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Path to success KOTA (RAJASTHAN )
CLASS TEST # 01
INORGANIC CHEMISTRY FULL SYLLABUS TIME : 30 MIN

SECTION–I : (i) Only One option correct Type

This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)
1. Choose the correct option in which all compounds are having same electron geometry of their central
atom :-
(I) XeO2F2 (II) BrF3 (III) SiF2Cl2 (IV) XeO3F2
(A) I and II only (B) II and III only (C) I, II and III only (D) I, II and IV only
2. Which of the following complex is inner orbital as well as diamagnetic in nature.
(A) [Cr(NH3)6]3+ (B) MnO42– (C) [Fe(EDTA)]– (D) [Co(H2O)6]3+
3. Identify the correct statement
(A) The ppt of BaCO3 is insoluble in dil HCl
(B) Hg(NO3)2 + Na2S white ppt of HgS
(C) Na2SO4 + Hg(NO3)2 yellow ppt of HgSO4.2HgO
(D) H2S turns lime water milky
4. Identify the metal chloride salt (P) which give colourless clear solution with excess of NaOH and excess
of NH4OH. When metal chloride salt (P) treated with ammonium sulphide then white ppt is formed :
(A) ZnCl2 (B) MnCl2 (C) FeCl2 (D) SnCl2
5. Which of the following compound is/are used for oxygenating the submarine or spaceshuttle
(1) Na2O2 (2) KO2 (3) KO3 (4) All of these
6. Which of the following statement is correct -
(A) Froth floatation method can only be used for sulphide ore
(B) Tin stone is consisting of wolframite as non-magnetic impurity
(C) In cyanide process for the extraction of silver, Zn used as leaching agent
(D) Bessemerization process is used in the extraction of copper from copper pyrite
(ii) One or more options correct Type
This section contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
7. A sample of bauxite ore is made up of Al2O3 + SiO2 + TiO2 + Fe2O3. This ore is treated with conc.
NaOH solution at 500 K and 35 bar pressure for few hours and filtered the species present in filtrate
is / are :
(A) Na[Al(OH)4] (B) Na2[Ti(OH)6] (C) Na2SiO3 (D) Na[Fe(OH)4]
8. Choose the CORRECT statement from following :
(A) On hydrolysis of SOF4 both products are acidic in nature
(B) The state of hybridisation of S-atom remains same in the hydrolysis product as in SOF4
(C) The general formula for cyclic silicate and pyroxene chain silicate is same
(D) The number of planes containing maximum number of atoms in IF5 is 3
9. The electronic configuration of four element are-
(i) [Xe],6s2 (ii) [Xe], 4f14, , 5d1, 6s2
(iii) [Ne], 3s2 , 3p5 (iv) [Ar] , 3d7 , 4s2
which of the following statements about these elements are true ?
(A) (i) is a strong reducing agent
(B) (ii) is a d-block element
(C) (iii) has more EA than fluorine (F).
(D) (iv) to get its dipositive ion two electrons are removed from 4s orbital

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Path to success KOTA (RAJASTHAN )
CLASS TEST # 01
10. Choose the CORRECT statement from the following :
(A) Bond angle BFB increases due to back bonding in BF3
(B) Bond angles are affected in PF3 due to back bonding
(C) Bond angles are not affected in B(OMe)3 due to back bonding
(D) B – F bond length decreases in BF3 due to back bonding
(iii) Paragraph Type
This section contains 02 paragraphs each describing theory, experiment, data etc. Four questions
relate to two paragraphs with two questions on each paragraph. Each question of a paragraph has
only one correct answer among the four choices (A), (B), (C) and (D).
Paragraph for Question 11 to 13
The crystal field theory is now much more widely accepted than the valence bond theory. It assumes
that the attraction between the central metal atom and the ligands in a complex is purely electrostatic.
11. The complex K4[Zn(CN)4(O2)2] is oxidised to K2[Zn(CN)4(O2)2], then which of the following is
correct -
(A) Zn (II) is oxidised into Zn(IV) (B) O–O bond length decreases
(C) Paramagnetic nature decreases (D) Complex becomes diamagnetic
12. Which of the following statement is correct -
(A) With d2sp3 hybridisation [FeCl(CN)4(O2)]4– complex is diamagnetic
(B) [NiCl4]2– complex is more stable than [Ni(dmg)2] due to higher C.F.S.E. value
–
(C) [V(CO)6] is not very stable and easily reduces to [V(CO)6]

(D) Ligand such as CO in [Ni(CO)4] acts as -electron donor due to presence of filled -molecular
orbital.
13. Which of the following complex is inner orbital as well as low spin complex -
(A) [Cr(H2O)6]3+ (B) [Fe(CN)6]3– (C) [Cu(CN)4]3– (D) [Mn(NH3)6]2+

Paragraph for Question 14 to 16

H2O
Acidic gas (A) + Yellowish green gas (B) (C) (D) + (E)

NaOH

(F) + (G)

(i) D and E are both acids while F and G both are salts.
(ii) F(solid) + conc. H2SO4 + K2Cr2O7(s) reddish brown vapour which is passed into NaOH
solution to give yellow solution.
(iii) Solution of (G) + CaCl2 Filtered White residue insoluble in dil. mineral acid
14. The gas ‘B’ is
(A) SO2 (B) CO2 (C) CO (D) Cl2

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Path to success KOTA (RAJASTHAN )
CLASS TEST # 01
15. The compound (C) is -
(A) COCl2 (B) SOCl2 (C) SO2Cl2 (D) CSCl2
16. The hybridisation state of central atom of the compound present in reddish brown vapour is-
(A) sp3 (B) sp3d (C) d3s (D) sp2
SECTION–II : Matrix-Match Type
This Section contains 02 question. Question has four statements (A, B, C and D) given in Column
I and five statements (P, Q, R, S and T) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS. 8(0)
1. Match the column :
Column-I Column-I
(Cation in solution) (Correct characteristics when no
where excess reagent is used)
+ 2+
(A) Ag and Pb (P) can be distinguished by Na2HPO4 solution
(B) Ba2+ and Mg2+ (Q) can be distinguished by dil.HCl

(C) Pb2+ and Hg22+ (R) can be distinguished by KI solution

(D) Ag+ and Fe3+ (S) can be distinguished by NaOH solution

2. Match the column
Column-I (Compound) Column-II (Uses)
(A) H2 (P) As rocket fuel
(B) H2 O (Q) As moderators in nuclear reactors
(C) D2 O (R) Bleaching agent
(D) H2O2 (S) For drinking purpose
(T) Fuel cell
SECTION-IV (NUMERICAL ANSWER)
1. All the alkali and alkaline earth metals dissolved in liquid ammonia, but few of them yields the metal on
evaporation of ammonia from solution. Find the total number of such metals.
Na, K , Mg, Sr, Ca , Rb , Cs
2. Find total number of conditions in which reduction of Fe+3 (aq) ions to iron(II) takes place
(i) On exposure to air (ii) On addition of conc. HNO3
(iii) On reaction with SnCl2 (iv) On reaction with H2O2 / H+
(v) On reaction with MnO4–/ H+ (vi) On reaction with KI
2– +
(vii) On reaction with Cr2O7 / H (viii) H2S / H+
3. Total number of elements which have less IE1 than that of 'N'.
Be, B, C, F, P, He
4. Assuming 2s-2p mixing is not operative , the paramagnetic species among the following are
Li2, B2, C2, N2, O2, O2+, NO
5. Find sum of unpaired electrons in following compounds
Na3[FeF6] ; [Ni(H2O)6]SO4 ; K4[MnF 6] ; Brown ring complex ; K2[NiCl4] ; O2 ; KO2

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