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage If safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoll. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up ‘Soak up with inert absorbent material Pick up and transfer to properly labeled containers. Page 3/9502+ Cyanide & Phenol, WasteWatR™ vision Date 12-0c1-2015 7. HANDLING AND STORAGE = eee Precautions fo: si Handling Handi in accordance wth good industalhyglene and safety practice. Avoid contact with skin eyes or cething.n case of isufcient vetlaton, wear suitable respiratory equipment Use only wih adequate ventlaion and in closed systems. Do not cat, drink or smoke when using this product. Tako off contaminated clothing and wash before reuse Conditions for safe storage, including any incompatibilities Storage Keep containers ight closed in a dry, cool and wel-ventlated pace, Protect rom moisture, Stora locked up. Keop out ofthe reach of chdren. Sore away from oer mates. Incompatible Products ‘aids. Bases. Oxidizing agent. 8, EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters: Exposure Guldetines ‘This product as supplied, does not contin any hazardous materials wih occupational exposure limits established by the region speci regulator bodies honed Name ACGIH TLV OSHA PEL MOSHIOLE Son yeas Caing 2a Twa? moi DUE TO mom 10732 (vacate) Gang? gine Ceiing!2 mgm? Appropriate engineering controls Showers Eyewash stations Ventilation systems ct Eyalface protection Face protection shield Skin and body protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant apron. Impervious gloves. Respiratory protection No protective equipment is needed under normal use condos. if exposure iis are ‘exceeded or irtation is experienced, ventilation and evacuation may be required. Hyglone Measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eyertace protection, Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. For environmental protection, remove and wash all Contaminated protective equipment before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES. hy ties Physical state Liquid Liquid ‘Appearance Clear, coloriess Odor Odoriess Color No information available Odor Threshold No information available Property. pH a7 Melting / freezing point ‘no data available None known Boiling point / boiling range ‘no data available None known Flash Point no data available None known Evaporation Rate ‘no data available None known Flammability (solid, gas) ‘no data available None known Flammability Limit in Air None known Upper flammability limit no data available Page 4/9502- Cyanide & Phenol, WasteWath™ Rovision Date 12-00-2015 Lower flammability limit, no data available Vapor pressure 1 data available None known Vapor density ‘no data available None known Specific Gravity 1 None known Water Solubility Soluble in wator None known ‘Solubility in other solvents 1 data available None known Partition coefficient: n-octanoliwaterno jlable None known Autoignition temperature ‘no data available None known Decomposition tomperature no data available "None known Kinematic viscosity no data available None known Dynamic viscosity no data available None known Explosive properties Oxidizing properties Other Information Softening Point no data available no data available no data available 40. STABILITY AND REACTIVITY no data avaiable. ‘Ghemical stability Stable under recommended storage conditions. None under normal processing Hazardous Pelymerization Hazardous polymerization does not occur. Conditions toavold Exposure to air or moisture over prolonged periods. Incompatible materials ‘Acids. Bases. Oxidizing agent. Carbon oxides. 41. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Eye contact, ‘Skin contact Ingestion ‘Specific test data for the substance or mixture is not available. Corrosive by inhalation. (based on components). Inhalation of corrosive fumes/gases may cause coughing, choking, headache, dizziness, and weakness for several hours, Pulmonary edema may occur with tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and Increased heart rate. inhaled corrosive substances can lead to a toxic edema ofthe lungs. Pulmonary edema can be fatal. May cause irritation of respiratory tract. ‘Specific test data forthe substance or mixture is not available, Causes burs. (based on ‘components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes. ‘Specific test data for the substance or mixture is not available. May cause iriation, Prolonged contact may cause redness and irtation. ‘Specific test data for the substance or mixture is not available. Causes burns. (based on ‘components). Ingestion causes buns of the upper digestive and respiratory tracts. May ‘cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the ‘mouth. Swelling ofthe throat may cause shortness of breath and choking. May cause lung damage if swallowed. May be fatal f swallowed and enters airways. Ingestion may cause intation to mucous membranes. Ingestion may cause gastrointestinal iritation, nausea, Page 5/9Revision Date 12-Oct-2015, vomiting and diarrhea. ‘Component information (Groniea Name ‘Oral WED Dermal (DSO Tnalation LO ‘odum Hygroxde i 7350 mpg ( RabDED 110-73-2 Information on toxicological effects ‘Buming. May cause blindness. Coughing andi or wheezing. iLas chronic sure No information available, Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. TARC (international Agency for Research on Cancer) (Group 3 - Nol Classifabie as 9 Carcinegenicy in Humans. Reproductive toxicity No information available, STOT - single exposure No information available, STOT - repeated exposure No information available, Chronic toxicity No known effect based on information supplied. Chronic exposure to corrosive fumes/gases: may cause erosion ofthe teeth followed by jaw necrosis. Bronchial iitation with chronic ‘cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Carcinogenic potential is unknown, Target Organ Effects Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Aspiration Hazard No information availabe, ‘Numerical measures of toxicity Product Information ‘The following values are calculated based on chapter 3.1 of the GHS document ATEmix (Inhalation-dustimist) 501.00 mg/L ATEmix (inhalation-vapor) 3,000.00 ATEmix 12. ECOLOGICAL INFORMATION ‘otoxici Harmful to aquatic if. ‘Chemical Name Toxicity to Algae Toxicity to Fish Toxiety to Daphnia Magna (Water Microorganisms Flea) ‘Sodium Fyeroxide ‘Goh LCBO: = 45.4 mele 1310-732 {Oncorrynchus mykiss) Persistence and Degradability No information available. Bioaccumulation No information available Other adverse effects No information available. Page 6/9502- Cyanide & Phenol, WasteWatR™ Revision Date 12-0ct2015, 43. DISPOSAL CONSIDERATIONS: method Disposal methods ‘This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261), Contaminated Packaging Dispose of contents/containers in accordance with local regulations. US EPA Wasts Number oo2 California Hazardous Waste Codes _122 ‘Chemical Name ‘Calfornia Hazardous Waste Sodium Hycroxds Toxic 4310-732 corrosive 44. TRANSPORT INFORMATION. por ‘Not regulated Proper Shipping Name NON REGULATED Hazard Class. NA Tos Not regulated MEX Not regulated Icao. Not regulated IATA Not regulated Proper Shipping Name NON REGULATED, Special Provisions None imps Not regulated ‘Special Provisions None Marine Pollutant Not applicable RID, Not regulated Special Provisions None ADR. Not regulated Special Provisions None ‘ADN Not regulated e 15, REGULATORY INFORMATION International Inventori TSCA, Complies pst. Al components are listed either on the DSL or NDSL. ENCS Contact supplier for inventory compliance status KECL Contact supplier for inventory compliance status Piccs Contact supplier for inventory compliance status Alcs Contact supplier for inventory compliance status TSCA United States Toxic Substances Control Act Section 8(b) Inventory DSLINDSL - Canadian Domestic Substances ListNon- Domestic Substances List EINECSIELINCS - European inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and Now Chemical Substances IECSC ~ China Inventory of Existing Chemical Substances KECL.- Koraan Existing and Evaluated Chemical Substances PICCS - Philippines Invenory of Chemicals and Chemical Substances AICS - Australian Inveniory of Chemical Substances Page 7/9502- Cyanide & Phenol, Ws Revision Date 12-00-2015 US Federal Regulations SARA 313 Section 313 of Tite Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any ‘chemicals which are subject tothe reporting requirements of the Act and Tile 40 of the Code of Federal Regulations, Part 372 SARA 3 Categor ‘Acute Health Hazard Yes Chronic Health Hazard No Fire Hazare No ‘Sudden roloase of pressure hazard No Reactive Hazard No ator Act ‘This product does not contain any substances regul CFR 122.42), 1d as pollutants pursuant tothe Clean Water Act (40 CFR 122.21 and 40 ‘Chemial Name | — GWA Reparaila GWA Tors Paints” GWA- Pari Paania | — GWA“ Fasard Sunmtiee ‘Substances Taian Fras ‘me gorse ‘Tris material, a supplied, das not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and bly Act (CERCLA) (40 CFR 302) or the Superund kensraons and Reauthorization Act (SARA) (4 CFR 355), There may be specie reporting requemants atthe local regional, or state level ortalning to releaes of tha mstral Choma tame Hazardous Subaiances WO —sremely Hazardous Sabana aa mae Sam Tare ae Ra peo aR ere eg uotig tral RO US State Reaulations ition 63 “ris product contains fhe flowing Proposition 65 chemicals US, State Right-to-Know Regulations: Jnternational Regulations Component Tachogea Sats Epon Unie Soften Pyne Tones Gongs a moreso) Canada Wits Hazard Class Not determined 16. OTHER INFORMATION. NFPA Health Hazards 3 Flammability 0 Instability 0 Physical and Chemical Hazards - Hs Health Hazards 3. Flammability 0 Physical Hazard 0 Personal Protection x Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 Issuing Date 12-Oct-2015 Revision Date 12-Oct-2015 Revision Note No information available Disclaimer ‘The information provided inthis Sefety Data Sheet is corect othe best of our knowledge, information and belief at the date of ts publication. The Page 8/9Revision Date 12-00-2015 information giver is designed only as a guidance for safe handling, use, processing, sorage, transportation, disposal and release and isnot to be Conadered a waranty or quay specication. The Information relaies only tothe specic material designated and may not be vals or such ‘atonal used io combination with any oer matera's orn any process, unless specified in the text The supplier identified below generated this SDS using he UL SOS template, UL didnot test, crt, or approve the substance described in tis S08, and a information inthis SOS was provided by the supplier or was reproduced trom publically avaiable regulatory data souroos. ‘UL makes no representations or warranties regarding the comleteness of accuracy of he information inthis SDS and disclaims all ability in connection withthe use ofthis information or the substance described in his SDS. The layout, appearance and format ofthis SDS is © 2014 UL -LC. Allrightsresorvod End of Safety Data Sheet Page 9/9PtrS HOE ana ata Seton ta bet once bot Isannes sevsragoned sepals este aio bre tangas oi eos vinane sanceie a anare o bse SIob UL ald ‘ote aie Pace aed Deamon ana ‘Puse te 202 ert osm orb @ gusoN 2p heme is manswecacn Jaye! PB et BS wh orias B02 we nates mes ile ro seg ac ey! gb: at OOF ante bese tas ee oe Se rad GM gacoen eaten Wo MNES geoige a se Ay Mou gee aw oer i anc BEI hss” demain Sayin sth 2 tnd ylotee Yo bas 1 | |