Structure of Atom With PYQ

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Structure of Atom

Q. If no. of protons in X–2 is 16. then no. of e– in X+2 will be–


(1) 14 (2) 16 (3) 18 (4) None
Q. In C12 atom if mass of e– is doubled and mass of proton is halved, then
calculate the percentage change in mass no. of C12.
Q. Assuming that atomic weight of C12 is 150 unit from atomic table, then
according to this assumption, the weight of O16 will be :
Q. An element have three isotopes and their isotopic weight are 11, 12 , 13 unit
and their percentage of occurance in nature is 85, 10, 5 respectively then
calculate the average atomic weight of element.
Q. Average atomic weight of an element M is 51.7. If two isotopes of M, M 50 ,
M52 are present then calculate the percentage of occurance of M50 in nature.
Q. Calculate the percentage of Deuterium in heavy water.
Q. If the mass of neutrons is doubled & mass of electron is halved then find out
the atomic mass of 6C12 and the percent by which it is increased.
Q. If mass of neutron is doubled, mass of proton is halved and mass of electron
is doubled then find out the change in At. wt of 6C12
Q. The vividh Bharti station of All India Radio broadcast on a frequency of 1368
Kilo Hertz. Calculate the wave length of the Electromagnetic waves emited by
the transmitter.
Q. Calculate ѷ in cm–1 and of yellow radiations have wavelength of 5800 Å
Q. A particular radiostation broadcast at a frequency of 1120 Kilo Hertz another
radio station broadcast at a frequency of 98.7 mega Hertz. What are the wave
length of radiations from each station.
Q. How long would it take a radio wave of frequency 6 × 103 sec–1 to travel from
mars to the earth, a distance of 8 × 107 km ?
Q. What will be the frequency of photon of wavelength 2225 Å traveling in
vacuum ?
Q. Calculate the energy of a photon of sodium light of wave length 5.862 × 10 –
16
m in Joules.
Q. Calculate the frequency & energy of a photon of wave length 4000 Å
Q. Calculate the λ and frequency of a photon having an energy of 2 electron volt.
Q. Which has a higher energy ?
(a) A photon of violet light with wave length 4000 Å
Or
(b) A photon of red light with wave length 7000 Å
Q. How many photons of lights having a wave length of 5000 Å are necessary to
provide 1 Joule of energy.
Q. Calculate the energy associated with the photon passing through vacuum
with wavelength 9900 Å.
Q. Calculate the radius of 1st,2nd,3rd,4th Bohr's Orbit of hydrogen.
Q. Calculate the radius ratio of 3rd & 5th orbit of He+
Q. Calculate the radius ratio of 2nd orbit of hydrogen and 3rd orbit of Li+2
Q. The ratio of the radius of two Bohr's orbit of Li+2 is 1:9. what Would be their
nomenclature.
Q. Calculate the radius of 2nd excited state of Li+2.
Q. Calculate the radius ratio of 2nd excited state of H & 1st excited state of Li+2.
Q. Calculate the energy of Li+2 atom for 2nd excited state.
Q. Calculate the ratio of energies of He+ for 1st & 2nd excited state .
Q. If the P.E. of an electron is –6.8 eV in hydrogen atom then find out K.E., E of
orbit where electron exist & radius of orbit.
Q. The ionization energy for the hydrogen atom is 13.6 ev then calculate the
required energy in ev to excite it from the ground state to 1st excited state.
Q. If the total energy of an electron is –1.51 ev in hydrogen atom then find out
K.E, P.E, orbit radius and velocity of the electron in that orbit.
Q. Calculate the velocity of an electron placed in the 3rd orbit of the Li2+ ion.
Also calculate the number of revolutions per second that it makes around the
nucleus.
Q. In a hydrogen spectrum if electron moves from 7 to 1 orbit by transition in
multi steps then find out the total number of lines in the spectrum.
Q. In a hydrogen spectrum if electron moves from 6th to 3rd orbit by transition
in multi steps then find out the following steps :
(a) Total number of lines in spectrum
(b) Total number of lines in U.V. region
(c) Total number of lines in visible region
(d) Total number of lines in IR region
Q. In Balmer series of H atom/spectrum, which electronic transitions represents
3rd line ?
Q. Calculate the wavelength of 1st line of Balmer series in Hydrogen spectrum.
Q. Calculate the frequency of the last line of the lyman series in hydrogen
spectrum.
Q. Calculate wavelength of 3rd line of Bracket series in hydrogen spectrum.
Q. What will be the shortest and longest wavelength of absorption lines of
hydrogen gas containing atoms in ground state ? Give Z = 1, R = 109737.5
Q. A series of lines in the spectrum of atomic hydrogen lies at wavelengths
656.46, 482.7, 434.17, 410.29 nm. What is the wavelength of next line in this
series.
Q. The wave number of 1st line of Balmer series of hydrogen spectrum is 15200
cm–1 . The wave number of 1St line of Balmer series of Li+2 spectrum will be?
Q. Calculate the ratio of maximum λof Lyman & Balmer series ?
Q. A certain electronic transition from an excited state to ground state of the
Hydrogen atom in one or more steps gives rise of 5 lines in the ultra violet region
of the spectrum. How many lines does this transition produce in the infra red
region of the spectrum?
Q. Two particles X and Y are in motion. If the wavelength associated with particle
X is 4 × 10–8 m, calculate the wavelength associated with particle Y if its
momentum is half of X.
Q. Calculate the de Broglie wavelength of a ball of mass 0.1 kg moving with a
speed of 30 ms–1.
Q. Why electron cannot exist inside the nucleus according to Heisenberg's
uncertainty principle ?
Q. The mass of a particle is 1 mg and its velocity is 4.5 × 105 cm per second. What
should be the wavelength of this particle if h = 6.652 × 10–27 erg second.
(1) 1.4722 × 10–24 cm
(2) 1.4722 × 10–29 cm
(3) 1.4722 × 10–32 cm
(4) 1.4722 × 10–34 cm

Q. Which of the following should be the wavelength of an electron if its mass is


9.1× 10–31 kg and its velocity is 1/10 of that of light and the value of h is 6.6252×
10–24 joule second?
(1) 2.446 × 10–7 metre
(2) 2.246 × 10–9 metre
(3) 2.246 × 10–11 metre
(4) 2.246 × 10–13 metre

Q. What should be the momentum (in gram cm per second) of a particle if its De
Broglie wavelength is 1 Å and the value of h is 6.6252 × 10–27 erg second ?
(1) 6.6252 × 10–19 (2) 6.6252 × 10–21
(3) 6.6252 × 10–24 (4) 6.6252 × 10–27

Q. What should be the mass of the sodium photon if its wavelength is 5894Å,
the velocity of light is 3 × 108 metre/second and the value of h is 6.6252 × 10–34
kg m2/sec.?

Q. What should be the uncertainty in the velocity of an electron if the


uncertainty in its position is 0.005 nm, the mass of electron is 9.109 × 10–31 kg
and the value of h is 6.6252 × 10–34 joule/second?
(1) 2.316 × 105 (2) 1.158 × 107
(3) 2.316 × 109 (4) 2.316 × 1011

Q. What should be the uncertainty in velocity of a particle of 1 kg mass if


uncertainty in position is 1Å and the value of h is 6.6252 × 10–34 Joule sec.?
(1) 1.055 × 10–22 (2) 1.055 × 1022
(3) 5.25 × 10–25 (4) 1.055 × 1024

Q. What should be the uncertainty in position if uncertainty in momentum is 1


× 10–2 g cm/sec. and value of h is 6.6252 × 10–34 Joule sec. ?
(1) 1.054 × 10–22 m (2) 1.054 × 10–25 m
(3) 0.525 × 10–27 m (4) 1.054 × 10–32 m

Q. A ball weighs 25 g moves with a velocity of 6.6 × 104 cm/sec then find out the
De Broglie λ associated with it.
Q. Which of the following has least De Broglie if they have same velocity.
1. e– 2. p 3. CO2 4. SO2

Q. If uncertainty in position of an e– is same as the Δx of He atom. If Δp of e– is


32 ×105 then find Δp in He atom.
Q. Calculate the uncertainty in the position of a particle when the uncertainty in
momentum is (a) 1 × 10–3g cm sec–1 (b) Zero.
Q. The uncertainty in position and velocity of a particle are 10–10 m and 5.27 ×
10–24 ms–1 respectively. Calculate the mass of the particle (h = 6.625 × 10–34 Joule
Sec.)
Q. Calculate the uncertainty in velocity of a cricket ball of mass 150 g if the
uncertainty in its position is of the order of 1Å (h= 6.6 × 10–34 kg m2 s–1).
Q. Find out the angular momentum of an electron in (a) 4s orbital (b) 3p orbital
(c) 4th orbital
Q. Given below are the sets of quantum numbers for given orbitals. Name these
orbitals. (i) n = 4, ℓ = 2, m = 0 (ii) n = 3, ℓ = 1, m = ±1
(iii) n = 4, ℓ = 0, m = 0 (iv) n = 3, ℓ = 2, m = ±2

Q. We know that fully filled and half filled orbital are more stable. Can you write
the electronic configuration of Cr(Z = 24) ?
Q. A compound of vanadium has a magnetic moment of 1.73 BM work out the
electronic configuration of the vanadium in the compound.
Q. A photon of wavelength 3000 Å strikes a metal surface, the work function of
the metal being 2.20 eV. Calculate (i) the energy of the photon in eV (ii) the
kinetic energy of the emitted photo electron and (iii) the velocity of the photo
electron.
Q. Photoelectrons are liberated by ultra violet light of wavelength 2000 Å from
a metallic surface for which the photoelectric threshold is 4000 Å. Calculate the
de Broglie wavelength of electrons emitted with maximum kinetic energy.
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