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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 28.04.2014 Version number 2 Revision: 28.04.2014

1 Identification of the substance/mixture and of the company/

undertaking
· Product identifier
· Trade name: HFA 7025
· CAS Number:
61790-12-3
· Relevant identified uses of the substance or mixture and uses advised against
Lubricity Improver
· Sector of Use Oil industry
· Product category PC13 Fuels
· Application of the substance / the mixture Additive
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
WRT B.V.
Strawinskylaan 3067
1077ZX Amsterdam
The Netherlands
Tel.: 00-31-(0)20-644 2831
Fax.: 00-31-(0)20-642 3962
[email protected]
· Further information obtainable from:
Product Safety Department
Tel.: 00-31-(0)-644 2831
[email protected]
Support is only given in the following languages: Dutch, English and German
· Emergency telephone number:
Product Safety department
In case of a spill or accident, you can contact us at:
Tel.: 00-31-(0)20-644 2831
During office hours we can be contacted for general information at
Tel.: 00-31-(0)20-6442831
Support is only given in the following languages: Dutch, English, and German

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
The substance is not classified according to the CLP regulation.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.
· Information concerning particular hazards for human and environment: Not applicable.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Substances
· CAS No. Description
61790-12-3 Tall oil fatty acid
(Contd. on page 2)
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 Page 2/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 28.04.2014 Version number 2 Revision: 28.04.2014

Trade name: HFA 7025

(Contd. of page 1)
· Identification number(s) EINECS: 263-107-3

4 First aid measures

· Description of first aid measures
· General information: No special measures required.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Generally the product does not irritate the skin.
Rinse with warm water.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing:
Rinse out mouth and then drink plenty of water.
If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
· Advice for firefighters
· Protective equipment:
Wear fully protective suit.
Wear self-contained respiratory protective device.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· Reference to other sections
No dangerous substances are released.
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· Handling:
· Precautions for safe handling
(Contd. on page 3)
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 Page 3/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 28.04.2014 Version number 2 Revision: 28.04.2014

Trade name: HFA 7025

(Contd. of page 2)
Contaminated rags and cloths must be put in fireproof containers for disposal. Observe good industrial
hygiene. Porous material such as rags, paper, insulation, or organic clay may spontaneoulsy combust when
wetted with this material. May auto-oxidize with sufficient heat generation to ignite if spread ( as a thin film ) or
absorbed on porous or fibrous material.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
· Respiratory protection: Not required.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Goggles recommended during refilling

9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: Yellow
· Odour: Mild
· Odour threshold: Not determined.
· pH-value: Not applicable.
· Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: > 200 °C
· Pour point minus 8 °C
· Flash point: 205 °C
(Contd. on page 4)
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 Page 4/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 28.04.2014 Version number 2 Revision: 28.04.2014

Trade name: HFA 7025

(Contd. of page 3)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 257 °C
· Decomposition temperature: Not determined.
· Self-igniting: Not determined.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure at 150 °C: 3 mbar
· Density at 15 °C: 0.90 - 0.91 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: 12.6 mg/l at 20 degrees Celsius
· Partition coefficient (n-octanol/water) at
30 °C: 4.9 - 6.0 log POW
· Viscosity:
Dynamic at 20 °C: 30 mPas
Kinematic: Not determined.
· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity
· Chemical stability Stable under normal conditions
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
Strong oxidizing agents. Avoid temperatures exceeding the flash point. Porous material such as rags, paper,
insulation, or organic clay may spontaneously combust when wetted with this material.
· Incompatible materials: This product may react with strong oxidizing agents.
· Hazardous decomposition products:
Upon decomposition this product emits acrid dense smoke with carbon dioxide, carbon monoxide, water and
other products of combustion.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
When used and handled according to specifications, the product does not have any harmful effects to our
experience and the information provided to us.
(Contd. on page 5)
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 Page 5/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 28.04.2014 Version number 2 Revision: 28.04.2014

Trade name: HFA 7025

(Contd. of page 4)
The substance is not subject to classification according to the latest version of the EU lists.

12 Ecological information
· Toxicity
· Aquatic toxicity:
61790-12-3 Tall oil fatty acid
EC50 > 10000 mg/l 16 hr (bac)
EL50 > 1000 mg/l 48 hr (daphnia) (OECD 202)
> 1000 mg/l 72 hr growth rate (algae) (OECD 201)
LL50 > 10000 mg/l 96 hr (rat)
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
The generation of waste should be avoided or minimised wherever possible. Significant quantities of waste
product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment
plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in safe way. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product
residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally.
Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.
· Uncleaned packaging:
· Recommendation:
Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning.

14 Transport information
· UN-Number
· ADR, ADN, IMDG, IATA Void
· UN proper shipping name
· ADR, ADN, IMDG, IATA Void
(Contd. on page 6)
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 Page 6/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 28.04.2014 Version number 2 Revision: 28.04.2014

Trade name: HFA 7025

(Contd. of page 5)
· Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· Packing group
· ADR, IMDG, IATA Void
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Not applicable.
· Transport
in bulk according to Annex II
of MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": -

15 Regulatory information
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing MSDS: Product safety department
· Contact: Mr. G.C. Spruijt
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
CAS: Chemical Abstracts Service (division of the American Chemical Society)
·* Data compared to the previous version altered. New format
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