Etp Leather Garment PDF
Etp Leather Garment PDF
Etp Leather Garment PDF
in Leather Garments
Course Material
garment industry
7. Pattern designing 42
8. Pattern grading 55
9. Garment cutting 77
2
CHAPTER 1
3
UNIT OPERATIONS IN LEATHER PROCESSING
Veg. tanning
E.I. Leathers Wet Blue
Stripping & souring Retanning
Dyeing &
Fatliquoring
Finishing
FINISHED LEATHERS
4
PHYSICAL TESTING REQUIREMENTS
Clothing Glove
Max ash (%) 2 2
5
% Cr2O3 (min) 2.5 2.5- - -
- Glazing
- Plating
- Printing
- Roller coating
- Finiflex
- Ironing
- Spraying
6
FINISHING
Resin Glaze
(Aniline)
(Protein)
Chrome Tanning:
Tanning:
Combination tannages:
7
Bleaching of chrome leathers
1. Removal of some surface chromium
1. Use of oxalic acid, sod. oxalate or EDTA and its salts for removal of
chromium (2% agent is used)
2. Use of white syntans of good light fastness and tanning properties. (10 –
20% of a liquid product for 1 hr)
100% Water
2% Oxalic acid
10% Light fast white liquid syntan – 1hr washing twice;
neutralisation to pH 6.0
100% Water 650C
3% Synthetic fatliquor
1% Tio2
0.25% Optical bleach
5.0% White Talcum powder (5 m) 1 hr
8
POST TANNING PROCESS
- Rechroming - Stripping
- Neutralisation - Souring
- Retanning - Chrome tanning
- Dyeing - Neutralisation
- Fatliquoring - Fatliquoring
- Finishing - Finishing
Neutralisation:
Retanning:
Fatliquoring:
9
Subsequent Operations on Shaved Weight
Neutralisation
1. Washing
400 – 600 % Water 30’, Drain
400% Water 15’, Drain
400% Water 15, Drain
2. Neutralisation
10
pH pH
Classical uppers Softie uppers
Grain 6.0 – 6.5 5.5
Middle 3.6 – 3.8 5.0 – 4.5
Flesh 6.0 – 6.5 5.5
100% Water
Neutralising Agents
11
Retanning
Retanning agents
Basic chromium salts – soft leathers – high quality grain and
suede leathers Basic aluminium salts – pole coloured soft leathers –
bright colour shades – suedes Basic zirconium salts – white leathers
– good scuff resistance – tanning at low pH with masking salts (citric-
lactic) – fixing at pH 6.0 vegetable tannins – dry crust leathers –
condensed tannins such as wattle, mimosa synthetic tannins –
auxiliary, combination and neutral syntans are used at the
commencement of retannage – retannage after dyeing for better
depth in colour.
12
Light Retannage Dt Calf, Kid, sides
Neutralise to pH 4.5 to 5.5
Sorting
* Accurate sorting for substance, grain quality etc.
Samming
13
Splitting & Shaving
Dyeing
14
* Metal complex dyes – medium & pastel shades
* Extensively used in aniline leathers
Basic dye stuffs
FAT LIQUROING
Aim of fatliquoring
* To coat the fibres with oil which reduces the friction coefficient
between the fibres
Mode of attachment
By ionic or polar bonds
Mode of Introduction
15
CHAPTER 2
16
Assortment of Finished Leathers
Leather industry produces a variety of leathers such as upper, sole, lining,
suede garment, grain garment, glove, industrial and sports goods leathers,
The assessment of the leather quality is based on various types of testing and
analysis which differ for different types of leathers.
These tests are
a. visual
b. physical
c. chemical
d. microscopical and
e. bacteriological examination.
Before discussing the assortment procedures for hides and skins and
finished leathers based on selection it is relevant to understand and identify
the defects in hides and skins as they would be the most important criteria
for the purpose.
17
As by-products of meat industry, no special attention is normally
bestowed to improve the quality of hides and skins and hence a tannery has
to make the best use of the available raw material by sorting them out into
various categories depending upon the post & ante mortal defects, structural
and surface characteristics, size, thickness, general appearance of the
hide/skin etc. The hides and skins show variations over the area as well as in
different species and origins.
Selection of raw hides and skins in the trade is cumbersome process and
is done mostly by visual inspection even today because it reveals various
surface defects preset in them. Though this type of selection reveals various
defects to a certain extent, it is not altogether possible to detect all the
18
defects present in hides and skins and the quality of the grain at the raw
stage. Hence a tanner always faces a major problem in the selection of
proper quality raw material for a particular type of leather. This compels the
tanner to resort to selection at various stages of processing such as after
liming, pickling, tanning and at the crust stage.
The hides and skins are classified into different categories according to
their weights and are graded on the basis of their quality. The quality
gradation takes place according to prescribed norms. Variations, how-ever,
exist in these norms in different countries. Unfortunately, no uniform
grading system exists in India today. Gradation according to weight, size and
quality are made by the individual raw hide/skin dealer and the buyer has to
accept the same. Often hides/skins are sold as assorted lots. Some tanners
resort to their own grading of hides and skins, procured from small traders,
as per their requirements. All these practices result in considerable hardship
to many of the tanners and particularly in small scale sector.
The factors of grading of hides and skins are hair, substance and defects
such as deep flay cuts or holes various grain damages caused by parasitic,
viral and helminthic diseases, brand mark, putrefaction etc. Skins/hides free
from all defects and blemishes are classified as primes or I quality, those
having one or two minor defects are classified as Grade 2 and the rest as
19
Grade 3 and Grade 4 which are normally called rejections and double
rejections respectively in the trade.
Goat and sheep skins are generally classified according to their length
(inches) from the tail root to the back of the nack into the following
categories;
Lambs Below 28”
Light 28 to 31”
Medium 32 to 35”
Heavy 36 to 39”
Extra heavy 40” and above
The E.I. skins and kip tannage are classified as “premium”, “semi-
premium”, and “market quality”. The first two classes originate from
individual tanning houses and the market quality goods are selected by the
merchants in leather markets/trade houses from the production of number of
small tanning units. Market quality leather materials vary in colour
according to the local tanning methods adopted. The E.I. skins and kips are
selected and marketed as:
i. Run: seconds and thirds and fourths quality
iv. Rejections
20
Run selection Extra Heavy Heavy Medium Light
Fifths 40 50 40 60
IF (Inferior Fifths) 20 15 15 20
Rejections 25 15 25 10
The wet blue leathers are sorted into usually 3 categories, the first
containing the probable ABC grade, second containing the DEF grade, third
containing GH grade.
21
It is hoped that newer techniques like ultrasonic imaging will help in
better detection of defects although practical application of such techniques
on commercial scale has to be looked into.
22
CHAPTER 3
23
INTRODUCTION to Leather garment industry
Garment industry is the second most important of the leather products sector. A
relatively new entrant into the global trade, leather garment is highly material intensive. It
is also one of the sectors of the leather industry whose export performance in the last 5
years has been very striking.
The low capital investment in terms of machinery for setting up a leather garment
unit, the convenience of locating it as a light industry and the fact that it does not require
a license due to its status as a small-scale unit are all responsible for the growth of this
sector. The Government has exempted the garment sector from excise duty as there is no
intensive nature makes it ideally suited to the Indian situation. Some of the accessories
and components required for this industry are not available in India and hence these are
being imported and due to the recent liberalisation policy, this too has become easier.
The country has a total production capacity of nearly 300,000. The break up of
24
6. Pune 5,000
7. Calcutta 25,000
8. Jallandhar 10,000
9. Kanpur 5,000
10. Dewas 10,000
11. Others 10,000
Total 2,85,000
The leather garments produced in the country are predominantly exported, except
for some negligible quantity that may be sold in the domestic market.
The speciality of global trade in leather garment is that producers are not
consumers and consumers are not producers. Leather garments production is
concentrated in the Asian region. South Korea is the largest exporter of leather garments
in the world. The other important exporters are Turkey, China, India and Pakistan. Trends
indicate that global trade is expected to grow substantially. It is becoming increasingly a
fashion item as well as utility item in the West. The major importing countries and value
of their imports are presented in the following table.
MAJOR IMPORTERS
(in million US $)
USA 1804 28
Germany 1146 18
Japan 944 15
25
France 376 6
UK 296 5
Currently China is the largest producer and exporter of leather garments in the
world. The other major players in the world market of leather garments are Turkey, Italy,
India, Pakistan, Bangladesh, Yugoslavia, etc. Hong Kong is also important but most of
this is re-exported.
Fashion styling and design and development are in its infancy in India. The Indian
leather garment units merely function as “jobbers” for the western market. Following the
footsteps of development of the footwear sector, the garment industry must make efforts
towards indigenous development of designs and styles.
It should be also realised that at present the leather garment production has export
prospects mainly for low priced wastern markets. A proper attention in the areas of
styling, design & development and quality production techniques would definitely
enhance further value addition to this exotic commodity.
26
27
A typical process flow chart for manufacture of leather garments is given below
ASSORTMENT
Sample Making
MATCHING
MARKING
Pattern Grading
Lining cutting CUTTING
FUSING
ASSEMBLY &
Wadding STITCHING
BUTTONING
THREAD
CUTTING
TRIMMING
FINISHING
INSPECTION
PACKING
SHIPPING
27
CHAPTER 4
28
Material needs for Leather garments
1. Accessories
* Waddings
* Fusible
lining
* Sponge
* Zips
* Threads
* Elastic
* Buttons
* Glue
2. Leathers
* Goat
Nappa
* Sheep
Nappa
* Cow Nappa
3. Linings
* Cotton
* Silk
* Synthetic
Materials
29
30
CHAPTER 5
31
Selection of leather for garments
Classification
Garment leathers can be broadly classified into three categories. Viz., Fur
Garment Leather, Grain Garment Leather (Nappa) and Suede Garment Leather.
Fur Garment Leather is generally made from sheep skins with fine wool.
Among Fur Garment Leather, there are two types viz., Hair-on Leather and Double-face
Fur skin leather. In the case of Hair-on, emphasis is given only on Hair/Fur side, special
technique is followed to treat the fur-for softness, lustre, shade, etc. In this case only one
side can be used i.e. Fur side, whereas in the case of Double-face, both sides can be used
i.e. Fur side and Flesh side. On the flesh side, a fine “nap” is raised and dyed in the
desired shade and fur is also dressed. In this cases, dyeing can be done either fur side
alone or flesh side alone or on both sides by using special types of dyes. This category of
garment leathers are not made as much in India as the fine fur bearing sheep are not
available in India. To some extent, somewhat fine hair/wool sheep skins are available in
cold regions like Punjab and Kashmir.
Grain Garment Leather is finished on the grain side either in Glaze Finish or in
Resin Finish. They are usually made from Red hair sheep skins or wool sheep skins.
Sometimes they are also made from goat skins, cow calf, skins, buff calf skins and cow
hides. But the quality will differ from species to species.
32
Suede Garment Leathers are finished on the flesh side by raising “nap” and
dyed in desired shades. These leathers are usually made from hair sheep & wool sheep
skins. Also they are made from goat skins by shaving off the grain.
Normally red hair sheep skins and goat skins are preferred for suede leather
and wool sheep skins for grain clothing leather. Wool sheep skins have a smoother
grain and drape as well. They are also used for suedes of the cheaper variety. However,
they yield a loose nap as evidenced by the wrinkles produced when the leather is folded
flesh side in.
The percentage of tick damaged skins appears to be greater among sheep skins
than in the case of goats. The latter are also economically priced but this is to some
extent, compensated for by the greater area yield of sheep. The dyeing in the case of goat
skins is more uniform and the undertone cleaner.
One method of differentiating wool sheep from red hair sheep is by checking on
the structure of the lower most hips of the butt areas on both sides of the skin. In the case
of the former, those portions are found to be loose and the grain is found moving almost
independently of the corium when the leather is rolled between the fingers.
Yet another feature of the wool sheep is its somewhat coarse necm distinctly
displaying a tendency towards fattiness. In general, the wool skin is softer and looser as
compared to the red hair variety which resembles almost a goat skin except for its softer
and smoother grain. The wool sheep skin has in addition looser flanks.
33
The most important quality requirements for garment leather:
Requirements
Tests
Finished grain leather Aniline, nubuk and suede
leather
Rub fastness Rub cycles Rub cycles
Test felt dry 50 20
Test felt wet 20 10
With perspiration 20 10
solution staining of
the felt – grey scale not below rating not below rating 3
3
Light fastness Min. rating 4 Min rating 3
Flexing endurance Min. 50000 -
Adhesion of finish Min 2.0 N cm -
Split tear strength Min. 200 N cm Min. 150 n cm
Tensile strength 1200 N cm 2 1200 N cm2
Stitch tear strength Min 25 da N cm Min 25 da N cm
Elongation at break Max 60% Max 60%
Wettability 15 minutes 10 minutes
Resistance to dry cleaning No stripping of the finish No change of handle
and no change of handle after cleaning and
after cleaning fatliquoring. Change of
and fatliquoring colour < rating 3-4:
change of colour <rating change of area <=3%
3-4: area
<=3%
Washability No change of leather handle after washing drying and light
staking;
34
Garment Nappa Leather
Term: The term “nappa” is a collective name for all types of soft. Elastic
grain leather. The original nappa leather was manufactured from alum tanned
glove leather by retanning with gambler extract and chrome alum, but later by
modern, efficient tanning methods. The thickness of leather are 0.6 – 1.0mm
depending on use.
Raw stock: Small skins of all provenance’s, cattle and horse hides, pig
skins, calf skin and red deer skins, which are processed from rawstock, wet blue
or crust. Grain skivers of sheep and lamb skins are also used for garment
leathers. However due to their low strength properties they have to be glued with
stretch materials. Manufacture of the formerly widely used East Indian skins, i.e.
vegetable tanned goat, hair sheep and lamb skins, has decreased to a minimum.
35
Raw stock: Same as that used for the production of grain leathers.
Besides lamb skins, goat and calf skins are preferred on account of their denser
fibre texture and good strength properties.
36
CHAPTER 6
37
Functions of each unit in Leather garment industry
38
Cutting Division
* Material inputs
Nappa / suede leathers from
Sheep
Goat
Cow
* Proper selection of raw
material
* Assorting
- COLOUR
- Grain Pattern
- Gloss – Finish
- Size
- Defect
* Visual
* Functional
Lighting source to simulate day-night is pre-requisite for assorting
* Cutting
- Using
patterns Route card is attached
- Size – Wise
- Storing
39
Pasting / Preparation
* Fusible linings are fixed by Hand / machine ironing
* Size – wise storing in bundles for movement to Tailoring Division
* All stitched ends are flat folded, pasted and hammered
* Other intermediate pasting and some other small works are also
attended.
* Cutting
- Making multi layers by folding
- Chalk marking by placing patterns
- Cutting size – wise
Cloth cutting machines are use
(disc knife / vertical knife)
* Storing (Intermediate)
* Stitching
- Pockets in lining cover
- Size cable attaching
- Complete inner lining
* Storing
Size – wise in cartons
40
Tailoring Division
* Initial joining
* Stitching of panels and flanks
* Decorative stitching
* Elastic stitching
* Collar stitching
* Zip stitching
* Pocket stitching (with lining)
* Final assembly of outer coat with
inner lining
* Intermediate inspection for quality
control
Finishing Division
* Buttons fixing
* Rivets fixing
* Other fashionable accessories fitting
* Cleaning
* Final Finishing
* Final inspection before packing
* Proper storing
* Packing for shipment
41
CHAPTER 7
42
Pattern Designing
Preamble
The most satisfactory garment is one that has been specifically fitted
to the individual who wears it. Fitting a garment is a time consuming art.
Traditionally there have been two major methods of producing a specifically
fitted garment patterns namely draping and drafting
43
system consistently produces patterns that fit as well as those that have been
produced by draping.
Construction
44
Mark button placements, determine cross-over value.
Outline lines corresponding to model: seams, yokes, pockets,
pleats, etc.
Assemble front and back with darts closed. Place pattern on the
dummy. This will help to indicate if volumes are correct. Make
changes if necessary.
Place pattern on cutting table; construct collar, sleeve, pleats,
lining, etc.
Notches
45
Pocket position
Along assembly lines of two identical curves (one or
several notches)
Folding lines.
Seam Allowance
Name of model
Reference number
46
Waist
Name of the numbered piece (Nomenclature: Back, Back yoke,
Front Sleeve, Cuff… etc)
The number of times each pattern piece is cut. Example: X2
The straight grain on each pattern piece; the centre of garment;
the position of buttons and buttonholes; pockets; certain
construction lines necessary for grading (example: the hipline).
List the nomenclature on to the back of garment, along with a
list of supplies necessary for assembly (example: belt buckle,
zipper, etc).
a. Basic Blocks:
47
Thus the basic block is the foundation pattern constructed
to fit a specific figure. In the garment industry the blocks are
constructed to a set of standard measurements for a particular
size. It is used as a basis for interpreting a design and
producing a finished pattern. The design shape may change
dramatically but the basic fit of the pattern will conform to the
size of the basic blocks.
48
c. Final (Sample) Pattern:
d. Production Pattern
e. Grading
49
Planning the objectives for the forthcoming seasons
Resource collection
➢ Sample
➢ Lining fabric
➢ Buttons
➢ Accessories & fittings
Creating new collections
➢ Working sketches
➢ Specification sheets
Supervising the sample garment production
Liaison with Production control
Maintenance of records
➢ Sampling
➢ Costing
Training new recruits
Overall responsibility of sample room and staffs
50
h) Construction marks (these include darts, button holes, pocket
placing pleats or punch holes
i) Seam allowances
j) Number of pieces to be cut (Mention if it is a single piece, a
mirrored piece or a paired piece)
51
Typical working sketch, size chart and material chart are given in
the following pages
52
Typical Size Chart
Size 46 48 50 52 54 56 58 Measurement
Margin +/-
Measurements
Back Length 82 82 83 83 84 84 85
Biceps
Cross Front
Cross Back
Neck Width
Cuff Round 15 15 16 16 17 17 18
Cuff Height
Waistband width
53
Typical Material Chart
CUSTOMER:
Light :
Mediu
m :
Heavy
ACCESSORIES
54
CHAPTER 8
55
Pattern Grading
The grader should know preferably the technical principles of the garment and the
methods of pattern cutting. He must be aware of the aesthetic notions associated with
56
In fact, if one only has to change a pattern mathematically, one could quite
happily enlarge or reduce the shape at precise points and the work would be finished;
but it is absolutely essential to take into account adjustments and details so as not to
57
Different methods of grading
1. Shifting method
It is used for simple and large forms, with few style details. The
pattern is moved vertically or horizontally according to the amount of
enlargement or reduction.
2. Construction method
The grading growth information’s are fed into the computer and a
graded by the computer and the patterns are cut with the help of a
58
Basics of Lines & Points in grading
horizontal Line
Base size(BS) = 50
Waist growth = 10 mm
Horizontal grading
No. of increments = 3 points
(Say 52-54-56(LS))
Vertical Line
Base size = 50
Vertical grading points
Hip length growth = 5 mm
No. of increments = 3
59
(Say 52-54-56(LS))
Oblique line
Base size(BS) = 50
No of increments
=3 (52-54-56(LS)) Oblique
Grading points
Note: LS: Large size
60
Measuring for Grading
The method used to find a point by measuring horizontally and then vertically is shown here.
From base point 1 measure horizontally required measurement. Mark point 2, square across.
Measure vertically required measurement to point 3. Draw a line through the points 1 and 3 for a
grading line. Points for further grading can be made along this line
Before developing the draft/construction pattern from the basic block it should be assured that the
size of the basic block & the garment sample size is same. If it differs the basic block should be
graded to the required size. Grading of some of the basic blocks is explained below.
61
Skirt Block Grading
62
Bodice Block (Women) Grading
63
Sleeve block Grading
64
Trouser block grading
65
Grading of special types of sleeves
Tailored sleeve
66
Raglan sleeve
67
Computer Aided Pattern Grading
Introduction
68
Information required for grading
Grading method
-x X
-Y
Co-Ordinates
69
Back patterns size 38 and 40
A grade rule
70
units. This variation is related to the type of computer system,
some of which offer a choice
71
always written as 0 in both X and Y directions and is used wher
no grade rule is required.
72
Nested grades
Digitising patterns
73
Digitiser cursor
74
numbers to be typed in to the system on the relevant points as
the pattern profile is digitized.
75
Grading techniques
76
CHAPTER 9
77
Garment Cutting
One of the important operations in leather garment production is
cutting. The major objectives in garment cutting are
* quality cutting
* material optimisation
panels optimally
* Hand cutting
* Clicking
* Automated Computer Aided Cutting
Methods of Cutting
Footwear / leather goods manufacture due to large scale in
production, lend most of their components clicked with the help of
standard dye blocks and a clicking machine. But since the leather
garment patterns are large in size and total numbers of garments to
be cut are less, manual cutting is employed.
78
Hand Cutting
This is the most practiced method in leather garment
manufacture. Here the cardboard patterns are placed over the leather
and with the help of a hand held knife by cutting along the contour of
the cardboard panel. The following figure shows hand cutting.
Clicking
This method is mainly employed when the panels to be cut are
of standard size and they are in large numbers. We may consider the
production of gent’s wallet, say 10,000 pieces. The wallet has
components which do not charge in their sizes, and they are required
79
in large numbers. In such cases a metal dye block is made for each
component and this placed over the leather on a clicking board and
cut using the clicking machine as shown in Figure.
80
This type of cutting is economically viable when multi layers of
fabric which has uniform finish and properties is cut for the bulk
production of readymade garments.
material is cow / buffalo hide, finished as full hide (without cutting into
81
Basic Patterns
The basic patterns required for the specific garment are
generated and graded for varying sizes. These patterns are traced
over a thick cardboard, labeled appropriately (style name, size and
cutting instructions) and stored size wise.
Cutting Skins
82
from a normal view point. Leather is sold by area and grade. Whilst
grade is associated with quality, it is not necessarily associated with
performance.
83
CHAPTER 10
84
Machinery requirement for Leather garment production
1. Flat bed single needle drop feed medium duty sewing machine
85
3. Flat bed single needle unison feed heavy duty sewing machine
86
5. Electronically controlled sewing machine
Apart from sewing machines the following equipments are used for
different unit operations
87
Requirements of tools
Cuddapah slab
Teflon head hammer
Scissor
Stitch remover
Bone folder
Stainless scale
88
CHAPTER 11
89
Leather Garments – Production and Quality
90
2. Leather issue for matching and cutting:
91
should be attached with a ROUTE CARD which when filled in at
various stages clearly identifies the person who handled the particular
part of the job. The card contains columns for each individual work
performed.
The cut bundles are issued to the fusing section for fusing and for
final bundle inspection before issuing it to the stitching section. While
fusing care should be taken to see that the correct quality of fuse
material is used for fusing and should be done at the correct
temperature so that the skins do not get damaged. The fuse material
should be of the correct thickness, correct material content (fusing
wax, cloth or paper) and the correct width. After fusing, the bundles
should be checked completely for all points of quality, i.e. cutting,
fusing, total no of pcs to be in each bundle, grain setting & color
matching of all the parts. Only after complete inspection is the bundle
sent for the stitching section.
92
square meter). After inspecting the shell, the line supervisor releases
the lining that is to be attached to the garment. Meanwhile the pastors
along with their work are also incharge of helping the tailors by way of
collecting the necessary accessories that is to be attached to the
garment like the shoulder pads, pocket zips, main zips, washcare
labels, main labels, size labels and content labile. Once the lining is
also attached and all the stitches are over except the final top stitch
the garment is once again subject to inspection. The accessories like
the buttons if any that has to be fixed before the final closing of the
garment should be done at this stage.
Once all these works are clear and the inspections with respect
to the stitch, finish, measurement extra are over the final stitch is
done. This finished garment is now sent to the cleaning and final
inspection section.
These pcs are then put in a box of 10 each and then is again
covered with plastic sheets for safety. Then these boxes are strapped
and are again packed in gunny bags for added safety. The packed
boxes are labeled outside for its destination.
93
CHAPTER 12
94
Methods of Chemical Testing of Leathers
1. Volatile matter
2. Total ash
7. Epsom salt
8. Glucose
95
1. Volatile Matter:
Weigh app. 3g. of ground leather dry is an over at 102 2oC for 5hr,
weigh the difference
% Volatile matter = w1 – w2
w1 X 100
Weigh about 10g. ground leather place it soxhlet extractor with tared
% Extractable substance = w1
X 100
w2
W1 = wt. of residue; w1 = wt. of the material
96
4. Water solubles:
a mechanical shaker for 2hr. filter using whatman No. 11 filter paper,
(* for 10 g. of leather)
Take the residue obtained at 4 add few drops of con. H2SO4 fume over a
low flame Heat in a muffle furnace at 800 25oC for 15 mts. Cool &
weigh
97
W1 = wt. of ash
W2 = wt. of material taken before 3
8. Epsom salt:
orange with ammonia and boil, dilute to 150 ml Add 20 ml buffer and
98
% Epsom salt = 0.002465 x v
X 100
w
9. Glucose
Take 200ml water solubles 4 add 25ml lead acetate (saturated) to ppt.
Veg. Tannins; filter add excess of potassium oxalate salt stir for 15mts to
ppet. Excess lead; filter Take 150 ml of fhlrqdu`!dd`%=l□(corn. HCl boil
under reflex for 2 hr to convert cane sugar into reducing sugar Neutralise
with Na2CO3 make it to 200ml pipette 25 ml each of fehling’s solutions 1
& 2 add 50 ml of test solution bring to boil in 4 mts; boil for 2 mts. Filter
in weighed Gooch crucible thro’ asbestos; dry & weigh as cuprous oxide.
From the Munsen & walker’s table calculate the Glucose content.
Take 5 g. of water
Add 100 ml water
Shake in a shaker for 16 – 24 hrs.
Measure pH.
It pH is between 4 – 10 dilute 10 ml of solubles to 100 ml measure pH
weigh 38, of leather in a Kjeldahl flask add 30ml conc. H2SO4. Add
5gm of catalyst (K2SO4 6 gms, CuSO4 100 mg) digest in a flame. Add
99
40% NaoH; 1ml phenolphthalein Distill NH3 into 4% Boric acid with
mixed indicator, Titrate with std, acid to pale pink colour.
% N = 1.4 V N
W
V = vol. of standard acid
N = Strength of acid
W = wt. of the material taken
% Hide substance = 5.62 x % N
10