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    Homework 5

    Uploaded by

    Victor Camilo

    Copyright:

    © All Rights Reserved
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    Homework 5

    Uploaded by

    Victor Camilo
    8 views3 pages

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    © © All Rights Reserved

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    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    8 views3 pages

    Homework 5

    Uploaded by

    Victor Camilo

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 3

    Homework 5

    August 24th 2018


    7.1.
    Solution:

    AVV = ( ∂∂ μN  )TV


    Using the chain rule:

    (∂∂ μN  ) =−(∂∂ μN  ) ∗(∂∂ VV   )


    TV TV
    ∂μ   ∂V  
    ¿−( ) ∗(
    ∂V TN ∂N )
    ∂μ  
    ¿−V (
    ∂V ) TN
    Using the total derivative of the chemical potential.

    dμ=−SdT +VdP
    ∂μ  ∂ P 
    ( ) ( )
    ∂ V TN
    =V
    ∂ V TN
    =V A VV

    ∂μ   ∂P 
    −V( )∂V TN( )
    =−V 2
    ∂ V TN
    =V 2 A VV

    ∂ P 
    ( )
    AVV =−V 2
    ∂ V TN
    =V 2 A VV

    ANSWER: Therefor when AVV =0, AVV =0

    7.3.

    Solution: The Stability Criteria for a pure component is given by:

    (∂∂ VP   ) >0 Eq.1


    T

    Applying the stability criteria to the van der Waals equation of state, and at the limit os
    stability.
    ∂P 
    ( )
    ∂V T
    =0

    RT a
    P= − Eq.2
    V −b V 2

    1
    (∂∂ VP   ) = (V−RT
    T
    2
    2a
    + =0 Eq .3
    −b) V3

    Using the expression determined for the constants a and b in example 7.2 from the Tester
    and Model Book

    27 R 2 T 2C
    a=
    64 PC

    RTC
    b=
    8 PC
    In order to calculate the temperature at the limit of stability we should know the volume,
    using the equations 2 and 3, we get the next expression.

    P V 3−aV +2 ab=0 Eq .4
    The tree roots from the polynomial (eq 4) with P= 1 bar, are:

    m3
    V 1=−0.0024
    mol
    m3
    V 2=0.00013
    mol
    m3
    V 3=0.0022
    mol

    The negative root does not have any sense physically.

    ANSWER: Using the equation 3 and the volume 2 and 3 the maximum temperature at
    stability is:

    For V2

    T =258.49 K
    ForV3
    T =55.19 K

    In comparison between the VDW result and the experimental (269 K) the result for the
    liquid spinodal at 1 bar is close.

    7.8.
    Solution:
    The pressure is function of the Temperature and volume
    P=f (T ,V )
    The total derivative of the pressure.

    2
    dP= ( ∂∂TP   ) dT +(∂∂ VP   ) dV
    V T
    At the spinodal curve we kwon that AVV =0.

    AVV = ( ∂∂VP   ) =0
    T
    Then.
    ∂P  
    dP= ( ) dT
    ∂T V

    dP ∂ P  
    =
    dT ∂ T( ) V
    7.11.

    A. Using internal energy as the basis function


    y 0=U =f ( V , S )
    For a pure component.
    y 1= A
    Using the criteria of stability at critical point.

    y 122= AVV =− ( ∂∂VP   ) =0 T


    −1 ∂V   −1
    KT= ( )
    V ∂P T
    =
    ∂P  
    V ( )
    ∂V T

    ANSWER: Then, if (∂∂ VP   ) =0, then at the critical point K


    T
    T tends to infinite

    Using internal energy as the basis function


    y 0=U =f ( S , V )
    For a pure component.
    y 1=H
    Using the criteria of stability at critical point.

    y 122=H SS = ( ∂T∂ S   ) =0 P

    C P =T ( ∂∂TS   ) = ∂ TT  
    P
    (∂ S ) P
    ∂T  
    ANSWER: Then, if ( )
    ∂S P
    =0, then at the critical point C P tends to infinite

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