CHEMISTRY

TARGET: JEE (ADVANCED)

MEDIUM : ENGLISH

CRITICAL
QUESTIONS
BANK
SUBJECT : CHEMISTRY MEDIUM : ENGLISH

Contents
1. Questions 1 - 31

2. Answer Key 32

3. Hints & Solutions 33 - 48

 QUESTION FORMAT & MARKING CRITERIA
SUBJECT : CHEMISTRY
A. Questions Format

In the booklet check that it contains all the 189 questions and corresponding answer choices are legible. Read carefully the
Instructions printed at the beginning of each section.
1. Section 1 contains 45 multiple choice questions. Each question has Four choices (A), (B), (C) and (D) out of which only ONE
is correct.
2. Section 2 contains 41 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or
MORE are correct.
3. Section 3 contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which Only ONE is
correct.
4. Section 4 contains 14 paragraphs each describing theory, experiment, data etc. 18 questions related to Fourteen paragraphs
with one or two or three questions on each paragraph. Each question of a paragraph has ONLY ONE correct answer among
the four choices (A), (B), (C) and (D).
5. Section 5 contains 5 questions. Each question contains statements given in two columns which have to be matched.
Statements in Column I are labelled as A,B,C and D whereas statements in Column II are labelled as p,q,r,s and t. The
answers to these questions have to be appropriately bubbled as illustrated in the following example.
6. Section 6 contains 52 questions. The answer to each question is a single-digit integer, ranging from 0 to 9 (both inclusive).
8. Section 7 contains 23 questions. The answer to each question is a double-digit integer, ranging from 00 to 99 (both inclusive).

B. Marking Scheme

9. For each question in Section 1, you will be awarded 3 marks if you darken the bubble corresponding to only the correct answer
and zero mark if no bubbles are darkened. In all other cases, minus one (–1) mark will be awarded.

10. For each question in Section 2, you will be awarded 4 marks if you darken the bubble(s) corresponding to only the correct
answer and zero mark if no bubbles are darkened. No negative marks will be awarded for incorrect answers in this section.

11. For each question in Section 3, you will be awarded 4 marks if you darken all the bubble(s) corresponding to only the correct
answer(s) and zero mark if no bubbles are darkened.

12. Section 4 contains 5 paragraphs each describing theory, experiment, data etc. Ten questions related to Five paragraphs with
two questions on each paragraph. Each question of a paragraph has ONLY ONE correct answer among the four choices (A),
(B), (C) and (D).

13. For each question in Section–5, you will be awarded 2 marks for each row in which you have darkened the bubble
corresponding to the correct answer. Thus, each question in this section carries a maximum of 8 marks. There is no negative
marking for incorrect answer(s) in this section.

14. For each question in Section 6, you will be awarded 4 marks if you darken the bubble corresponding to only the correct answer
and zero mark if no bubbles are darkened. No negative marks will be awarded for incorrect answers in this section.

15. For each question in Section 7, you will be awarded 4 marks if you darken all the bubble(s) corresponding to only the correct
answer(s) and zero mark if no bubbles are darkened. No negative marks will be awarded for incorrect answers in this section.
 CHEMISTRY

CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27,
Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65,
As = 75, Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Only One option correct Type)

This section contains 45 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

1. How many grams of concentrated nitric acid solution should be used to prepare 250 mL of 2.0M HNO3 ?
The concentrated acid is 70% HNO3.
(A) 90.0 g conc. HNO3 (B) 70.0 g conc. HNO3
(C) 54.0 g conc. HNO3 (D) 45.0 g conc. HNO3

2. What is the concentration of nitrate ions if equal volumes of 0.1 M AgNO3 and 0.1 M NaCl are mixed
together :
(A) 0.1 M (B) 0.2 M (C) 0.05 M (D) 0.25 M

3. 4.14 g of pure lead was dissolved in nitric acid and was made to react with HCl, Cl2 and NH4Cl to convert lead
completely into (NH4)2PbCl6. However, only 2.28 g of (NH4)2PbCl6 was actually produced. The percentage
yield of the product is.
(Atomic wt. of Pb = 207)
(A) 75 (B) 37.5 (C) 50 (D) 25

4. 10 ml of KMnO4 solution is mixed with excess of KI solution in acidic medium. The iodine hence liberated
required 20 ml of Na2S2O3 solution for titration. If the molarity of KMnO4 solution is 0.05, Find molarity of
Na2S2O3 solution.
(A) 1 (B) 1.25 (C) 5 (D) 4.5

5. When Cr(s) + OH–(aq)  Cr(OH)4– (aq) + H2(g) (basic solution) is balanced, the sum of the coefficients
of all the reactants and products is:
(A) 14 (B) 15 (C) 17 (D) 9

6. Photons emitted when electrons in a H-atom make transition from a higher energy state to lower energy
state, whose difference in angular momentum is h/ , are made to incident on sodium metal (work function,
W = 2.3 eV). The maximum possible kinetic energy of emitted photoelectrons is :
(A) 7.9 eV (B) 0.25 eV (C) 10.45 eV (D) 9.79 eV

7. At 57°C, gaseous dinitrogen tetraoxide is 50% dissociated. Calculate the standard free energy change per
mole of N2O4 (g) at this temperature and at 1 atm.
R = 8.3 JK–1 mol–1 , In 10 = 2.3 , log 2 = 0.3 , log 3 = 0.48
(A) – 756 J mol–1 (B) – 856 J mol–1 (C) – 656 J mol–1 (D) None of these

8. Calculate the pH of a 0.1 M K3PO4 solution. The third dissociation constant of phosphoric acid is 10–12.
Given (0.41)1/2 = 0.64 ; log 3 = 0.48
(A) 12.5 (B) 12.44 (C) 12.25 (D) 12

9. Find the pH of a solution after 20 ml of 0.2 M NaOH is added to 80 ml of 0.15 M HCN.

(Kb of CN– = 5 × 10–5). (log 2 = 0.3)
(A) 9 (B) 9.4 (C) 9.7 (D) 10

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10. The solubility of Fe(OH)3 in a buffer solution of pH = 4 is 4.32 × 10–2 mol/L. How many times is this solubility
greater than its solubility in pure water. (Ignore the hydrolysis of Fe3+ ions) Given: 4.32 / 0.4 = 6.83
(A) 1011 (B) 6.83 x 106 (C) 2.16 x 109 (D) none of these

11. A solution contains 0.01 M Zn2+ and Cu2+ ions. It is saturated by passing H2S gas in the solution. The
solubility products of ZnS and CuS are 3.0 × 10–22 and 8.0 × 10–36 respectively. Which of the following is true?
K1 = 10—7, K2 = 10—14, [H2S, aq]saturated=0.1M
(A) ZnS will precipitate (B) CuS will precipitate
(C) Both ZnS and CuS will precipitate (D) Both Zn2+ and Cu2+ will remain in the solution.

12. In the electrolysis of brine (NaCl) using mercury cathode, the mass of amalgam (NaHg) produced is 6.69 g.
Find the time for which 9.65 A current is passed.
(A) 300 sec (B) 600 sec (C) 100 sec (D) 400 sec

13. Which of the following expressions correctly represents the equivalent conductance at infinite dilution of
Al2(SO4)3. Given that  Al3+ and  SO 2  are the equivalent conductances at infinite dilution of the
4

respective ions?

(A) 2  Al3+ +3  SO 2  (B)  Al3+ +  SO 2 

4 4

1  1
(C) (  Al3+ + 3  SO 2  ) × 6 (D) +  SO 2 
3 Al3+

4 2 4

14. Time after which one millimole of potassium metal is deposited by the passage of 9.65 ampere through
aqueous solution of potassium ions is
(A) 30 s (B) 10 s (C) 30,000 s (D) infinite

15. In the closest packing of atoms,

(A) The size of tetrahedral void is greater than that of octahedral void
(B) The size of tetrahedral void is smaller than that of octahedral void
(C) The size of tetrahedral void is equal to that octahedral void
(D) The size of tetrahedral void may be greater or smaller or equal to that octahedral void depending
upon the size of atoms.

16. The olivine series of minerals consists of crystal in which Fe2+ and Mg2+ ions may substitute for each-other
causing substitutional impurity defect without changing the volume of the unit cell. In olivine series of
1 1
mineral, oxide ion exist as fcc with Si4+ occupying th of octahedral void and divalent ion occupying th of
4 4
tetrahedral void. The density of forsterite (Magnesium silicate) is 3.21 g/cc and that of fayalite (Ferrous
silicate) is 4.34 g/cc. If density of olivine is 3.88 g/cc, then which of the following statement is INCORRECT.
(A) Forsterite = Mg2SiO4 ; Fayalite = Fe2SiO4
(B) An olivine contains 40.71% Forsterite and 59.29% Fayalite
(C) Forsterite Mg2SiO4 with 59.29% percentage
(D) (A) & (B)

17. Which of the following planes of FCC are identical ?

(i) (ii) (iii) (iv)

(A) (i), (ii) and (iii) (B) (i) and (iv) (C) (i) and (ii) (D) None

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18. Which of the following has been named correctly ?
(A) S2O32– thiosulphite ion (B) N3– nitride ion
(C) HAsO3–2 monohydrogenarsenite ion (D) H2PO4– dihydrogenphosphite ion

19. Which of the following is not an ambidentate ligand ?

(A) CN– (B) SCN– (C) NH3 (D) NO2–

20. Which of the following is not correctly matched ?

(A) Sodium (ethylenediaminetetraacetato)chromate(II) – Na2[Cr(CH3COO)4 (en)]
(B) Dichloridobis(ethane-1, 2-diamine)cobalt(III) ion – [Co(Cl)2(en)2]+
(C) Tris(bipyridyl)iron(II)ion – [Fe (NH4C5–C5H4N)3]2+
(D) Ammineaquadibromidocopper(II) – [Cu(NH3)(H2O)Br2]

21. Which of the following combination of ions will have highest polarisation :
(A) Fe2+, Br– (B) Mn+3, I– (C) Ni2+, Cl– (D) Fe, Br–

22. The calgon process of softening hard water makes use of

(A) Sodiumaluminium silicate (B) Sodium hexametaphosphate
(C) Calcium hydroxide (D) Washing soda

23. The colour of light absorbed by an aqueous solution of NiSO4 is :

(A) orange–red (B) blue-green (C) red-violet (D) yellow

24. Compound 'X' has significant amount of enol 'Y'. 'X' racemises during enolisation. ' X ' can be :

Cl
|
(A) O  HC — C — CH  O (B)
|
H

(C) (D)

25. Which of the statement is incorrect about following resonating structures ?

 

(A) IInd and IIIrd are resonating structure.

(B) Ist structure is most stable resonating structure.
(C) The stability order is I = II > III
(D) The resonance hybrid is more stable then I, II & III

26. Which of the following groups exerts significant +M effect as well as –I effect?

(A) group (B) group (C) –ONO group (D) –NO2 group

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27. Which of the following is not correct for dipole moment ?

Cl
Cl

(A) > (B) =

Cl
Cl

(C) > (D) >

28. The most and least stable carbocations among the following are respectively :

(A) V & II (B) II & IV (C) I & III (D) I & II

IBr
29. The product of reaction is 
CCl 4

I I Br Br
(A) (B) (C) (D)
Br Br I I

30. The hydrolysis product of the following can not be distinguished by :

O

H O
(A) Tollen’s Reagent (B) Lucas Reagent. (C) Fehling solution (D) I 2  NaOH

31. Diazocoupling reaction in aromatic compounds is an electrophilic substitution reaction. In which of the
following reaction the ring subsitution is most suitable for diazocoupling reaction ?

N2 Cl OH N2 Cl
OCOCH3

(A) + (B) +

OCH3 NO2 CH3

N2 Cl N2 Cl
N(CH3)2 NH2

(C) + (D) +

SO3H NH2

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32. The rates of decarboxylation (on heating) and dehydration (base catalyzed) are respectively faster in

and

(A) I and III (B) II and III (C) II and IV (D) I and IV

(1) NaOH 3    (2) PBr

2 ( 3 ) KOH ( 4) SOCl
33.       
 (II) Product
( Aprotic solvent ) DMSO

In this reaction I and II are,

(A) Enantiomers (B) Structure isomers
(C) Geometrical isomers (D) Identical compounds

(i) CO + NaOH, 
34.  2    (P > Q) % yield

(ii) H

Select the correct option :

(A) Boiling point , (P > Q) (B) Melting point , (Q > P)
(C) Water solubility , (P > Q) (D) Acid Strength , (Q > P)

35. Consider H2C=CH2 , ethene. If one CH2 group is held in its position, while the other CH2 group is rotated about
the axis passing through nuclei C–C in ethene, then : Which of the following is wrong ?
(A) the other CH2 group moves out of plane of first CH2 group.
(B) C–C  bond breaks
(C) C–C  bond breaks
(D) C–C bond length increases

COCH3

H OH
H OH
36. One mole of was treated with NaOH / I and then acidified. The product after acidification has
2

NO2
COCH2I

isolated and then heated with 3 equivalents of NaOH to give a new ionic species. The ionic species
formed will be :

- - -
COO COCH3 COO COO

- - -
H O H O H O H OH
(A) H - (B) H - (C) H (D) H -
O O OH O

NO2 NO2 NO2 NO2

- - -
COCH2I COO COO COO

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*
37. Br2 / h
D    major product

(Dextrorotatory isomer)

The number (x) of optically active products and number (y) of fractions obtained after distillation of mixture of
major products are respectively :
(A) 1, 3 (B) 3, 1 (C) 2, 2 (D) 4, 4

38. Product of given reaction is :

O=C–NH2

H2 / Catalyst
C=O Excess
H

O=C–NH2 CH2–NH2 CH2–NH2

(A) (B) (C) (D)

CH2OH CH2 OH CH2–OH

39. The true statement about the given compound is :

(A) It has centre of symmetry (B) It has axis of symmetry

(C) It has plane of symmetry (D) It is a meso compound

40. The compound of the formula CH3CO(CH2)5CH=CH–COOH would be expected to

I : rotate the plane polarised light
II : contain chiral centre
III : Contain three stereocentres
IV : show geometrical isomerism
(A) only I, II, III correct (B) only II, IV correct (C) I, II, III, IV correct (D) only IV correct

41. The number of fractions on fractional distillation of the mixture of all stereoisomer of the following compound?

(A) 3 (B) 4 (C) 5 (D) 6

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42. The most polar form of 1-Nitropropane is :

(A) (B)

(C) (D)

43. What is not true about the following compoud?

Cis–(1R,3S)–di-sec-butylcyclobutane

(A) It has a centre of symmetry (inversion centre)

(B) It has a plane of symmetry.
(C) It does not have two fold axis (C2) of symmetry.
(D) It is an achiral molecule.

44. The most stable form of meso in strong basic medium is :

(A) Anti form (B) Gauche form

(C) Fully eclipsed from (D) Partially eclipsed form

45. The incorrect statement about the following reaction is :

OMe
|
Me H Cl  C  C  Ph
| || |
| O H
Ph  C  NH2 + Ph  C  NH2      
| |
H Me

(A) The product mixture is optically active.

(B) Two optically active products are formed.
(C) All components of product mixture have different melting point.
(D) The products have mirror image nonsuperimposable relationship.

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SECTION – 2 : (One or more options correct Type)

This section contains 41 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE or MORE are correct.

46. 100 ppm (w/w) of He (by mass) is present in an Ar sample at 0ºC, in a rigid 22.4 L vessel. Which of the
following units remain unchanged as the temperature is raised to 100°C ?
(A) ppm (w/w) (B) mole fraction (C) molality (D) grams per litre

47. 10 ml of a sample of H2O2 solution liberates 112 ml of O2 gas at STP upon decomposition. Identify the correct
statement(s) :
(A) Normality of the above sample of H2O2 is 0.5 N
(B) 15 ml of the same sample of H2O2 solution liberates 224 ml of O2 gas at 1.5 atm and 273°C
(C) Milliequivalents of hypo required for the titration of liberated I2 when 10 ml of the same sample of H2O2
solution is treated with excess of acidified solution of KI are 20
(D) % (w/v) of given sample of H2O2 is 3.4 %.

48. Identify the wrong statement (s) :

(A) Van der Waal's equation is applicable to liquid state as well.
(B) Van der Waal's equation is best applied to vapor-liquid equilibrium zone for a given substance.
(C) Van der Waal's constant b is always independent of temperature.
(D) Third virial coefficient C is always independent of temperature.

49. According to Maxwell's distribution of molecular speeds, for the below graph drawn for two different samples of
gases A and B at temperature T1 and T2 respectively, which of the following statements is/are INCORRECT :

(A) If T1 = T2, then molecular mass of gas B(MB) is greater than molecular mass of gas A(MA).
(B) If molecular mass of gas A(MA) is equal to molecular mass of gas B(MB), then T1 > T2.
(C) If T1 < T2 , then molecular mass of gas B(MB) is necessarily less than molecular mass of gas A (MA).
(D) If gas A is O2 and gas B is N2, then considering them to be ideal gases, T1 is necessarily less than T2.

50. The P–V isotherm shown here may be applicable for

(A) a real gas

(B) vapor - liquid equilibrium of a pure substance
(C) vapor - liquid equilibrium of an ideal mixture of volatile liquids
(D) azeotropic liquid mixture

51. A certain mass of gas A is kept in a closed container where it undergoes dimerisation, according to the
reaction :
2A (g)  A2(g)
Assuming temperature to remain constant, it was found that the partial pressure of A2 gas after time t was
one-fifth of the initial pressure in container. Then, select the correct statement(s) :
(A) The ratio of initial total pressure to the total pressure at time t is 3 : 2.
(B)The mole fraction of A2 in the vessel after time t is 0.2.
(C) The percentage dimerisation of A upto time t is 40%.
(D) If each molecule of gas A weighs 10–22g, then the average molecular mass of the mixture in the container
after time t is about 75 amu.

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52. The thermal dissociation equilibrium of NH4HS(s) is studied under different conditions.
NH4HS(s) NH3(g) + H2S(g)
For this equilibrium, the correct statement(s) is (are) :
(A)K depends on temperature
(B) K is independent of the initial amount of NH4HS(s)
(C) K is dependent on the pressure of NH3 and H2S at a given T
(D) If pressure of NH3(g) is increased at equilibrium than pressure of H2S(g) decreases at given temperature.

53. Select correct statements about solubility of CH3COOAg in a buffer solution of pH < 7.
(A) Solubility of CH3COOAg increases with decrease in pH
(B) Solubility of CH3COOAg decreases with decrease in pH
(C) Solubility of CH3COOAg in a buffer solution of pH = 5 will be greater than that in pure water

(D) Solution of CH3COOAg in a buffer solution of pH = 6 will be smaller than K sp where Ksp is the solubility
product of CH3COOAg.

54. To 100 ml of an aqueous solution of 0.1M CH3COOH (Ka = 2 × 10–5), 0.01 mol of HCl(g) is passed. Select
correct options regarding the resulting solution.
(A) Degree of dissociation of acetic acid in resulting solution is 10–4
(B) pH of resulting solution is nearly 1
(C) Degree of dissociation of water in resulting solution is 1.8 × 10–15
(D) Concentration of OH– ions contributed by water is resulting solution is 10–7 M.

55. The standard reduction potential data at 25ºC is given below.

Eº (Fe3+.Fe2+) = + 0.77 V ;
Eº (Fe2+.Fe) = – 0.44 V ;
Eº (Cu2+.Cu) = + 0.34 V ;
Eº (Cu+.Cu) = + 0.52 V ;
Eº (O2(g) + 4H+ + 4e–  2H2O) = + 1.23 V ;
Eº (O2(g) + 2H2O + 4e–  4OH–) = + 0.40 V
Eº (Cr3+.Cr) = – 0.74 V ;
Eº (Cr2+.Cr) = – 0.91 V
Which of the following statements is/are correct on the basis of above data :
(A) O2 is a better oxidising agent in acidic medium.
(B) Cr2+ show disproportionation to Cr and Cr3+ in water.
(C) O2 oxidises Fe2+ to Fe3+ in acidic medium.
(D) Cu+ oxidises Fe to Fe2+ and H2O to O2 in acidic medium.

56. CCl4 and acetone form a non-ideal solution at room temperature in a copper container. For this process, the
true statement(s) is (are) :
(A) G is positive (B) Ssystem is positive
(C) Ssurroundings < 0 (D) H > 0

57. Which of the following is/are correct statement(s).

(A) Pure substance freezes at fixed pressure and temperature until all the liquid has frozen, Where as for a
dilute solution the freezing points keeps dropping.
(B) Boiling point of a pure liquid is always constant and is independent of pressure.
(C) The correct order of decreasing osmotic pressure of aqueous solution is
0.1 M NaCl > 0.1 M CH3COOH > 0.1 M urea.
(D) The higher the molecular weight of the non electrolyte solute, the smaller the freezing point depression
produced by one gram of that solute in 1000 g of solvent .

58. Which of the following is true regarding the following coordination compounds –
CrCl3.6NH3, PtCl4.4NH3, Co(NO2)3.3KNO2, PtCl2.2NH3
(A) PtCl2.2NH3 shows stereoisomers.
(B) PtCl4.4NH3 has maximum electrical conductance at infinite dilution.
(C) Co(NO2)3.3KNO2 is colourless.
(D) CrCl3.6NH3 has the maximum spin only magnetic moment.

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59. Which of the following is/are correct about
Tetraamminedithiocyanato-S-cobalt (III) tris(oxalato) cobaltate (III)?
(A) Formula of the complex is [Co(SCN)2(NH3)4] [Co(ox)3]
(B) It is a chelating complex and show linkage isomerism
(C) It shows optical isomerism
(D) It shows geometrical isomerism

60. The compound(s) that exhibit(s) geometrical isomerism or optical isomerism or both is(are) :
(A) [Ni(en)Br2] (B) [Pt(en)3]Cl4 (C) K2[NiCl2Br2] (D) [Pt(NH3)2(CN)2]

61. A d-block element forms octahedral complex but its spin magnetic moment remains same either in strong
field or in weak field ligand. Which of the following is /are correct?
(A) Element always forms colourless compound.
(B) Number of electrons in t2g orbitals are higher than in eg orbitals.
(C) It can have either d3 or d8 configuration.
(D) It can have either d7 or d8 configuration.

62. In the crystal field of the complex [Fe(Cl) (CN)4(O2)]4– the electronic configuration of metal is found to be
t 62g , e 0g then which of the following is true about this complex ion :
(A) It is a paramagnetic complex
(B) O–O bond length will be less than found in O2 molecule
(C) Its IUPAC name will be chlorotetracyanosuperoxidoferrate () ion
(D) It is a diamagnetic complex

63. Select the correct statement(s) about the compound NO[BF4] :

(A) It has 5 and 2 bond (B) Nitrogen-oxygen bond length is higher than in nitric oxide (NO)
(C) It is a diamagnetic species (D) B—F bond length in this compound is lower than in BF3

64. At least one element in its highest possible oxidation state is present in which of the following ?
(A) ClO3– (B) HNO3 (C) F2 (D) XeF6

65. Which of the following can produce B2O3 ?

(A) Heating borax with conc. H2SO4 (B) Passing CO2 through aq. NaBO2
(C) Combustion of diborane, B2H6. (D) Warming H3BO3 crystals till red hot.

66. CO2 can be liberated by :

(A) adding to NaHCO3 (B) adding to NaHCO3

(C) Passing CO over red hot carbon (D) burning diamond in air.

67. Which of the following statements are true?

(A) ClO2 in alkaline solution undergoes disproportionation.
(B) Ionisation enthalpy of molecular oxygen is very close to that of xenon.
(C) Hydrolysis of XeF6 may involve a redox reaction.
(D) Both P4O6 and P4O10 contain 12 P–O bonds

I II
68. Pyrolusite is MnO2 used to prepare KMnO4. Steps are, MnO2  MnO42–  MnO4– .
Steps I and II are respectively :
(A) fuse with KOH / air and electrolytic oxidation.
(B) fuse with KOH / KNO3 and electrolytic oxidation.
(C) fuse with conc. HNO3 / air and electrolytic reduction.
(D) dissolve in H2O and oxidation.

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69. A salt (X) is heated in a dry test tube. Reddish brown fumes (Y) are evolved which turn potassium dichromate
paper green and starch iodide paper blue (Y) is found to be paramagnetic. Then :
(A) X may be KNO3 (B) X may be ZnBr2
(C) X may be Mg(NO3)2 (D) Y turns red litmus blue

70. Which of the following molecules have been correctly named as per IUPAC nomenclature ?

(A) Ethyl 3-cyanobenzenecarboxylate

(B) 3-Cyanophenyl ethanoate

(C) Benzenecarboxylic 3-carbamoylbenzencarboxylic anhydride

(D) 1-(3-carbamoylphenyl) pentane-1,3-dione

71. The correct statement(s) concerning the structures P,Q,R & S is/are :

(P) (Q) (R) (S)

(A) Q & S are tautomers.

(B) R & S are resonating structures.
(C) P & R are tautomers.
(D) P & Q are resonating structures.

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 CHEMISTRY
72. Which of the following is correct ?
(A) > [Basic strength]

(B) > [Acidic strength]

(C) > [Basic strength]

(D) > [Basic strength]

73. Which of the following is / are correctly mathced

(A) Teflon – Vinyl fluoride
(B) Natural rubber – chloroprene
(C) Bakelite – Phenol + Formaldehyde
(D) Nylon-6,6 – Adipic acid + hexamethylene diamine

74. In which of the following reactions correct major product has been mentioned ?

(A) + OH 
H2 SO 4


O–N=O
HNO
3
(B)  
 
H2SO 4

O
S–OH
(C) conc . H2 SO 4
  
O

(D)

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75.

The correct statements about (I) and (II) are :

(A) The acid catalysed hydrolysis of (I) and (II) yields one product identical.
(B) For Wolff Kishner reduction (I) is the better reactant.
(C) (II) gives positive haloform reaction.
(D) Reduction by LiAlH4 forms a diol in both the cases.

76. Consider the following sequence of reaction.

O
(1) CH3MgBr H2SO4 O3
X Y Z
(2) H2O Zn/H2O
O
The compound X can be :

O O O
CHO

(A) (B) (C) (D)

77. Compound (X) C H O decolourises Baeyer’s reagent. It undergoes hydrolysis on reaction with dil. H SO and
4 8 2 4

produces (Y) and (Z). Both (Y) and (Z) give Iodoform test positive. Only (Y) gives Tollen’s test positive.
Choose the correct statements.
aq. NaOH(10%) 
(A) (Y)   CH3–CH=CH–CHO
Pyridinium chlorochromate (PCC)
(B) (Z)   (Y)

CH2 – CH – O – CH2 – CH3

Br2 /CCl4
(C) (X)  | |

 Br Br

(i) O3
(D) (X) 
(ii) Zn/H O
(Y) + other product
2

78. Which of the following reactions involve a carbocation intermediate ?

2Cl
(A) HCl + (B) 
 FeCl3

KCN
(C)  (D) H O
HCN 2

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79. In which of the following reactions D-exchange will take place ?

O
C H O K C 2H5O K  

(A) 2 
5

 (B)   
C 2H5 OD /  C 2H5OD
OC2H5


C 2H5O K 
NaOD
(C)    (D)  
C 2H5OD D 2O
Br

P2O5
CONH2 P

80.
Q

Which statement(s) is/are correct :

(A) Reduced product of P and Q will be metamers to each other.
(B) By dry distillation of hydrolysed products of P with Ca(OH) , gives benzophenone.
2

(C) Hydrolysed product of Q, reacts with NaNO2 + HCl followed by reaction with phenol, gives orange red
dye.
(D) Electrophile involved in the formation of Q is dichlorocarbene.

81. Primary (1º) amine group is formed in :

(A) NaHS (B) Br / KOH

 2

(C) CH NH / Cu O / 
3 22 (D) Zn / HCl
   

82. Which isomers are not separable from their mixture by any physical method of separation ?
(A) Enantiomers (B) Conformational isomers
(C) Geometrical isomers (D) Functional isomers

83. The correct statement(s) about the compound H3C(HO)HC–CH=CH–CH(OH)CH3 (X) is(are) :
(A) The total number of stereoisomers possible for X is 6.
(B) The total number of meso isomers possible for X is 2.
(C) The number of fractions on fractional distillation of all stereoisomeric mixture of X is 4.
(D) If the stereochemistry about the double bond in X is cis, the number of enantiomers possible for X is 2.
84. Which statement is incorrect about the following structures :

( I) (II)

(A) II has steric strain zero. (B) I has angle strain. (C) I has zero torsional strain.
(D) II has maximum van der waal strain between two vicinal hydrogen atoms at C2 – C3 or C5 – C6.

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85. Consider the ozonolysis of trans-4, 5-dimethyl cyclohexene having the configuration given below.

Which product(s) possible is/are formed in the above reaction ?

(A) (B) (C) (D)

86. Which of the following is/are biomolecular Nucleophilic substitution ?

I NaOH NaOH
(A)  

DMSO
(B)  



NaOH
(C)  
 (D) OH 
HI


NO2

SECTION - 3 (True & False Statement Type)

This Section Contains 5 questions. Each questions contains 4 statements S1, S2, S3 & S4. Each
statement is either true (T) or false (F). Each questions has 4 choices (A), (B), (C) and (D) each of which
contains whether S1, S2, S3 & S4 are true or false. Exactly one choice contains the correct order of truthness
or falseness of S1, S2, S3 & S4 respectively and is the correct choice.

87. S1 : The IUPAC name of the compound [Cr(NH3)5(NCS)] [ZnCl4] is pentaamminethiocyanato-N-chromate(III)

tetrachlorozincate (II).
S2 : Mohr’s salt FeSO4.(NH4)2SO4.6H2O is an example of double salt.
S3 : In [Co(NH3)4(NO2)2]NO3 coordination number of cobalt is 6.
S4 : In [Fe(CO)5] secondary valency of iron is 0.
(A) F T T F (B) T T T T (C) F T T F (D) T T T F

88. S1 : There are only 12 bonding electrons available in one molecule of diborane.
S2 : B3N3H6 is an electron deficient compound
S3 : Al2Cl6 sublimes on heating
S4 : In (Si2O5)n2n– anion, three oxygen of a SiO44– tetrahedran are shared with another SiO44– tetrahedron.
(A) FFFF (B) TTTT (C) TTFF (D) TFTT

89. S1 : Hybridisation of nitrogen atom is sp2 in pyrrole.

S2 : Positive charge in anilinium ion is not delocalised.
S3 : Buta-1,3-diene has all equivalent resonating structure.
S4 : Carbonate dianion has all carbon oxygen bond lengths equivalent.
(A) T F F T (B) T T F F (C) T F T F (D) T T F T

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 CHEMISTRY
90. S1 : Chiral molecules are never superimposable over their mirror image.
S2 : Diastereomers have different physical properties.
S3 : A meso compound is always superimposable over its mirror image.
S4 : Enantiomers have same physical properties.
(A) T T T F (B) T T T T (C) F T T F (D) F F T F

91. S1 : The chair form of cyclohexane has no angle strain.

S2 : The boat form of cyclohexane has maximum torsional strain.
S3 : The twist boat form of cyclohexane is chiral.
S4 : Half chair form of cyclohexane is least stable conformation.
(A) T T T F (B) T T T T (C) F T T F (D) F F T F

SECTION – 4 : (Paragraph Type)

This section contains 14 paragraphs each describing theory, experiment, data etc. Eighteen questions
relate to two paragraphs with one or two or three questions on each paragraph. Each question of a
paragraph has only one correct answer among the four choices (A), (B), (C) and (D).

Paragraph for Question Nos. 92

Colligative properties i.e., the properties of solution which depend upon the number of particles present in
solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour
pressure. Experimental values of colligative properties for electrolytes are always higher than those obtained
theoretically because electrolytes dissociate to furnish more ions in solution. On the other hand experimentally
obtained values of colligative properties for associating nature of solute are lower than those obtained
theoretically. The ratio of experimental colligative properties to theoretical colligative properties is called as
vant Hoff factor (i).

92. For 1 M solution of HA, the dissociation constant Ka in terms of vant Hoff factor (i) can be written as (where
C 2
Ka = , C  concentration) :
1 

(i  1)2 (i  1)2 i (i  1) 2
(A) (B) (C) 2 (D)
i i (i  1) ( 2  i)

Paragraph for Question Nos. 93

Consider the given plots for four gases at 300 K :

1.01

A
1.0

0.99 B

Z
0.98
C
Vm = Molar volume
0.97 Z = Compressibility
factor
D
0.96
0 0.02 0.04 0.06 0.08 0.1
1
Vm

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 CHEMISTRY
93. If the slope of line B is –0.10 Lmol–1, what is the relationship between vander Waal's constants 'a' and 'b'?
(Ignore the higher terms of Virial equation)

 1  1  1 
(A) a =  b   atm L2 mol–2 (B) b =  a    24.6 L mol–1
 10  24.6  10 

 1   1 
(C) a =  b    24.6 atm L2 mol–2 (D) b =  a    24.6 L mol–1
 10   10 

Paragraph for Question Nos. 94

Dehydration of salts is an important class of heterogenous reaction. The salt hydrates often dissociate in
steps to form a number of intermediate hydrates according to the prevailing pressure of moisture in contact
with the solid hydrates. Thus copper sulphate pentahydrate on dissociation yields trihydrates, monohydrates
and then the anhydrous salts in the above order as follows.

94. The ratio of equilibrium constant between pentahydrate and trihydrate and equilbrium between trihydrate and
monohydrate is :
(A) 1.9 (B) 2.9 (C) 8.6 (D) 5.6

Paragraph for Question Nos. 95

The cell potential for the unbalanced chemical reaction :
Hg22+ + NO3– + H3O+  Hg2+ + HNO2 + H2O
under standard state conditions is Eºcell = 0.02 V
2.303RT
Given : NO3– + 3H3O+ + 2e–  HNO2 + 4H2O, Eº = 0.94 V and = 0.06.
F

95. At what pH will the cell potential be zero if the concentration of other components are equal to one ?
1 1 2 2
(A) (B) (C) (D)
6 3 3 9

Paragraph for Question Nos. 96

Addition of a non-volatile solute to a solvent lowers its vapour pressure. Therefore , the vapour pressure of a
solution (i.e.,V.P. of solvent in a solution) is lower than that of pure solvent , at the same temperature. A
higher temperature is needed to raise the vapour pressure upto one atmosphere pressure , when boiling point
is attained. However , increase in b.pt. is small. For example , 0.1 molal aqueous sucrose solution boils at
100.050 C. Sea water , an aqueous solution, which is rich in Na+ and Cl– ions , freezes about 10 C lower than
frozen water. Temperature at which vapour pressure of solid becomes equal to vapour pressure of liquid is
called freezing point of liquid or melting point of solid.

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 CHEMISTRY
96. When 250 mg of eugenol is added to 100 g of camphor (kf = 39.7 K molality–1 ) , it lowered the freezing point
by 0.620 C. The molar mass of eugenol which an nonelectrolyte is :
(A) 1.6 × 102 g/mol (B) 1.6 × 104 g/mol (C) 1.6 × 103 g/mol (D) 200 g/mol

Paragraph for Question Nos. 97

Complex compounds are molecular compounds which retain their identities even when dissolved in water.
They do not give all the simple ions in solution but instead furnish complex ions. The complex compounds
are often called coordination compounds because certain groups called ligands are attached to the central
metal ion by coordinate or dative bonds. Coordination compounds exhibit isomerism, both structural and
stereoisomerism. The structure, magnetic property, colour and electrical properties of complexes are explained
by various theories.

97. In which of the following pairs, both complexes have the same geometry ?
(A) [NiCl4]2– , [Ni(CN)4]2– (B) [Cu(NH3)4]2+, [AuCl4]–
(C) [Ni(CO)4] , [Ni(CN)4]2– (D) [Cu(NH3)4]+ , [Ni(NH3)4]2+

Paragraph for Question Nos. 98

Curcumin (pronounced “ Kur kyoo min”) is the principal curcuminoid of the popular Indian spice turmeric,
which is a member of the ginger family (Zingiberaceae). The curcuminoids are natural phenols that are
responsible for the yellow color of turmeric. Curcumin is bright yellow colored and may be used as a food
coloring.

Curcumin can exist in several tautomeric forms, including a 1,3-diketo form and two equivalent enol forms.
The enol form is more energetically stable in the solid phase and in solution.

98. Curcumin can be used for boron quantification in the curcumin method. It reacts with boric acid to form a red-
colored compound, rosocyanine.

The entire skeleton of curcumin is in resonance with the 1,3-dicarbonyl section, making the backbone an
extended cojugated system. Investigations of the structure have shown that the positive charge is distributed
used throughout the molecule. In rosocyanine, the two curcumin groups are :
(A) coplanar
(B) perpendicular relative to one another
(C) free to rotate about tetracoordinate boron
(D) at an angle of 109.5 degrees to each other, approximately

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 CHEMISTRY
Paragraph for Question Nos. 99
Observe the following sequence of reaction and answer the related questions.

99. The product P will shows positive test with :

(A) Tollen’s reagent (B) I2 / NaOH (C) 2,4.D.N.P (D) All A, B & C

Paragraph for Questions 100

Observe the given compound.

H CH3 (CH2)4 — NH2 CH2—Ph

H3N C — NH C — NH C — NH COO
|| || ||
O O O
H H H H

100. This compound is a :

(A) Tripeptide (B) Tetrapeptide (C) A single -amino acid (D) Pentapeptide

Paragraph for Questions 101

H3C
C CH2 (i) O 3
CH3 OH/H Conc. H2 SO 4 ,   
  (X)   (Y) (ii) Zn/H2O (W) + (Z)
H3CH2C O

NaOI

(yellow crystals)

101. The compound ‘W’ is

(A) An aldehyde (B) An ester (C) A ketone (D) An Alkoxy ketone

Paragraph for Question Nos. 102

An unsaturated compound X (C5H10O) exists as four stereoisomers. Y, (structural isomer of X) is neither

unsaturated nor shows any stereoisomerism. X and Y have same functional group. The third isomer (Z) is a
positional isomer of X, and has only two stereoisomers.

102. The compound Z cannot be ?

(A) CH2 = CH– CH –CH2 CH3 (B) H2C = CH–CH2– CH –CH3
| |
OH OH

CH3
|
(C) CH3 – CH = CH–CH2–CH2–OH (D) H2C=C–CH–CH3
|
OH

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 CHEMISTRY
Paragraph for Question Nos. 103 to 104
Concentration of a solution can be represented in many ways. Some of the important concentration terms
are as follows :
number of moles
Molarity of solution =
volume of solution in litre
Let a solution is prepared by dissolving w gm of solute of mol.wt. M in V ml water.
w
 Number of moles of solute dissolved =
M

number of moles of solute

molality =  1000
mass of solvent in gram

mass of solute in gm
% w/v =  100
mass of solution in ml

103. Equal volume of 1M NaOH, 10% w/v NaOH and 1m NaOH (d = 1.2 g/ml) are mixed then what will be M of final
solution. (All aqueous)
121 310 39
(A) (B) (C) (D) None of these
78 617 17

104. 120 gm of 1 M aqueous NaOH solution (d = 1.2 g/ml) is mixed with x ml of 9.8% w/v H2SO4 solution. pH of
resulting solution is 13 then value of x will be :
(A) 50.92 (B) 75.27 (C) 15.75 (D) 42.85

Paragraph for Question Nos. 105 to 106

6 gm of magnesium (Mg) is burnt with insufficient amount of oxygen. The residue is treated with 100 ml of
H2SO4 solution (30% by mass, 1.4 gm/ml density), resulting in an evolution of 3.36 litre of H2 gas at STP.
After the reaction, density of H2SO4 solution is found to be 1.25 gm/ml. Assume no change in volume of
H2SO4 solution.

105. Percentage w/w of final H2SO4 solution is :

(A) 15 (B) 18 (C) 14 (D) 9

106. Mass of oxygen used is :

(A) 3.2 g (B) 1.2 g (C) 2.4 g (D) 1.6 g

Paragraph for Question Nos. 107 to 109


An aromatic compound P(C8H7OD) looses optical activity in O H /H2O (very dilute solution) At equilibrium

the product mixture is resolvable. When P is kept in O D /D2O then also it looses optical activity but the
product (R) is non resolvable. 'Q' another isomer of P forms terephthalic acid (benzene–1,4–dicarboxylic
acid) on KMnO4 oxidation.

107. The compound 'P' is :

(A) (B) (C) (D)

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 CHEMISTRY
108. The product 'R' is :

(A) (B) (C) (D)

109. The compound 'Q' is :

(A) (B) (C) (D)

SECTION - 5
Matrix - Match Type

This section contains 5 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column-I are labelled A,
B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
given statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be drakened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t;
then the correct darkening of bubbles will look like the following :

110. Column - I Column - II

(A) In a sample of H–atom for 5  2 transition (p) Maximum 6 spectral lines will be observed from the
sample
36
(B) In a sample of He+ ion for 5  1 transition (q) A photon of wavelength  = can be emitted.
5R

7R
(C) In a sample of H–atom for 7  3 transition (r) A photon of wave number  = can be emitted
144

(D) In a sample of He+ ion for 7  4 transition (s) When single isolated atom/ion is considered,
maximum 4 spectral lines are observed for given
transition.
(t) At least one photon is visible.

111. Column – I Column – II

(A) 1 : 0.2 M KCl, 2 :0.2 M NaCl (p) 1 is hypertonic to .
(B) 1 : 0.2 M ZnSO4, 2 : 0.1 M Glucose (q) 1 is hypotonic to 2.
(C) 1 : 0.1 M Sucrose, 2 : 0.1 M Urea (r) 1 and 2 are isotonic.
(D) 1 : 0.1 M KCl, 2 : 0.1 M Na2SO4 (s) Across the SPM (semi permeable membrane)
no net migration of solvent in these solutions.
(t) 1 < 2

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 CHEMISTRY
112. Column-I Column-II
(A) NO2 (p) Hydrolysis occurs through redox reaction
(B) SOF2 (q) Hydrolysed products have no hydra acid.
(C) XeF4 (r) All hydrolysed products are acids
(D) Cl5 (s) Hybridisation of central atom remains same in final hydrolysed product
(t) One of the hydrolysed product react with glass.

113. Column - I Column - II

Compounds Properties of compounds

(A) (p) Optically active

(B) (q) Plane of symmetry

(C) (r) Centre of symmetry

(D) (s) Axis of symmetry (Besides C1)

(t) Optically inactive

114. Column - I Column - II

(A) TeCl4 (p) Central atom has one lone pair.

(B) SiF6 –2 (q) Central atom has two lone pair.

(C) BrF3 (r) Central atom is sp3d2 hybridised.

(D) [PI4]+ (s) All possible bond angles are identical.

(t) Central atom is sp2 hybridised.

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 CHEMISTRY

SECTION – 6 : (Integer value correct Type)

This section contains 52 questions. The answer to each question is a single digit integer, ranging from
0 to 9 (both inclusive).

115. If the sum of mole fraction of NaOH in its aqueous solution and the mole fraction of H2O in an another
aqueous solution of KOH is equal to one, find the molality of KOH solution if the molality of NaOH solution is
'm'.
Report your answer as 'Y' where Y = (Molality of KOH solution) (Molality of NaOH solution)

116. Due to partial corrosion of a piece of copper into cuprous sulphide Cu2S, it gains weight. If the % of total
copper that has undergone corrosion is 31.75%, then % gain in weight of piece of copper is :

117. A mercury column of length 10 cm is in the middle of a horizontal tube of length 1 m closed at both
ends containing same amount of a gas in both columns. If the tube is placed vertically, the mercury
225
column will shift through a distance of cm from its initial position. Find the final pressure of gas
13
in upper column (in cm of Hg) when the tube is placed vertically.

118. For the reaction A C, the concentration and time is shown as

Calcualte the value of KC for the reaction 2 C 2A

119. [Au(CN)2]– is a very stable complex under certain conditions and Kf of [Au(CN)2]– is 4  1028. x  10–y M
concentration of cyanide ion is required to maintain the equilibrium at which 99 mol % of the gold is in the
form of the cyanide complex then (y – x) will be :

120. To 1L solution, which is 0.1 M in AgNO3 and 0.2 M in CuSO4, a 1L 0.4 M NaCl solution is added.
If the final concentration of Cu+ in the solution is x × 10–y (x and y are natural numbers) then (x + y) is. (Ksp
(AgCl) = 1.6 × 10–10, Ksp (CuCl) = 10–6)

121. 32 g of hydrated magnesium sulphate MgSO4.x H2O , when dissolved in 84 g of water, the solution freezes at
–4.836 C . If Kf = 1.86 K kg mol-1 and MgSO4 is a strong electrolyte, what is the value of x ?

122.

Arrangement -I Arrangement -II

The difference in height of the mercury column in two arms of U tube manometer in arrangement– is h1 = 660
mm. In another arrangement– at same temperature, 222 gm of CaCl2 is dissolved in 324 gm of water and
difference in height of mercury column in two arms is found to be h2 = 680 mm. If the value of degree of
dissociation for CaCl2 in arrangement– is  then the value of 6.4  is : [Atmospheric pressure = 1 atm]

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 CHEMISTRY
123. Vapour pressure of an equimolar mixture of benzene and toluene at a given temperature was found to be
80 mm Hg. If vapour above the liquid phase is condensed in a beaker, vapour pressure of this condensate at
the
same temperature was found to be 100 mm Hg. If the pure state vapour pressure of benzene and toluene is
x  2y
respectively x and y. Then determine value of :
50

124. 1.0 gram of a monobasic acid HA in 100 gram H2O lower the freezing point by 0.155 K. 0.45 gram of same
1
acid require 15 ml of M KOH solution for complete neutralisation. If the degree of dissociation of acid is ,
5
then value of ‘20’ is : (Kf for H2O = 1.86 K.Kg/mole)

125. How many of the following statements is/are true ?

(1) Silica gel absorbs water molecule from moist air.
(2) The entropy of gas decreases when it gets adsorbed on charcoal.
(3) Heterogeneous catalysts like Ni(s) in the hydrogenation of vegetable oil function by chemisorption.
(4) The enthalpy of physisorption is smaller in magnitude than enthalpy of chemisorption.
(5) As temperature increase, the extent of physisorption decrease but it can get converted to chemisorption
at higher temperature.

(6)

Graph A represent chemisorption and graph B represent physisorption.

126. Consider the following cell reaction :

2AgCl(s) + H2(g)  Ag(s) + 2H+(aq) + 2 Cl– (aq) E° = 0.19 V.
At [Cl–] = 10–3 M and P(H2) = 0.01 atm, find the pH, if the cell potential is 0.43 V at 25°C.
2.303R(298)
(Take = 0.06)
F

127. The sum of number of hexagonal and triangular faces that are present in a truncated tetrahedron is :

128. How many type of isomerism is exhibited by the complex [Co(NH3)4 (NO2)2]Cl ?

129. Coordination number of underlined or mentioned atom is greater than or equal to 4 in how many of the
following ?
(i) Na2 SiF6
(ii) Silicon in Silica
(iii) CaSiO3 (where the silicate unit is cyclic trisilicate)
(iv) Silicon
(v) [Ag(S2O3)2]3–
(vi) SO32–
(vii) H3PO3
(viii) N2O5
(ix) B2H6

130. If for [FeF6]3– EAN (effective atomic number) is xy then value of x + y is :

131. How many of the following are diamagnetic ?

(a) K4[Fe(CN)6] (b) Na3[Co(ox)3] (c) [Pt(NH3)3Cl] Br (d) [Fe(H2O)6]2+
2–
(e) [Zn(NH3)4] Cl2 (f) [MnO4] (g) Li[AlH4] (h) [V(H2O)6]2+

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 CHEMISTRY
132. In how many of the following salts, IUPAC name ends with 'ate'.
KClO2 Ca(H2PO2)2, CaCO3
Na2S2O3, CaC2O4, KSCN
K2HPO3, Ca3(PO4)2, Na2ZnO2

133. How many of the following contain all or some iron in +2 oxidation state?
(a) FeS2 (b) Haematite
(c) Magnetite (d) Brown ring complex
(e) Na2[Fe(CN)5(NO)] (f) Fe[Fe(CN)6]
(g) K2Fe[Fe(CN)6] (h) Ferrocene ([Fe(C5H5)2])
(i) FeWO4

134. In how many of the following molecules/ions, the number of electrons in  molecular orbital (both  & ) are
more than or equal to 9. (In ground state)
(a) N2 (b) N2

(c) Be2 (d) B2– (e) B2 (f) C2–
2

(i) Li2 (j) O 2 (k) F2

  
(g) C2 (h) H2

135. The number of equivalent contributing structures possible for XeO64 – is m. The bond order of Xe – O bond is
n. Find (m  n) × 0.2. Round off your answer to the nearest integer.

136. In how many of the following species the central atoms have two lone pairs of electrons ?
XeF4 XeF5– F2SeO2
XeF3+ XeOF4 ClOF3
ICl
4
–
SCl2 OSF4

137. Adding H to a given anion may significantly change the bond length between existing atoms of the original
anion due to change in their bond order. This is observed on addition of H to how many of the following
anions ?
TeO66– , O65– , XeO64– , C22–, O22– , N3–, 3–

138. How many of the following species have exactly four equally contributing resonance structures ?

COO –
ClO4– , PO43–, XeO64– , oxalate : | , CH3–COO– , SF4, N3– , HCO3–
–
COO

139. How many of the following elements have +3 as their most stable oxidation state in their compounds.
Al, Tl, Mn, Bi, P, Cr, Cu, Sc, Si

140. How many of the following produce N2 on being heated ?

(a) (NH4)2SO4 (b) NH4NO2 (c) NH4NO3 (d) Ba(N3)2
(e) NaN3 (f) NH4ClO4 (g) (NH4)2Cr2O7 (h) Pb(NO3)2

141. In a study of the equilibrium, H2(g) + I2(g) 2HI(g) 1 mole of H2 and 3 moles of I2 gives x mole of HI.
Addition of a further 2 moles of H2 gave an additional x mole of HI at equilibrium. calculate value of ‘10x'.

142. How many of the following liberate coloured vapours/gas with concentrated H2SO4?
KCl (s) + K2Cr2O7 (s), KNO2 (s), KI (s), K2S (s), KCl (s)
KBr (s) + MnO2 (s), KNO3 (s), KCI(s) + MnO2 (s), K2SO3

143. (i) Ti is purified by Van Arkel method. In it formula of metal iodide vapour formed is TiP.
(ii) Oxidation state of Fe in Fool's gold is q.
(iii) In the test of Ni2+ rosy red ppt. of [Ni(dmg)2] is formed.
In it r five membered rings and s six membered. H-bonding having ring are formed.

p qr  s
Value of   is ....... .
 2 

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 CHEMISTRY

144. If the number of compounds amongs the following where d x 2  y 2 orbitals will not take part in hybridisation is
(A). Determine value of (A).
(1) [Pt(NH3Cl (H2O)Br] (2) SF4 (3) [Cu(NH3)4]2+ (4) [XeO3F2]
(5) [XeO2F2] (6) [Co(en)3]3+ (7) [Fe(CO)5] (8) POCl3
(9) PCl5 (10) XeO64–

145. How many enol form are possible for ?

146. How many acids (given below) react with NaHCO3 and liberate CO2 ?

CCl3 – COOH CH3–CH2–OH HCl

147. How many p-orbitals are parallel to each other in the following conjugated system?

CH2

148. How many of the following groups an exert –M effect ?

O
CH3 , , ,

O–CH3

O–C = N , –C = N
O
+
.....NO2, .....
–O–C–CH3 , .....–N = N

O
.....–CH=CH–C–H

O
149. CH2=CH–CH2–C C–CH=CH–C–H
The maximum number of –electron pairs in direct conjugation with each other is :

150. The number of deuterium atoms found in the tautomer of when it is kept in OD/D2O for a long

period of time ?

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 CHEMISTRY

151. Number of carbocations which are more stable than CH  CH  CH2 from the following is :

(i) (ii) (iii) (iv) (v) (vi)

(vii) (viii) (ix)

152. How many compounds are more reactive than ethene towards electrophilic addition?

O
CH3–CH=CH2 , H–C–CH=CH2 , Cl–CH=CH2 , CH3–O–CH=CH2 , H–CC–H ,
I II III IV V
Ph–CH=CH2 , CH2=CH–CH=CH2
VI VII

1 1
CH == O CH == O
2 2
H H H OH
3 3
HO H H H
153. 4
PhNHNH2 4
PhNHNH2 ;
H OH H OH
5 5
H OH H 6
OH
6
CH2OH CH2OH
(A) (B)
D-2- Deoxy glucose D-3-Deoxy glucose

The sum of total number of moles of PhNHNH used with A & B _____. 2

154. How many of these amino acid are negatively charged at pH = 7.0 ?
Alanine Lysine Cysteine Glumatic acid
Glycine Leucine Aspartic acid Arginine

155. How many compounds are more reactive than benzene towards Nitration ?

CH3 Cl OCH3 COOH OCOCH3

, , , , , N ,
H

CD3 N=O

, , ,
N

156. How many aldol products are possible (structural only) when mixture of HCHO, CH3CHO and
O
CH 3–C–CH3 are reacted in dilute NaOH ?

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 CHEMISTRY

O
Et
157. Total number of -Keto monocarboxylic acids (including stereoisomers) which on heating give .

158. Rearrangement of carbon skeleton of substrate is possible in which of the following reactions ?
EAS (Electrophilic aromatic substitution), electrophilic addition on alkenes, free radical substitution of alkanes,
SN1, SN2, E1, E2, E1cB, SN2Th, SN2Ar
159. Find the number of products (stereoisomers) formed in the following reaction (consider only major product) ?

Ph
CH3 Cl
CH3 H
alc. KOH (excess)
CH3 H
CH3 Cl (–2HCl)

Ph

(X)
HBr /R2O2 /light
160. H  
Mg/ether
 CO
2
(1)  
(Major)
OCH3

(Z)

fractional distillation
 (Y)
No. of fractions
H2O

Find the value of (Z).

161. A mixture of 1 amides (benzenoid) having molecular formula (C8H9NO) reacted with Br2/NaOH. The number
of 1 amines products formed will be :
162. Number of meso compounds from the following is :

(i) (ii) (iii)

(iv) (v) (vi)

(vii) (viii)

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 CHEMISTRY
163. The total number of structural isomers which can show geometrical isomerism with molecular formula C3H7N
is :

164. In the following sequence of reaction number of Nucleophilic substitution is :

165. A compound(P) with formula C4H6O2 has a fruity smell. It produces no color with phenolphthalein. On adding
NaOH to (P) and phenolphthalein mixture, a pink color is seen. But this color of phenolphthalein fades away
slowly on reaction with (P). Number of possible structural isomers for (P) is:

166. The compound ‘X’ is composed of carbon, Hydrogen and Oxygen. It has 2 geometrical isomers. It has 4
stereoisomers. All 4 stereoisomers are optically active. If X is the smallest alkenoic acid which satisfies all
these conditions then calculate total number of carbon present in compound X.

SECTION – 7 : (Integer value correct Type)

This section contains 23 questions. The answer to each question is a Two digit integer, ranging from
00 to 99 (both inclusive).

167. A mixture of O2 and gas “Y” (mol. wt. 80) in the mole ratio a : b has a mean molecular weight 40. What would
be mean molecular weight, if the gases are mixed in the ratio b : a under identical conditions ? (gases are
non-reacting) :

168. 1 mole of each of the following acids exactly neutralize a maximum of how many moles of NaOH, under
required favourable conditions?
HCl, HNO3, H2SO4, H2SO3, H3PO4, H3PO3, H3PO2, H4P2O5, H3BO3, H3P3O9

169. 2 moles of a mixture of O2 and O3 is reacted with excess of acidified solution of KI. The iodine liberated
require 1L of 2M hypo solution for complete reaction. The weight % of O3 in the initial sample is x. Find x.

170. Consider the following equilibrium in a closed container.

PCl5(g) PCl3 (g) + Cl2(g)
PCl5 gas at a certain pressure is introduced in the container at 27°C. However , the total pressure at equilibrium
at 207°C was found to be double the initial value. The % dissociation of PCl5 at 207° C is :

171. A sparingly soluble salt MX is dissolved in water to prepare 1 lit. saturated solution. Now 10–6 mol NaX is
added into this. Conductivity of this solution is 29  10–6 S/m. If KSP of MX is a  10–b then find value of (a + b)?

Given 0x –  4  10 –3 S m2 mol–

0Na   5  10 –3 S m2 mol–

0M  6  10 –3 S m2 mol–

172. A solute’S’ undergoes a reversible trimerization when dissolved in a certain solvent. The boiling point elevation
of its 0.1 molal solution was found to be identical to the boiling point elevation in case of a 0.08 molal solution
of a solute which neither undergoes association nor dissociation. To what percent had the solute ‘S’ undergone
trimerization?

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 CHEMISTRY
173. A complex compound is represented as CoCl3.xNH3. Its 0.1 M solution in water shows depression in freezing
point equal to 0.558K. Assuming 100% ionisation of complex and coordination number of Co to be six,
calculate the value of ‘3x’. Kf for H2O is 1.86 K kgmol–1.
174. How many next nearest neighbours are present for Zn+2 ions in FCC arrangement of ZnS.

175. If for complex [Cr(H2O)6]2+ CFSE is (–RO) calculated from general formula of CFSE than determine value of
100 R.

176. How many of the following molecules or ions may act as a multidentate ligand ?
CO32– NO3– edta [N(CH2–COO)3]3–
C2O42– SO42– CH3COCHCOCH3– gly
CH3C  N SCN¯ dmg dipy

177. (i) Number of P–P bonds in P4S3 is (A).

(ii) Amongs the following number of planar species is (B).
XeF2, ClF3, H2O, [XeF5]–, I3–, BCl3, XeF4, SF4, PCl5, SF6, IF7.
Determine the value of (A + B).

178. How many of the following species have been correctly matched with their property (Give your answer by
multiplying with two).
(i) Cl2O : bond angle greater than 109º28'.
(ii) O3– : Paramganetic.
(iii) H2S2O8 : Contains a peroxy linkage.
(iv) XeF4 : d orbitals involved in hybridisation of central atom.
x2 y2

(v) N2H4 : NN bond length greater than expected.

(vi) P3O105– : 3 different types of P–O bond length are observed.

179. How many of the following produce a characterstic coloration/ppt with neutral FeCl3 ?

OH OH CH3
CH3COONa, , , ,

NO2 CH2–OH

O
COOH
C–ONa
, OH

SO3Na

180. How many aromatic diazonium chlorides of xylene can be reduced to meta-xylene by H3PO2?

H PO2 , 
3   (m-Xylene)

181. Many aromatic compounds can be drawn with molecular formula C8H8O2. Find out the no. of aromatic
compounds which can be drawn with this molecular formula and which also contains an – O – (ether)
linkage.

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 CHEMISTRY

(1) O /  (1) O2/

182.    2   ?
( 2 ) dil. H2SO 4 /  (2) ruqH2SO4/

Total number of organic products formed (major, minor all).

CH2 — Br
CH2 ( COOEt )2 / OH /  OH /  ester hydrolysis CO2 NaOH / CaO
183. |                    ( P)
CH2 — Br (1) ( 2) 
( 3 ) OH / H2O /   
H /

Find out the molecular weight of end product (P).

+
184. O
3 NH2OH / H  NH2OH/H
    
excess v kf/kD;

The total number of isomeric products (including stereomers) formed at the end of the reaction is :

185. An aromatic tetracarboxylic acid (C10H6O8) can form two type of monoanhydrides on heating with P2O5. The
sum of locants of all carboxylic groups in this compound will be :

186. In the following sequence of reactions all stereoisomers of (X) have been taken.
( i ) O3 NH 2OH
CH3  CH  CH  CH  CH  CH3     (Y)    (Z)
(ii ) Zn / H2O
| |
D D

(X)

Here P = Total number of stereoisomers of X

Q = Total number of stereoisomers of Y
R = Total number of stereoisomers of Z
What is sum of P, Q and R in the above reaction.

187. Sum of total number of optically active and optical inactive isomers of following compound.

188. The total number of isomers for the alkyne with molecular formula C3HDClBr is :

189. How many position isomers of dibromonaphthalene is possible if each ring of naphthalene has one
halogen?

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 CHEMISTRY

CRITICAL QUESTION BANK

ANSWER KEY
1. (D) 2. (C) 3. (D) 4. (B) 5. (B) 6. (D) 7. (A)

8. (B) 9. (B) 10. (A) 11. (B) 12. (A) 13. (B) 14. (B)

15. (B) 16. (C) 17. (C) 18. (C) 19. (C) 20. (A) 21. (B)

22. (B) 23. (C) 24. (B) 25. (C) 26. (C) 27. (A) 28. (C)

29. (D) 30. (D) 31. (C) 32. (D) 33. (C) 34. (B) 35. (C)

36. (D) 37. (C) 38. (B) 39. (B) 40. (D) 41. (D) 42. (A)

43. (A) 44. (A) 45. (D) 46. (ABCD) 47. (BCD) 48. (BD) 49. (ABCD)

50. (ABD) 51. (CD) 52. (ABD) 53. (AC) 54. (BC) 55. (AC) 56. (BCD)

57. (ACD) 58. (AD) 59. (BCD) 60. (BD) 61. (BC) 62. (AC) 63. (AC)

64. (BC) 65. (ACD) 66. (AD) 67. (ABCD) 68. (AB) 69. (CD) 70. (ABC)

71. (BCD) 72. (AD) 73. (CD) 74. (ACD) 75. (AB) 76. (ABC) 77. (ABC)

78. (ABD) 79. (ABD) 80. (BCD) 81. (ABD) 82. (AB) 83. (ABCD) 84. (ABD)

85. (ACD) 86. (ABCD) 87. (C) 88. (D) 89. (D) 90. (B) 91. (B)

92. (D) 93. (C) 94. (A) 95. (D) 96. (A) 97. (B) 98. (B)

99. (D) 100. (B) 101. (B) 102. (D) 103. (A) 104. (D) 105. (C)

106. (D) 107. (B) 108. (D) 109. (C)

110. (A–p, q, r, t), (B–s, t), (C–r, s), (D–p, q, t) 111. (A– r , s), (B – p) ; (C – r, s) ; (D – q, t)
112. (A – p, q, r, s), (B – r, s, t), (C – p, t), (D – r, t) 113. (A – p,s), (B – q, r, t), (C – p,s), (D – p,s)
114. (A – p), (B –r), (C–q), (D–s)

115. (1) 116. (8) 117. (8) 118. (4) 119. (9) 120. (6) 121. (7)
122. (4) 123. (4) 124. (5) 125. (5) 126. (2) 127. (8) 128. (3)
129. (6) 130. (8) 131. (5) 132. (6) 133. (6) 134. (5) 135. (4)
136. (5) 137. (3) 138. (3) 139. (4) 140. (5) 141. (15) 142. (6)
143. (5) 144. (6) 145. (7) 146. (6) 147. (7) 148. (6) 149. (3)

150. (3) 151. (5) 152. (4) 153. (4) 154. (6) 155. (6) 156. (6)

157. (6) 158. (3) 159. (1) 160. (4) 161. (04) 162. (5) 163. (3)

164. (2) 165. (6) 166. (6) 167. (72) 168. (18) 169. (60) 170. (25)

171. (18) 172. (30) 173. (15) 174. (12) 175. (60) 176. (10) 177. (10)

178. 10 179. (05) 180. (03) 181. (07) 182. (06) 183. (42)

184. (04) 185. (10) 186. (12) 187.. (05) 188. (08) 189. (06)

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 CHEMISTRY

CRITICAL QUESTION BANK

SOLUTIONS
Mass 1000 7. N2O4(g) 2NO2(g)
1. 2 
63 250 t=0 1 0
t = eq. 1 – 0.5 2  0.5
63
mass = gm
2 0 .5 1
PN2O4 = atm PNO2 = atm
1.5 1 .5
70 63
mass of acid × 
100 2
2
mass of acid = 45 gm  1 
 
 1.5  4
KP = =
0.1V  0 0 .1  0.5  3
2. [NO3–] = =  
2V 2 = 0.05 M  1.5 

HNO3 HCl NH4Cl

3. Pb     (NH4)PbCl6 4
Cl2 G° = – 2.3  8.3  330  log  
3
(4.14 g) (2.28 g)
Applying POAC on Pb : = – 2.3  8.3  330  ( 0.6 – 0.48)
1 × nPb = 1 × n(NH ) PbCl = – 756 J mol–1
42 6

4.14 mNH4  PbCl6 exp ected 

2
 1× =1×
207 456
Kw 10 14
8. Kh = = = 10–2
 mNH4 2 PbCl6 (expected) = 9.12 g K a3 10 12

2.28
 % yield of product = 9.12 × 100 = 25%. Ch 2
Kh =
(1  h)
4. MnO4– + H+ + I–  I2 + Mn2+
I2 + S2O32– I– + S4O62–
milliequivalents of MnO4– Kh 10 2
= 5 × 0.5 × 10 = 25 as 1 – h = 1, h = = = 0.316
milliequivalents of I2 formed = 25 C 0.1
Milliequivalents of S2O32– = milliequivalents of I2.
 M × 20 × 1 = 25.  M = 1.25 as h > 0.1  1–h  1

5. 2Cr(s) + 2OH–(aq) + 6H2O  2Cr(OH)4– (aq) + 3H2(g) 10 1  h 2

 10–2 = or 0.1 (1 – h) = h2
2 + 2 + 6 + 2 + 3 = 15 (1  h)

or, 0.1 – 0.1 h = h2

h or, h2 + 0.1 h – 0.1 = 0
6. Difference in angular momentum =

 0.1  (0.1)2  4  0.1
h h or, h = = 0.27
 (n2 – n1) =  n2 – n1 = 2 (Difference in shell no.) 2
2 
For photoelectric effect to be observed, as, PO43– + H2O HPO42– + OH–
Energy of photon > Work function (2.3 eV) c(1 – h) ch ch
 Two photons are possible in H–atom where difference in shell  [OH–] = ch
number is 2 and energy > 2.3 eV
= 0.1  0.27
 Ephoton = 12.09 eV (From 3  1 transition)
= 27  10–3
& 2.55 eV (From 4  2 transition)
pOH = 3 – log 27 = 3 – log33 = 3 – 3 log 3
Max KE of photoelectron will correspond to max energy of incident
= 3 – 3  0.48
photon.
= 1.56
 (KE)max = 12.09 – 2.3 = 9.79 eV
pH = 14 – 1.56 = 12.44

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 CHEMISTRY
19. Ligands which can ligate through either of two different atoms
KW 10 –14
9. Ka(HCN) = = = 2 × 10–10 present in it are called ambidentate ligands. Examples of such
K b (CN ) 5  10 –5
–
ligands are the CN–, NO2– and SCN¯ ions. NH3 is not an
 HCN + NaOH  NaCN + H2O ambidentate ligand
Initially 80 × 0.15 20 × 0.2
= 12 =4 0 0
20. Na2[Cr (EDTA)] is correct representation.
final 8 0 4 4
solution is buffer
21. Due to large charge on cation and big size of anion.
[CN– ]
pH = pKa + log 22. Na2 [Na4(PO3)6] + 2Ca2+  Na2 [Ca2(PO3)6] + 4Na+
[HCN]
calgon
4
= 10 – log 2 + log
8 23. NiSO4 will be absorbing red-violet colour & hence will be of green
1 colour.
= 10 – log 2 + log
2
= 10 – 2 log 2
= 10 – 2 × 0.3 = 9.4 Cl
|
10. Fe(OH)3 Fe3+ + 3OH– 24. 1. O  HC — C — CH  O optically inactive
S' 10–10 S' = 4.32 × 10–2 mol/L. |
 Ksp = [Fe3+] [OH–]3 = 4.32 × 10–2 (10–10)3 = 4.32 x 10–32
Let S = solubility in pure water. H
Now, Ksp = [Fe3+] [OH–]3
4.32 x 10—32 = S × (10–7)3
 S = 4.32 × 10–11 mol/L.
S'
Ratio = = 10111
S
2.
11. Only the ionic product of CuS exceeds its Ksp and hence, it is
precipitated.
enol form exists due to carbanion stability.
12. Na+ + e–  Na
Na + Hg  NaHg

6.69
nNaHg = = 0.03
223 3. and
moles of electron (e–) = 0.03
Charge = 0.03 × 96500 = 9.65 × t.
t = 300 sec. no significant enol form.

13. At infinite dilution, when dissociation is complete, each ion makes

25. I, II & III are resonating structures in which I is most stable.
a definite contribution towards molar conductance of the
electrolyte irrespective of the nature of the other ion with which it
is associated. 31. The aryl diazonium ion (ArN2+ ) functions as electrophile, so
 3+ +  presence of electron withdrawing group (–SO3H) increases its
Hence  Al2(SO = 
)
43
Al SO 24  electrophilicity. Diazocoupling is possible only in strongly activated
rings.
14. w = zit

39
39  1 10–3 =  9.65  t
96500
t = 10 s. 
32. (i) 
 CO2
16. According to given data :

1 1
O2– = 8 × +6× =4
8 2
-keto acid
1 1
Si4+ = × octahedral void = ×4=1
4 4
1 1
M++ = × tetrahedral void = × 8 = 2.
4 4 
OH
(iv) 
 Forsterite = Mg2SiO4 Fayalite = Fe2SiO4 E1 cb
Let the forsterite is x% and fayalite is (100–x) % then (–H2O)
x  3.21  (100  x )  4.34
= 3.88
100
x = 40.71% (Forsterite) and 59.29% (Fayalite).

RESONANCE Page - 34
 CHEMISTRY
49. At constant temperature, decrease in molecular mass causes
H OH flattening of the graph. For same molecular mass of gas, increase
(1) NaOH in temperature causes flattening of the graph.
33. H H
Cl     
( Aprotic solvent ) H (Vmp)T < (Vmp)T
1 2
CH3 CH3 T1 T2 T2 MB
OH  <  >
H MA MB T1 MA
(2) PBr ( 3 ) KOH H H
3 H MB
 Br    But,
DMSO
CH3 M A can be less than or greater than 1
CH3
Cl MA T1
( 4) SOCl2 Similarly , >
 H
 MB T2
H
If gas A is O2 and gas B is N2, then MA > MB.
CH3
51. 2A  A2
OH OH t=0 n 0
CHO t=t n–x x/2
(i) CHCl3 NaOH, 
34.       +
(ii) H Pi Pf
 P  moles  = .......(1)
(P) CHO n x
n–
(Q) 2
-
COCH3 COOH COO Also, from Dalton's law, pA2 = XA2 × Pf  pA2

 x 
H OH NaOH/  H OH H OH  
36. 2 3 NaOH
H OH


H H OH 
H O
-  2 
=  x  × Pf ......(2)
n– 
NO2 NO2 NO2
 2
COCH2I -
COOH COO
1
And, pA2 = × Pi .......(3)
Br 5
From equations (1), (2) and (3),
* * *
37. Br2 / h
D  
 2n Pi n n 5
D x= =
5

Pf x = n =
4
[Two Diastereomers] n– n–
2 5
Fractional
Two fractions
Distillation  x 
 
40. It show geometrical isomerism due to double bond.  2  n/5
XA2 =  x = = 0.25
 n –  4n/5
43. It is a meso achiral compound and it is no centre of symmetry  2
and no axis of symmetry but plane of symmetry.
x 2n / 5
% dimerisation = × 100 = × 100 = 40%
44. In strong basic medium will be stable n n
Mol. mass of A = 10–22 × 6 × 1023 = 60 amu
in its anti form to minimise e-repulsion. n A  MA  n A 2  MA 2
 Mavg. =
nA  nA2
d
45. d + l  dd + l d (optically active mixture of
diastereomers)
3n n
 60   120
47. 10 ml of H2O2 solution liberates 112 ml O2 at STP 5 5
 1 L of H2O2 solution liberates 11.2 L O2 at STP = = 75 amu.
3n n
 volume strength of H2O2 solution = 11.2 V 
5 5
V 11.2 N  17
N= = =2 % w/v = = 3.4%
5 .6 5 .6 10 52. (A) Equilibrium constant depends on temperature.
(B) Equilibrium constant is a constant.
15  112
15 ml of same H2O2 solution liberates ml O2 at STP (C) pNH3 and pH2S depend on K.
10
15  112 2 (D) K = pNH3 × pH2S
=   2 ml O2 at 1.5atm and 273°C
10 3 so if at equilibrium pNH3 is increased, then automatically
= 224 ml O2
meq. of H2O2 reacted with KI = N  V = 2  10 =20 pH2S will decrease.
 meq. of hypo required = 20

RESONANCE Page - 35
 CHEMISTRY
n
54. CH3COOH = 0.1 × 0.1 = 0.01 mol.
n
HCl = 0.01 mol 4+
N en
0.01 N N
[H+]f = = 0.1M
0. 1
(B) [Pt(en)3]Cl4 : en Pt optically active
pH = 1
CH3COOH CH3COO– + H+ N N
0.1 – x x (x + 0.1) en
N
x  0 .1
2 × 10–5 = (C) [NiCl2Br2]2– = tetrahedral, no, G, no optical isomerism
0.1
x = 2 × 10–5 (D) [Pt(NH3)2(CN)2] : Pt is in +2 oxidation state having 5d8
configuration. Hence the hybridisation of complex is dsp2 and
2  10 5 geometry is square planar.
 CH3COOH = = 2 × 10–4
0.1
H2O H+ + OH–, 10–14 = 0.1 × [OH–]
[OH–] = 10–13 M

10 13
(H2O) =
1000
18
= 18 × 10–16 = 1.8 × 10–15
62. The given complex is actually
4
 
55. (A) As EO /H O ;H  EO /OH
 
2 2 2
Fe (Cl) (CN) 4 (O 2 )
  2  1 4 1  
So, O2 is better oxidising agent in acidic medium.
hence Fe() is t2g6, eg0 due to effect of strong ligands but it is
(B) 3Cr2+  2Cr3+ + Cr
paramagnetic due to O2–1 ligand.

63. NO+ [BF4]–



 x × 1 + 2(– 0.91) = –0.74 × 3 No. of  bonds in [BF4]– = 4

 x = –2.22 + 1.82 = –0.40 V.

Eocell  ECr
o
2
/Cr
o
– ECr 3
/Cr 2  B.O. of NO+ = 3.0, i.e., one sigma bond and two  bonds
= – 0.91 – (– 0.40)  No. of  bonds = 2
= – 0.51 V. No. of  bond = 5
As this is negative, B.O. of NO+ = 3.0
So reaction is non spontaneous. and B.O. of NO = 2.5
(C) As SRP of O2 in acidic medium is more than SRP of Fe3+
So, O2 oxidises Fe2+ to Fe3+.
 NO+ is diamagnetic and BF4– is also diamagnetic
(D) As SRP of Cu+/Cu is more than
SRP of Fe2+/Fe, Cu+ oxidises Fe. B—F bonds are longer in BF4– than in BF3 due to absence
But SRP of Cu+/Cu is less than SRP of O2/H2O in acidic
medium. So Cu+ do not oxidise H2O to O2 in acidic medium. This of p-p back bonding in [ BF4– ].
does not take place.
67. ClO2 is powerful oxidising agent, also strong chlorinating agent.
56. G = – ve, Ssystem = + ve Always for solution formation. Its bleaching power is almost 30 times stronger than Cl2. In
Ssurr. < 0 Heat absorbed by solution from surrounding. alkaline solution undergoes disproportionation.
H > 0 For this solution as CCl4 is non-polar but
acetone is polar 2ClO2 + 2NaOH  NaClO + NaClO3 + H2O

58. PtCl2.2NH3 is [Pt(NH3)2Cl2] 68. Fuse with KOH in presence of air or oxidising agents like KNO3
CrCl3.6NH3 is [Cr(NH3)6]Cl3 , KClO3 etc.
PtCl4.4NH3 is [Pt(NH3)4Cl2]Cl2 fuse
2MnO2 + 4KOH + O2  2K2MnO4 + 2H2O
Co(NO2)3.3KNO2 is K3[Co(NO2)6]
electrolyt ic oxidation
MnO42–    MnO4– + e–

69. Y is NO2. Hence (X) may be Mg(NO3)2.

60. (A) [Ni(en)Br2] : exists only in one form. 71. R and S, P and Q are resonating structures while P and R are
tautomers structures.

RESONANCE Page - 36
 CHEMISTRY
73. Teflon is polymer of tetrafluoro ethylene and Natural rubber is
polymer of isoprene.

78. (A) is electrophilic addition ; +

75. (I) H3O  + CH3OH


are formed in the first step.

(II) H O + CH3COOH
3
(B) is EAS ; is formed
Wolff Kishner reduction is not used in presence of base sensitive
group.

77. C4H8O
D.U. = 4 + 1 – 4 = 1

HO H (C) is formed (SN2 Th) (D) is formed (SN1)

dil. H2SO 4
CH2=CH—O—CH2—CH3 CH2=CH—OH + CH3—CH2—OH
(z)
(x)
CH3—CH=O
(y)

80.

H3C
CH=O
O /H O CH=O
81. NaHS 85. 3 
2

 Zn H3C
Chiral

Br / KOH 87. S1 : Pentaamminethiocyanato—N—chromium(III)

2
tetrachlorozincate (II).
or
Pentaammineisothiocyanatochromium(III)
tetrachlorozincate (II).
CH NH / Cu O / 
3 22 S2 : According to defination.
 
S3 : In it Cobalt is bonded by -bond with 6 monodented ligands.
S4 : In it primary valency (ON) of iron is 0.

92. HA H+ + A¯
NaNH 2 / NH 3 (  ) i=1+
     

  = (i – 1)

C 2 (i  1) 2
Now Ka =  Ka =
83. (X) has configurations 1  1  (i  1)
(A) R Z R (B) S Z S (C) R Z S (D) R E R

84. Cyclohexane in chair form is free from all strains. The boat form (i  1)2
 Ka =
has maximum VDW strain between flagpoles hydrogen atom. 2i

RESONANCE Page - 37
 CHEMISTRY

B H3C
93. Z = 1 + CH OH/H
V 101. C 3
CH2 
comparing with O
y=m×+c
H3CH2C

a
m=B=b– = –0.1 L mol CH2CH3
RT
a Conc. l kUnzH SO , 
 b + 0.1 = CH3O CH3 
2 4

RT
a = (b + 0.1) RT
CH2OH
 1 
= b   × 24.6 atm.L ml–2.
 10 
3 (i) O
CH3O–C–CH2–CH3  
(ii) Zn/H2 O
94. CuSO4.5H2O CuSO4.3H2O + 2H2O(g) CH–CH3
Kp = (7.8)2 = 60.84
CuSO4.3H2O CuSO4.H2O + 2H2O(g) CH 3O–C–CH 2–CH 3 + CH3CHO

K p'  (PH2O )2 = (5.6)2 = 31.36 O

Kp 60.84
The ratio = = 1.9
CH3
K p' 31.36 |
102. (Z) is not H2C=C–CH–CH3
|
OH
95. Cathode : NO3– + 3H3O+ + 2e–  HNO2 + 4H2O ;
Eº = 0.94 V

Anode : 2Hg2+ + 2e–  Hg22+ ; Eº = 0.92 V 10 V 1200 V

1V  
Overall balanced cell reaction : 40  0.1 1040 121
103. M = = .
NO3– + 3H3O+ + Hg22+  2Hg2+ + HNO2 + 4H2O ;
3V 78
Eº = 0.02 V
104. 2NaOH + H2SO4  Na2SO4 + 2H2O
0.06 [Hg2 ]2 [HNO2 ] 1M 1M
E = Eºcell – log 100ml x ml
2 [NO3– ][H3 O  ]3 [Hg22 ]
100 – 2x 0

0.06 1 100 – 2x 90
E = Eºcell – log = 0.1 x= = 42.85 ml
2 [H3O  ]3 100  x 2.1

1 105 & 106.

0 = 0.02 – 0.03log
[H3O  ]3 1
Mg + O  MgO
0 = 0.02 – 0.03 × 3 (pH) 2 2

0.02 2 0.1 mol 0.1 mol

pH = =  .
0.03  3 9 Mg + H2SO4  MgSO4 + H2 
0.15 mol 0.15 mol

250  103 MgO + H2SO4  MgSO4 + H2O

96. 0.62 = × 1000 × 39.7 × 1
M  100
0.1 mol
M = 160 or 1.6 × 102 g/mol
WH2SO4 i = 100  1.4  0.3 = 42 gm
WH2SO4 f = 42 – 0.25  98 = 17.5 gm
99.
17 .5
(a) % w/w of final H2SO4 solution =  100 = 14%
100  1.25

0 .1
(b) WO2 used =  32 = 1.6 gm
2

RESONANCE Page - 38
 CHEMISTRY
107, 108 & 109.
36
To emit photon of  = , transition should be from 3  2
D 5R
H C CH=O (Not possibe)


2 OH / H O 7R
   To emit photon of  = transition should be from 4  3
Sol. enolisatio n and + 144
recemisati on
(possibe)
(P)
For single isolated atom, maximum spectral lines = 4 (7  6,
Achiral 6  5, 5  4, 4  3)

(D) For 7  4 transition in He+ ion sample,

D
D C CH=O 3 (3  1)
Max. spectral lines = =6
2
(H)3  2 = (He+)6  4 (possible for given sample)

OD / D O
  2 36
(R)
 photon of  = , can be emitted
5R
Achiral
(H)4  3 = (He+)8  6 (Not possible for given sample)
For single isolated ion, maximum spectral lines = 3 (7  6, 6
 5, 5  4)
Any photon whose energy is 1.55 to 3.1 ev, will be visible.

KMnO 4 /  / OH  112. (A)

  
( oxidation )
Hybridisation reamin same.

(B) SOF2 + 2H2O  2HF + H2SO3

Non-redox reaction, hybridisation reamin same (sp3)
110. For 5  2 transition in H – atom sample HF can react with SiO2 (glass)

n(n  1) 3  4 SiO2 + 6HF  H2SiF6 + 2H2O

Max. spectral lines = = =6
2 2
(C) XeF4 + H2O  Xe + O2 + XeO3 + HF
1 Redox reaction and HF can react with SiO2
 of photon corresponding to 3  2 transition : = R(1)2
 (D) Cl5 + 3H2O  HO3 + 5HCl
Non-redox reaction. HF reacts with glass.
 1 1 36
 2  2  =
2 3  5R
 of photon corresponding to 4  3 transition :  = R (1)2 F
–2
F F
 1 1 7R
 2  2 = Si
3 4  144
114.
For single isolated atom, maximum spectral lines = 3 (5  4, F F
4  3, 3  2) F

(B) For 5  1 transition in He+ ion sample, = 180 all bond angles are not identical.
= 90
n(n  1) 5  4 all bond lengths are identical.
Max. spectral lines = = = 10
2 2
+
(H)3  2 = (He+)6  4 (Not possible for given sample) I
+
F
(H)4  3 = (He )8  6 (Not possible for given sample)
For single isolated ion, maximum spectral lines = 4 (5  4, 4 P
 3, 3  2, 2  1) Br F 
(C) For 7  3 transition in H atom sample, I I
I
4( 4  1)
Max. spectral lines = = 10 F
2
all bond angles identical (109 28')

RESONANCE Page - 39
 CHEMISTRY
115. Let mole fraction of NaOH in its aqueous solution be X. 120. Ag+ + Cl–  AgCl ; K = 1.6 × 10–10
 Mole fraction of H2O in an aqueous solution of KOH = 1 – X t=0 0.1 0.4
so, mole fraction of KOH in its aqueous solution = 1 – (1 – X) = X
Thus, both aqueous NaOH solution and aqueous KOH solution final 0  0.3
have same mole fraction of solute. Cu+ + Cl– CuCl K = 106
Xsolute1000 t=0 0.1 0.3
Now, molality = final  0  0.2 mole
1  Xsolute  Mol.Masssolvent
Since both solutions have same solvent (H2O) and same mole
0.2
fraction of solute, so they will have same molality [Cl–] = = 0.1 M
 Molality of aq. KOH solution = m 2
 Y =m/m=1
CuCl(s), is at equilibrium after precipitation stopes so [Cu+][Cl–]
117. Case – 1 = 10–6

10 –6
 [Cu+] = = 10–5 = 1 × 10–5  x + y = 6
0.1
Case – 2

121. molar mass of salt = 120 + 18x

18 x
mass of water present in the salt =  32 g
120  18 x

 
32  1000 
Molality of the solution =  
120  18 x  18 32 x 
84
 120  18 x 
 225   225 
(Pg – P)   45   = (Pg – P+ 10)   45   = nRT
 13   13 
 Pg – P = 8 cm
4000
=
1260  261 x
118. A C

4000
Kf 0 .3 1 [ C] Tf = 4.836 = 2  1.86 
1260  261 x
 K = 0 . 6 = KC = 2 = [ A ]
b
x = 6.9  7
2C 2A

1 122. MCaCl2 = 111 g

KC' = = 4.
K2
222 324
nCaCl2 = = 2 mole nH2O = = 18 mole
119. +
Au + 2CN –
[Au(CN)2] – 111 18
99 mol% [Au(CN)2]–
Relative lowering in vapour pressure
[ Au(CN2 )]  99
It means = P0  PS n1i 100  80 i 2
[ Au  ]  [ Au(CN2 )]  100 R.L.V.P. = =
P0 n1i  n 2 = 100
=
i  2  18
[ Au(CN2 )]  99
bld k vFkZgS   = 2i
[ Au ]  [ Au(CN2 )] 100 or 0.2 = or 0.4i + 3.6 = 2i
100[Au(CN)2]– = 99[Au+] + 99[Au(CN)2]–
2i  18

i = 2.25.
[ Au(CN2 )] 
[Au+] = – (I) So i = 2.25
99
For CaCl2  i = 1 + (n –1) 
[ Au(CN2 )] 
Kƒ = 2.25 = 1 + (3 – 1) 
[ Au  ] [CN ]2
+
Putting the [Au ] from (I) in Kƒ
1.25
 = = 0.625.
99 2
4 × 1028 =
[CN ] 2 6.4 × 0.625 = 4.
 [CN–] = 5 × 10–14 M

RESONANCE Page - 40
 CHEMISTRY
123. XB = 0.5 XT = 0.5
 2  2
0.06 log [H ] [Cl ]
ptotal = PBº x B + PTº . XT 126. E = Eº –
2 PH2
80 = 0.5 PBº + 0.5 PTº
 2 3 2
160 = PBº + PTº .........(1) 0.06 [H ]  (10 )
 0.43 = 0.19 – log
2 2
10
PBº . XB P º .  0 .5 PBº
yB = p = B =
total 80 160 0.06
 0.43 = 0.19 – log[H+]2 × (10–2)2
PTº . XT PTº .  0.5 PTº 2
yT = p = =
total 80 160  0.43 = 0.19 – 0.06 log (H+) + 0.12
 0.12 = 0.06 pH
ptotal = 100 = PBº . yB + PTº . yT  pH = 2

127. On truncating tetrahedron, triangle is generated at each corner

PBº Pº
= 100 = PBº . + PTº . T and hexagon on each face. Hence 4 triangular and 4 hexagonal
160 160 faces.
2 2
PBº + PTº = 100 × 160 128. (i) Ionisation isomers
[Co(NH3)4 (NO2)2]C and [Co(NH3)4 (NO2) (C)] NO2
From (1) Eq.
(ii) Linkage isomers
( PBº + PTº ) = 160 [Co(NH3)4 (NO2)2]C and [Co(NH3)4 (ONO)2 ] C
(iii) Geometrical isomers ; cis & trans
2 2
( PBº + PTº )2 = 1602 = Pº
B
+ Pº
T
+ 2 PBº × PTº 129. (i) 6

2 2
= PBº + PTº + 2 PBº PTº

= 100 × 160 + 2 PBº PTº

(ii) 4
2 PBº PTº = 1602 – 160 × 100 = 160 × 60

PBº PTº = 160 × 30; PBº + PTº = 160

PBº = 120 = x ; PTº = 40 = y

x  2y (iii) CaSiO3
 =4
50

 Wacid  1000 
124. TF = KF × m = KF ×  
 Macid  H2O  Hence the coordination number is 4.
(Macid)exp = 120
Also N1V1 = N2V2 (iv) Silicon  Each Si is bonded to four silicon atoms.
0.45 1 1 (v) Coordination Number is 2
(Macid )thor = 5 × 15 × 1000 '
(vi) C.N. is 3.
0.45  5  1000
(Macid)thor = = 150
15

 Mthor  150
 
i=  Mexp  = = 1.25
  120 (vii) C.N. is 4.

  = (i – 1) = 1.25 – 1 = 0.25.
20 = 5

125. (1) Silica gel adsorbs moisture

(2) True (viii) C.N. is 3
(3) True. (Bonds weaken on the surface)
(4) True
(5) True (Chemisorption need activation energy.
(6) True, physisorption is due to weak attractive forces, hence
it occurs little farther from surface atoms in comparison to (ix) CN = 4
chemisorption. Moreover the decrease in potential energy is more
in chemisorption than in physisorption.

RESONANCE Page - 41
 CHEMISTRY
130. EAN = 26 – 3 + 6 × 2 = 35
3 + 5 = 8.

131. (a) Fe+2 = d6 , CN¯ is SFL so all paired ( t 62g e0g ) F2SeO2

(b) Co3+ = d6 , ( t 62g e0g )

(c) Pt2+ = 5d8, CN = 4, all paired, square planar +
F
(d) Fe2+ = d6 , H2O is WFL, so paramagnetic |
(e) Zn2+ = d10 , diamagnetic XeF3+ Xe – F
(f) Mn+6 = d1 , paramagnetic |
(g) Al3+ - diamagnetic F
(h) V2+ = d3, paramagnetic.

F
132. CaCO3 , Na2S2O3, CaC2O4, KSCN, Ca3(PO4)2, Na2ZnO2 ends F Xe F
with 'ate'. XeOF4
F O
2 3 2
133. Fe S2 , Fe 2 O3 , Fe 3 O 4 ( Fe O + Fe 2 O 3 ),

1 2 3 3
[ Fe (H2O)5(NO)]2+, Na2[ Fe (CN)5(NO)], Fe [ Fe (CN)6], ClOF3

2 2 2 2
K2 Fe [ Fe (CN)6], Fe (C5H5)2, Fe WO4 –
Cl Cl

134.  for molecules upto N2, 1s2 *1s2 2s2 *2s2 2 p2x = ICl4– I

2
2 p y 2 p2z order is followed. Cl Cl

Hence in (a) 10e– (b) 9e– (c) 7e–

(d) 8e– (e) 8e– (f) 10e–
(g) 8e– (h) 2e– (i) 5e– are present
SCl2 S
Cl Cl
135. Bond order of XeO64 – is 4/3 = n

OSF4

It has 15 possible structures 137. O65– , XeO64– , N3–.

 m = 15
138. 4 structures each :
4
Thus mn = 15  = 20  0.2 mn = 0.2 × 20 = 4
3

, ,
F

136. XeF4

139. Most stable states :

–
F
F
XeF5– Xe F

F
F Most stable state of Mn is +2 in acidic medium and +4 in alkaline/
neutral media.

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 CHEMISTRY
140. (NH4)2SO4  2NH3 + SO3(g) + H2O
d
x 2  y 2 orbital involved in dsp & sp d /d sp hybridisation
2 3 2 2 3
(NH4)NO2  N2 + 2H2O 144.
(NH4)NO3  N2O + 2H2O
(1) [Pt(NH3Cl (H2O)Br]  dsp2
Ba(N3)2  Ba + 3N2
(2) SF4  sp3d
2NH4ClO4  N2 + Cl2 + 4H2O + 2O2 (3) [Cu(NH3)4]2+  dsp2
(NH4)2Cr2O7  N2 + 4H2O + Cr2O3 (4) [XeO3F2]  sp3d
(5) [XeO2F2]  sp3d
1
Pb(NO3)2  PbO + 2NO2 + O (6) [Co(en)3]3+  d2sp3
2 2 (7) [Fe(CO)5]  dsp3
2NaN3  2Na + 3N2 (8) POCl3  sp3
(9) PCl5  sp3d
(10) XeO64–  sp3d2
141. H2(g) + I2(g) 2HI(g)
t=0 1 3 0

x x
t = (teq)1 1 – 3– x 145. ,
2 2
t = (teq)2 3 – x 3–x 2x

,
x2 4x 2
KC = x x =
(1  )(3  ) (3  x ) 2
2 2

gy d jusij = x = 1.5

142. (i) 4Cl– + Cr2O72– + 6H+  2CrO2Cl2  (deep red) + 3H2O
(ii) NO2– + H+ HNO2 ; 3HNO2  HNO3 + NO  + 2H2O
,
2NO  + O2   NO2  (brown)

(iii) 3I– + 2H2SO4  I3–  (violet) + SO42– + 2H2O + SO2

(iv) K2S + H2SO4  H2S  (colourless) + K2SO4

–
(v) Cl– + H2SO4  HCl  (colourless) + HSO4
146. CCl3 – COOH

(vi) 2KBr + MnO2 + 2H2SO4 

Br2  (reddish-brown) + 2K+ + Mn2+ + 2SO42– + 2H2O

(vii) KNO3 + H2SO4  KHSO4 + HNO3 ;

4HNO3  + 2H2O + O2 + 4NO2  (brown)

HCl
(viii) 2KCl + MnO2 + 3H2SO4 
2KHSO4 + MnSO4 + Cl2  (yellowish green) + 2H2O

(ix) SO32– + 2H+  SO2  (colourless) + H2O

143. (i) Van Arkel method

Ti 
 2 2  Ti 4
( vapour ) ( vapour )


   
 Ti + 22
high temperature (pure )


(ii) Fools gold FeS2  Fe2+ S —S

147.
(iii)

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 CHEMISTRY
159. Only one product (Single stereoisomers)
O
148. CH3 , –C–O–CH3 , –CN, H3C Ph
H3C C == C
C == C CH3
–NO2,
+ Ph CH3
–N = N , –CH=CH–CHO show –M effect.

(Trans-Trans)

150. OD / D O
  2 HBr /R O /Light
160. 2 2

OCH3

151. 5 (i, ii, iv, v, vii)

H (1) Mg/ether
153. (A) has no C–OH group,  to the CH=O group. So it forms only (2) CO2
(3) H2 O
phenylhydrazone with 1 mole of PhNHNH2. OCH3 Br 
(B) has (C–OH) group  to the CH=O group, so it forms only (X)
ozazone by reaction with 3 mole of PhNHNH2.

154. Neutral amino acid & acidic amino acid are negatively charged
at pH = 7.0 H
Alanine , Cysteine , Glumatic acid , Glycine, Leucine , Aspartic
acid OCH3 COOH (Y)

CH3 OCH3 OCOCH3 S R R

S R S
155. , , , N , S S R
H Z=4 
fractional distillation
 S S S

CD3 All diasteromers

,
O O
O
are more reactive than benzene towards nitration. CH2–C–NH2 C–NH2 C–NH2
161. + +
CH3
OH CH3
156. HCHO + CH3CHO + CH3COCH 3
HOCH 2–CH 2–CHO + HOCH 2–CH2COCH3 + CH 3–CH–CH 2–CHO
O
2–CH 2COCH 3 + CH 3–CH–CH 2–CHO C–NH 2 CH2–NH2
OH Br2+NaOH
+ +
CH3
+ CH–C–CH2–COCH3 + CH3–CH–CH2–COCH3 CH3
OH OH
NH2
CH3 NH2 NH2
+ CH 3–C–CH 2–CHO CH3
+ +
OH CH3
CH3

O O
162. (iii), (iv), (vi), (vii), (viii)
Et HOOC Et
157. , Total = 2 + 4 = 6
COOH 163. CH3–CH2–CH=NH, CH3–CH=CH–NH2, CH3–CH=N–CH3

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 CHEMISTRY

H–C–O– 480 P
165. H–C–O–  Total pressure at eq. at 207°C = –P' + 2P' = 2P
O 300
O
(given)
H–C–O– H–C–O– 8P
 + P' = 2P
O O 5
O 2P
CH 2=CH–C–O–CH 3  P' =
5

P'
166. The smallest optically active alkenoic acid which can also show  % dissociation of PCl5 at 207°C =  100
 480 P 
geometrical isomerism can be written as  
 300 
COOH
2 P/5
H3C H =
8 P / 5  100 = 25%
CH = CH – CH3
171. MX M + + X–
Hence its molecular formula is C6H10O2. –6
x x + 10
[Na+] = 10–6 M
167. Let mole fraction of O2 is x
KSol = K M + K X– + K Na
40 = 32 × x + 80 (1 – x) or x=5/6
3
29  10 = 10 [6  10 x + (4  10–3 (x + 10–6) + (5  10–3  10–6)]
–6 –3

5 1 x = 2  10–6
a + b = x : (1 – x) = :
6 6 KSP = 6  10–12
When ratio is changed
172. 3S S3
1 5 1 0
Mmixture = 32 × + 80 × = 72
6 6  2
1–  i=1–
3 3
168. H2SO4, H2SO3, H3PO3, H4P2O5 are diprotic. HCl, HNO3,
H3PO2, H3BO3 are monoprotic, H3P3O9, H3PO4 is triprotic
 2 
Now 0.1 1   = 0.08  = 0.3. 30% trimerization.
 3 
169. KI + O3  I2 + H2O + O2.
v.f = 2 v.f = 2
173. Tf = i Kf m i = 1 + (n – 1) 
moles
0.558 = i × 1.86 × 0.1 3 = 1 + (n – 1).1
= x. i=3 n=3
[Co(NH3)5Cl].Cl2  x = 5
I2 + Na2S2O3  I– + Na2S4O6
v.f = 2 M=2 174. Next nearest neighbour of Zn+2 would be = no of nearest
V = 1L surrounded Zn2+ ions
v.f = 1 next nearest neighbour of S2– would be = no of nearest S2– ions
eq of O3 = eq of I2 = eq of hypo = 12 (due to FCC)
 2x=2 and their number of neighbour ratio is 1 : 1 and that make Zn2+
x = 1 mole neighbour are 12.

1 48 175. 2+
= [Ar] 3d4 (as H2O is WFE Ligand). Therefore 2+
 weight % of O3 =  100 24Cr 24Cr is
1 48  1 32
t12,1g,1 , e1g,0
3 or CFSE = (–3 × 0.4 + 1 × 0.6)0
=  100 = 60% Ans. 60.
5 = – 0.6 0 .

176. CO32– and NO3– : 1 or 2 donor oxygen atoms.

170. PCl5 PCl3 + Cl2 edta : 5 or 6 donor atoms (N and O).
t=0 P 0 0 (at 27°C) C2O42– : 2 donor oxygen atoms.
SO42– : 1 or 2 donor oxygen atoms.
480 P CH3COCHCOCH3– : 2 donor oxygen atoms.
t=0 0 0 (at 207°C) CH3C  N : 1 donor nitrogen atom.
300 SCN¯ : Either one nitrogen atom or one sulphur atom.
dmg : 2 donor nitrogen atoms.
480 P [N(CH2–COO)3]3– (or nta) : quadridentate ligand, 3 donor O
t = eq. –P' P' P' (at 207°C)
300 atoms and 1 N atom.
gly : 1 donor N atom and 1 donor O atom.
dipy : 2 donor N atoms

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 CHEMISTRY
177. (i) 3

O /
182. 2


(ii) 7.
Planar molecules : XeF2, ClF3, H2O, [XeF5]–, I3–, BCl3, XeF4.
SF4 – See - Saw shape
PCl5 – Trigonal bipyramidal
SF6 – Square bipyramidal
IF7 – Pentagonal bipyramidal

178. Incorrect are :

(v) N2H4 : NN bond length same as expected since the two lone
pairs on N–atoms are at anti position wrt each other so LP–LP
replusion is not effective.

–
179. R–C–O produces red coloration with neutral FeCl3
dil. H SO / 
O  2 
4 

(tested in Inorganic Qual. analysis as well) while phenolic

–
OH group produces violet coloration with neutral FeCl3.

H PO / 
180. (i) 3  
2 

H PO /  + +
(ii) 3  
2 

major

H PO / 
(iii) 3  
2 

+ +

181.

[Total product 6]

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 CHEMISTRY

CH2 — Br 186. X has 3 stereocentres with similar ends. Hence, 6

183. | CH2 ( COOEt )2 / OH  / 
   
CH2 — Br stereoisomers. Y= has one sterteocentre,

hence 2 stereoisomers. Z= has 2

CH2 — CH(COOEt )2
| OH 
CH2 — Br  
 stereocentres, hence 4 stereoisomers.

Ans.



CO 2

Ph Ph
CH3 H

NaOH / CaO /  H H
 CH3 H H3C CH3
Ph Ph
187.
H H
H H
POS POS

184. O3


Ph Ph
NH OH / H CH 3 H
2  
 
excess H H
CH H3C H H CH 3
H Ph
cis - cis H CH 3
Ph H
trans - trans
POS POS POS
cis R trans
trans S cis
Total isomeric product = 4

Ph
CH 3
O O
COOH C H
H H
1 H
2 COOH C O COS & POS
185.
CH 3
3
COOH COOH Ph
4
COOH COOH

05 all optically inactive.

O
C COOH
C O CO
+ O
COOH CO
COOH COOH

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 CHEMISTRY

188. enantiomer

enantiomer

enantiomer

enantiomer

189.

RESONANCE Page - 48