Safety Data Sheet As Per Commission Regulation (EU) 2015/830 Product: Aminoethylethanolamine (AEEA)

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Safety data sheet as per Commission Regulation (EU) 2015/830

Product: Aminoethylethanolamine (AEEA)

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Trade name Aminoethylethanolamine (AEEA)
Chemical Name 2-(2-aminoethylamino)ethanol
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses As a chelating agent and surfactant
Uses identified against Not for use other than those specified
1.3 Details of the supplier of the safety data sheet:
Manufacturer Prasol Chemicals Pvt. Ltd.,
Prasol House, Plot No.A-17/2/3,
T.T.C. Indl. Area, Khairne M.I.D.C.,
Navi Mumbai - 400 710.
Maharashtra, India.
Telephone +91-22-27782555/ 61952500
Telefax +91-22-61952577
e-mail address sales@prasolc hem.com; [email protected]
1.4 Emergency telephone number
Telephone +91-22- 27782555/ 61952500
Language English

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Skin Corrosion Category 1B H314 Causes severe skin burns and eye damage
Skin Sensitizer Category 1 H317 May cause an allergic skin reaction
Eye Damage Category 1 H318 Causes serious eye damage
Reproduction toxicity Category 1B H360 May damage fertility or the unborn child
Information concerning particular hazards for human and environment: No further information
2.2 Label elements
Labeling according to Regulation (EC) No 1272/2008 (CLP)
Hazard
pictograms

GHS05 GHS07 GHS08


Signal word Danger
Hazard state me nts H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H360 May damage fertility or the unborn child
Precautionary statements
General P103 Read label before use.
Prevention P203 Obtain, read and follow all safety instructions before use.
P260 Do not breathe dusts or mists.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of workplace.
P280 Use protective gloves and eye protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately
rinse with water for several minutes.
Response P302+P352 IF ON SKIN: Wash with plenty of water
P304 + P340 IF INHALED: remove person to fresh air and keep comfortable for breathing
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P318 IF exposed or concerned: Get medical advice.
P316 Get emergency help immediately.
P321 Specific treatment- wash with plenty of water and mild soap.
P333+P317 If skin irritation or rash occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
Revision: 21-03 Replaces Version: 20-02 Page 1 of 6
Issue Date: 01.07.2021
Safety data sheet as per Commission Regulation (EU) 2015/830
Product: Aminoethylethanolamine (AEEA)

P363 Wash contaminated clothing before reuse.


Storage P405 Store locked up.
Disposal P501 Dispose of contents/container to in accordance with national regulations.
2.3 Other hazards
Not a PBT, vPVB substance according to the criteria of REACH regulation

SECTION 3: Composition/information on ingredients


3.1 Substances
Name Aminoethylethanolamine (AEEA)
CAS Number 111-41-1
EC Number 203-867-5
Molecular Formula C4H12N2O
Molecular Weight 104.15
Ingredient Classification Concentration (%)
Skin Corr. 1B, Skin Sens. 1, Eye Dam. 1,
Aminoethylethanolamine
Repro. Tox. 1B, 99.5 min
(AEEA)
H314, H317, H318, H360
3.2 Mixtures not applicable

SECTION 4: First aid measures


4.1 Description of first aid measures
General information Take off all contaminated clothing immediately.
After inhalation If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If
unconscious, evaluate the need for artificial respiration. Get immediate medical
attention
After skin contact Wash off with plenty of water immediately, seek medical advice if necessary.
After eye contact Rinse with plenty of water immediately and seek medical advice. Small
amounts splashed into eyes can cause irreversible tissue damage and blindness.
After swallowing Do not induce vomiting and seek medical advice immediately.
4.2 Most important symptoms Causes eye, skin, and respiratory tract irritation
and effects, both acute and Central nervous system depression, headache, dizziness, fatigue, muscular
delayed weakness, drowsiness and in extreme cases, loss of consciousness. Blood
disorders, Dermatitis, Blurred vision.
4.3 Indication of any immediate Treat symptomatically
medical attention and special
treatment needed

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media CO2, dry powder, foam or water spray
Unsuitable extinguishing media water jet
5.2 Special hazards arising from Heating/fire can release toxic gas (Nitrogen oxides (NOx), Carbon
the substance or mixture monoxide)
5.3 Advice for firefighters Do not expose to high temperature.
Use fine water spray to cool endangered containers.
Move undamaged containers from immediate hazard area.
Do not allow fire water to penetrate into surface or ground water.

SECTION 6: Accidental release measures


6.1 Personal precautions, Remove persons not involved upwind.
protective equipment and Wear a self-contained breathing apparatus and chemical protective clothing.
emergency procedures Solvent-resistant protective clothing recommended.
6.2 Environmental precautions Plug leak if safely possible.
Do not allow to enter drains, surface waters, basements or pits.
6.3 Methods and material for In case of spills of large quantities: Dam spills and pump to remove. Absorb
containment and cleaning up leftover product with non-flammable liquid-binding material (e.g. earth,
sand, vermiculite or ground sand stone) and place in closed containers for
disposal.
Revision: 21-03 Replaces Version: 20-02 Page 2 of 6
Issue Date: 01.07.2021
Safety data sheet as per Commission Regulation (EU) 2015/830
Product: Aminoethylethanolamine (AEEA)

6.4 Reference to other sections Section 8 for information on personal protection equipment.
Section 13 for disposal information

SECTION 7: Handling and storage


7.1 Precautions for safe Provide adequate ventilation, and local exhaust as needed. Provide room air
handling exhaust at ground level. Concentrated vapours are heavier than air. Avoid the
formation of aerosol. Do not breathe vapours. Use only explosion-protected
equipment/instruments.
7.2 Conditions for safe storage, including any incompatibilities
Advice on protection against Keep away from sources of ignition. - No smoking. Take precautionary
fire and explosion measures against static discharge. Beware of re-ignition.
Storage Keep container dry. Keep container tightly closed in a cool, well-ventilated
place. Protect from direct sunlight.
Advice on common storage Observe prohibition against storing together!
Storage class -
Storage stability Stable under recommended storage conditions
7.3 Specific end use(s) As given in Section 1

SECTION 8: Exposure controls/personal protection


8.1 Control parameters no exposure limits have been determined
8.2 Exposure controls
Appropriate engineering Provide good ventilation and/or an exhaust system in the work area.
controls
Personal protective equipment
Eye/ face protection closed goggles, face shield
Skin protection
Hand protection Butyl-rubber 0.5 mm > 480 min
Body protection Use solvent-resistant protective clothing.
Flame-retardant antistatic protective clothing; safety shoes
Respiratory protection Respiratory equipment with suitable filter or a self-contained respiratory apparatus.
Thermal hazards Do not expose to extreme heat
Industrial hygiene Do not inhale vapours / aerosols. Avoid contact with skin and eyes. Remove
immediately all contaminated clothing. Use disposable clothing if appropriate.
Smoking, eating and drinking should be prohibited in the application area.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Appearance Colourless to pale yellow liquid
Odour amine like
Odour threshold no data available
pH 12 of 25% solution in water
Melting point -38°C (pour point)
Boiling point 243°C
Flash point 132°C (closed cup)
Evaporation rate no data available
Flammability (solid, gas) not applicable
Flammability limits not applicable
Vapour pressure 0.012 hPa at 20°C
Vapour density 3.6 (air =1)
Relative density 1.02 at 25°C
Solubility in water miscible (>1000g/L)
Partition coefficient -1.46 (pH 10.6-11.0)
Ignition temperature 368°C
Decomposition temperature no data available
Viscosity at 20 °C 41mPas
Explosive properties no explosive properties (structural reasons)
Oxidizing properties no oxidizing properties (structural reasons)
9.2 Other information no further relevant information available
Revision: 21-03 Replaces Version: 20-02 Page 3 of 6
Issue Date: 01.07.2021
Safety data sheet as per Commission Regulation (EU) 2015/830
Product: Aminoethylethanolamine (AEEA)

SECTION 10: Stability and reactivity


10.1 Reactivity No dangerous reactions if stored and handled as indicated.
Forms no flammable gases in contact with water.
10.2 Chemical stability Under storage at normal ambient temperatures (-40°C to +40°C), the
product is stable.
10.3 Possibility of hazardous reactions This substance is not self-reactive or oxidizable. Heat may be generated
when mixed with acids and oxidizing compound.
10.4 Conditions to avoid Heat, flames and sparks.
10.5 Incompatible materials Acids and oxidizing compounds.
10.6 Hazardous decomposition Burning can produce carbon monoxide, nitrogen oxides
products

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Acute toxicity
LD50 oral rat 2150mg/kg bw
LC0 inhalation rat 51.3mg/m3
LD50 dermal mouse >2000mg/kg bw
Skin irritation causes burns Skin Corr. 1B, H314
Serious eye irritation risk of severe eye irritation Eye Dam. 1, H318
Respiratory or skin sensitization sensitizer Skin Sens, 1, H317
Germ cell mutagenicity weakly mutagenic
Carcinogenicity no indications for a carcinogenic potential
Reproductive toxicity May cause harm to the unborn child, May cause harm to breast-fed children
Repro. Tox. 1B, H360
STOT-single exposure Inhalation - May cause respiratory irritation. - Lungs
STOT-repeated exposure NOAEL 1000 mg/kg bw/ day (dermal)
Aspiration hazard no data available

SECTION 12: Ecological information


12.1 Toxicity
Aquatic toxicity
Toxicity to fish LC50 96h 640mg/L Pimephales promelas
Toxicity to aquatic invertebrates EC50 48h 22mg/L Daphnia magna
Toxicity to aquatic algae and cyanobacteria ERC50 72h 358mg/L Desmodesmus subspicatus
Toxicity to microorganisms EC50 30 min >1003mg activated sludge
12.2 Persistence and degradability
Biodegradation readily biodegradable (52% in 10days)
12.3 Bioaccumulative potential BCF 2.1 to <3.7; low potential for bioaccumulation
12.4 Mobility in soil The product is miscible in water and readily biodegradable in both
water and soil. Accumulation is not expected. Groundwater
contamination is unlikely
12.5 Results of PBT and vPvB assessment Not a PBT, vPvB substance according to the REACH regulation
12.6 Other adverse effects No further information available

SECTION 13: Disposal considerations


13.1 Waste treatment Observe all federal, state, and local environmental re gulations.
met hods Contact a licensed professional waste d isposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical
incinerator equipped with an afterburner and scrubber.
Do not dispose in sewage.

SECTION 14: Transport information


ADR/RID IMDG ICAO/IATA
14.1 UN Number 2735 2735 2735
14.2 UN proper shipping name Amines, liquid, corrosive, n.o.s.(Aminoethylethanolamine)
14.3 Transport hazard class 8 8 8
14.4 Packaging group II II II
Revision: 21-03 Replaces Version: 20-02 Page 4 of 6
Issue Date: 01.07.2021
Safety data sheet as per Commission Regulation (EU) 2015/830
Product: Aminoethylethanolamine (AEEA)

14.5 Environmental hazards not a marine pollutant


14.6 Special precautions for the user corrosive and irritant; Danger
EMS Number F-A, S-B
14.7 Transport in bulk according to See regulatory information for transport approval
Annex II of MARPOL73/78 and
the IBC Code

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Major accident hazard Seveso III no
International Chemical Inventory Status
USA (TSCA) Listed (Tracking No 27508)
Canada (DSL) listed
Australia (AICS) listed
Japan (MITI) Listed (MITI No 2-304)
Korea (KECL) Listed (KE-01366)
Philippines (PICCS) listed
China (IECSC) listed
New Zealand (NZloC) listed
Taiwan (TCSI) listed
15.2 Chemical safety A Chemical Safety Assessment will be carried out at the time of
assessment REACH registration

SECTION 16: Other information


This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Further information:
Sections in which changes have been made since the last version are marked with a diamond in the left hand
margin.
Abbreviations and acrony ms in English language:
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
AICS Australian Inventory of Chemical Substances
CAS Chemical Abstracts Service (division of the American Chemical Society)
CLP Classification for Labeling and Packaging
DSL Domestic Substances List
EC European Commission
EC50 Half maximal effective concentration
EINECS European Inventory of Existing Commercial Chemical Substances
GHS Globally Harmonized System of Classification and Labeling of Chemicals
IATA International Air Transport Association
IBC International Bulk Chemical
ICAO International Civil Aviation Organization
IMDG International Maritime Code for Dangerous Goods
KECL Korea Existing Chemicals List
KOC Soil adsorption coefficient
KOW Partition Coefficient octanol-water
LC50 Lethal concentration, 50 percent
LD50 Lethal dose, 50 percent
MARPOL International Convention for the Prevention of Pollution from Ships
MITI Ministry of International Trade and Industry
NOAEC No Observed Adverse Effect Concentration
NOAEL No Observed Adverse Effect Level
PBT Persistent, bioaccumulative and toxic substances
PICCS Philippine Inventory of Chemicals and Chemical Substances
RID Regulations Concerning the International Transport of Dangerous Goods by Rail
STOT Specific target organ toxicity
TSCA Toxic Substances Control Act
UN United Nations
vPVB (very) Persistent, (very) Bioaccumulative
Source s
Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the
European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH)
ECHA https://echa.europa.eu/registration-dossier/-/registered-dossier/31740

Revision: 21-03 Replaces Version: 20-02 Page 5 of 6


Issue Date: 01.07.2021
Safety data sheet as per Commission Regulation (EU) 2015/830
Product: Aminoethylethanolamine (AEEA)

Information herein is given in good faith. Prasol Chemicals Pvt. Ltd. makes no representations or warranties as to the
completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving the same will
make their own determination as to its suitability for their purpose prior to use. Prasol Chemicals Pvt. Ltd. shall not be
responsible for damages of any nature whatsoever resulting from the use or reliance upon this information. The data
provided are based on samples tested and are not guaranteed for all samples or applications. Such data are intended as
guides only. No representations or warranties for a particular purpose or any other nature are made with respect to this
information or the product.

----End of document---

Revision: 21-03 Replaces Version: 20-02 Page 6 of 6


Issue Date: 01.07.2021

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