Anexo 1 - Sds-Midsun-Hvic-G-New 2019
Anexo 1 - Sds-Midsun-Hvic-G-New 2019
Anexo 1 - Sds-Midsun-Hvic-G-New 2019
Midsun HVIC
HIGH VOLTAGE INSULATOR COATING
LAST REVISED: February 13, 2019
Classified to the 2012 OSHA Hazard Communication Standard 29 CFR 1920.1200.
SAFETY DATA SHEET
SECTION 1: IDENTIFICATION
Flammable Liquids 3
Eye Damage/Irritation 2A
Sensitization – Skin 1B
Toxic to Reproduction 2
STOT RE - Specific Toxic Organ Toxicity (Repeated Exposure) 2
Response: In case of fire: Use water fog, foam, dry chemical powder, carbon dioxide
(CO2) to extinguish.
Specific treatment (see Section 8 on this label).
If on skin (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
Wash contaminated clothing before reuse.
If skin irritation or a rash occurs: Get medical advice/attention.
If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Disposal: Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Skin contact: Remove contaminated clothing immediately and wash skin with soap and
water. Wash contaminated clothing before reuse. In case of eczema or other
skin disorders: Seek medical attention and bring along these instructions.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Get medical
attention if irritation develops and persists.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to physicians: Treat symptomatically. Thermal burns: Flush with water immediately. While
flushing, remove clothes that do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital.
Specific treatments: In case of accident or if you feel unwell, seek medical advice (show the label
or SDS where possible).
Safe storage: Keep away from heat, sparks and open flame. Keep container tightly closed.
Store in a cool and well-ventilated place. Keep in an area equipped with
sprinklers. Store away from incompatible materials (see Section 10 of the
SDS).
Specific use: Coating
Exposure limits:
General: Eyewash fountain and emergency showers are recommended. Use personal
protective equipment as required.
Eye protection: Wear safety glasses with side shields (or goggles).
Hand protection: Wear appropriate chemical resistant gloves.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits (where applicable) or to an acceptable level (in
countries where exposure limits have not been established), an approved
respirator must be worn.
Skin and body protection: Wear appropriate chemical resistant clothing.
Hygiene measures: When using, do not smoke. Always observe good personal hygiene measures,
such as washing after handling the material and before eating, drinking,
and/or smoking. Routinely wash work clothing and protective equipment to
remove contaminants. Contaminated work clothing should not be allowed
out of the workplace.
Thermal hazards: Wear appropriate thermal protective clothing, when necessary.
Environmental exposure controls: Environmental manager must be informed of all major releases.
10.1 REACTIVITY The product is stable and non-reactive under normal conditions of use,
storage and transport.
10.4 CONDITIONS TO AVOID Avoid heat, sparks, open flames and other ignition sources. Contact with
incompatible materials.
Acute toxicity: May cause an allergic skin reaction. Dermatitis. Rash. Causes serious eye
irritation. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision.
Likely routes of exposure: Skin contact. Eye contact. Inhalation.
Eye: Causes serious eye irritation. Symptoms may include stinging,
tearing, redness, swelling, and blurred vision.
Skin: May cause an allergic skin reaction. Dermatitis. Rash.
Ingestion: Not an expected route of exposure. Expected to be a low ingestion
hazard.
Inhalation: Not an expected route of exposure. No adverse effects due to
inhalation are expected.
LD50/LC50 values relevant to this classification:
Butan-2-one O,O',O"-(methylsilylidyne)trioxime
Oral rat LD50 2463 mg/kg bw
Oral rat LD50 ca. 2500mg/kg bw
Derm rat LD50 > 2000 mg/kg bw
Octamethylcyclotetrasiloxane
Oral rat LD50 > 2000 mg/kg bw
Oral rat LD50 > 4800 mg/kg bw
Oral rat LD50 > 61440 mg/kg bw
Oral mouse LD50 1700 mg/kg bw
Inhal rat LC50 2,975 ppm
Derm rat LD50 >2400 mg/kg bw
Derm rat LD50 > 2000 mg/kg bw
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin corrosion/irritation: Based on available data, this product is not expected to cause skin corrosion
or irritation. Prolonged skin contact may cause dryness, redness, or cracking.
Serious eye damage/irritation: Causes serious eye irritation. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision.
Respiratory sensitization: Based on available data, this product is not expected to cause respiratory
sensitization.
Skin sensitization: May cause an allergic skin reaction.
Symptoms and target organs: Prolonged exposure may cause chronic effects. Suspected of damaging
fertility or the unborn child. May cause damage to organs <blood,
cardiovascular> through prolonged or repeated exposure <oral>. May cause
an allergic skin reaction. Dermatitis. Rash. Causes serious eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred
vision.
Chronic health effects: Prolonged exposure may cause chronic effects. Suspected of damaging
fertility or the unborn child. May cause damage to organs <blood,
cardiovascular> through prolonged or repeated exposure <oral>.
Carcinogenicity: This product is not classified as a carcinogen. Due to the form of the product,
exposure to the potentially carcinogenic components is not expected.
Material OSHA(O) ACGIH(G) NTP(N) IARC(I)
Silica, quartz (dust) Not listed A2 K 1
Titanium dioxide (dust) Not listed A4 Not listed 2B
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
OSHA (O) =Occupational Safety and Health Administration NTP (N) =National Toxicology Program
Ca/Yes = Expected to be carcinogenic K =Known to be a carcinogen
not listed = Not expected to be carcinogenic R = Reasonably anticipated to be a carcinogen
not listed = Not expected to be carcinogenic
ACGIH (G) =American Conference of Governmental Industrial Hygienists IARC (I) =International Agency for Research on Cancer
A1 =Confirmed human carcinogen 1 =Carcinogenic to humans
A2 =Suspected human carcinogen 2A =Probably carcinogenic to humans
A3 =Animal carcinogen 2B =Possibly carcinogenic to humans
A4 =Not classifiable as a human carcinogen 3 =Not classifiable as to its carcinogenicity to humans
A5 =Not suspected as a human carcinogen 4 =Probably not carcinogenic to humans
not listed = Not expected to be carcinogenic not listed = Not expected to be carcinogenic
12.1 ECOTOXICITY
Ecotoxicity: The product is not classified as environmentally hazardous. However, this
does not exclude the possibility that large or frequent spills can have a
harmful or damaging effect on the environment.
Acute aquatic toxicity: The product is not classified as acutely environmentally hazardous. However,
this does not exclude the possibility that large or frequent spills can have a
harmful or damaging effect on the environment.
Chronic toxicity: The product is not classified as having a chronic environmental hazard.
However, this does not exclude the possibility that large or frequent spills can
have a harmful or damaging effect on the environment.
Environmental effects: The product is not classified as environmentally hazardous. However, this
does not exclude the possibility that large or frequent spills can have a
harmful or damaging effect on the environment.
12.4 MOBILITY
Mobility: No data available.
Mobility in soil: No data available.
Mobility in non-soil: No data available.
DOT Non-Bulk
UN: UN1139
Proper shipping name: Coating solution
Hazard class: 3 Packing group: PG III
DOT Bulk
UN: UN1139
Proper shipping name: Coating solution
Hazard class: 3 Packing group: PG III
IMO/IMDG
UN: UN1139
Proper shipping name: Coating solution
Hazard class: 3 Packing group: PG III
ICAO/IATA
UN: UN1139
Proper shipping name: Coating solution
Hazard class: 3 Packing group: PG III
Reportable quantity: Package sizes shipped in quantities less than the product reportable quantity are not subject
to the RQ (reportable quantity) transportation requirements.
This information is not intended to convey all specific regulatory or operational requirements/information relating to this
product. Additional transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating
to the transportation of the material
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE CHEMICAL
US Federal Regulations:
U.S. OSHA (Occupational Safety and Health Administration) Specifically Regulated Substances (29 CFR
1910.1001-1050)
No components of this product are present at concentration greater than or equal to 0.1% and
are identified as a carcinogen or potential carcinogen by OSHA.
New Jersey
Community
Minnesota Environme New Jersey Rhode
California Massachus Employee ntal Hazard Right-to- Pennsylvan Island
Proposition etts Right- Right-to- Right-to- Know ia Right-to- Right-to-
Material 65 to-Know Know Know Substance Know Know
Silica, quartz (dust) Cancer Listed Listed Listed Listed Listed
(airborne,
unbound
particles of
respirable
size) Not listed
Titanium dioxide (dust) Cancer Listed Listed Listed Listed
(airborne,
unbound
particles of
respirable
size) Not listed Not listed
Aluminum Oxide Not listed Listed Listed Not listed Listed Listed Listed
Silicon dioxide Not listed Listed Listed Not listed Not listed Not listed Not listed
Octane Not listed Listed Listed Not listed Listed Listed Not listed
n-Heptate Not listed Listed Listed Not listed Listed Listed Not listed
Toluene Dev Listed Listed Listed Listed Listed Listed
Ethylbenzene (trace <0.01%) Cancer Listed Listed Listed Listed Listed Listed
Benzene (trace <0.01%) Cancer, Listed Listed Listed Listed Listed Listed
Dev
California:
Proposition 65:
WARNING: This product can expose you to chemicals including Ethylbenzene and Benzene,
which are known to the State of California to cause cancer, and Toluene and Benzene, which are
known to the State of California to cause birth defects or other reproductive harm. For more
information, go to www.P65Warnings.ca.gov.
Global Inventories:
Notification status:
US - TSCA All substances are listed
Canada -DSL All substances are listed
Canada - NDSL No substances are listed
EU - EINECS All substances are listed
EU - ELINCS No substances are listed
EU - NLP No substances are listed
Australia – AICS All substances are listed
China - EICSC All substances are listed
Japan - ENCS All substances are listed
Korea - KECI All substances are listed
Taiwan - NECI All substances are listed
New Zealand - NZloC Not all substances are listed
Philippine - PICCS All substances are listed
EU - REACH Status:
A registration number is not available for substances in this mixture as the substances are
exempted from registration or the annual tonnage does not require a registration.
Flammable Liquids 3
Eye Damage/Irritation 2A
Sensitization – Skin 1B
Toxic to Reproduction 2
STOT RE - Specific Toxic Organ Toxicity (Repeated Exposure) 2
Flammable Liquids 3
Eye Damage/Irritation 2A
Sensitization – Skin 1B
Toxic to Reproduction 2
STOT RE - Specific Toxic Organ Toxicity (Repeated Exposure) 2
MEXICO (GHS):
Flammable Liquids 3
Eye Damage/Irritation 2A
Sensitization – Skin 1B
Toxic to Reproduction 2
STOT RE - Specific Toxic Organ Toxicity (Repeated Exposure) 2
Health: 2*
Flammability: 2
Physical: 0
Health 2
Fire 3
Reactivity 0
Legend:
DOT US Department of Transportation
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods
ACGIH American Conference of Governmental Industrial Hygienists
NTP National Toxicology Program
IARC International Agency for Research on Cancer