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    Characteristic IR Band Positions: ALS Home Page Quick Guide For Users Beamlines Table BL 1.4

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    Prasanna Kumar
    This document lists common characteristic infrared band positions for different molecular groups. It provides the frequency ranges in wavenumbers (cm-1) that correspond to stretching and bending vibrations of common bonds and functional groups including OH, NH, CH, SH, C=N, C=C, C=O, C-C and C-O bonds. The table acts as a quick reference guide for identifying molecular structures using infrared spectroscopy.

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    Characteristic IR Band Positions: ALS Home Page Quick Guide For Users Beamlines Table BL 1.4

    Uploaded by

    Prasanna Kumar
    44 views2 pages
    This document lists common characteristic infrared band positions for different molecular groups. It provides the frequency ranges in wavenumbers (cm-1) that correspond to stretching and bending vibrations of common bonds and functional groups including OH, NH, CH, SH, C=N, C=C, C=O, C-C and C-O bonds. The table acts as a quick reference guide for identifying molecular structures using infrared spectroscopy.

    Original Description:

    iR spectrum and characteristics

    Original Title

    Characteristic bands

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    This document lists common characteristic infrared band positions for different molecular groups. It provides the frequency ranges in wavenumbers (cm-1) that correspond to stretching and bending vibrations of common bonds and functional groups including OH, NH, CH, SH, C=N, C=C, C=O, C-C and C-O bonds. The table acts as a quick reference guide for identifying molecular structures using infrared spectroscopy.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    44 views2 pages

    Characteristic IR Band Positions: ALS Home Page Quick Guide For Users Beamlines Table BL 1.4

    Uploaded by

    Prasanna Kumar
    This document lists common characteristic infrared band positions for different molecular groups. It provides the frequency ranges in wavenumbers (cm-1) that correspond to stretching and bending vibrations of common bonds and functional groups including OH, NH, CH, SH, C=N, C=C, C=O, C-C and C-O bonds. The table acts as a quick reference guide for identifying molecular structures using infrared spectroscopy.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    ALS Home Page | Quick

    Guide for Users |


    Beamlines
    Table | BL 1.4

    Characteristic IR Band Positions


     Group Frequency Range (cm-1)
    OH stretching vibrations
      Free OH 3610-3645 (sharp)
      Intramolecular H bonds 3450-3600 (sharp)
      Intermolecular H Bonds 3200-3550 (broad)
      Chelate Compounds 2500-3200 (very broad)
    NH Stretching vibrations
      Free NH 3300-3500
      H bonded NH 3070-3350
    CH Stretching vibrations
      =-C-H 3280-3340
      =C-H 3000-3100
      C-CH3 2862-2882, 2652-2972
      O-CH3 2815-2832
      N-CH3 (aromatic) 2810-2820
      N-CH3 (aliphatic) 2780-2805
      CH2 2843-2863,2916-2936
      CH 2880-2900
    SH Stretching Vibrations
      Free SH 2550-2600
    C=-N Stretching Vibrations
      Nonconjugated 2240-2260
      Conjugated 2215-2240
    C=-C Stretching Vibrations
      C=-CH (terminal) 2100-2140
      C-C=-C-C 2190-2260
      C-C=-C-C=-CH 2040-2200
    C=O Stretching Vibrations
      Nonconjugated 1700-1900
      Conjugated 1590-1750
      Amides ~1650
    C=C Sretching Vibrations
      Nonconjugated 1620-1680
      Conjugated 1585-1625
    CH Bending Vibrations
      CH2 1405-1465
      CH3 1355-1395, 1430-1470
    C-O-C Vibrations in Esters
      Formates ~1175
      Acetates ~1240, 1010-1040
      Benzoates ~1275
    C-OH Stretching Vibrations
      Secondary Cyclic Alcohols 990-1060
    CH out-of-plane bending vibrations

       in substituted ethylenic systems


      -CH=CH2 905-915, 985-995
      -CH=CH-(cis) 650-750
      -CH=CH-(trans) 960-970
      C=CH2 885-895

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    ALS Home Page | Quick


    Guide for Users |
    Beamlines
    Table | BL 1.4

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