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Q/JS J0520-2017

Standard Code J1251-001


Replaced
Q/JS J0520-2016
Standard
Main Drafter Han Tao\Da Yu
Assessor Chu Peigen
Release Implement Modified Standardization
Version Modification Gu Guijiang
Date Date Date Censor
Cao
NO.6 NO.0 20/9/2017 20/9/2017 / Approved by Guoron Date 20/9
g

SAFE USE INSTRUCTIONS OF ROVING

For Continuous Glass Fiber Products

INTRODUCTION
According to the European Regulation(ER) on Chemicals No.1907/2006(REACH)
enforced from June 1st2007, Material Safety Data Sheets (MSDS) are required only for
hazardous substances and preparations. Continuous glass fiber products of our
company are defined as “articles” under REACH and therefore MSDS are not required
for them.
In order to ensure our customers’ acquisition of information on proper handling and
use of glass fiber products, Jushi Group provides the customers with this Safe Use
Instructions.

SECTION 1 –IDENTIFICATION
PRODUCT IDENTIFICATION
Continuous Glass Fiber Products include Assembled Roving, Direct Roving, Dry
Chopped Strands, Wet Chopped Strands, Woven Roving, Stitch Chopped Strand Mat,
Powder Chopped Strand Mat, Emulsion Chopped Strand Mat, Stitch Combo Mat, Woven
Roving Combo Mat, Glass Filament Yarn, Marketable Cake, Cut Strands, Texturized
Roving and Milled Fiber.
MANUFACTURER INFORMATION:
JUSHI GROUP CO., LTD.
No.669Wenhua Rd. (S.), Tongxiang Economic Development Zone, Zhejiang 314500,
China
FAX:
Customer Service: +86-573-88181388
International Sales: +86-573-88181058
Domestic Sales: +86-573-88136222
COMPANY EMERGENCY TELEPHONE : (8:30-16:40 in Beijing, from Monday to
Saturday)
Customer Service: +86-573-88136367

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International Sales: +86-573-88181025


Domestic Sales: +86-573-88181016
E-mail: [email protected]

JUSHI INDIA PVT LTD


G19/20 CREATIVE INDUSTRIAL ESTATE N/M. JOSHI MARG MUMBAI 420011 India
PHONE: 0091 022 40234401/2/3/4/5
FAX: 0091 022 40234401
E-mail: [email protected]

JUSHI KOREA CO., LTD


Rm No. 2001, Hyundai 41Tower, 293, Mokdongdong-Ro,Yangcheon-gu, Seoul, 158-723,
Korea
PHONE: 0082 2 21683288
FAX: 0082 2 21683286
Email: [email protected]

JUSHI JAPAN CO., LTD


Eisen Blad, 5F1-6-3, Yurakucho Chiyoda Tokyo, Japan
PHONE: 0081 3 62688508
FAX: 0081 3 35028080
Email: [email protected]

JUSHI ITALY SRL


VIA ADIGE 10/12 21043 CASTIGLIONE OLONA (VA)
PHONE: 0039 0331857918
FAX: 0039 0331825521
E-mail: [email protected]

JUSHI SPAIN, S.A.


EDIFICIO GAMMA (Parque Empresarial Omega) Avd. de Barajas, 24 Planta 228108 Alc
obendas (Madrid) Spain
PHONE: 0034 917678817
FAX: 0034 917678818
E-mail: [email protected]

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Q/JS J0520-2017

JUSHI FRANCE SAS


ZI DU CHAMP DOLIN, PARC TECHNOLAND 3 ALLEE DU LAZIO, BATIMENT C
69800 ST PRIEST, FRANCE
PHONE: 0033 (0)472782073
FAX: 0033 (0)472782041
E-mail: [email protected]

JUSHI USA
4982 4th Street Irwindale,CA 91706 U.S.A.
PHONE: 00626 960-2038
FAX: 00626 960-2037
E-mail: [email protected]

JUSHI CANADA FIBERGLASS CO., LTD.


Markham, Toronto Canada
PHONE: 001 9054777628
FAX: 001 9054776047
E-mail: [email protected]

JUSHI GROUP SINOSIA SA COMPOSITE MATERIALS


4/65 Nerl Hare Road, Atlantis Industrial7350, Capetown, South Africa
PHONE: 0027 21 5772747/00852 2541 1114
FAX: 0027 21 5772727
E-mail: [email protected]/ [email protected]

HELM AG HAMBURG
Nordkanal Strasse 28 D-20097 Hamburg Germany
Phone: +49 40 2375 1203
Mobile: +49 172 426 9085
E-mail:[email protected]

If you are not able to reach the above phone numbers, please call the company
emergency number.

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Q/JS J0520-2017

SECTION 2 – HAZARD(S) IDENTIFICATION


With regard to their composition, these products are articles and not classified as
hazardous according to European Directive67/548/EEC and 99/45/EC and
ST/SG/AC.10/30/Rev6 and their latest amendments.
Glass Fiber products do not contain hazardous substances which can be released
under normal or reasonably foreseeable conditions.
Hazard classification and labeling:
Classification Labeling
Pictogram Hazard
Hazard Hazard UN Model Signal statement
Hazard statement
class category GHS Regulation word codes
s
May be harmful if
Oral H303
swallowed.
Acute No Not May be harmful in
5 Dermal Warning H313
toxicity pictogram required contact with skin.
May be harmful if
Inhalation H333
inhaled.
Skin No Not Causes mild skin
3 Warning H316
irritation pictogram required irritation.
Eye No Not Causes eye
2B Warning H320
irritation pictogram required irritation.

Precautionary statements
Prevention:Wash skin thoroughly after handling
Wear protective eye/face protection

Other hazards:Not available.


This product is no classified hazardous according to European RegulationNo.1272/2008.
This section identifies the potential hazards related to the article i.e. its shape, its
dimensions and other physical characteristics.

SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS


Product Composition:
Product Name Glass, % Sizing, % Binder, % Water, %
Assembled Roving 98.75±0.75 1.05±0.75 / ≤0.20
Direct Roving 99.28±0.58 0.62±0.48 / 0.10±0.1
Dry Chopped Strands 99.08±0.82 0.82±0.75 / ≤0.10

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Q/JS J0520-2017

Product Name Glass, % Sizing, % Binder, % Water, %


Wet Chopped Strands 89.90±2.10 0.10±0.10 / 10.0±2.0
Flame Retardant Fiber Glass 99.08±0.82 0.82±0.75 / ≤0.10
Woven Roving 99.33±0.53 0.57±0.43 / 0.10±0.1
Power Chopped Strand Mat 95.40±2.95 0.85±0.50 3.65±2.35 0.10±0.1
Emulsion Chopped Strand Mat 94.85±1.80 0.85±0.50 4.20±1.20 0.10±0.1
Glass Filament Yarn 98.90±0.30 1.00±0.20 / 0.10±0.1
Cut Strands 88.50±3.50 / / 11.5±3.5
Marketable Cake 99.45±0.25 0.45±0.15 / 0.10±0.1
Texturized Roving 99.55±0.35 0.35±0.25 / 0.10±0.1
Milled Fiber 98.98±0.82 0.82±0.75 / ≤0.20
CAS No.:
Glass Fiber: 65997-17-3
Sizing: N/A
Sizing :
Sizing is a mixture of chemicals applied to the strand surface. It mainly consists of
high-molecular polymers of no reactivity (usually natural ingredients, such as starch)
which are not listed in the appendices of EINECS or ELINCS.
In some cases, sizing maybe also contains substances of organic-silane family or other
substances. The manufacturer considers this risk as negligible as, even though listed as
hazardous substance, their concentration is extremely low (under 0.1% of total weight)
and they are polymerized during the production of glass fibers.

SECTION 4 – FIRST-AID MEASURES


Skin Contact:
If irritation occurs to the skin, rinse with soap and water. Make sure to refrain from
rinsing with warm water since warm water will make the skin pores open to allow glass
fiber to penetrate deeper. If glass fiber penetrates the skin, use a wash cloth to help pull
out the glass fiber. Do not rub or scratch affected skin to any further any further
deterioration. Please go to a doctor if irritation increases. Make sure to refrain from using
compressed air to remove glass fiber from skin.
Eye Contact:
Immediately flush eyes with clean water for at least 15 minutes. Please go to a
doctor if irritation increases.
Inhalation:
Immediately move to fresh air. Please go to a doctor if irritation increases.
Ingestion:

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Normally, ingestion is less than likely. If it does occur, keep the person under
observation for several days to make sure that no gastrointestinal disturbance occurs.
Do not induce vomiting unless required by medical staff. Please go to a doctor if irritation
increases.

SECTION 5 – FIRE-FIGHTING MEASURES


Continuous glass fiber products are neither flammable nor incombustible.
Only the sizing and the packing materials are combustible and could release small
quantities of hazardous gas in case of major and prolonged heat or fire.
Hazardous Combustion Products :
Primary combustion products are carbon monoxide, hydrogen, carbon dioxide and
water. Other undetermined compounds can be released in small quantities.
Fire-Fighting Methods:
Use dry chemical, foam, carbon dioxide and water as extinguishing media.
Fire-Fighting Instructions:
Fire fighters should use self-contained breathing apparatus and wear full protective
gear.

SECTION 6 – ACCIDENTAL RELEASE MEASURES


Personal precautions:
Avoid contact with the skin and the eyes.
Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Methods for Clean-up:
a) Pick up and transfer to properly labeled containers.
b) Avoid dry sweeping.
c) Shovel the major part of spilled material into a container.
d) Use an industrial vacuum cleaner with a high efficiency filter to clean up dust and
residual spilled material.
e) After vacuum cleaning, flush away with water.

SECTION 7 – HANDLING AND STORAGE


Handling:
Try to prevent the packing material from being damaged and keep the product
inside the packing material to minimize the generation of dusts. Maintain a clean work
environment and avoid generation of glass fiber fragments from improper handling.
Storage:
Keep the product in its packaging until use to minimize potential dust generation.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION


Continuous glass fibers are not respirable. However, certain mechanical processes
might generate airborne dust or fibers. The occupational exposure limits below
mentioned are applicable to airborne fiber exposure and/or to dust exposure.

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Exposure limits:
NOTE: The user of continuous glass fibers products has to comply with the national
regulations on occupational health protection. Occupational exposure limit values in
some European countries are illustrated as below. (8-hour work day)
Respirable dust Total Dust Respirable Fiber
ACGIH 3 mg/m 3 10 mg/m 3 1fiber/ml
Austria 6mg/m 3 / 0.5fiber/ml
Denmark 5 mg/m 3 10 mg/m 3 1fiber/ml
Finland / 10 mg/m 3 1fiber/ml
France / 10 mg/m 3 1fiber/ml
Germany 3 mg/m 3 4 mg/m 3 0.25fiber/ml
Ireland 5 mg/m 3 / 2fiber/ml
Italy 3 mg/m 3 10 mg/m 3 1fiber/ml
Netherlands 2 mg/m 3 10 mg/m 3 1fiber/ml
Norway 5 mg/m 3 10 mg/m 3 1fiber/ml
Portugal / 4 mg/m 3 1fiber/ml
Spain 3 mg/m 3 10 mg/m 3 1fiber/ml
United Kingdom 5 mg/m 3 10 mg/m 3 2fiber/ml
Engineering Control:
Production areas are closed off and a required relative humidity is maintained.
Respiratory Protection:
Wear a suitable mask when working in an environment where dust concentration is
high.
Eye Protection:
Wear safety glasses and face shield.
Body Protection:
Normal loose working clothing (long-sleeved shirts and long pants) is recommended.
Skin irritation occurs primarily at the contact areas such as around the neck and waist.
Hand Protection:
Wear gloves. Skin irritation occurs primarily at the contact areas such as wrists and
between the fingers.

SECTION 9 – PHYSICLAL AND CHEMICAL PROPERTIES AND


SAFETY CHARACTERISTICS
Product Appearance and Properties: White or off-white solid;No odor.
Flash Point: Not applicable
PH Value: Not applicable.
Ignition Temperature: Not applicable.
Melting Point :> 800°C.

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Explosion Upper Limit: Not applicable.


Boiling Point: Not applicable.
Explosion Lower Limit: Not applicable.
Relative Density: 2.6 Times that of water.
Solubility (in Water): Insoluble
Relative Vapor Density: Not applicable
Product Use:
Glass fiber is an inorganic nonmetal material and is used for plastic reinforcement, acoustic absorption and insulation.

SECTION 10 – STABILITY AND REACTIVITY


Chemical Stability:
Stable under normal conditions.
Materials to Avoid:
None.
Conditions to Avoid:
None.
Possibility of Hazardous Reactions:
Hazardous reaction does not occur.

SECTION 11 – TOXICOLOGICAL INFORMATION


Local Effects:
Dusts and fibers may cause irritation to eyes and skin. The irritation disappears
when the exposure ceases. Inhalation may cause coughing, nose and throat irritation
and sneezing. High exposures may cause difficult breathing, chest distress and
congestion, Mechanical irritation is not considered as a health hazard under the
European directive 76/548/EC on hazardous substances. It is required to classify
continuous glass fibers as an irritant under the European directive 97/69/EC.
Long Term Health Effects:
The International Agency for Research on Cancer (IARC), agency of the World
Health Organization (WHO), has determined that glass fiber is a non-carcinogenic
material because the evidence is inadequate to prove that glass fiber can cause humans
and experimental animals to develop cancer.
Continuous glass fibers do not possess cleavage planes which would allow them to
split length-wise into fibers with smaller diameters, rather they break across the fiber,
resulting in fibers which are of the same diameter as the original fiber with a shorter
length and a small amount of dust.
Continuous glass fibers are not carcinogenic. (See section 15)

SECTION 12 – ECOLOGICAL INFORMATION


Glass fiber products are not listed as a material harmful to animals, plants and fish.
No specific data available for glass fiber products at present.

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SECTION 13 – DISPOSAL CONSIDERATIONS


RCRA Hazard Class:
Non-Hazardous.
European code number for waste is 101103.
Disposal Instructions:
Dispose waste materials as per local environmental regulations.

SECTION 14 – TRANSPORT INFORMATION


IMDG/IM–RID–ADR–ICAO–IATA–DOT–TDG–MEX
Not regulated
Transport Instructions:
Rolling and moisture should be avoided in transit.

SECTION 15 – REGULATORY INFORMATION


This product is not hazardous according to European Directive 99/45/EC,
67/548/EEC and their latest amendments.
Information on Non-carcinogenicity:
According to EU Directives, the continuous glass fibers in these products are not
classified as carcinogenic.
Continuous glass fibers are not within the scope of Amendment 97/69/EC of
Directive 67/548/EEC since they are not “fibers with random orientation”.
The International Agency for Research on Cancer (IARC) categorized continuous
glass fiber as not classifiable with respect to human carcinogenicity (Group 3) in
June1987 and October 2001. The evidence from human, as well as, animal studies was
evaluated by IARC as insufficient to classify continuous glass fiber as a confirmed,
probable or even possible cancer causing material.
National Chemicals Inventory
Based on the rules enforced with regards to the marketing and use of chemicals in
countries where our Jushi products are manufactured, each chemical ingredient of these
finished products has to be listed on the National Chemicals Inventory of the specific
country where the products are produced.
However, continuous glass fiber products are “articles” under the chemicals
inventories listed below and consequently are exempt from listing on these inventories:
- The European Inventory of Existing Chemical Substances: EINECS/ELINCS,
- The US EPA Toxic Substance Control Act: TSCA,
- The Canadian Chemical Registration Regulations: NDSL/DSL,
- The Japanese Chemical Substances Control Law under METI: CSCL,
- The Australian Inventory of Chemical Substances: AICS,
- The Philippine Inventory of Chemicals and Chemical Substances: PICCS,
- The Korean Existing Chemicals List: (K) ECL and
- The Chinese List on New Chemical Substances.

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SECTION 16 – OTHER INFORMATION


Preparation Date:SEPTEMBER 2017
Prepared by:QA&EHS Dept
Data Verified by:Vice President of Jushi Group
Modification Information:The Sixth Version.
This document is prepared with reference to GBT 16483-2008 "Safety Data Sheet for
Chemical Products——Content and Order of Sections" and ST / SG / AC.10 / 30 / Rev6
"GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF
CHEMICALS (GHS) SIXTH REVISED EDITION" in compliance with REACH regulations.

Disclaimer
Reasonable care has been taken in the preparation of this information, but the
manufacturer makes no warranty of accuracy or any other warranty, expressed or
implied, with respect to this information. The manufacturer makes no representations
and assumes no liability for any direct, incidental or consequential damages resulting
form its use.

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