Safety Data Sheet

Hazardous, Dangerous Goods

1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION

Product name: Octane Booster

Synonyms Product Code
Octane Booster ADOCTB375
HS Code: 3811.19.00 -

Recommended use: Multipurpose fuel additive.

Supplier: Penrite Oil Company Pty Ltd

ABN: 25 005 001 525
Street Address: Australia:
110-116 Greens Road
Dandenong South VIC 3175

New Zealand:
75 Lady Ruby Drive
East Tamaki Auckland 2013

Telephone: Australia: 1300 736 748; New Zealand: 0800 533 698
Facsimile: Australia: 1800 736 748; New Zealand: 0800 533 698

Emergency Telephone number: Australia: 1300 736 748; New Zealand: 0800 533 698

2. HAZARDS IDENTIFICATION

Classification

This material is hazardous according to the criteria of Safe Work Australia GHS 7.

Hazard Classifications
Flammable Liquids - Category 4
Acute Toxicity - Oral - Category 4
Acute Toxicity - Inhalation - Category 4
Aspiration Hazard - Category 1
Skin Corrosion/Irritation - Category 2
Eye Damage/Irritation - Category 2A
Specific Target Organ Toxicity (Single Exposure) - Category 3 Narcotic Effects
Acute Hazard to the Aquatic Environment - Category 2
Chronic Hazard to the Aquatic Environment - Category 2

Label Elements

Hazard Pictogram(s)

Signal Word
Danger

Hazard Statements
H227 Combustible liquid.

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H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Prevention Precautionary Statements

P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing fume, gas, mist, vapours or spray.
P264 Wash hands, face and all exposed skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing including eye/face protection and suitable
respirator.

Response Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P302+P352 IF ON SKIN: Wash with plenty of water and soap.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse
P391 Collect spillage.

Storage Precautionary Statements

P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Disposal Precautionary Statement

P501 Dispose of contents/container in accordance with local, regional, national and
international regulations.

Poison Schedule: Not Applicable

Child-resistant fastening: Not Applicable

Tactile warning: Not Applicable

DANGEROUS GOOD CLASSIFICATION

Classified as Dangerous Goods by the criteria of the "Australian Code for the Transport of Dangerous Goods by
Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".

Dangerous Goods Class: 9

Australian Special Provisions; AU01: Environmentally Hazardous Substances meeting the description of UN 3077
or UN 3082 are not subject to this Code (ADG 07) when transported by road or rail in;
(a) packagings that do not incorporate a receptacle exceeding 500 Kg (L); or
(b) IBCs.

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Classified as a C1 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the
requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

3. COMPOSITION INFORMATION

CHEMICAL ENTITY CAS NO PROPORTION

Solvent naphtha, petroleum, medium aliphatic 64742-88-7 >60 %

Distillates, petroleum, hydrotreated light 64742-47-8 10 - 30 %
1-Hexanol, 2-ethyl- 104-76-7 10 - 30 %
Solvent naphtha, petroleum, heavy aromatic 64742-94-5 1-5%
Manganese, tricarbonyl[(1,2,3,4,5-.eta.)-1-methyl-2,4-cyclopentadien-1-yl]- 12108-13-3 1-5%
Polyolefin alkyl hydroxy benzene alkyl amine - 1-5%
Polyether polyol - 1-5%
Naphthalene 91-20-3 <1 %
____________
100%

4. FIRST AID MEASURES

If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand 0800
764 766).

Inhalation: Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and
loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until
fully recovered. If breathing laboured and patient cyanotic (blue), ensure airways are clear and have a qualified
person give oxygen through a facemask. If breathing has stopped apply artificial respiration at once. In the event
of cardiac arrest, apply external cardiac massage. Seek immediate medical advice.

Skin Contact: If skin or hair contact occurs, immediately remove contaminated clothing and flush skin and hair
with running water. Continue flushing with water until advised to stop by the Poisons Information Centre or a
Doctor; or for 15 minutes and transport to Doctor or Hospital. For gross contamination, immediately drench with
water and remove clothing. Continue to flush skin and hair with plenty of water (and soap if material is insoluble).
For skin burns, cover with a clean, dry dressing until medical help is available. If blistering occurs, do NOT break
blisters. If swelling, redness, blistering, or irritation occurs seek medical assistance.

Eye contact: If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing
until advised to stop by the Poisons Information Centre or a Doctor; or for at least 15 minutes and transport to
Doctor or Hospital.

Ingestion: Immediately rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to
drink. Never give anything by the mouth to an unconscious patient. If vomiting occurs give further water.
Immediately call Poisons Centre or Doctor.

PPE for First Aiders: Wear safety shoes, overalls, gloves, chemical goggles, respirator. Use with adequate
ventilation. If inhalation risk exists wear organic vapour/particulate respirator meeting the requirements of
AS/NZS 1715 and AS/NZS 1716. Available information suggests that gloves made from nitrile rubber should be
suitable for intermittent contact. However, due to variations in glove construction and local conditions, the user
should make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash
contaminated clothing and other protective equipment before storing or re-using.

Notes to physician: Treat symptomatically.

5. FIRE FIGHTING MEASURES

Hazchem Code: •3Z

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Suitable extinguishing media: If material is involved in a fire use alcohol resistant foam or dry agent (carbon
dioxide, dry chemical powder).

Specific hazards: Combustible liquid.

Fire fighting further advice: On burning or decomposing may emit toxic fumes. Fire fighters to wear self-
contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of
combustion or decomposition.

6. ACCIDENTAL RELEASE MEASURES

SMALL SPILLS
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours or dust. Wipe up
with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal.

LARGE SPILLS
If safe to do so, shut off all possible sources of ignition. Clear area of all unprotected personnel. Slippery when
spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination
and the inhalation of vapours. Work up wind or increase ventilation. Contain - prevent run off into drains and
waterways. Use absorbent (soil, sand or other inert material). Use a spark-free shovel. Collect and seal in
properly labelled containers or drums for disposal. If contamination of crops, sewers or waterways has occurred
advise local emergency services.

Dangerous Goods - Initial Emergency Response Guide No: 47

7. HANDLING AND STORAGE

Handling: Avoid eye contact and skin contact. Avoid inhalation of vapour, mist or aerosols.

Storage: Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from foodstuffs. Store
away from incompatible materials described in Section 10. Store away from sources of heat and/or ignition.
Store locked up. Keep container standing upright. Keep containers closed when not in use - check regularly for
leaks.

Classified as a C1 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the
requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

This material is classified as a Class 9 Miscellaneous Dangerous Good as per the criteria of the "Australian Code
for the Transport of Dangerous Goods by Road & Rail" and/or the "New Zealand NZS5433: Transport of
Dangerous Goods on Land" and must be stored in accordance with the relevant regulations.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

National occupational exposure limits:

TWA STEL NOTICES

ppm mg/m3 ppm mg/m3

Methylcyclopentadienyl manganese tricarbonyl - 0.2 - - Sk

(as Mn)
Naphthalene 10 52 15 79 -
Oil mist, refined mineral - 5 - - -

As published by Safe Work Australia.

TWA - The time-weighted average airborne concentration over an eight-hour working day, for a five-day working
week over an entire working life.

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STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not
be exceeded at any time during a normal eight-hour workday.

‘Sk' Notice - absorption through the skin may be a significant source of exposure. The exposure standard is
invalidated if such contact should occur.

These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.

If the directions for use on the product label are followed, exposure of individuals using the product should not
exceed the above standard. The standard was created for workers who are routinely, potentially exposed during
product manufacture.

Biological Limit Values: As per the "National Model Regulations for the Control of Workplace Hazardous
Substances (Safe Work Australia)" the ingredients in this material do not have a Biological Limit Allocated.

Engineering Measures: Ensure ventilation is adequate to maintain air concentrations below Exposure
Standards. Use only in well ventilated areas. Use with local exhaust ventilation or while wearing appropriate
respirator. Vapour heavier than air - prevent concentration in hollows or sumps. Do NOT enter confined spaces
where vapour may have collected.

Personal Protection Equipment: SAFETY SHOES, OVERALLS, GLOVES, CHEMICAL GOGGLES,

RESPIRATOR.

Personal protective equipment (PPE) must be suitable for the nature of the work and any hazard associated with
the work as identified by the risk assessment conducted.

Wear safety shoes, overalls, gloves, chemical goggles, respirator. Use with adequate ventilation. If inhalation
risk exists wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS
1716. Available information suggests that gloves made from nitrile rubber should be suitable for intermittent
contact. However, due to variations in glove construction and local conditions, the user should make a final
assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated
clothing and other protective equipment before storing or re-using.

Hygiene measures: Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or
smoke. Wash hands prior to eating, drinking or smoking. Avoid contact with clothing. Avoid eye contact and skin
contact. Avoid inhalation of vapour, mist or aerosols. Ensure that eyewash stations and safety showers are close
to the workstation location.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Liquid
Colour: Amber
Odour: Petroleum

Solubility: Immiscible in water

Density: 0.805 g/cm³ @ 15°C
Relative Vapour Density (air=1): >1
Vapour Pressure (20 °C): <0.001 kPa
Flash Point (°C): 71
Flammability Limits (%): N Av
Autoignition Temperature (°C): N Av
Melting Point/Range (°C): N Av
Boiling Point/Range (°C): N Av
pH: N Av
Viscosity: 1.26 cSt @ 40°C
Total VOC (g/Litre): N Av

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(Typical values only - consult specification sheet)
N Av = Not available, N App = Not applicable

10. STABILITY AND REACTIVITY

Chemical stability: This material is thermally stable when stored and used as directed.

Conditions to avoid: Elevated temperatures and sources of ignition.

Incompatible materials: Oxidising agents.

Hazardous decomposition products: Oxides of carbon and nitrogen, smoke and other toxic fumes.

Hazardous reactions: No known hazardous reactions.

11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the
product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Acute Effects

Inhalation: Harmful if inhaled. Material may be an irritant to mucous membranes and respiratory tract. Inhalation
of vapour can result in headaches, dizziness and possible nausea. Inhalation of high concentrations can produce
central nervous system depression, which can lead to loss of co-ordination, impaired judgement and if exposure
is prolonged, unconsciousness.

Skin contact: Contact with skin will result in irritation.

Ingestion: Harmful if swallowed. Swallowing can result in nausea, vomiting and irritation of the gastrointestinal
tract. May cause lung damage if swallowed. Small amounts of liquid aspirated into the respiratory system during
ingestion or vomiting may cause bronchopneumonia or pulmonary oedema.

Eye contact: An eye irritant.

Acute toxicity

Inhalation: This material has been classified as a Category 4 Hazard. Acute toxicity estimate (based on
ingredients): 10.0 < LC50 ≤ 20.0 mg/L for vapours or 1.0 < LC50 ≤ 5.0 mg/L for dust and mist.

Skin contact: This material has been classified as not hazardous for acute dermal exposure. Acute toxicity
estimate (based on ingredients): LD50 > 2,000 mg/Kg bw

Ingestion: This material has been classified as a Category 4 Hazard. Acute toxicity estimate (based on
ingredients): 300 < LD50 ≤ 2,000 mg/Kg bw

Corrosion/Irritancy: Eye: this material has been classified as a Category 2A Hazard (reversible effects to eyes).
Skin: this material has been classified as a Category 2 Hazard (reversible effects to skin).

Sensitisation: Inhalation: this material has been classified as not a respiratory sensitiser. Skin: this material has
been classified as not a skin sensitiser.

Aspiration hazard: This material has been classified as Aspiration Hazard - Category 1

Specific target organ toxicity (single exposure): This material has been classified as a Category 3 Hazard.
Exposure via inhalation may result in depression of the central nervous system.

Chronic Toxicity

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Mutagenicity: This material has been classified as not a mutagen.

Carcinogenicity: This material has been classified as not a carcinogen.

Reproductive toxicity (including via lactation): This material has been classified as not a reproductive
toxicant.

Specific target organ toxicity (repeat exposure): This material has been classified as not a specific hazard to
target organs by repeat exposure.

12. ECOLOGICAL INFORMATION

Avoid contaminating waterways.

Acute aquatic hazard: This material has been classified as a Category Acute 2 Hazard. Acute toxicity estimate
(based on ingredients): > 1 ≤ 10 mg/L

Long-term aquatic hazard: This material has been classified as a Category Chronic 2 Hazard. Non-rapidly or
rapidly degradable substance for which there are adequate chronic toxicity data available OR in the absence of
chronic toxicity data, Acute toxicity estimate (based on ingredients): 1 - 10 mg/L, where the substance is not
rapidly degradable and/or BCF ≥ 500 and/or log Kow ≥ 4.

Ecotoxicity: No information available.

Persistence and degradability: No information available.

Bioaccumulative potential: No information available.

Mobility: No information available.

13. DISPOSAL CONSIDERATIONS

Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal
protection equipment is used, see "Section 8. Exposure Controls and Personal Protection" of this SDS.

If possible material and its container should be recycled. If material or container cannot be recycled, dispose in
accordance with local, regional, national and international Regulations.

14. TRANSPORT INFORMATION

ROAD AND RAIL TRANSPORT

Classified as Dangerous Goods by the criteria of the “Australian Code for the Transport of Dangerous Goods by
Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".

Australian Special Provisions; AU01: Environmentally Hazardous Substances meeting the description of UN 3077
or UN 3082 are not subject to this Code (ADG 07) when transported by road or rail in;
(c) packagings that do not incorporate a receptacle exceeding 500 Kg (L); or
(d) IBCs.

UN No: 3082
Dangerous Goods Class: 9
Packing Group: III

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Hazchem Code: •3Z
Emergency Response Guide No: 47
Limited Quantities 5L

Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (SOLVENT NAPHTHA, PETROLEUM, MEDIUM
ALIPHATIC)

Segregation Dangerous Goods: Not to be loaded with explosives (Class 1). Note 1: Materials that are fire risks
are incompatible with oxidising agents (Class 5.1) or organic peroxides (Class 5.2). Exemptions may apply.

MARINE TRANSPORT
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)
for transport by sea. This material is classified as a Marine Pollutant (P) according to the International Maritime
Dangerous Goods Code.

UN No: 3082
Dangerous Goods Class: 9
Packing Group: III

Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (SOLVENT NAPHTHA, PETROLEUM, MEDIUM
ALIPHATIC)

AIR TRANSPORT
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous
Goods Regulations for transport by air.

UN No: 3082
Dangerous Goods Class: 9
Packing Group: III

Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (SOLVENT NAPHTHA, PETROLEUM, MEDIUM
ALIPHATIC)

15. REGULATORY INFORMATION

This material is not subject to the following international agreements:

Montreal Protocol (Ozone depleting substances)
The Stockholm Convention (Persistent Organic Pollutants)
The Rotterdam Convention (Prior Informed Consent)

This material is subject to the following international agreements:

Basel Convention (Hazardous Waste)
• Waste mineral oils unfit for their originally intended use

International Convention for the Prevention of Pollution from Ships (MARPOL)

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• Annex I - Oil
• Annex III - Harmful Substances carried in Packaged Form

This material/constituent(s) is covered by the following requirements:

The Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) established under the Therapeutic
Goods Act (Commonwealth): Not Applicable.

AICIS Status: All components of this product are listed on or exempt from the Australian Inventory of Industrial
Chemicals (AIIC).

NZ EPA Status: All components of this product are listed on or exempt from the New Zealand Inventory of
Chemical (NZIoC).

HSNO Group Standard: HSR002602 - Lubricants (Combustible) Group Standard 2020

16. OTHER INFORMATION

Reason for issue: Revised. Updated to GHS 7.

This Safety Data Sheet has been prepared by Chemical Data Services Pty Ltd on behalf of its client.

Safety Data Sheets are updated frequently. Please ensure that you have a current copy.

This information was prepared in good faith from the best information available at the time of issue. It is based on
the present level of research and to this extent we believe it is accurate. However, no guarantee of accuracy is
made or implied and since conditions of use are beyond our control, all information relevant to usage is offered
without warranty. The manufacturer will not be held responsible for any unauthorised use of this information or for
any modified or altered versions.

If clarification or further information is needed to ensure that an appropriate assessment can be made, the user
should contact this company.

Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to
our customers and is also available upon request.

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