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    Dzexams Uploads Sujets 2622716

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    The document describes two chemistry experiments. The first involves reacting calcium carbonate with hydrochloric acid, producing carbon dioxide gas. The second involves reacting zinc with hydrochloric acid, producing hydrogen gas. For both experiments, the document asks to: identify reactants and products, construct reaction progress tables, determine maximum reaction progress, calculate gas volumes and reactant amounts, and graph reaction progress curves.

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    Dzexams Uploads Sujets 2622716

    Uploaded by

    abdelhalim
    464 views8 pages
    The document describes two chemistry experiments. The first involves reacting calcium carbonate with hydrochloric acid, producing carbon dioxide gas. The second involves reacting zinc with hydrochloric acid, producing hydrogen gas. For both experiments, the document asks to: identify reactants and products, construct reaction progress tables, determine maximum reaction progress, calculate gas volumes and reactant amounts, and graph reaction progress curves.

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    1 as physique

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    The document describes two chemistry experiments. The first involves reacting calcium carbonate with hydrochloric acid, producing carbon dioxide gas. The second involves reacting zinc with hydrochloric acid, producing hydrogen gas. For both experiments, the document asks to: identify reactants and products, construct reaction progress tables, determine maximum reaction progress, calculate gas volumes and reactant amounts, and graph reaction progress curves.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    464 views8 pages

    Dzexams Uploads Sujets 2622716

    Uploaded by

    abdelhalim
    The document describes two chemistry experiments. The first involves reacting calcium carbonate with hydrochloric acid, producing carbon dioxide gas. The second involves reacting zinc with hydrochloric acid, producing hydrogen gas. For both experiments, the document asks to: identify reactants and products, construct reaction progress tables, determine maximum reaction progress, calculate gas volumes and reactant amounts, and graph reaction progress curves.

    Copyright:

    © All Rights Reserved
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    of 8

    ‫‪www.sites.google.

    com/site/faresfergani‬‬ ‫تاريخ آخر تحديث ‪2022/04/25 :‬‬

    ‫اﻟﺠﻤﻬﻮرﻳﺔ اﻟﺠﺰاﺋﺮﻳﺔ اﻟﺪﻳﻤﻘﺮاﻃﻴﺔ اﻟﺸﻌﺒﻴﺔ‬


    ‫ﺛﺎﻧﻮﻳﺔ ﻣﻮﻟﻮد ﻗﺎﺳﻢ ﻧﺎﻳﺖ ﺑﻠﻘﺎﺳﻢ ‪ -‬اﻟﺨﺮوب ‪ .‬ﻗﺴﻨﻄﻴﻨﺔ‬ ‫وزارة اﻟﺘﺮﺑﻴﺔ اﻟﻮﻃﻨﻴﺔ‬
    ‫اﻷﺳﺘﺎذ ﻓﺮﻗﺎﻧﻲ ﻓﺎرس‬ ‫اﺧﺘﺒﺎر اﻟﺜﻼﺛﻲ اﻟﺜﺎﻟﺚ ﻟﻠﺴﻨﺔ أوﻟﻰ ﺛﺎﻧﻮي‬
    ‫اﻟﺴﻨﺔ اﻟﺪراﺳﻴﺔ ‪2022/2021 :‬‬ ‫اﻟﺸﻌﺒﺔ ‪ :‬ﺟﺬع ﻣﺸﺘﺮك ﻋﻠﻮم و ﺗﻜﻨﻮﻟﻮﺟﻴﺎ‬
    ‫اﻟﻤﺪة ‪ 02 :‬ﺳﺎﻋﺔ‬ ‫اﺧﺘﺒﺎر ﺗﺠﺮﻳﺒﻲ ﻓﻲ ﻣﺎدة ‪ :‬اﻟﻌﻠﻮم اﻟﻔﻴﺰﻳﺎﺋﻴﺔ‬

    ‫الموضوع ‪ 1‬ثا ‪25 -‬‬ ‫)‪(U11-Ex25‬‬ ‫اﻝﺘﻤرﻴن اﻷول ‪:‬‬


    ‫ﻓﻲ إطﺎر ﺒﺤث ﺠﻴوﻝوﺠﻲ أراد ﻓرﻴق ﻤن اﻝﺒﺎﺤﺜﻴن زﻴﺎرة ﻤﻐﺎرة ﺤﻴث ﺘوﺠد‬
    ‫ﺨطورة اﺴﺘﻨﺸﺎق ﻏﺎز ‪ CO2‬اﻝذي ﻴﻤﻜن أن ﻴﺘﺴرب ‪ .‬إن ﻨﺴﺒﺔ ﺘﺴرب‬
    ‫ﻏﺎز ‪ CO2‬ﺒﻜﺜﺎﻓﺔ ﻜﺒﻴرة ﻤﻤﻜن أن ﺘؤدي إﻝﻰ اﻹﻏﻤﺎء و ﺤﺘﻰ إﻝﻰ‬
    ‫اﻝﻤوت ‪.‬‬
    ‫إن ﻏﺎز ‪ CO2‬ﻴﺘﺸﻜل ﺒﺴﺒب ﺘﺄﺜﻴر اﻝﻤﻴﺎﻩ اﻝﺒﺎطﻨﻴﺔ اﻝﺠﺎرﻴﺔ و اﻝﺤﻤﻀﻴﺔ‬
    ‫ﻋﻠﻰ ﻜرﺒوﻨﺎت اﻝﻜﺎﻝﺴﻴوم ‪ CaCO3‬اﻝﻤﺘواﺠدة ﻓﻲ اﻝﺼﺨور ‪ ،‬ﻝدراﺴﺔ ﻫذا‬
    ‫اﻝﺘﻔﺎﻋل ﻨﻀﻊ ﻜﺘﻠﺔ ‪ m = 2 g‬ﻤن ﻜرﺒوﻨﺎت اﻝﻜﺎﻝﺴﻴوم ‪ CaCO3‬ﻓﻲ ﺤوﺠﻠﺔ ﺘﺤﺘوي ﻋﻠﻰ ﻤﺤﻠول ﻤﺎﺌﻲ ﻝﺤﻤض ﻜﻠور‬
    ‫اﻝﻤﺎء ))‪ (H3O+(aq)+Cl-(aq‬ﺤﺠﻤﻪ ‪ V = 100 ml‬و ﺘرﻜﻴزﻩ اﻝﻤوﻝﻲ ‪ ، C = 0,5 mol/L‬ﻓﻴﻨﺘﺞ ﻏﺎز ‪ CO2‬ﺨﻼل‬
    ‫اﻝﺘﻔﺎﻋل ‪ ،‬اﻝﺘﺤول اﻝﻜﻴﻤﻴﺎﺌﻲ اﻝﺤﺎدث ﻴﻨﻤذج ﺒﺘﻔﺎﻋل ﻤﻌﺎدﻝﺘﻪ ‪:‬‬
    ‫‪CaCO3‬‬ ‫)‪(s‬‬ ‫)‪+ 2H3O+(aq) = Ca+2(aq) + CO2 (g) + 3H2O(ℓ‬‬
    ‫‪ -1‬ﻋﻴن ﻜﻤﻴﺔ اﻝﻤﺎدة اﻹﺒﺘداﺌﻴﺔ ﻝﻜل ﻤﺘﻔﺎﻋل ‪.‬‬
    ‫‪ -2‬اﻨﺸﺊ ﺠدوﻻ ﻝﺘﻘدم اﻝﺘﻔﺎﻋل ﺜم ﺤدد ﻗﻴﻤﺔ اﻝﺘﻘدم اﻷﻋظﻤﻲ ‪ xmax‬و اﺴﺘﻨﺘﺞ اﻝﻤﺘﻔﺎﻋل اﻝﻤﺤد إن وﺠد ‪.‬‬
    ‫‪ -3‬أﺤﺴب ﻓﻲ ﻨﻬﺎﻴﺔ اﻝﺘﻔﺎﻋل ‪:‬‬
    ‫أ‪ -‬ﺤﺠم ﻏﺎز ﺜﻨﺎﺌﻲ أﻜﺴﻴد اﻝﻜرﺒون ‪ CO2‬اﻝﻨﺎﺘﺞ ﻓﻲ اﻝﺸرطﻴن اﻝﻨظﺎﻤﻴﻴن ‪.‬‬
    ‫ب‪ -‬ﻜﺘﻠﺔ ﻜرﺒوﻨﺎت اﻝﻜﺎﻝﺴﻴوم ‪ CaCO3‬اﻝﻤﺘﻔﺎﻋﻠﺔ ‪.‬‬
    ‫ﺠـ‪ -‬ﺘرﻜﻴز اﻝوﺴط اﻝﺘﻔﺎﻋﻠﻲ ﺒﺎﻝﺸوارد ‪ Cl- ، H3O+ ، Ca2+‬ﻓﻲ ﻨﻬﺎﻴﺔ اﻝﺘﻔﺎﻋل ‪.‬‬
    ‫‪ -4‬أرﺴم ﻋﻠﻰ ﻨﻔس اﻝﻤﺨطط اﻝﻤﻨﺤﻨﻴﺎت اﻝﺒﻴﺎﻨﻴﺔ اﻝﺘﺎﻝﻴﺔ ‪. n(CaCO3) = g(x) ، n(H3O+) = f(x) :‬‬
    ‫ﻴﻌطﻰ ‪M(Ca) = 40 g/mol ، M(O) = 16 g/mol ، M(C) = 12 g/mol :‬‬

    ‫)‪(U11-Ex11‬‬ ‫اﻝﺘﻤرﻴن اﻝﺜﺎﻨﻲ ‪:‬‬


    ‫ﻝدﻴﻨﺎ ﻤﺤﻠول ﻤن ﺤﻤض ﻜﻠور اﻝﻬﻴدروﺠﻴن ))‪ (H3O+(aq)+ Cl-(aq‬ﺤﺠﻤﻪ ‪ ، 200 mL‬ﺘرﻜﻴزﻩ اﻝﻤوﻝﻲ‬
    ‫‪ ، C0 = 0.2 mol/L‬أدﺨﻠﻨﺎ ﻓﻴﻪ ﻗطﻌﺔ ﻤن اﻝزﻨك ‪ Zn‬ﻜﺘﻠﺘﻬﺎ ‪ . m0‬ﻨﻼﺤظ ﺤدوث ﺘﺤول ﻜﻴﻤﻴﺎﺌﻲ ﻤرﻓق ﺒﺎﻨطﻼق‬

    ‫א‪ 1:‬‬
    ‫ﻏﺎز اﻝﻬﻴدروﺠﻴن ﻨﻘﻴس ﺤﺠﻤﻪ ﻓﻲ اﻝﺸرطﻴن اﻝﻨظﺎﻤﻴﻴن ﻓﻨﺠد ‪ .V(H2) = 0.224 L‬اﻝﺘﺤول اﻝﻜﻴﻤﻴﺎﺌﻲ اﻝﺤﺎدث ﻤﻨﻤذج‬
    ‫ﺒﺎﻝﻤﻌﺎدﻝﺔ اﻝﻜﻴﻤﻴﺎﺌﻴﺔ اﻝﺘﺎﻝﻴﺔ ‪:‬‬
    ‫)‪Zn(s) + 2H3O+aq) = Zn2+(aq) + H2(g) + 2H2O(ℓ‬‬
    ‫‪ -1‬ﻤﺜل ﻤﺨططﺎ ﻝﻠﺘﺠرﺒﺔ ‪ ،‬ﻤﻊ ﺸـرح اﻝطرﻴﻘـﺔ اﻝﺘـﻲ ﺘـﺴﻤﺢ ﻝﻠﺘﻼﻤﻴـذ ﺒﺤﺠـز اﻝﻐـﺎز اﻝﻤﻨطﻠـق ‪ ،‬و ﻗﻴـﺎس ﺤﺠﻤـﻪ و اﻝﻜـﺸف‬
    ‫ﻋﻨﻪ ‪.‬‬
    ‫‪ -2‬أﻨﺸﺊ ﺠدوﻻ ﻝﺘﻘدم ﻫذا اﻝﺘﻔﺎﻋل ‪.‬‬
    ‫‪ -3‬أوﺠد ﻗﻴﻤﺔ اﻝﺘﻘدم اﻷﻋظﻤﻲ ‪. xmax‬‬
    ‫‪ -4‬اﻋﺘﻤﺎدا ﻋﻠﻰ ﺠدول اﻝﺘﻘدم أوﺠد ‪:‬‬
    ‫أ‪ -‬ﺤدد اﻝﻤﺘﻔﺎﻋل اﻝﻤﺤد ‪.‬‬
    ‫ب‪ -‬اﻝﻜﺘﻠﺔ اﻻﺒﺘداﺌﻴﺔ ‪ m0‬ﻝﻘطﻌﺔ اﻝزﻨك ‪.‬‬
    ‫ﺠـ‪ -‬أذﻜر اﻝﺸوارد اﻝﻤﺘواﺠدة ﻓﻲ اﻝوﺴط اﻝﺘﻔﺎﻋﻠﻲ ﻓﻲ ﻨﻬﺎﻴﺔ اﻝﺘﻔﺎﻋل ﺜم أﺤﺴب ﺘراﻜﻴزﻫﺎ ﻋﻨدﺌذ ‪.‬‬
    ‫ﻴﻌطﻰ ‪. M(Zn) = 65 g/mol :‬‬

    ‫)‪(U11-Ex13‬‬ ‫اﻝﺘﻤرﻴن اﻝﺜﺎﻝث ‪:‬‬


    ‫ﻨﻤزج ﺤﺠﻤﺎ ‪ V1 = 100 mL‬ﻤن ﻤﺤﻠول ﻤﺎﺌﻲ ﻝﻴود اﻝﺒوﺘﺎﺴﻴوم )‪ (K+ + I-‬ﺘرﻜﻴزﻩ اﻝﻤوﻝﻲ ‪) C1‬ﻤﺠﻬول( ﻤﻊ ﺤﺠم‬
    ‫‪ (2K+‬ﺘرﻜﻴزﻩ‬ ‫‪ V2 = 100 mL‬ﻤن ﻤﺤﻠول ﻤﺎﺌﻲ ﻝﺒﻴروﻜﺴودﻴﻜﺒرﻴﺘﺎت اﻝﺒوﺘﺎﺴﻴوم )‪+ S2O82-‬‬
    ‫اﻝﻤوﻝﻲ ‪) C2‬ﻤﺠﻬول( ﻓﻨﺤﺼل ﻋﻠﻰ ﻤزﻴﺞ )‪ (S‬ﺤﺠﻤﻪ ‪ . VS = 200 mL‬اﻝﺘﺤول اﻝﻜﻴﻤﻴﺎﺌﻲ اﻝﺤﺎدث ﻤﻨﻤذج‬
    ‫ﺒﺎﻝﻤﻌﺎدﻝﺔ اﻝﻜﻴﻤﻴﺎﺌﻴﺔ اﻝﺘﺎﻝﻴﺔ ‪:‬‬
    ‫‪2I- + S2O82- = I2 + 2SO42-‬‬
    ‫ﺒﻴﺎن اﻝﺸﻜل اﻝﺘﺎﻝﻲ ﻴﻤﺜل ﺘﻐﻴرات ﻜﻤﻴﺔ ﻤﺎدة ﻜل ﻤن ﺸﺎردة‬
    ‫)‪n ( mol‬‬
    ‫‪ S2O82-‬و ﺜﻨﺎﺌﻲ اﻝﻴود ‪ I2‬ﺒدﻻﻝﺔ ﺘﻘدم‬ ‫اﻝﺒﻴروﻜﺴودﻴﻜﺒرﻴﺘﺎت‬
    ‫اﻝﺘﻔﺎﻋل ‪. x‬‬
    ‫‪I-‬‬
    ‫‪S2O82-‬‬ ‫‪ -1‬ﻫل ﻴوﺠد ﻤﺘﻔﺎﻋل ﻤﺤد ؟ اﺸرح ‪.‬‬
    ‫‪ -2‬ﻋﻴن ﻤن اﻝﺒﻴﺎن ﻗﻴﻤﺔ اﻝﺘﻘدم اﻷﻋظﻤﻲ ‪. xmax‬‬
    ‫‪ -3‬ﻤﺜل ﺠدوﻻ ﻝﺘﻘدم اﻝﺘﻔﺎﻋل ‪.‬‬
    ‫‪ -4‬اﻋﺘﻤﺎدا ﻋﻠﻰ ﺠدول اﻝﺘﻘدم ‪ ،‬أوﺠد ‪:‬‬
    ‫)‪x (mol‬‬ ‫أ‪ -‬اﻝﺘرﻜﻴزﻴن اﻝﻤوﻝﻴﻴن ‪ C2 ، C1‬ﺜم ﺤدد ﺴﻠم رﺴم ﻜﻤﻴﺔ اﻝﻤﺎدة‬
    ‫‪0.05‬‬ ‫ﻓﻲ اﻝﺒﻴﺎن ‪.‬‬
    ‫ب‪ -‬ﻜﺘﻠﺔ ﺜﻨﺎﺌﻲ اﻝﻴود ‪ I2‬اﻝﻨﺎﺘﺠﺔ ﻓﻲ ﻨﻬﺎﻴﺔ اﻝﺘﻔﺎﻋل ‪.‬‬
    ‫ﺠـ‪ -‬ﺘرﻜﻴز اﻝﻤزﻴﺞ )‪ (S‬ﺒﺎﻝﺸﺎردﻴن ‪ K+ ، S2O82-‬ﻓﻲ ﻨﻬﺎﻴﺔ اﻝﺘﻔﺎﻋل ‪.‬‬
    ‫ﻴﻌطﻰ ‪. M(I) = 108 g/mol :‬‬
    ‫א‪ 2:‬‬
    ‫حل التمرين األول‬

    ‫‪00000000000Sujet : 2AS 02 - 01‬‬

    ‫‪ -‬بفرض أن ‪ CaCO3‬متفاعل محد ‪:‬‬


    ‫‪0,02 - xmax = 0 → xmax = 0,02 mol‬‬
    ‫‪ -‬بفرض أن ‪ H3O+‬متفاعل محد ‪:‬‬
    ‫‪0,05 - 2xmax = 0 → xmax = 0,025 mol‬‬
    ‫إذن ‪ xmax = 0,02 mol‬و المتفاعل المحد ھو ‪. CaCO3‬‬

    ‫א‪ 3:‬‬
    ‫) ‪n f (Cl -‬‬
    ‫= ] ‪[Cl‬‬
    ‫‪-‬‬
    ‫‪V‬‬
    ‫‪ Cl-‬لم تدخل التفاعل و بالتالي كمية مادتھا في الحالة النھائية ھي نفسھا في الحالة االبتدائية و عليه ‪:‬‬
    ‫‪nf(Cl-) = n0(Cl-) = CV‬‬
    ‫و منه ‪:‬‬
    ‫‪[Cl - ] = C.V = C = 0,5 mol/L‬‬
    ‫‪V‬‬

    ‫‪0,05‬‬

    ‫‪0,02‬‬

    ‫א‪ 4:‬‬
    ‫حل التمرين الثاني‬

    ‫‪00000000000Sujet : 2AS 02 - 01‬‬

    ‫א‪ 5:‬‬
    ‫حل التمرين الثالث‬

    ‫‪00000000000Sujet : 2AS 02 - 01‬‬

    ‫א‪ 6:‬‬
    ‫‪0‬‬ ‫‪0‬‬

    ‫א‪ 7:‬‬
    ‫لتحميل نسخة من ھذا الملف و للمزيد ‪ .‬أدخل موقع األستاذ ‪:‬‬

    ‫‪www.sites.google.com/site/faresfergani‬‬

    ‫א‪ 8:‬‬

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