Sefox Spray Adhesi̇ve MSDS

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SAFETY DATA SHEET

ISSUE DATE: 04.01.2021

1. Identification
Product number Sefox Spray Adhesive
Product identifier Solvent Based Adhesive
Company information Sefa Kimya Petrol Ürünleri San.
Ve Dış Tic. A.Ş.
www.sefox.net

Company phone +90 312 815 47 94


Version # 01
Recommended use UPHOLSTERY ADHESIVE
Recommended restrictions None known.

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Germ cell mutagenicity Category 1
Carcinogenicity Category 1
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Danger


Hazard statement May cause genetic defects. May cause cancer.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Wear protective gloves/protective clothing/eye protection/face protection.
Response If exposed or concerned: Get medical advice/attention.
Storage Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Methylene Chloride 75-09-2 > %50
Other components below reportable levels < 40
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important Dizziness. Nausea. Irritation of eyes and mucous membranes. Skin irritation.
symptoms/effects, acute and
delayed
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire-fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
emergency procedures damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or
containment and cleaning up confined areas. Following product recovery, flush area with water.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Provide adequate ventilation. Should be handled in closed systems, if possible.
Wear appropriate personal protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in original tightly closed container. Refrigeration recommended. Store away
including any incompatibilities from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection


Occupational exposure limits

Components Type Value

Methylene Chloride (CAS STEL 125 ppm


75-09-2)
Components
Type Value

Methylene Chloride (CAS TWA 50 ppm


75-09-2)
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Methylene Chloride (CAS 0.3 mg/l Dichlorometha Urine *
75-09-2) ne
* - For sampling details, please see the source document.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece.
Hand protection Wear appropriate chemical resistant gloves.
Skin protection
Other Use of an impervious apron is recommended.
Skin protection
Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

9. Physical and chemical properties


Appearance
Physical state Liquid.
Form Liquid.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 40 °C estimated
range
Flash point >230.0 °C estimated
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 631.11 psig @39˚ C estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature 400 °C estimated
Decomposition temperature Not available.
Viscosity Not available.

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Ingestion Not available.
Inhalation No adverse effects due to inhalation are expected. Skin
contact No adverse effects due to skin contact are expected. Eye
contact Direct contact with eyes may cause temporary irritation.
Symptoms related to the Dizziness. Nausea. Irritation of eyes and mucous membranes. Skin irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity
Components Species Test Results
Methylene Chloride (CAS 75-09-2)
Acute
Dermal
LD50 Rat > 2000 mg/kg, Days
Inhalation
LC50 Mouse 49 mg/l, 7 Hours

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
IARC Monographs. Overall Evaluation of Carcinogenicity
Methylene Chloride (CAS 75-09-2) 2B Possibly carcinogenic to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Methylene Chloride (CAS 75-09-2) Cancer
US. National Toxicology Program (NTP) Report on Carcinogens
Methylene Chloride (CAS 75-09-2) Reasonably Anticipated to be a Human Carcinogen.

Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not available.
Chronic effects Prolonged exposure may cause chronic effects.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
Methylene Chloride (CAS 75-09-2)
Aquatic
Algae IC50 Algae 500.0001 mg/L, 72 Hours
Crustacea EC50 Daphnia 1689.5 mg/L, 48 Hours
Water flea (Daphnia magna) 1250 mg/l, 48 hours
Fish LC50 Fathead minnow (Pimephales promelas) 140.8 - 277.8 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
Methylene Chloride 1.25
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
US RCRA Hazardous Waste U List: Reference
Methylene Chloride (CAS 75-09-2) U080
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
ADR / RID
UN number Not applicable
Packing Group This product does not fall within any category of dangerous substance
Proper shipping name Not applicable
IATA
UN number Not applicable
Packing Group This product does not fall within any category of dangerous substance
Proper shipping name Not applicable
IMDG
UN number Not applicable
Packing Group This product does not fall within any category of dangerous substance
Proper shipping name Not applicable

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