Safety data sheet

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

MasterInject 1315 PART A

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Product for construction chemicals

Uses advised against: Not suitable for consumers.

1.3. Details of the supplier of the safety data sheet

Company: Contact address:

BASF Construction Chemicals Egypt BASF SE
Factory: Piece 118, Zone 4 67056 Ludwigshafen
Sadat City - Monoufaia, Egypt GERMANY

Telephone: +49 621 60-0

E-mail address: [email protected]

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

Skin Corr./Irrit. 2
Eye Dam./Irrit. 2
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
Skin Sens. 1
Aquatic Chronic 2

H319, H315, H317, H411

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements

According to Regulation (EC) No 1272/2008 [CLP]

Pictogram:

Signal Word:
Warning

Hazard Statement:
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements (Prevention):

P280 Wear protective gloves and eye/face protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P272 Contaminated work clothing should not be allowed out of the workplace.
P264 Wash with plenty of water and soap thoroughly after handling.

Precautionary Statements (Response):

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water.
P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or
doctor/physician.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash before reuse.
P391 Collect spillage.
P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Precautionary Statements (Disposal):

P501 Dispose of contents/container to hazardous or special waste collection
point.

According to Regulation (EC) No 1272/2008 [CLP]

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019

Labeling of special preparations (GHS):

EUH205: Contains epoxy constituents. May produce an allergic reaction.

According to Regulation (EC) No 1272/2008 [CLP]

Hazard determining component(s) for labelling: BISPHENOL-A-EPICHLORHYDRIN RESINS M

<=700, MONO[(C12/C14-ALKYLOXY)METHYL]OXIRANE DERIVATIVES

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.

SECTION 3: Composition/Information on Ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Chemical nature

Preparation based on: epoxy resin

Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecularweight ≤ 700)

Content (W/W): <= 100 % Skin Corr./Irrit. 2
CAS Number: 25068-38-6 Eye Dam./Irrit. 2
EC-Number: 500-033-5 Skin Sens. 1
INDEX-Number: 603-074-00-8 Aquatic Chronic 2
H319, H315, H317, H411

Specific concentration limit:

Skin Irrit. 2: >= 5 %
Eye Irrit. 2: >= 5 %

oxirane, mono[(C12-14-alkyloxy)methyl] derivs.

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
Content (W/W): <= 100 % Skin Corr./Irrit. 2
CAS Number: 68609-97-2 Skin Sens. 1
EC-Number: 271-846-8 H315, H317
REACH registration number: 01-
2119485289-22
INDEX-Number: 603-103-00-4

For the classifications not written out in full in this section, including the hazard classes and the
hazard statements, the full text is listed in section 16.

SECTION 4: First-Aid Measures

4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. Immediately remove contaminated
clothing.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.

On skin contact:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances
should organic solvent be used. If irritation develops, seek medical attention.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: Eye irritation, skin irritation, allergic contact dermatitis

4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
foam, water spray, dry powder, carbon dioxide

Unsuitable extinguishing media for safety reasons:

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
water jet

5.2. Special hazards arising from the substance or mixture

Carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black

5.3. Advice for fire-fighters

Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. If exposed to fire,
keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do
not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed
of in accordance with official regulations.

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures
Do not breathe vapour/aerosol/spray mists. Wear eye/face protection. If exposed to high vapour
concentration, leave area immediately. Use personal protective clothing. Handle in accordance with
good building materials hygiene and safety practice.

6.2. Environmental precautions

Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.

6.3. Methods and material for containment and cleaning up

For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of
contaminated material as prescribed.
For large amounts: Pump off product.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling
Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skin contact. No special measures
necessary provided product is used correctly.

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Keep only in the original container in a cool, dry, well-
ventilated place away from ignition sources, heat or flame. Protect from direct sunlight.

Not frost sensitive.

not heat sensitive
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

8.2. Exposure controls

Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Combination filter for gases/vapours of
organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).

Hand protection:
Chemical resistant protective gloves (EN 374)
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.

Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness

Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN 374)
polyvinylchloride (PVC) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
Do not inhale gases/vapours/aerosols. Avoid contact with the skin, eyes and clothing. Avoid
exposure - obtain special instructions before use. Handle in accordance with good building materials
hygiene and safety practice. Wearing of closed work clothing is recommended. When using, do not
eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be
inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Form: liquid
Colour: colourless to slightly yellow
pH value:
not applicable
Boiling range: > 200 °C
Flash point: approx. 148 °C
Density: approx. 1.11 g/cm3
(25 °C)
Solubility (qualitative) :
insoluble
Self ignition: not self-igniting

Thermal decomposition: > 200 °C

No decomposition if stored and handled as prescribed/indicated.
Viscosity, dynamic: approx. 600 - 900 mPa.s
(25 °C)
Explosion hazard: not explosive

9.2. Other information

Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

SECTION 10: Stability and Reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals: No corrosive effect on metal.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

The product is stable if stored and handled as prescribed/indicated.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
10.4. Conditions to avoid
No conditions to avoid anticipated.

10.5. Incompatible materials

Substances to avoid:
No substances known that should be avoided.

10.6. Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Based on available Data, the classification criteria are not
met.

Irritation

Assessment of irritating effects:

Eye contact causes irritation. Skin contact causes irritation.

Respiratory/Skin sensitization

Assessment of sensitization:
Sensitization after skin contact possible.

Germ cell mutagenicity

Assessment of mutagenicity:
The chemical structure does not suggest a specific alert for such an effect. Based on available Data,
the classification criteria are not met.

Carcinogenicity

Assessment of carcinogenicity:
Based on the ingredients there is no suspicion of a carcinogenic effect in humans. Based on
available Data, the classification criteria are not met.

Reproductive toxicity

Assessment of reproduction toxicity:

The chemical structure does not suggest a specific alert for such an effect. Based on available Data,
the classification criteria are not met.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019

Developmental toxicity

Assessment of teratogenicity:
The chemical structure does not suggest a specific alert for such an effect. Based on available Data,
the classification criteria are not met.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

No reliable data was available concerning repeated dose toxicity. Based on available Data, the
classification criteria are not met.

Other relevant toxicity information

Based on our experience and the information available, no adverse health effects are expected if
handled as recommended with suitable precautions for designated uses. The product has not been
tested. The statements on toxicology have been derived from the properties of the individual
components.

SECTION 12: Ecological Information

12.1. Toxicity

Assessment of aquatic toxicity:

Acutely toxic for aquatic organisms. May cause long-term adverse effects in the aquatic
environment. The inhibition of the degradation activity of activated sludge is not anticipated when
introduced to biological treatment plants in appropriate low concentrations.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):

Not readily biodegradable (by OECD criteria).
The product is virtually insoluble in water and can thus be separated from water mechanically in
suitable effluent treatment plants.

12.3. Bioaccumulative potential

Bioaccumulation potential:
Because of the product's consistency and low water solubility, bioavailability is improbable.

12.4. Mobility in soil

Assessment transport between environmental compartments:

Volatility: The substance will not evaporate into the atmosphere from the water surface.
Adsorption in soil: Following exposure to soil, adsorption to solid soil particles is probable, therefore
contamination of groundwater is not expected.

12.5. Results of PBT and vPvB assessment

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very
persistent/very bioaccumulative).

12.6. Other adverse effects

The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on
substances that deplete the ozone layer.

12.7. Additional information

Other ecotoxicological advice:

Do not discharge product into the environment without control. The product has not been tested. The
statements on ecotoxicology have been derived from the properties of the individual components.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods

Observe national and local legal requirements.

Residues should be disposed of in the same manner as the substance/product.

Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.

SECTION 14: Transport Information

Land transport

ADR
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains EPOXY RESIN)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for Tunnel code: E
user:

RID
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains EPOXY RESIN)
Transport hazard class(es): 9, EHSM
Packing group: III
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
Environmental hazards: yes
Special precautions for None known
user:

Inland waterway transport

ADN
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains EPOXY RESIN)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:
Transport in inland Not evaluated
waterway vessel:

Sea transport

IMDG
UN number: UN 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains EPOXY RESIN)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Marine pollutant: YES
Special precautions for None known
user:

Air transport

IATA/ICAO
UN number: UN 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains EPOXY RESIN)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:

14.1. UN number
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.

14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.

14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.

14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

15.2. Chemical Safety Assessment

Chemical Safety Assessment not required

SECTION 16: Other Information

Full text of the classifications, including the hazard classes and the hazard statements, if mentioned
in section 2 or 3:
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 01.09.2015 Version: 1.0
Product: MasterInject 1315 PART A
(ID no. 30601721/SDS_GEN_EU/EN)
Date of print 13.03.2019
Skin Sens. Skin sensitization
Aquatic Chronic Hazardous to the aquatic environment - chronic
Skin Irrit. Skin irritation
Eye Irrit. Serious eye irritation
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.