Exam 2 Chemistry

Exam II A - CHEM 102/014 - Solutions
Loyola University Chicago

March 14, 2018
You have 50 minutes to complete the 27 questions on the exam. Choose the best answer
for each question. The double numbered questions count twice and you should mark both
numbers on the answer sheet.
Please use pencil marks for the answer sheet and make sure that it is not too light
and fill in the whole bubble.
Please fill in your name and a 10 digit identification number in the bubbles on your
answer sheet.
Good Luck!!
REMOVE THE COVER FROM YOUR CALCULATOR AND PLACE ALL NON-
TEST MATERIALS OUT OF VIEW!!
Supportive material
Please note that both [H+] and [H3O+] are used interchangeably throughout the exam.
[X] means concentration of X in mol/L or M; pressures are measured in atmospheres.
Equilibrium constants are given where required.
R = 8.314 J/molK
NA = 6.0221 * 1023/mol Avogadro's Number

1amu = 1.661* 10-24g
°C = 5/9 (°F -32)
F = 9/5 (°C) +32
1,2) Consider the following reaction at equilibrium:
2CO2 (g) 2CO (g) + O2 (g) ΔH° = -514 kJ
Le Châtelier's principle predicts that an increase in temperature will ________.
a) increase the partial pressure of O2 (g)

b) decrease the partial pressure of CO2 (g)
c) decrease the value of the equilibrium constant
d) increase the value of the equilibrium constant
e) increase the partial pressure of CO
3) What is the conjugated acid of NH3?
a) NH3
b) NH2+
c) NH3+
d) NH4+
e) NH4OH
4) The reaction below is exothermic:
2NH3(g) <-> N2(g) + 3H2(g)
Le Chaterlier’s principle predicts that adding N2(g) to the system at equilibrium will
result in_________.
a) a decrease in the concentration of NH3(g)

b) a decrease in the concentration of H2(g)
c) an increase in the value of the equilibrium constant
d) a lower partial pressure of N2(g)
e) removal of all H2(g)
5) The molar concentration of hydronium ion [H3O+] in pure water is______?
a) 0.00
b) 1.0x10-7
c) 1.0x10-14
d) 1.00
e) 7.00
6,7) HZ is a weak acid. An aqueous solution of HZ is prepared by dissolving 0.20 mol
of HZ in 1 liter solution. The pH of the solution is 2.74. What is the Ka of HZ?
a) 1.7x10-5
b) 9.5x10-3
c) 1.4x10-9
d) 6.9x10-2
e) 3.8x10-7
8) Which solution below has the highest concentration of hydroxide ions?
a) pH = 3.21
b) pH = 12.59
c) pH = 7.93
d) pH = 9.82
e) pH = 7.00
9,10) A reaction vessel is charged with hydrogen iodide, which partially decomposes to
molecular hydrogen and iodine:
2HI(g) <-> H2(g) + I2(g)
When the system comes to equilibrium, pHI = 0.708atm, and pH2=pI2 = 0.0960atm. The
value for Keq is_________________.
a) 6.80x10-2
b) 1.30x10-2
c) Keq cannot be calculated for this reaction when the volume is not given.
d) 54.3
e) 1.84x10-2
11) What is the pH of a 0.015M aqueous solution of Sr(OH)2?
a) 12.48
b) 12.18
c) 1.82
d) 10.35
e) 1.52
12) The value of Keq for the equilibrium
H2(g) +I2(g) <-> 2HI(g)

is 794. What is the value of Keq for the equilibrium below?
1/2H2(g) + 1/2I2(g) <-> HI(g)
a) 397
b) 0.035
c) 28
d) 1588
e) 0.0013
13,14) What is the pH of a 0.025M aqueous solution of acetic acid?

Ka(acetic acid)=1.75x10-5
a) 3.18
b) 6.53x10-4
c) 10.82
d) 4.76
e) 9.24
15) The expression for Keq for the reaction below is_______.
4CuO(s) + CH4(g) <-> CO2(g) + 4Cu(s) + 2H2O(g)
( pCH 4)
a)
( p¿¿ CO 2)¿ ¿ ¿
( p CO2 ) ( p H 2 O)2 [ Cu]
b)
( p¿¿ CH 4)¿ ¿ ¿
( p CO2 ) ( p H 2 O)2
c)
( p¿¿ CH 4 )¿
( p CO2 ) ( p H 2 O)2
d)
( p ¿¿ CuO)¿
( p CH 4 )
e)
( p¿¿ H 2O)¿ ¿ ¿
16,17) At 400 K, the equilibrium constant for the reaction

Br2 (g) + Cl2 (g) 2BrCl (g)
is Kp = 7.0. A closed vessel at 400 K is charged with 1.00 atm of Br2 (g), 1.00 atm of
Cl2 (g), and 2.00 atm of BrCl (g). Use Q to determine which of the statements below is
true.
a) The equilibrium partial pressures of Br2, Cl2, and BrCl will be the same as the
initial values.
b) The equilibrium partial pressure of Br2 will be greater than 1.00 atm.
c) At equilibrium, the total pressure in the vessel will be less than the initial total
pressure.
d) The equilibrium partial pressure of BrCl (g) will be greater than 2.00 atm.
e) The reaction will go to completion since there are equal amounts of Br2 and Cl2.
18) Which of the following statements is true?
a) Q does not change with temperature.

b) Keq does not change with temperature, whereas Q is temperature dependent.
c) K does not depend on the concentrations or partial pressures of reaction
components.
d) Q does not depend on the concentrations or partial pressures of reaction
components.
e) Q is the same as Keq when a reaction is at equilibrium.
19) At equilibrium___________
a) all chemical reactions have ceased

b) the rates of forward and reverse reactions are equal
c) the rate constants of the forward and reverse reactions are zero
d) the value of the equilibrium constant is zero
e) the limiting reagent has been consumed
20,21) The equilibrium constant Keq is 0.0198 for the reaction:
2HI(g) <-> H2(g) + I2(g)
In a particular experiment, the partial pressures of H2 and I2 at equilibrium are 0.710atm

and 0.888atm, respectively. The partial pressure for HI is ____________atm.
a) 7.87
b) 1.98
c) 5.64
d) 0.125
e) 0.389
22) The equilibrium constant for reaction 1) is K. The equilibrium constant for
reaction 2) is____
1) SO2(g) + 1/2O2(g) <-> SO3(g)

2) 2SO3(g) <-> 2SO2(g) + O2(g)
a) K2
b) 2K
c) 1/2K
d) 1/K2
e) -K2
23,24) Calculate the pH of a 0.50M aqueous solution of NH3. The Kb of NH3 is 1.8x10-5.
a) 8.95
b) 11.48
c) 2.52
d) 5.05
e) 3.01
25) Of the following equilibria, only ________ will shift to the left in response to a
decrease in volume.
a) H2 (g) + Cl2 (g) 2 HCl (g)

b) 2 SO3 (g) 2 SO2 (g) + O2 (g)
c) N2 (g) + 3H2 (g) 2 NH3 (g)
d) 4 Fe (s) + 3 O2 (g) 2 Fe2O3 (s)
e) 2HI (g) H2 (g) + I2 (g)
26) Of the following, ________ will lower the activation energy for a reaction.
a) increasing the concentrations of reactants

b) raising the temperature of the reaction
c) adding a catalyst for the reaction
d) removing products as the reaction proceeds
e) increasing the pressure
27) Ozone O3 is formed in the atmosphere in the following way:
Cl + O → ClO (slow)
ClO + O2 → Cl + O3 (fast)
The intermediate reactant in the reaction is ________.
a) Cl
b) O
c) O3
d) ClO
e) There is no intermediate reactant.
END OF EXAM II
http://ap.kmacgill.com/wp-content/uploads/2013/01/ch_13_equilib_quiz_a.pdf
http://ap.kmacgill.com/wp-
content/uploads/2014/04/ch_16_practice_test_entropy_free_energy.pdf
https://www.unf.edu/~michael.lufaso/chem2046/practice_exam_answers.pdf

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Exam II A - CHEM 102/014 - Solutions

Loyola University Chicago

[X] means concentration of X in mol/L or M; pressures are measured in atmospheres.

Equilibrium constants are given where required.

NA = 6.0221 * 1023/mol Avogadro's Number

2CO2 (g) 2CO (g) + O2 (g) ΔH° = -514 kJ

Le Châtelier's principle predicts that an increase in temperature will ________.

a) increase the partial pressure of O2 (g)

3) What is the conjugated acid of NH3?

4) The reaction below is exothermic:

2NH3(g) <-> N2(g) + 3H2(g)

a) a decrease in the concentration of NH3(g)

5) The molar concentration of hydronium ion [H3O+] in pure water is______?

8) Which solution below has the highest concentration of hydroxide ions?

2HI(g) <-> H2(g) + I2(g)

11) What is the pH of a 0.015M aqueous solution of Sr(OH)2?

12) The value of Keq for the equilibrium

H2(g) +I2(g) <-> 2HI(g)

1/2H2(g) + 1/2I2(g) <-> HI(g)

13,14) What is the pH of a 0.025M aqueous solution of acetic acid?

4CuO(s) + CH4(g) <-> CO2(g) + 4Cu(s) + 2H2O(g)

16,17) At 400 K, the equilibrium constant for the reaction

18) Which of the following statements is true?

a) Q does not change with temperature.

a) all chemical reactions have ceased

20,21) The equilibrium constant Keq is 0.0198 for the reaction:

2HI(g) <-> H2(g) + I2(g)

In a particular experiment, the partial pressures of H2 and I2 at equilibrium are 0.710atm

1) SO2(g) + 1/2O2(g) <-> SO3(g)

a) H2 (g) + Cl2 (g) 2 HCl (g)

a) increasing the concentrations of reactants

The intermediate reactant in the reaction is ________.

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