Advection Dispersion Equations,: Their Solutions and Applications For Water Quality in River

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Advection dispersion equations,

their solutions and applications for


water quality in river.

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Important Constituents and their
representative values

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Effect of Treatment on Five Important
Constituents

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Constituent Transport
• Flux, flow rate per unit area, or, quantity per
unit area per unit time. (gm/m2.sec)
• Mechanism of Transport
– ADVECTION (or CONVECTION)
– DISPERSION

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ADVECTION
• Advection (or Convection) is bodily transport
due to the motion of fluid.
• The constituent moves with the fluid velocity
• Flux of constituents F = UC, U is velocity of
flow, and C is concentration of constituents

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Diffusion
• Diffusion is process of transport of
constituents in the direction of decreasing
concentration of the constituents
• Flux in case of diffusion is proportional to
concentration gradient
• Fick’s First Law of Diffusion:

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Diffusion
• Molecular Diffusion
– It occurs in stagnant water or in laminar flow
– It is of interest to chemist
• Turbulent Diffusion
– It is of interest to river engineers, as turbulent flow is dominant
– Turbulent Diffusivity in all direction is same for homogeneous
turbulence, thus Ex= Ey= Ez
– Turbulent Diffusivity is of order of 1 to 10,000 cm2/sec (0.001 to
10 ft2/sec)
– Diffusivity is measured using tracer studies.
– It is difficult to measure, so it is taken as Calibration Parameter.

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Shear-Flow Dispersion
• It is diffusion type transport process
• It occurs due to non-uniform velocity
distribution (variation of velocity)

Advection and Turbulent Diffusion Only Advection + Turbulent Diffusion + Shear Dispersion.
U and C are average over the cross-section U is non-Uniform, that causes non-uniform mixing,
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and skewed concentration
Shear-Flow Dispersion
• When velocity is uniform, only advection and turbulent
diffusion occurs
• When Velocity is non uniform, an Additional Longitudinal
Mixing Process Occurs, that is called Shear-Flow Dispersion
• Far below the point of injection, a balance is achieved
between shear and transverse mixing, and a one-d analysis
is suitable, using a Longitudinal Diffusivity EL.
• Close to point of injection, 2-d or 3-d analysis should be
carried out.
• Magnitude of EL is 100 to 1000 times greater than turbulent
diffusivities (EX, EY, EZ)
• Effect of Shear-Flow Dispersion should be taken when 1-d
or 2-d analysis is carried out.

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Governing Advective-Diffusion
Equation
• Governing equation can be derived by
applying conservation of mass in a control
volume. (Ref to book of Chang, for derivations).
• 3d- AD Equation

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Governing Advective-Diffusion
Equation
• 2-d AD Equation

• 1-d AD Equation

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Water Quality Models
EPA
• AQUATOX :
• BASINS: Better Assessment Science Integrating Point
and Nonpoint Source
• QUAL2K: River and Stream Water Quality Program
• SWMM: Storm Water Management Model
• WASP: Water Quality Analysis Simulation Program

USGS
• SPARROW : It is Statistical Analysis System SAS based
Water Quality Program

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HEC RAS and WATER QUALITY
• HEC Ras can perform:
– detailed temperature analysis, and
– transport of a limited number of water quality constituents;
• Algae,
• Dissolved Oxygen (DO),
• Carbonaceous Biological Oxygen Demand BOD,
• Dissolved Orthophosphate,
• Dissolved Organic Phosphorous,
• Dissolved Ammonium Nitrate,
• Dissolved Nitrite Nitrogen,
• Dissolved Nitrate Nitrogen, and
• Dissolved Organic Nitrogen,

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