S.L.O.P - Paper 1: Unit 3 Quantitative Chemistry
S.L.O.P - Paper 1: Unit 3 Quantitative Chemistry
S.L.O.P - Paper 1: Unit 3 Quantitative Chemistry
2 atoms of Na
(sodium) 1 atom of C 3 atoms of O
(carbon) (oxygen)
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Revision 1.1: © L. Tull 2019
Use of brackets in formulae Example:
The number of atoms of each element inside the brackets is
multiplied by the number on the bottom right outside the
Al2(SO4)3
brackets. 4 atoms of O
Al (SO )
2
(oxygen) inside the brackets,
4 3 however multiply by 3 as
2 atoms of Al that’s the number outside:
(aluminium) 1 atom of S 4 x 3 = 12 atoms of O
(sulfur) inside the brackets, however
multiply by 3 as that’s the number = 17 atoms in total
outside: 1 x 3 = 3 atoms of S
__ Al + __ O2 → __ Al2O3
2. Count the number of
atoms of each element Al = 1 Al = 2
currently in the equation. O= 2 O= 3
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Task 4: Balance these equations:
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Calculating Relative Formula Mass (Mr) Example:
Look for the elements’ symbols on the periodic table, you FeCl3
need to use the mass numbers (They’re the massive ones!).
Note: Sometimes they give you the mass numbers of each element in the Q.
FeCl3
1 atom of iron 3 atoms of chlorine
1 x 56 = 56 3 x 35.5 = 106.5
Al2(SO4)3
2 atoms of Aluminium
2 x 27 = 54
3 atoms of Sulfur
3 x 32 = 96 12 atoms of Oxygen
12 x 16 = 192
Now apply what you’ve learned to the questions on the next page.
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Task 5: Calculate the Relative Formula Mass (Mr) of each substance:
Note: Use your copy of the periodic table to find the relative atomic mass:
a) FeCl3
b) H2SO4
c) AgNO3
d) K2SO4
e) CH4
f) NH3
g) SiO2
h) Mg(NO3)2
i) Ca(OH)2
j) Fe(C2O4)3
k) Al2(CO3)3
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Calculating Elemental Percentage Example:
Sometimes you will be asked a question like this:
“What is the percentage by mass in Al2O3 , of aluminium?
Al2O3
Step 1: Calculate Mr
54 + 48 = Mr = 102 g/mol
Step 2: Divide the total mass of the particular element by the Mr then x 100
Aluminium made up 54 out of the total of 102 so:
54
x 100 = 52.9 %
102
a) FeCl3 %Fe?
b) H2SO4 %O?
c) Ca(OH)2 %H?
d) Al2(CO3)3 %C?
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The Mole
Chemical amounts are measured in moles, the symbol for the unit mole is mol.
The mass of one mole of a substance is equal to its relative formula mass (Mr) in
grams
This is why the units of relative formula mass are “grams per mole” – It’s how
many
grams 1 mole would weigh! So two moles of a substance would be twice its Mr….
mass mass
mol = Mr =
Mr mol
The mass in this equation needs to be in grams, but modern papers are giving you
masses in:
Whatever number they give you (if not in grams), just multiply by the correct power
as above and slot into the equation → remembering these is easier than
remembering conversions!
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The Mole examples…..
Example 1:
What is the mass of 3.5 moles of Methane (CH4)?, Mr = 16 g/mol
Mass = Mr x mol
Mass = 16 x 3.5 = 56 g
Example 2:
How many moles are in 348 g of aluminium oxide (Al2O3)? Mr = 102 g/mol
Mol = mass / Mr
Mol = 348 / 102 = 3.41 mol
Example 3:
What is the Mr of two moles of a compound that weighs 204 g?
Mr = mass/mol
Mol = 204 / 2 = 102 g/mol
Therefore it must be aluminium oxide…
Example 4:
How many moles are in 5 kg of carbon dioxide (CO2)? Mr = 44 g/mol
Mol = mass / Mr
Mol = 5 x 103 / 44 = 113.6 mol
Example 5:
How many moles in 600 mg of paracetamol? (C8H9NO2) Mr = 151 g/mol
Mol = mass / Mr
Mol = 600 x 10-3 / 151 = 3.97 x 10-3 mol
Make sure you know the powers of ten that each prefix stands for, this will
save you time in your biology, physics and chemistry papers!
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Task 7: Using the mole equation:
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Task 8: Moles challenge – For levels 5 and higher:
How many moles of each substance are there? You will first need to calculate Mr in
order to use the equation mol = mass / Mr
What is the mass of each substance? You will first need to calculate Mr in order to
calculate mass using the equation mass = Mr x mol
d) 3 moles of Vanadium, V
h) 5.4 moles of Y has a mass of 162g, Calculate the Mr of Y and suggest its identity
by writing a formula that matches the Mr you calculated.
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Avogadro’s Constant
The real world masses of atoms doesn’t match our metric system.
However the mass = Mr x mol equation makes it so that 1 mole of
a substance weights exactly its Mr in grams.
Avogadro found that one mole of a substance will weigh its relative
formula mass (Mr) in grams, if one mole of a substance contains:
71 g/mol
= 1.18 x 10-22 g
6.02 x 1023 molecules / mol
b) One mole of any substance weighs exactly the same as its relative
formula mass Mr in _____________.
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The Law of Conservation of Mass
The mass of all reactants will be equal to the mass of all products.
For example, when 148 g calcium hydroxide reacts with 146 g hydrochloric acid,
222 g of calcium chloride and 72 g of water are produced, we can show that the
mass of reactants is equal to the mass of products:
Reactants Products
Ca(OH)2 + 2 HCl → CaCl2 + 2 H2O
294 g = 294 g
We can use this rule to work out the mass of an unknown when all other masses
are given, for example:
2 Mg + O2 → 2 MgO
144 g + x = 240 g
a) Show that when 230 g of sodium reacts with 80g of oxygen to produce
310 g of sodium oxide, that this reaction obeys the law of conservation of
mass:
4 Na + O2 → 2 Na2O
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b) When an unknown mass of hydrogen reacts with 288g of oxygen, 324g
of water is produced. What mass of hydrogen reacted?
2 H2 + O2 → 2 H2O
2 Fe2O3 + 3C → 3 CO2 + 4 Fe
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Conservation of mass, when a product is a gas:
To understand this next section you first need to understand state
symbols: (s) = solid, (l) = liquid, (g) = gas, (aq) = Aqueous solution.
Take for example the reaction of any metal carbonate with acid:
CaCO3 (s) + 2 HCl (aq) → CaCl2 (aq) + H2O (l) + CO2 (g)
The aqueous
Solid calcium calcium chloride
carbonate and solution and liquid
aqueous water will stay in
hydrochloric acid the flask so will be
solution will stay in weighed, however
flask so will be the carbon dioxide
weighed. 173 g 129 g is a gas so will
escape and will not
be weighed.
Example Q:
Why does the reaction flask and its contents appear to decrease in mass
for this reaction?
MgCO3 (s) + 2 HCl (aq) → MgCl2 (aq) + H2O (l) + CO2 (g)
48g 80 g
Example Q:
Why does the reaction crucible and its contents appear to increase in
mass for this reaction?
So technically the reaction still obeys the law of conservation of mass, it just looks
like it hasn’t because the mass of the gas was incorporated into the product. 17
Task 11: When a reactant or product is a gas
a) Why does the reaction crucible and its contents appear to decrease in
mass?
b) Why does this reaction crucible and its contents appear to increase in
mass?
c) How will the mass of the reaction flask and its contents appear to
change in this reaction and why?
Na2CO3 (s) + 2 HNO3 (aq) → 2 NaNO3 (aq) + CO2 (g) + H2O (l)
d) How will the mass of the reaction crucible and its contents appear to
change in this reaction and why?
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Calculating the mass of a product or reactant
This skill is challenging but stick with it and you will ace these questions!
Key knowledge:
2 Mg + O2 → 2 MgO
Therefore if you had 0.5 moles of magnesium, you would have 0.25
moles of oxygen and 0.5 moles of magnesium oxide, and so on….
Example Question:
2 Fe2O3 + 3 C → 3 CO2 + 4 Fe
1. Write mass, Mr
and mol down in a Mass: 500g Mass:
column from the
one you know Mr: Mr:
something about,
and the one you Mol: Mol:
are trying to find
out about.
2. Pluck the info 3. Sometimes you’re given the Mr if so,
from the question just put them in the right place, if not
carefully and put work them out. IGNORE THE BIG
into the right zone. NUMBERS WITH Mr ! 19
Example question continued:
2 Fe2O3 + 3 C → 3 CO2 + 4 Fe
6. Now use
Mass = Mr x mol to Mass: 500g Mass:
calculate the mass
of the one your Mr: 160 g/mol Mr: 56 g/mol
looking for.
Mol: 3.125 mol Mol: 6.25 mol
Mass Fe
Mass = Mr x mol
Mass = 56 x 6.25 = 350g
Put this mass value in the correct
column/row…
2 Fe2O3 + 3 C → 3 CO2 + 4 Fe
Tips:
1. The big numbers only apply as the ratio to the mol row, don’t
use the big numbers when calculating Mr !
2. Write Mass, Mr and Mol in the right order underneath the
equation as this will prompt you to remember the
mass = Mr x mol equation. If you don’t have space re-write
the equation so you have space underneath.
3. Divide moles by BIG number in its own column, then multiply
this answer by BIG number in target column. 21
Task 12: Calculating the mass of a product or reactant. If you show your
working it makes it easier for a teacher/examiner to either diagnose your
work and give you help, or to give you marks even if you made a mistake!
b) A student has 200 g of Sodium (Na), what mass of sodium oxide (Na2O)
will they produce? SHOW ALL STAGES OF WORKING.
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c) A fire produced 170 g of carbon monoxide via incomplete combustion,
how many grams of oxygen are needed to convert it fully to CO2?
SHOW ALL STAGES OF WORKING.
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Balancing equations using moles
You can use mole values to balance an equation. The mole values will
follow the same ratio as the balancing numbers in the equation.
Example Question:
__ Cl2 + __ KI → __ KCl + __ I2
1. Write mass, Mr and mol down in a column underneath
everything, then fill with known values from the question.
__ Cl2 + __ KI → __ KCl + __ I2
Mass: 142 g Mass: 620 g Mass: 298 g Mass: 508 g
Mr: 71 g/mol Mr: 155 g/mol Mr: 74.5 g/mol Mr: 254 g/mol
__ Cl2 + __ KI → __ KCl + __ I2
Mass: 142 g Mass: 620 g Mass:298 g Mass: 508 g
÷ ÷ ÷ ÷
Mr: 71 g/mol Mr: 155 g/mol Mr: 74.5 g/mol Mr: 254 g/mol
__ Cl2 + __ KI → __ KCl + __ I2
Mass: 142 g Mass: 620 g Mass:298 g Mass: 508 g
Mr: 71 g/mol Mr: 155 g/mol Mr: 74.5 g/mol Mr: 254 g/mol
1 2 2 1
1 Cl2 + 2 KI → 2 KCl + 1 I2
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b) 378 g of nitric acid (Mr 63 g/mol) reacts with 120 g of calcium
(Mr 40 g/mol) to produce 492 g of calcium nitrate (Mr 164 g/mol) and
6 g of hydrogen (Mr 2 g/mol). Use these values to show how you can
balance the equation.
1. Use basic law of conservation of mass to work out the mass of water
formed.
2. Use these values to show how you can balance the equation.
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Concentrations in g/dm3
Example 1:
A solution has a volume of 75 cm3, what is this volume in cubic
decimetres? 3
75 cm
Volume in dm3 = = 0.075 dm3
1000 cm3/dm3
Example 2:
A solution has a volume of 2.3 dm3, what is this volume in cubic
centimetres?
Example 3:
A student dissolved 10g of chlorine in 200 cm3, calculate the
concentration in g/dm3.
1. Convert cm3 to dm3
200 cm3
Volume in dm3 = 3 3
= 0.2 dm3
1000 cm /dm
2. Divide mass in g by volume in dm3.
10 g
Concentration in g/dm3 = = 50 g/dm3
0.2 dm3
ii) 25 cm3
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i) A solution of copper sulfate has a concentration of 1.5 g/dm3, what
mass of copper sulfate is dissolved in 50 cm3?
k) A student made a 0.25 g/dm3 solution using 50g of iron sulfate, what
volume in dm3 did they make it up to?
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Notes:
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Answers
Task 1 Task 7 Continued…. Task 13
a) 2 e) i) 29.5 g a) 4 mol : 2 mol : 2 mol
b) 3 ii) 12 g 2:1:1
c) 1 iii) 1632 g b) 6 mol : 3 mol : 3 mol : 3 mol
d) 3 2:1:1:1
e) 3 Task 8 c) 1. Water = 144g
a) 0.94 mol 2.
Task 2 b) 4.9 mol 2 mol : 10 mol : 6 mol : 8 mol
a) Fe = 1, Cl = 3, Total = 4 c) 5.1 mol 1:5:3:4
b) H = 2, S = 1, O = 4, Total = 7 d) 153 g
c) Ag = 1, N = 1, O = 3, Total = 5 e) 322.5 g Task 14
d) K = 2, S = 1, O = 4, Total = 7 f) 534 g a) Concentration = mass / volume
e) C = 1, H = 4, Total = 5 g) 17 g/mol therefore NH3 or OH- b) Mass = concentration x volume
f) N = 1, H = 3, Total = 4 (accept other correct) c) Volume = mass / concentration
g) Si = 1, O = 2, Total = 3 h) 30 g/mol therefore NO (accept d) 1000 cm3
other correct) e) i) 0.7 dm3
Task 3 ii) 0.025 dm3
a) Mg = 1, N = 2, O = 6, Total = 9 Task 9 iii) 2.5 dm3
b) Ca = 1, O = 2, H = 2, Total = 5 a) 6.02 x 1023 f) i) 2800 cm3
c) Fe = 1, C = 6, O = 12, Total = b) Grams ii) 10 cm3
19 c) Atoms, ions or molecules iii) 500 cm3
d) Al = 2, C = 3, O = 9, Total = 14 d) 3.82 x 10-23 g g) 3.3r g/dm3
e) 2.66 x 10-23 g h) 85.7 g/dm3
Task 4 f) 1.06 x 10-23 g i) 0.075 g
a) 2 : 3 : 2 g) 2 j) 0.02 g/dm3
b) 1 : 2 : 1 : 1 k) 200 dm3
c) 1 : 1 : 2 Task 10
d) 1 : 2 : 2 a) 230 + 80 = 310, so reactant mass
e) 2 : 3 : 3 : 4 equals product mass.
f) 2 : 2 : 2 : 1 b) 36 g
c) 308 g
Task 5 d) 180 tonnes
a) 162.5 g/mol
b) 98 g/mol Task 11
c) 170 g/mol a) Carbon dioxide is a product and is a
d) 174 g/mol gas, so it escapes and is not
e) 16 g/mol weighed at the end of the reaction.
f) 17 g/mol b) Chlorine is a reactant and is a gas,
g) 60 g/mol so is not weighed at the start but is
h) 148 g/mol weighed when it becomes part of
i) 74 g/mol the solid product.
j) 320 g/mol c) Will appear to decrease in mass as
k) 234 g/mol carbon dioxide is a product and is a
gas, so it escapes and is not
Task 6 weighed at the end of the reaction.
a) 34.5 % d) Will appear to increase in mass as
b) 65.3 % fluorine is a reactant and a gas, so is
c) 2.8% not weighed at the start but is
d) 15.4 % weighed when it becomes part of This is a working document so if you
the solid product. spot any errors in the text or mark
Task 7 scheme please email:
a) Mass = Mr x mol Task 12
b) Mol = mass / Mr a) 316.6r g [email protected]
c) Mr = mass / mol b) 269.6r g
d) i) 1.25 mol c) 97.1 g Revision 1.1
ii) 1.54 x 10-6 mol d) 37.8 g © 4th April 2019
iii) 1.85 x 106 mol e) 101.1 g
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