Blackhorn 209

Western Powders, Inc.

Issue Date: 11/05/2015
Safety Data Sheet according to OSHA HazCom Standard (2012) requirements

Section 1 - Identification of the Mixture and of the Company

Product Name:
Blackhorn 209

Trade Names and Synonyms:

Silver Strike

Relevant Identified Uses:

Product is intended for use as a propellant in muzzle-loading firearms.

Manufactured By: WESTERN POWDERS, INC.

P.O. Box 158
Miles City, Montana 59301
Telephone: (406)234-0422
Fax: (406)234-0430
Website www.westernpowders.com
Email: [email protected]
Emergencies – Chemtrec – 1-800-424-9300

Section 2 - HAZARD IDENTIFICATION

Classification of the Mixture:
Explosives Division 1.3

GHS Classification:

Signal Word: Danger

Hazard Statements:
H203 Explosive; fire, blast or projection hazard.
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H371 May cause damage to organs
(circulatory system, blood, kidneys, liver) through prolonged or repeated exposure.

Precautionary Statements
Prevention
P210 Keep away from heat.
P240 Ground or bond container and receiving equipment
P250 Do not subject to shock or friction.
P260 Do not breathe dust.
P280 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P281 Wear protective gloves, protective clothing and eye protection.

Response
 P370 Explosion risk. In case of fire: Evacuate area. Use water to extinguish. Do NOT
fight fire when fire reaches explosives.
P312 If swallowed: Call a poison control center or doctor if you feel unwell.
P330 Rinse mouth.
P305 If in eyes: Rinse cautiously with water for several minutes.
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P303 If on skin: Wash with plenty of water.
P337 If eye irritation persists: Call a doctor.
P333 If skin rash persists: Call a doctor.
P363 Wash contaminated clothing before reuse.
Storage
P410+412 Store in a well-ventilated place away from direct sunlight.
P404 Keep container tightly closed.
P420 Store away from ignition sources.
Disposal
P501 Store and dispose of container, waste and residues in accordance with all applicable legal and regulatory
requirements.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Substances:
Product is a mixture.
CAS Number %[Weight] Name
Not Disclosed 30-90 Nitrate Ester
Not Disclosed 1-5 Stabilizer, Proprietary
Not Disclosed 0-25 Oxidizer, Mineral
Not Disclosed 0-25 Oxidizer, Organic
Proprietary 0-10 Carbonaceous Substance

Section 4 - FIRST AID MEASURES

Inhalation
 Remove to fresh air.
 If not breathing, institute rescue breathing.
 If breathing is difficult, ensure airway is clear, give oxygen and continue to monitor.
 If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR).
 Keep affected person warm and at rest. Get immediate medical attention.
Eye Contact
 Do not rub eyes.
 Immediately flush with plenty of water for up to 15 minutes.
 Remove any contact lenses and open eyelids wide apart. If eye irritation develops,
call a physician.

Skin Contact
 Immediately wash exposed skin with plenty of soap and water while removing contaminated clothing and shoes.
 May be absorbed through the skin in harmful amounts.
 Call a physician if you feel unwell.
 Wash clothing before re-use.
 If clothing is to be laundered, inform the person performing the operation of the contaminants hazardous
properties.
Ingestion
  Rinse mouth thoroughly with water and give large amounts water to people not unconscious.
 Do NOT induce vomiting. Get immediate medical attention.
 Do not give anything by mouth if the person is unconscious or if having convulsions.

Most important symptoms and effects, both acute and delayed.

Eye irritation. Symptoms may include itching, burning, redness and tearing. Skin contact may cause
redness and pain. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. High
concentrations of dust may irritate throat and respiratory system and cause coughing.

Indications of any immediate medical attention and special treatment needed.

Provide general supportive measures and treat symptomatically. Keep victim under observation.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA:
Large volumes of water should be applied as quickly as possible from automatic sprinklers or fire hose.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this may spread fire.

Special Hazards arising from the substrate or mixture.

Toxic vapors/gases may be formed during a fire. Combustion products vary depending on fire conditions and other
combustibles present. The predominant products will be carbon dioxide and oxides of nitrogen, Under some conditions,
methane, carbon monoxide, irritating aldehydes and carboxylic acids, and hydrogen cyanide may be formed.

Special protective equipment

and precautions for firefighters
Self-contained breathing apparatus (SCBA) and full protective clothing must be worn in case of fire. This includes, but is
not limited to, impervious boots, gloves, hard hat and chemically impermeable suit.

Fire-fighting equipment/instructions
Fires involving smokeless propellant should NOT be fought unless extinguishing media can be applied from a well
protected (e.g. behind a berm or barricade) and distant location from the point of fire.

Specific methods
Evacuate personnel to a safe area according to pre-determined evacuation plan. Use standard firefighting procedures and
consider the hazards of other involved materials.

General fire hazards

Explosive; fire, blast or projection hazard.

Section 6 - ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures.

Keep unnecessary personnel away. Eliminate all ignition sources. Use only non-sparking tools. Wear
appropriate protective equipment and non-flammable or flame retardant clothing during clean-up. Avoid
inhalation of dust. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fumes at
levels exceeding the exposure limits. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of this SDS.

Methods and materials for containment and cleaning up

Avoid dispersal of dust in the air (e.g. clearing dust surfaces with compressed air). Clean-up spills
immediately using non-sparking utensils. Wet down spilled materials prior to initiating clean-up and keep
material wet until ready for disposal. Avoid contamination of water bodies during clean up and disposal.
This material is heavier than water. Create an overflow dam with filtration capabilities to retain material.
Collect dust using a vacuum cleaner equipped with HEPA filter. Large Spills: Sweep, shovel or vacuum
up spillage and collect in suitable container for disposal. For a spillage into water: where possible, remove
any intact containers from the water. Clean contaminated surfaces thoroughly to remove residual
contamination. Never return spilled material to original containers for re-use. For waste disposal, see
section 13 of this SDS.

Section 7 - HANDLING AND STORAGE

Precautions for Safe Handling

Do not handle until all safety precautions have been read and understood. Do not subject to mechanical
shock. Avoid exposure to sunlight or artificial ultraviolet light. Minimize dust generation and accumulation.
Provide appropriate exhaust ventilation. Avoid breathing dust. Avoid contact with eyes, skin and clothing.
Do not taste or swallow. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.
Smokeless powder contains stabilizers and deteriorates very slowly under proper storage conditions. Old smokeless powder
should be checked for deterioration regularly. Deteriorating smokeless powder produces an acidic odor and may produce
reddish-brown fumes. Dispose of deteriorating smokeless powder through, for example, controlled open burning in small
quantities (products should be submerged in water until burned). Smokeless powder should not be exposed to excessive
heat, as this can accelerate deterioration. Deterioration produces an acidity that accelerates further reaction and has been
known, because of heat generated by the reaction, to cause spontaneous combustion.
Conditions for safe storage, including any incompatibilities
Store at 21°C (70°F), 50% relative humidity (decomposition becomes measurable above 50°C (122°F).
Store in original container. Keep container tightly closed. Store in a cool, dry, well-ventilated place away
from all sources of ignition. Store away from incompatible materials (see Section 10 of this SDS).
For additional information regarding handling and storage guidelines, see “Properties and Storage of
Smokeless Powder” published by the SPORTING ARMS AND AMMUNITION MANUFACTURERS
INSTITUTE, INC (SAAMI), 11 Mile High Road, Newtown, CT 06405 (www.saami.org)

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters
Occupation Exposure Limits (OEL)
Chemical Name CAS Number ACGIH TLV OSHA PEL Other Information
Nitrate Ester None established None established
Stabilizer, Proprietary None established
Oxidizer, Mineral None established
Oxidizer, Organic None established
Carbonaceous Substance None established

Biological limit values

 No biological exposure limits noted for the ingredient(s).

Exposure Controls
Appropriate engineering Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can
Controls be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
 Process controls which involve changing the way a job activity or process is done to reduce the risk.
 Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Personal protection

Eye and face protection  Safety glasses with side shields.

Skin protection Wear appropriate chemical resistant, flame retardant clothing (e.g.
 coveralls or lab coat).
Hands/feet protection Wear impermeable gloves.
Respiratory protection Use a NIOSH/MSHA approved respirator with organic vapor cartridge
and particulate filter if there is a risk of exposure to dust/fume at levels
exceeding the exposure limits.

General hygiene Considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or
 smoking. Routinely wash work clothing and protective equipment to remove contaminants.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Granular grey to black colored solid

Physical state Solid Relative density (Water = 1) Bulk density 0.5 - 1.1 (g/cc)
Odor Odorless Partition coefficient Not available
n-octanol / water
Odor threshold Not Available Auto-ignition temperature 190-200°C (374-392°F)
(°C
pH (as supplied Not applicable Decomposition Decomposition becomes measurable
temperature above 50°C (122°F).
Melting point / Not applicable Viscosity (cSt) Not applicable
freezing
point (°C)
Initial boiling point Not applicable Viscosity and other Product can explode if ignited and confined
and Information
boiling range (°C)
Flash point (°C) Not applicable
Evaporation rate Not applicable
Flammability Flammable Solid
Upper Explosive Not available
Limit (%
Lower Explosive Not Available
Limit (%)
Vapor pressure <1 mm Hg
(kPa)
Solubility in water Negligible
(g/L)
Vapor density Not applicable

Section 10 - STABILITY AND REACTIVITY

Reactivity Can ignite due to mechanical shock and/or impact. Can ignite due to static discharge (minimum ignition energy 200mJ).
Product can explode if ignited and confined.
Chemical stability Unstable when exposed to sources of heat, sunlight or artificial ultraviolet light.
Possibility of hazardous Hazardous polymerization does not occur.
Reactions
Conditions to avoid Avoid contact with incompatible materials. Direct sunlight,
artificial ultraviolet light, flame, and heat.
Incompatible materials Strong acids, alkalis, oxidizers, and amines.
Hazardous decomposition Carbon monoxide, carbon dioxide, oxides of nitrogen.
Products Decomposition becomes measurable above 50°C (122°F)

Section 11 - TOXICOLOGICAL INFORMATION

Inhaled  Dust may irritate respiratory system.
 Inhalation of vapors may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-
ordination and vertigo.
 Central nervous system (CNS) depression may include general discomfort, symptoms of giddiness, headache, dizziness, nausea, anaesthetic
effects, slowed reaction time, slurred speech and may progress to unconsciousness.
 Serious poisonings may result in respiratory depression and may be fatal.
Ingestion  Harmful if swallowed.
 Ingestion may cause gastrointestinal irritation.
Skin Contact  May be harmful in contact with skin.
 May cause skin irritation.
 May cause an allergic skin reaction.
Eye  Causes eye irritation.
Chronic  This product contains Diphenylamine, which has been shown to induce kidney damage. The low concentration of this material in, and the nature of
the product, would preclude development of such an effect.

Information on toxicological effects

Acute toxicity Excessive exposure to dust by inhalation has been reported to cause bladder damage, rapid heartbeat, increased blood pressure, and skin rash.
Skin corrosion/irritation May cause skin irritation.
Serious eye damage/eye irritation Causes serious eye irritation
Respiratory sensitization May cause respiratory irritation.
Skin sensitization May cause skin sensitization.
Germ cell mutagenicity This product or any of its ingredients are not known or reported to be mutagenic
Carcinogenicity No component of this solid mixture is listed as a carcinogen in IARC, NIOSH-NTP, or OSHA Lists.
Reproductive toxicity May damage fertility or the unborn child.
Specific target organ toxicity - single Not Classified
exposure
Specific target organ toxicity - May cause damage to the circulatory system, blood, kidneys, and liver through prolonged or repeated exposure.
repeated exposure
Aspiration hazard Due to the physical form of the product it is not an aspiration hazard.

Section 12 - ECOLOGICAL INFORMATION

AQUATIC TOXICITY: Do not discharge into sewers or waterways.

Ecotoxicity Toxic to aquatic life with long lasting effects.
Persistence and degradability No data available on product mixture
Bioaccumulative potential No data available on product mixture
Mobility in soil No data available on product mixture
Other adverse effects No other adverse environmental effects known.

Section 13 - DISPOSAL CONSIDERATIONS

Disposal instructions:
If material becomes a waste, it may be treated by controlled burning in small quantities if permissible by
relevant regulatory agencies (such as in a RCRA permitted open burn unit or incinerator). Material should be
spread into thin layers and ignited from a safe distance. Dispose of in accordance with applicable federal, state,
and local regulations. Do not discharge into drains, water courses or onto the ground.

Local disposal regulations

Dispose of in accordance with local regulations.

Waste from residues/unused products

Care must be taken to prevent environmental contamination from the use of this material. The user has
the responsibility to dispose of unused material, residues, and containers in compliance with all relevant
laws and regulations.

Section 14 - TRANSPORT INFORMATION

DOT / IMDG:
UN Number 0499, NA 3178
UN Proper Shipping Name Propellant Solid
Transport Hazard Class(es) 1.3 C
Packing Group Not applicable
Special precautions for user This material is a dangerous good for transport. All involved staff must be appropriately trained.
Other information Above classification relates to the specific packaging in which this material is supplied by the manufacturer. If the material is
repackaged, this classification will no longer be relevant.

IATA:
UN Number Forbidden
UN Proper Shipping Name Forbidden
Transport Hazard Class(es) Forbidden
Packing Group Forbidden

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

Section 15 - REGULATORY INFORMATION

US Federal Regulations
This product is regulated as a DOT Hazardous Material
CERCLA Hazardous Substance List (40 CFR 302.4)
Not Applicable
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories:

Immediate Hazard Yes

Delayed Hazard No
Fire Hazard Yes
Pressure Hazard No
Reactivity Hazard Yes

SARA 302 Extremely hazardous substance

Not listed.
SARA 313 (TRI reporting
Not Applicable
US State Regulations

Section 16 - OTHER INFORMATION

Revision Date: 11/05/2015

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

The information contained herein is believed to be accurate and represents the best information currently available
to Western Powders, Inc. No warranty or guarantee, express or implied, with regard to the safety or suitability of
these products, or to the results obtained from their use, is offered by Western Powders, Inc. Buyer and user
assume any and all risk, responsibility and liability for any injury (including death), loss or damage arising from
usage of these products.