TexCare SRN 170 &

TexCare SRA300
LATAM CONDITIONS

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TexCare SRN & SRA

Industrial & Consumer Specialties
Global Application Development
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Objetive and Formulations

– The objective is to test the soil release and the antiredeposition effect provided by
adding Texcare® SRA 300 and Texcare® SRN 170 over a market HDP.

– Test Formulations
- Market HDP (0.5% CMC)
- Market HDP + 0.30% Texcare® SRN 170
- Market HDP + 0.15% Texcare® SRA 300
Soil Release Performance

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TexCare SRN & SRA

Industrial & Consumer Specialties
Global Application Development
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Washing Test Conditions

Mexican Conditions
Equipment Tergotometer

Wash Volume 1,2 L

DetergentConcentration 2,0 g/L

Water Hardness 150 ppm (3 Ca2+ : 1 Mg2+)

Washing Temperature 25ºC

Rinse 2 seconds on slow water flow

Drying 24 h, Line drying

Fabrics PES
Mole Sauce
Stain
Dirty Motor Oil
Washing Ration 30:1
 Assessments
Fabric Quantity 4 swatches per pot

Replicates 12 swatches/formulations Color Difference DE CMC (0.11:2.11)

Washing Time 30 minutes D65 / 10º Illuminant

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La Corona - HDP Foca Fabric Pre-washing

Washing Test Procedure (Finishing Removal)

Washing Step –
Polymer Deposition
Washing Test
Soil application: Silk Screen
(Pressure and speed
 Objective: controlled)
– To test washing
performance Ageing and drying overnight
at room temperature
 The test:
– Very complex test Colorimetric Selection
– Different kinds of soil of the stains
– Different kinds of fabric
– Two different evaluations Washing Step

Visual Panel Colorimetric

and Statistical Evaluation and
Treatment (non Statistical Treatment
parametric) (parametric)
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Colorimetric Evaluation - DE CMC

 The color difference DE CMC is a calculation based on the Lab color system. It
takes into account the lightness, hue and chroma of the color. It also considers
the observer (10º of visual angle) and D65 as illuminant – the artificial light that
has spectral distribution close to the natural light.

CIE Lab Color Space

1/2
2 2 2
L
L* 100
(White) DE CMC (l:c) = cf * + C + H
l . SL c . Sc
Sh
+b*
(Yellow)

-a*
(Green) +a*
(Red)
Higher colour difference DE CMC
-b*
(Blue)
Better washing performance

L* 0
(Black)
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Colorimetric Evaluation

 Colorimetric Data: Parametric Test

Box & Whisker Plot
5

Normal Prob. Plot; Raw Residuals

(Analysis sample)
3,0 4

2,5

Outliers Removal
,99
2,0
,95 3
1,5

1,0

(Box-Plot)
,75
0,5
,55 2
0,0
,35
-0,5

-1,0 ,15
Expected Normal Value

-1,5 1
,05 Mean = 2.5
-2,0 Mean±SD
,01 = (1.3701, 3.6299)
-2,5 Mean±1.96*SD
-3,0 0 = (0.2855, 4.7145)
-0,012 -0,008 -0,004 0,000 0,004 0,008 0,012 Fórmula
-0,010 -0,006 -0,002 0,002 0,006 0,010

Residual

Predicted vs. Residual Values

4

1 Requirement Check:
0

-1
Data Homoscedasticity / Normality
Raw Residuals

-2

-3

-4

-5
8,5 9,0 9,5 10,0 10,5 11,0 11,5 12,0 12,5 13,0 13,5 14,0 14,5

Predicted Values

Tukey
Test* *95% of confidence level

A=A
*Same letters are statistically similar, with 5% of significance level. A = AB
AB = B
A≠B
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Visual Evaluation

 Visual Panel: Rank Test

12 evaluators
Based on ASTM 88C-2003.

 Objective: 3 or more tiles with the

replicates of each formulation
- Evaluation of washing performance of three
or more products: closer to reality
Instructions to organize the tiles in
order of cleanness
 The evaluation:

- Color of the background is standardized

Attribution of grades or selection
- Distance of the evaluator from the panel is the best one
standardized
Checking the statistical differences
- Light above the panel is standardized using the Software: Friedman-Mod.
Dan Test
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Results

– Knitt 100% Polyester soiled with Mole Sauce

Colorimetric Evaluation Visual Evaluation

HDP Ref HDP + HDP + HDP Ref HDP + HDP +

0.30% SRN 170 0.15% SRA 300 0.30% SRN 170 0.15% SRA 300

HDP Ref HDP + HDP +

0.30% SRN 170 0.15% SRA 300
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Results

– Knitt 100% Polyester soiled with Dirty Motor Oil

Colorimetric Evaluation Visual Evaluation

HDP Ref HDP + HDP + HDP Ref HDP + HDP +

0.30% SRN 170 0.15% SRA 300 0.30% SRN 170 0.15% SRA 300

HDP Ref HDP + HDP +

0.30% SRN 170 0.15% SRA 300
Antiredeposition Effect

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Industrial & Consumer Specialties
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Test conditions

Multi Cycle (3x)

Equipment Modified Jar Test (Clariant)
Detergent Concentration 1.0 g/L
Soil Carbon Black – Olive Oil
Soil Concentration 0.5 g/L
Soaking Time none
Washing Time 30 minutes
Solution Volume 1L
N° of 5cm x 5cm swatches per vessel 10
Substrates Knit 50% CO – 50% PES
Number of Replicates 2
Temperature 25°C

*** Water hardness: 150 ppm

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Soil Anti-Redeposition Procedure

Weight 10g of water

Addition of the soil on water

Detergent Solution (3 minutes

of stirring)

Addition of the detergent solution

solution to the soil solution

Dispersion of the soil for 5 minutes

Addition of the swatches, one at a time

and washing for 30 minutes

Rinse one swatch at a

time under a slow water flow
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Procedure Steps

– Weight 10g of water

– Addition of the soil on water
– Detergent Solution (3 minutes of stirring)
– Addition of the detergent solution to the soil solution
– Dispersion of the soil for 5 minutes
– Addition of the swatches, one at a time and washing for 30 minutes
– Rinse one swatch at a time under a slow water flow
– Drying overnight at room temperature
– Colorimetric reading
– Retest
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Results

Reference
0.3% SRN 170

HDP Reference HDP + 0.3% TexCare SRN 170

(0.5% CMC)

– The powder detergent with Texcare® SRN 170 presented a strong and clear anti-
redeposition effect.

CIE whiteness is the degree to which a surface is white. To promote uniformity of practice in the evaluation of whiteness of surface colors, it is recommended
that the formulæ for whiteness be used for comparisons of the whiteness of samples evaluated for CIE standard illuminant D65. In this case, the higher the
CIE Whiteness, the higher the cleansing effect of the product
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Results

HDP Ref HDP + HDP +

0.30% SRA 300 0.15% SRA 300

– The powder detergent with Texcare® SRA 300 presented a strong and clear anti-
redeposition effect, even at low concentration (0.15%wt).

CIE whiteness is the degree to which a surface is white. To promote uniformity of practice in the evaluation of whiteness of surface colors, it is recommended
that the formulæ for whiteness be used for comparisons of the whiteness of samples evaluated for CIE standard illuminant D65. In this case, the higher the
CIE Whiteness, the higher the cleansing effect of the product