Chemistry Unit 4&5
Chemistry Unit 4&5
Chemistry Unit 4&5
nit 4
Environmental chemistry
Environmental chemistry is a field of chemistry concerned with designing ways for the protection
of environment. It focuses on the methods of reducing pollution of the environment that results
from manufacturing activities, agriculture, waste products and so on.
Environmental chemistry is the chemistry of air, soil, and water. It also studies the chemical and
biochemical phenomenon that occur in the environment.
4.1 Air
Air is a homogenous mixture of different gases it consist of 78% Nitrogen, 21% Oxygen, 0.97%
Noble gases and 0.03% carbon dioxide by volume. The composition of air is not the same at all
places in the world. This is due to the fact that the atmospheric air of humid region contains more
water vapor than that of arid regions and the atmospheric air of highly an industrialized area
contains a higher percentage of carbon dioxide than areas with less industry.
Pollution is any discharge of material or energy in to the environment pollution causes short term
or long term harm to the air, water and land around us. Pollution affects the earth’s ecological
balance and lowers the quality of life in the environment
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Air pollution is the contamination of atmospheric air by gaseous substances and tiny solid
particles entering into it that are not normally present in the air. Air pollution is caused by the
emission of gaseous substances like CO2 which continually increases its concentration in the
atmosphere.
Types of Pollutants
In order to understand the causes of Air pollution, several divisions can be made. Primarily air
pollutants can be caused by primary sources or secondary sources. The pollutants that are a direct
result of the process can be called primary pollutants. A classic example of a primary pollutant
would be the sulfur-dioxide emitted from factories
Secondary pollutants are the ones that are caused by the inter mingling and reactions of primary
pollutants. Smog created by the interactions of several primary pollutants is known to be as
secondary pollutant.
1. Burning of Fossil Fuels: Sulfur dioxide emitted from the combustion of fossil fuels like coal,
petroleum and other factory combustibles is one the major cause of air pollution. Pollution
emitting from vehicles including trucks, jeeps, cars, trains, airplanes cause immense amount of
pollution. We rely on them to fulfill our daily basic needs of transportation. But, there overuse is
killing our environment as dangerous gases are polluting the environment. Carbon Monoxide
caused by improper or incomplete combustion and generally emitted from vehicles is another
major pollutant along with Nitrogen Oxides that is produced from both natural and manmade
processes.
3. Exhaust from factories and industries: Manufacturing industries release large amount of
carbon monoxide, hydrocarbons, organic compounds, and chemicals into the air thereby depleting
the quality of air. Manufacturing industries can be found at every corner of the earth and there is
no area that has not been affected by it. Petroleum refineries also release hydrocarbons and
various other chemicals that pollute the air and also cause land pollution.
1. Respiratory and heart problems: The effects of Air pollution are alarming. They are known
to create several respiratory and heart conditions along with Cancer, among other threats to the
body. Several millions are known to have died due to direct or indirect effects of Air pollution.
2. Global warming: Another direct effect is the immediate alterations that the world is
witnessing due to Global warming. With increased temperatures worldwide, increase in sea levels
and melting of ice from colder regions and icebergs.
3. Acid Rain: Harmful gases like nitrogen oxides and sulfur oxides are released into the
atmosphere during the burning of fossil fuels. When it rains, the water droplets combines with
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these air pollutants, becomes acidic and then falls on the ground in the form of acid rain. Acid rain
can cause great damage to human, animals and crops.
5. Effect on Wildlife: Just like humans, animals also face some devastating effects of air
pollution. Toxic chemicals present in the air can force wildlife species to move to new place and
change their habitat. The toxic pollutants deposit over the surface of the water and can also affect
sea animals.
6. Depletion of Ozone layer: Ozone exists in earth’s stratosphere and is responsible for
protecting humans from harmful ultraviolet (UV) rays. Earth’s ozone layer is depleting due to the
presence of chlorofluorocarbons, hydro chlorofluorocarbons in the atmosphere. As ozone layer
will go thin, it will emit harmful rays back on earth and can cause skin and eye related problems.
UV rays also have the capability to affect crops.
1. Use public mode of transportation: Encourage people to use more and more public modes
of transportation to reduce pollution. Also, try to make use of carpooling. If you and your
colleagues come from the same locality and have same timings you can explore this option to save
energy and money.
2. Conserve energy: Switch off fans and lights when you are going out. Large amount of fossil
fuels are burnt to produce electricity. You can save the environment from degradation by reducing
the amount of fossil fuels to be burned.
3. Understand the concept of Reduce, Reuse and Recycle : Do not throw away items that
are of no use to you. In-fact reuses them for some other purpose. For e.g. you can use old jars to
store cereals or pulses.
4. Emphasis on clean energy resources: Clean energy technologies like solar, wind and
geothermal are on high these days. Governments of various countries have been providing grants
to consumers who are interested in installing solar panels for their home. This will go a long way
to curb air pollution
Global warming
Global warming is an increase in the average temperature of the earth. Carbon dioxide occurs in
the air as a result of natural process such as respiration, decay and decomposition of organic
matter. Beside this human activities that involved the combustion of mineral coal and petroleum
have a resulted in a significant increase in concentration of carbon dioxide in atmospheric air.
Thus this increase in the amount of carbon dioxide in atmospheric air resulted in global warming
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Physical treatment involves processes that are carried out no chemical and biological
changes. The most common method of physical treatment are screening and filtration
Screening is a physical treatment used to remove large pieces of solid waste.
Filtration is a method used to remove fine suspended particles. This is achieved by passing
water through a filter medium.
Chemical treatment is the addition of chemicals to water to improve its quality. The
most common chemical treatment methods are chlorination and addition of aluminum
sulphate(Al2(SO4)3).
Chlorination is the addition of chlorine to water to kill bacteria and other
harmful micro-organisms. The chemicals used for this purpose is sodium
hypochlorite (NaOCl). The chlorine is sodium hypochlorite kills harmful
bacteria in water.
Addition of aluminium sulphate causes chemical reaction to occur to form
insoluble solid. This help to improve the clarity of water and removes
dissolved harmful substances.
Biological treatment is a method that uses microorganism, mostly bacteria
decompose waste substances in water. By the action of bacteria, waste substances can be
converted to carbon dioxide, water and other products biological treatment is mostly used
to treat waste while physical and chemical treatments are used to treat drinking water as
well as waste water.
Soil
Soil is the top layer of the earth. It is the growing medium for plants. The soil provides
plants with stability, water and essential minerals for their growth. Soil consist of solid,
liquid and gas components.
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The solid components of soil contains minerals and organic matter or humus this
component make up about 50% of the total soil volume.
The liquid component of soil consists of water and dissolved minerals. It make up about
25%of the total volume of soil.
The gas component of soil consists of air the composition of soil air is 78%nitrogen, 21%
oxygen and about 0.05% carbon dioxide by volume. The composition of soil in air is nearly
similar to that of the atmospheric air. However, percentage of carbon dioxide in soil air is
slightly higher than that of atmospheric air.
Acidic and alkaline soils
The nature of the soil depends on the material from which it is developed the materials it
contains and many other factors soil of all places is not the same. Naturally soil can be
acidic, basic (alkaline) or neutral.
Acidity and alkalinity is measured in terms of PH. PH is the measurement of acidity or
alkalinity of substances. Generally PH of substances depends on the concentration of
hydrogen and hydroxide ion. In acidic solution the concentration of H + is higher than that
of OH-. In alkaline solution the concentration of H+ is smaller than that of OH-. A neutral
solution and soil contain equal concentration of H+ and OH-
Plant nutrient and soil improvement
Plant nutrient are materials required by plants for their growth plants get the material
nutrient from the soil. A soil can produce good crop yield only if it contains all the
necessary plant nutrients. Plants do not need all nutrients in the same quantity for their
growth they require some nutrients which are called macro(major) plant nutrient in a
large amount and others which are known as micro(minor) plant nutrients only in a very
small quantity.
Major plant nutrients
The major plant nutrients are the elements required by plants in large amounts. These
elements are also called macronutrient. The major plant nutrients are Nitrogen,
Potassium, Phosphorus, magnesium, calcium and sulphur. The elements Carbon, Hydrogen
and Oxygen are also major plant nutrients.
Methods of improving soil fertility
A soil can be either fertile or infertile. A fertile soil contains the major plant nutrients as
well as other elements required by plants in small amount in sufficient quantities.
An infertile soil lacks some of the plant nutrients or may not contain them in sufficient
quantities. When the plant nutrients are not present in sufficient quantities in a soil, it is
very important to add fertilizers to improve its fertility.
Fertilizers are substances that are added to the soil to improve the growth, crop yield and
nutrient value of crops. Fertilizers are classified as natural (organic) fertilizers and
chemical (synthetic or artificial) fertilizers.
Organic (natural fertilizers are those derived from animals and plant. These include
animal dung , urine, and material
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Unit 5
Atomic mass is the average of the all isotopes of an element atomic mass is
calculated using this formula
the1 st isotopes ×the 1 st percentage abundance the2 nd isotopes ×the 2 nd percentage abundance
+
100 100
Example: Naturally occurring consist of two isotopes with the atomic mass of 10a.m.u and
11 a.m.u which have a relative abundance of 20% and 80% respectively what is the
average atomic mass of boron?
Solution:
10× 20 11 ×80
Average atomic mass of Boron = +
100 100
200 880
= 100 + 100
= 2 + 8.8 = 10.8 is the atomic mass of boron
Molecular mass: is the sum of the relative atomic masses of individual atoms it contains.
The term molecular mass refers to the mass of a molecule of an element or a compound.
Example : calculate the molecular mass of a molecule of ozone, O 3
(Atomic mass: O=16)
Solution:
Step 1: The only atom present in the molecule is ozone (O3)
Step 2: Number of O atoms = 3
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Formula mass: is the sum of the mass of each kind of atoms( ions) of elements in
the formula of the compound.
Example : Calculate the formula mass of Glucose (C6H12O6) ( Atomic mass : C=12,
H=1, O=16)
Solution :
Step 1: Elements present: Carbon, Hydrogen and Oxygen
Step 2: Number of atoms: C=6, H=12, O=6
Step 3: Total mass of each element: C=6×12=72, H= 1×12=12, O=6×16=96
Step 4: Formula mass of Glucose (C6H12O6) = 72 + 12 + 96 =180 a.m.u
Mole concept: the mole is the unit of measurement for amount of substance in the
international system of units. A mole of a substance or a mole of particles is defined
as exactly 6.022 × 1023 particles, which may be atoms, molecules, ions or electrons.
The mass of one mole of atoms, molecules or a compound is called molar mass. It is
denoted by ‘M’ and expressed by the unit gram per mole (g/mol).
Given mass∈grams m
Number of moles(n) = or n=
Molar mass of the substance∈gram per mole M
Example: How many moles are there in 120g Fe? (Atomic mass: Fe = 56)
Solution : Given mass= 120g
molar mass= 56g/mol
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Given mass∈grams m
Number of moles (n) of Fe = or n=
Molar mass of the substance∈gram per mole M
120 g
= = 2.14 mol of Fe
56 g /mol
Example: Calculate the number of molecules in 56 g of SO3 (Atomic mass S=32, O= 16)
Solution : Molar mass of SO3 = (1 × 32) + (3 × 16) = 80 g/mol
Given mass of SO3= 56g
m
No of molecules of SO3= × 6.022 × 1023
M
56 g
= × 6.022 × 1023
80 g /mol
Example : calculate the number of atoms in 0.8 mol of Aluminum atom (Atomic mass: Al =27)
solution:
Number of atoms = Number of moles of atoms × 6.022 × 1023
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Step3: Divide the component’s molar mass by the entire molecular mass and You
will now have a number between 0 and 1. Multiply it by 100% to get
percentage abundance
40
Step 3: % Ca = = 0.2941 ×100 = 29.41%
136
32
%S=
136
= 0.2352 ×100 = 23.52%
64
%O= = 0.47 ×100 = 47.05%
136
Determination of formula
Empirical formula: is the formula that shows the number of atoms of each type of
element present in the compound in the lowest possible ratio.it is the simple
formula of the compound.
Steps for determining empirical formula
Step1: write down the symbol of the consistent elements
Step2: write the mass or mass percentage of the elements under each element
Step3: find the number of moles of each element by dividing the percentage mass
of each element by the respective atomic mass
Step4: to get the simplest whole number value, divide the relative number of atoms
by the smallest of the set
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Step5: if the above ratio is not whole number, multiply all the values by a suitable
integer which will change them to simple whole number
Step 6: write the symbol of the consistent elements side by side and the number
obtained as subscript to get its empirical formula
Example: Find the empirical formula of an oxide formed by reacting 28g of iron
and 12g of oxygen (Atomic mass Fe=56, O=16)
Solution:
Step1: Elements: Fe O
Step2: Mass 28 12
28 12
Step3: Number of moles
56
= 0.5 16
= 0.75
0.5 0.75
Step4: Divide the smallest =1 = 1.5
0.5 0.5
Molecular formula : is the formula that shows the actual number of toms of each
type of element present in a compound
Example: The empirical formula of glucose is CH2O and its molecular mass is 180.
Find the molecular formula of glucose. (Atomic mass C=12, H=1, O=16)
Solution: Molecular formula = Empirical formula × n
Molecular mass of glucose = 180
= 180= (CH2O) x
= 180= (1×12 + 2×1+ 1×16) x
= 180 = 30x
180 30
=6 = =1
30 30
Molecular formula of glucose= (CH2O)6 = C6H12O6
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93.71 6.29
Step3: No of moles
12
= 7.81 1
= 6.29
7.81 6.29
Step4: Divide the smallest = 1.24 =1
6.29 6.29
∭∭ The End ∭∭
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EXERCISE
Choose the best answer from the given alternative
A, O2 B, N2 C, CO2 D, Ar
A, O2 B, N2 C, CO2 D, Ar
_______6, Which of the following pairs of gases is responsible for warming of the earth
_______7, which one of the following element is the most abundant noble gas in atmospheric air
A, Xe B, Kr C, Ar D, He
_____8, which one of the following is essential to green plants for the process of photosynthesis
A, NO2 B, CO2 C, O2 D, N2
_____11, Which air pollutant reduces the capacity of Hemoglobin to carry oxygen
_____12, the substance that protects the earth from Ultra violet rays is
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A, O3 B, CO2 C, O2 D, CO3
A, S8 B, O3 C, P4 D, N2
_____17, which one of the following is the major causes of air pollution Except
_____19, which one of the following is NOT the effect of air pollution
__20, Greenhouse effect is a natural process by which heat is trapped in the atmosphere by
_____22, Which one of the following is NOT the main causes of hardness of water
_____23, Which one of the following is the cause of temporary hardness of water
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______25, a water pollutant that refers to any solid or liquid materials discharge from our
houses in to the water is
______26, ________ is a physical treatment of water used to remove large pieces of solid waste
______27, A method that uses microorganism, mostly bacteria decompose waste substances
in water is
______29, Which one of the following is the major plant nutrients Except
A, Nitrogen B, Iron C, Potassium D, Magnesium
______30, A substances that are added to the soil to improve the growth, crop yield and
nutrient value of crop is
______32, A type of fuel that formed by the decay of plant remains in the absence of air for
hundred millions of years is
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______35, What is the formula mass of Ca3(PO4)2 (Atomic mass , Ca=40, P=31, O=16)
______36, Glycerol has the molecular formula of C3H8O3. Calculate its molar mass
(Atomic mass C=12, H=1, O=16)
______37, What is the mass of 4.01×1023 atoms of magnesium (Atomic mass: Mg=24)
______38, What is the mass of 3.01×1023 atoms of Iron (Atomic mass: Fe=56)
______40, Which one of the following compound contains the highest percentage of oxygen
_______41, A compound with the simplest formula C2H5 has a molecular mass of 180. The
molecular formula of the compound is (Atomic mass C=12, H=1,)
_______42, If you had 1.204×1024 molecules of nitrogen, how many moles would this be
_______43, A compound contains 93.8% Carbon and 6.2% Hydrogen by mass. What is the
empirical formula of this compound?
_______44, A compound of Carbon, Hydrogen and Oxygen contains 40%, 6.6% and 53.4%
respectively. If the molecular mass of the compound is 60, what is the molecular formula
of the compound?
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_______45, All of the following are true about the mole concept except
A, It has a mass equal to the mass of proton B, It is equal to gram atomic weight
_______46, How many moles of diammonium phosphate ((NH4)2HPO4) are there in 26.2g of
((NH4)2HPO4)
A, 65% B, 31% C, 56 % D, 13 %
_______48, Which one of the following quantities contains the same number of molecules
D, Molecular mass is the sum of the relative atomic masses of individual atoms it contains
_______50, How many moles are equivalent to 6.033 × 1023 molecules of SO4
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