Collision Theory: Effective Collision Occurs When

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Form 5 Chemistry

Collision Theory
- Collision theory is a theory used to explain chemical reaction in terms of collisions between particles,
effective collisions and activation energy.
- A chemical reaction occurs when the reactant particles collide with each other.
- Not all the collisions results in the formation of products.

Effective collision occurs when:


A. total energy greater than or equal to the activation energy. (Ea )
B. correct orientation

Activation energy:
- Minimum amount of energy required initiating a chemical reaction.
- Difference energy between the reactants and peak of the curve.

C h a p t e r 1 - R a t e o f R e a c ti o n
Exothermic reaction Endothermic reaction

Ea
Energy

Energy

Ea
Products
Reactants

Reactants

Products

Progress of reaction Progress of reaction

Relationship of the frequency of effective collision and the Activation energy with the Rate of Reaction

Frequency of effective collision Magnitude of activation collision

High Low High Low

High rate of reaction Low rate of reaction Low rate of reaction High rate of reaction
Form 5 Chemistry
Collision theory and factors affecting the rate of reaction

Effect of Surface area Temperature Concentration/ Pressure


Figure

Bigger-sized solid reactant Lower temperature Lower concentration

C h a p t e r 1 - R a t e o f R e a c ti o n

Lower-sized solid reactant Higher temperature Higher concentration

Particles Bigger-sized solid reactant Higher temperature Higher concentration


- small total surface area - move faster/ more energetic - more number of particles

Lower-sized solid reactant Lower temperature Lower concentration


- large total surface area - move slower/ less energetic - less number of particles
Collision Bigger-sized solid reactant Higher temperature Higher concentration
- less collision - better chance of colliding - more collision

Lower-sized solid reactant Lower temperature Lower concentration


- more collision - bad chance of colliding - less collision
Frequency of effective Bigger-sized solid reactant Higher temperature Higher concentration
collision - Lower - Higher - Higher

Lower-sized solid reactant Lower temperature Lower concentration


- Higher - Lower - Lower
Rate of reaction Bigger-sized solid reactant Higher temperature Higher concentration
- Lower - Higher - Higher

Lower-sized solid reactant Lower temperature Lower concentration


- Higher - Lower - Lower
Form 5 Chemistry
Effect of catalyst

When a positive catalyst is used,


 catalyst provides an alternative route which lower activation energy
 more particles will have enough energy to heat
 frequency of effective collision increases
 Rate of reaction increase

Energy

C h a p t e r 1 - R a t e o f R e a c ti o n
Ea

Ec
Reactants

Products

Reaction path
Ea= Activation without a catalyst
Ec= Activation energy with a catalyst

- Catalyst provide an alternative path for a reaction

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