DPPs 1,2,3,4,5 GEOMETRICAL ISOMERISM

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JEE Main, Advanced 2023

#1

DPP NO. (JEE MAIN+ADVANCED)


Max Marks: 48 48 Minutes Test

Identify the Cis/Trans configuration for:

1.
7.

2.
8.

3.
9.

4.
10.

5.
11.

6.

Page No. 1
19.

12.
20.

21.
13.

22.

14. 23.

24.

15.
25.

16.
26.

17.
27.

18.
28.

Page No. 2
29. 36.

37.
30.

31. 38.

32.
39.

33.
40.

OH

34.
41.

35.

42.

Page No. 3
OH
N

43.

46.

OH
N

44.

NH
47.

OH
N

45.

48.

Page No. 4
JEE Main, Advanced 2023

#2

DPP NO. (JEE MAIN+ADVANCED)


Max Marks: 48 48 Minutes Test

Identify the compounds that can show the Geometrical Isomerism:

1.
7.

2.
8.

3.
9.

4.
10.

5.
11.

6.

Page No. 1
19.

12.
20.

21.
13.

22.

14. 23.

24.

15.
25.

16.
26.

17.
27.

18.
28.

Page No. 2
29. 36.

37.
30.

31. 38.

32.
39.

33.
40.

OH

34.
41.

35.

42.

Page No. 3
OH
N

43.

46.

OH
N

44.

NH
47.

OH
N

45.

48.

Page No. 4
ANSWERS

Molecules that show G.I. are:


4, 6, 9, 11, 13, 16, 23, 24, 25, 26, 27, 30,
31, 33, 34, 35, 36, 38, 47, 40, 41, 44,

]
TB
[II
NA
RA
IN
CH
SA

Page No. 5
JEE Advanced, Main 2023

#3

DPP NO. (JEE MAIN+ADVANCED)


Max Marks: 20 30 Minutes Test

Assign E-Z to the following double bonds:


NC CH2NH2

]
TB
1. H
6. HO3S SO2Cl

2.
[II
H3C

C N

O
7. H OH
NA
O

COBr
RA

3. SO 3H

COCH3
IN

4. 8. O

IH2C CH2CCl3
CH

CH2COCH3 C

C
9. H2N NO2
SA

5. NHCOCH3

10.

Page No. 1
n-Pr

i-Pr

16.
NC HC CH2
11.
Cl OCH2CH3
17. OHC CHO

12. OCl OLi


COCH2CONH2
O

]
TB
O
O
18. H2C CH COCH2I

C C

O
[II T3C NHCOCH3
A
O
13. O
19. D3C I
N

H OH
O
RA

O O
18
14. D OH
IN

O2N O
CH

O O
20.
Cl
SA

15.

Page No. 2
ANSWERS

1. Z

2. Z

3. Z

4. E

5. Z

6. E

7. E

8. E

9. E

]
TB
10. Z

11. Z

12. Z

13. Z
[II
A
14. Z

15. E
N

16. Z
RA

17. Z

18. E

19. E
IN

20. E
CH
SA

Page No. 3
JEE 2023

#4

DPP NO. (JEE MAIN+ADVANCED)


Max Marks: 73 35 Minutes Test

Identify molecules that show Geometrical Isomerism.

]
TB
1. 6.

[II
2.
NA
7.
RA

3. 8.
IN
CH

4. 9.
SA

O
10.
5.

Page No. 1
NH
11.

18.

12.
19.

]
TB
13.

20. [II
NA
14.
RA

15. 21.
IN
CH

16. 22.
SA

17. 23.

Page No. 2
Cl

24. 29. Br

Br

25.
30.

]
TB
31. Br Br

26. [IICl
NA

32.
RA

27. Cl
IN

33. F
CH

28. Cl
SA

34.

Page No. 3
O O

35. 41.

HO

36. 42. F

HO

]
TB
37. O
43.
[II
NA
38. O
44.
RA

NH
IN

39. O
45.
CH
SA

HN

40. 46.

Page No. 4
O HO

O
47. 53.

HO
O
O

O
48.
54. OH

]
TB
49.
55.
[II
NA

50. 56.
RA

57.
IN

51.
CH

58.
SA

O
52.

59.

Page No. 5
60.
65.

61.
66.

]
TB
62.
67.
[II
NA
Cl

Cl Cl
63.
RA

68.
IN
CH

Br Br
64.
SA

69.

Page No. 6
O
D D
72.

O
70.

73.

71.

]
TB
[II
NA
RA
IN
CH
SA

Page No. 7
ANSWERS

Molecules that show G.I. are:


6, 9, 11, 12, 13, 14, 17,
18, 19, 20, 21, 22, 23, 25,
26, 28, 29, 30, 31, 33, 34,
35, 36, 37, 38, 39, 40, 41,
42, 43, 44, 45, 46, 47, 48,
49, 50, 51, 52, 53, 54, 59,
61, 62, 63, 67, 68, 69, 70,

]
TB
[II
NA
RA
IN
CH
SA

Page No. 8
JEE 2023

#5

DPP NO. (JEE MAIN+ADVANCED)


Max Marks: 15 38 Minutes Test

Find the number of only geometrical isomers in the following compounds


(Theoretical):

]
TB
6.

1.
7. [II
NA
8.

9.
RA

2.

10.
IN

Me Me
CH

3.
11. H H
SA

4.

5.

Page No. 1
H
19.
H

12.
H2C CH
20. CH CH Me

Me Me
Me
21. Me C

13. H H H

H H H Me

]
TB
14. Me Me H D

Me [II
22. H
A
15. Me
N
RA

23.
16.
Br
24. Br
IN
CH

17.
SA

25.

18.

Page No. 2
33.

H3C

26. H
34.

OH
35. N

27. O

]
TB
HC CH2
36. O

28.

H3C
H

H
[II
A
29. H
N

37.
RA

30.
IN

31.
CH

38.
32.
SA

Page No. 3
ANSWERS

1. 2 28. None
2. 8 29. 2
3. 8 30. 6
4. 8 31. 4
5. 4 32. 4
6. 3 33. 3
7. 6 34. 4

]
TB
8. 6 35. 4
9. 6 36. 2
10. 3 37. 8
11. 2
12. 2
[II
38. 4
NA
13. 2
14. 2
15. 2
RA

16. 2
17. 2
18. 4
IN

19. 6
20. 8
CH

21. 2
22. 2
23. 2
SA

24. 4
25. 2
26. 2
27. 4

Page No. 4
JEE Main, Advanced 2023

#1

DPP NO. (JEE MAIN+ADVANCED)


Max Marks: 48 48 Minutes Test

Identify the Cis/Trans configuration for:

1.
7.

2.
8.

3.
9.

4.
10.

5.
11.

6.

Page No. 1
19.

12.
20.

21.
13.

22.

14. 23.

24.

15.
25.

16.
26.

17.
27.

18.
28.

Page No. 2
29. 36.

37.
30.

31. 38.

32.
39.

33.
40.

OH

34.
41.

35.

42.

Page No. 3
OH
N

43.

46.

OH
N

44.

NH
47.

OH
N

45.

48.

Page No. 4
JEE Main, Advanced 2023

#1

DPP NO. (JEE MAIN+ADVANCED)


Max Marks: 48 48 Minutes Test

ANSWER KEY:

1.
7.

2.
8.

3.
9.

4.
10.

5.
11.

6.

Page No. 1
19.

12.
20.

21.
13.

22.

14. 23.

24.

15.
25.

16.
26.

17.
27.

18.
28.

Page No. 2
29. 36.

37.
30.

31. 38.

32.
39.

33.
40.

OH

34.
41.

35.

42.

Page No. 3
OH
N

43.

46.

OH
N

44.

NH
47.

OH
N

45.

48.

Page No. 4

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