Alkane Alkene Questions

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Organic Chemistry Homework 2 - Alkanes and Alkenes

Name: ………………………………………. Mark: / 100

Class: ……………………………………….. Date: ……………….

Paper 2 [Structured and Free Response Questions]

Section A [Structured Questions]

1 The table shows some data about the first six members of the alkane homologous series.

alkane number of melting boiling heat energy released by


carbon atoms point / oC point / oC complete combustion of
in one molecule 1 mole of alkane / kJ
X Y
methane 1 -182 -162 880
ethane 2 -183 -89 1540
propane 3 -188 -42 2200
butane 4 -138 0 2880
pentane 5 -130 36
hexane 6 -95 69 4140

(a) Plot a graph of Y against X on the graph grid below. [3]


4500
heat energy
released by 4000
complete
3500
combustion of
1 mole of 3000
alkane / kJ
2500

2000

1500

1000

500

0
0 1 2 3 4 5 6 7
number of carbon atoms in one molecule

(b) Use the graph to estimate the value of Y for pentane. Write your answer in the
table.
[2]

1
(c) Calculate the energy released by one gram of methane.

Amount of energy released =

[1]
(d) Give the molecular formula of an alkane which is a liquid at room temperature
and and pressure (25oC and 1 atmosphere).

[1]
(e) Draw the structural formula of four possible isomers of hexane.

[4]
(f) What is the difference in the formula of two successive members of a homologous
series?

[1]

2 Cracking is used to break big hydrocarbon molecules into smaller ones.

(a) (i) State the conditions for cracking.

(ii) State and explain one advantage to motor vehicles of cracking.

(b) A hydrocarbon, C14H30, is cracked to give two products. One of the products is
propane.
(i) What is the molecular formula of the other product?

(ii) Describe a chemical test to show that the other product is unsaturated.

test:

2
observation in test:

[2]

3 (a) An alkene has the molecular formula C5H10. This alkene reacts with bromine to
form a compound with the structural formula shown below.

H H H H H

H C C C C C H

H Br Br H H

(i) Draw the structural formula of C5H10.

(ii) Write the equation for the reaction of between C5H10 and bromine.

(i) Give the colours of


the alkene:

bromine:

the product of the reaction:

(iv) Explain why this reaction is called an addition reaction.

[7]

(b) The molecular formulas of the first three members of an homologous series of
hydrocarbons are:

C4H6 C5H8 C6H10


(i) What is the molecular formula of the next member of this series?

(ii) Suggest a physical property of these hydrocarbons which is likely to change as the
number of carbon atoms increases. How does it change?

[2]

4 The diagram shows how margarine is produced from vegetable oil.

3
H H H H H H H H H H H H H H

H2 + C C C C C C C C
nickel
hydrogen C C powder C C

H H H H H H H H

part of a vegetable oil molecule part of a margarine molecule

(a) What type of reaction takes place between hydrogen and vegetable oil?

Addition reaction.
[1]
(b) (i) What is the purpose of the nickel in this reaction?

The nickel acts as the catalyst in this reaction.

(ii) Why is the nickel in powder form?

Nickel powder has smaller particle size and a larger surface area. Exposing a larger
surface area for collisions between reacting particles results in more collision per unit
time. With more collisions, the number of effective collisions per unit time increases. The
speed of reaction increases.

[2]

(c) Some vegetable oil molecules contain more than one C=C bond. The number of
C=C bonds in a vegetable oil molecule can be found by reacting the oil with iodine.
Iodine reacts with C=C bonds in the same way as bromine. 0.05 mole of a vegetable
oil was found to increase its mass by 25.4 g when shaken with an excess solution of
iodine. How many C=C bonds are contained in one molecule of the oil?

Number of moles of iodine, I2, reacted = 25.4 / 2(127)


= 0.1 mol
0.05 mole of vegetable oil reacts with 0.1 mole of iodine, I2
Thus, 1 mole of vegetable oil will react with 0.1/0.05 = 2 mole of iodine, I2

One molecule of the oil contained 2 C=C bonds.


[2]

5 Many useful products can be made from crude oil (petroleum). This is shown in the
flow chart below.
Useful fuels
Petroleum process X e.g. butane,
‘cylinder gas’

4
reaction Y

reaction Z
Ethene, C2H4 Ethanol, C2H5OH

(a) Name

(i) process X: fractional distillation

(ii) reaction Y: cracking


[2]
(b) For reaction Z,

(i) what type of reaction takes place? Addition reaction

(ii) write the equation for the reaction: C2H4 + H2O  C2H5OH
[2]
(c) Butane forms two isomers. Draw the structural formula of both isomers.

[Refer to this website for the isomers of butane: http://www.gcsescience.com/o23.htm


Again, control-click on the link!]

[2]

(d) Butane is used as ‘cylinder gas’ for cooking.

(i) Construct the equation for the complete combustion of butane in air.

2C4H10(g) + 13O2(g)  8CO2(g) + 10H2O(l)

(ii) Why is good ventilation important when ‘cylinder gas’ is being used?

Good ventilation ensures that enough oxygen is available for complete


combustion of butane. If insufficient oxygen is present, incomplete combustion
of butane occurs and poisonous carbon monoxide gas will be produced.

6 The following questions refer to compounds with the structure drawn below.

5
Using the letters A to F as appropriate, answer the following questions.

(a) Which compound is an unsaturated hydrocarbon? D

(b) Which compounds are members of the same homologous series?

A and F

(c) Which compounds are isomers of each other? C and E

(d) Which compound is a product of the reaction of ethene with steam? B

(e) C16H34 undergoes cracking to produce C13H26 and another compound. What is the
other compound? F
[5]

Section B [Free Response Questions]

1 (a) Give the structure of methane.


H

H C H

H [1]

(b) Methane undergoes a reaction with chlorine.


(i) State the type of reaction that takes place and one important condition for
the reaction.

6
Substitution reaction. The important condition is that the mixture of methane and
chlorine gas is exposed to diffused sunlight or ultra-violet light.

(ii) Draw the structures of any two organic products of this reaction and write an
equation for the reaction producing one of them.

H H H Cl

H C H H C Cl Cl C Cl Cl C Cl

Cl Cl Cl Cl
[any 2]

CH4 + Cl2  CH3Cl + HCl


CH3Cl + Cl2  CH2Cl2 + HCl
CH2Cl2 + Cl2  CHCl3 + HCl
CHCl3 + Cl2  CCl4 + HCl

[any 1 equation]

(c) Methane is the first member of a homologous series. Another homologous series
has the general formula CnH(2n - 6), where n is a number greater than 5. Give the
formulas of the first two members of this series.

C6H6, C7H8 [2]

2 One of the compounds in crude oil is dodecane, C12H26.


(a) One of the reactions of dodecane is shown in the equation below.

C12H26  C8H18 + C4H8

(i) What is the name of this type of reaction? Cracking

(ii) State two conditions required for this reaction.


A high temperature and a solid catalyst (such as aluminium oxide or silicon(IV)
oxide)

(iii) In the reaction, 1.00 mol of dodecane, C12H26, gives only 22.8 g of octane,
C8H18. Calculate the percentage yield.

1 mole of dodecane, C12H26, produce 1 mole of octane, C8H18

7
Theoretical mass of octane produced = 1  [8(12) + 18(1)]
= 114 g
Thus, percentage yield = 22.8/114  100%
= 20 %
[5]
(b) (i) Draw the structural formulas of two isomers of C4H8.
[Refer to this website: http://www.gcsescience.com/o27.htm ]

(ii) Suggest one use of these isomers, other than as fuels.

The isomers can be polymerised to make plastic. / The isomers can react with
steam to make alcohol.
[3]
(c) Octane is a saturated hydrocarbon and butene, C4H8, is an unsaturated
hydrocarbon. Explain how aqueous bromine can be used to distinguish between
these two compounds.

Add the liquid octane into aqueous bromine in a test tube and shake. Since octane
is saturated, no visible change will be observed and the reddish-brown aqueous
bromine is not decolourised.

Bubble the gaseous butene into aqueous bromine in a test tube. Since butene is
unsaturated, the reddish-brown aqueous bromine will decolourise rapidly.

[2]

3 An organic liquid X has the following composition by mass:

carbon – 82.76% hydrogen – 17.24%

Its relative molecular mass is 58.

(a) Determine the empirical formula of X.

C H
Percentage by mass 82.76 17.24
Ar of element 12 1
Divide percentage by 82.76/12 = 6.89667 17.24/1 = 17.24
Ar
Divide by smallest 6.89667/6.89667 = 1 17.24/6.89667 =
number 2.5
Simplest ratio 2 5

8
Thus, the empirical formula of X is C2H5

(b) Hence, determine the molecular formula of X.

molecular formula of X = (C2H5)n

n = 58 / [2(12) + 5(1)]
=2

Thus, the molecular formula of X is (C2H5)2 = C4H10

(c) Draw the full structural formula and name two possible isomers of X.

[Refer to this website for the isomers of butane: http://www.gcsescience.com/o23.htm


Again, control-click on the link!]

(d) Write a balanced equation for the complete combustion of X.

2C4H10(g) + 13O2(g)  8CO2(g) + 10H2O(l)

(e) Describe what you would observe when a sample of X is shaken with aqueous
bromine in a test tube.

When X is shaken with aqueous bromine in a test tube, no visible change will be
observed and the reddish-brown aqueous bromine is not decolourised.

[7]

4 Artificial rubber is made from the compound below.

(a) (i) What is the mass of 1 mole of the compound?

Mass of 1 mole of the compound = 1  Mr of compound


= 1  [5(12) + 8(1)]
= 68 g

(ii) What maximum volume of hydrogen, measured at r.t.p., would you expect to
react with 1.36 g of the compound?

Number of moles of the compound = 1.36/68


= 0.02 mol

9
One mole of the compound reacts with 2 moles of hydrogen gas, H2

Thus, number of mole of hydrogen that would react = 2  0.02


= 0.04 mol

Volume of hydrogen that would react = 0.04  24 dm3


= 0.96 dm3

[4]
(b) Draw the structure of one isomer of the compound.

One possible isomer:

[1]

10

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