JEE Main 2019 - 10 April - Evening Shift MathonGo

PART –A (PHYSICS)
1. One mole of an ideal gas passes through a process where pressure and volume obey
 1  V 2 
the relation P  Po 1   o   . Here Po and Vo are constants. Calculate the change in
 2  V  
the temperature of the gas if its volume change from Vo to 2Vo
1 Po Vo 1 Po Vo
(A) (B)
4 R 2 R
5 Po Vo 3 Po Vo
(C) (D)
4 R 4 R

2. A solid sphere of mass M and radius R is divided into two unequal parts. The first part
7M
has a mass of and is converted into a uniform disc of radius 2R. The second part is
8
converted into a uniform solid sphere. Let I1 be the moment of inertia of the disc about its
axis and I2 be the moment of inertia of the new sphere about its axis. The ratio of I1/I2 is
given by:
(A) 285 (B) 185
(C) 65 (D) 140

3. The correct figure that shows, schematically, the wave pattern produced by
superposition of two waves of frequencies 9 Hz and 11 Hz,

(A) (B)

(C) (D)

4. In an experiment, brass and steel wires of length 1 m each with areas of cross section
1 mm2 are used. The wires are connected in series and one end of the combined wire is
connected to a rigid support and other end is subjected to elongation. The stress
requires to produced a new elongation of 0.2 mm is
[Given, the Young’s Modulus for steel and brass are respectively 120  109 N/m2 and 60
 109 N/m2]
(A) 1.8  106 N/m2 (B) 0.2  106 N/m2
6 2
(C) 1.2  10 N/m (D) 4.0  106 N/m2

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5. When heat Q is supplied to a diatomic gas of rigid molecules at constant volume its
temperature increases by T. The heat required to produce the same change in
temperature, at constant pressure is
3 5
(A) Q (B) Q
2 3
7 2
(C) Q (D) Q
5 3

6. A bullet of mass 20 g has an initial speed of 1 ms–1 just before it starts penetrating a mud
wall of thickness 20 cm. If the wall offers a mean resistances of 2.5  10–2 N, the speed
of the bullet after emerging from the other side of the wall is close to
(A) 0.7 ms–1 (B) 0.3 ms–1
–1
(C) 0.1 ms (D) 0.4 ms–1

7. The elastic limit of brass is 379 MPa. What should be the minimum diameter of a brass
rod if it is to support a 400 N load without exceeding its elastic limit?
(A) 1.00 mm (B) 1.16 mm
(C) 0.90 mm (D) 1.36 mm

8. A plane is inclined at an angle  = 30o with respect to the horizontal. A particle is

projected with a speed u = 2 ms–1, from the base of the plant, making an angle  = 15o
with respect to the plane as shown in the figure. The distance from the base at which the
particle hits the plane is close to
(Take g = 10 ms2)

(A) 18 cm (B) 14 cm
(C) 26 cm (D) 20 cm

9. The magnitude of the magnetic field at the centre of an equilateral triangular loop of side
1 m which is carrying a current of 10 A is: [Take o = 4  10–7 NA–2]
(A) 9T (B) 1T
(C) 3T (D) 18T

10. Two radioactive substances A and B have decay constants 5 and  respectively. At t =
0, a sample has the same number of the two nuclei. The time taken for the ratio of the
2
 1
number of nuclei to become   will be
e
(A) 1/ (B) 1/4
(C) 2/ (D) 1/2

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11. Two blocks A and B of masses mA = 1 kg and mB = 3 kg are kept on the table as shown
in figure. The coefficient of friction between A and B is 0.2 and between B and the
surface of the table is also 0.2. The maximum force F that can be applied on B
horizontal, so that the block A does not slide over the block B is:
[Take g = 10 m/s2]

(A) 8 N (B) 16 N
(C) 12 N (D) 40 N

12. The formula X = 5YZ2 X and Z have dimensions of capacitance and magnetic field
respectively. What are the dimensions of Y in SI units?
(A) [M-2 L0 T–4 A–2] (B) [M-3 L-2 T8 A–1]
-2 -2 6 3
(C) [M L T A ] (D) [M-1 L-2 T4 A2]

13. In Li++, electron in first Bohr orbit is excited to a level by a radiation of wavelength .
When the ion gets deexcited to the ground state in all possible ways(including
intermediate emission) a total of six spectral lines are observed. What is the value of ?
(Given: h = 6.63  1034 js; e = 3  108 ms–1)
(A) 10.8 nm (B) 11.4 nm
(C) 9.4 nm (D) 12.3 nm
14. The graph shows how the magnification m produced by a thin lens varies with image
distance . What is the focal length of the lens used?

b2 a
(A) (B)
ac c
b 2c b
(C) (D)
a c
15. A spaceship orbits around a planet at a height of 20 km from its surface. Assuming that
only gravitational field of the plant acts on the spaceship. What will be the number of
complete revolutions made by the spaceship in 24 hours around the plane?
[Given: Mass of plane = 8  1022 kg, Radius of planet = 2  106 m, Gravitational constant
G = 6.67  10–11 Mn2/kg2]
(A) 9 (B) 11
(C) 13 (D) 17

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16. Light is incident normally on a completely absorbing surface with an energy flux of
25 W cm–2. If the surface has an area of 25 cm2, the maximum transferred to the surface
in 40 min time duration will be
(A) 6.3  10–4 Ns (B) 3.5  10–6 Ns
–3
(C) 5.0  10 Ns (D) 1.4  10–6 Ns

17. The time dependence of the position of a particle of mass m = 2 is given by


r  t   2t ˆi  3t 2 ˆj Its angular momentum with respect to the origin at time t = 2 is .
(A) -48 k̂ (B) 48( î + ĵ )
(C) 36 k̂ (D) -34( k̂ - î )

18. Water from a tap emerges vertically downwards with an initial speed of 1.0 ms–1. The
cross-sectional area of the tap is 10–4m2. Assume that the pressure is constant
throughout the stream of water and that flow is streamlined. The cross-sectional area of
the stream, 0.15 m below the tap would be:
(take g = 110 ms–2)
(A) 5  10–4 m2 (B) 5  10–5 m2
–5 2
(C) 1  10 m (D) 2  10–5 m2

19. Space between two concentric conducting spheres of radii a and b (b >a) is filled with a
medium of resistivity . The resistance between the two spheres will be
  1 1   1 1
(A)    (B)   
2  a b  2  a b 
  1 1   1 1
(C)    (D)   
4  a b  4  a b 

20. A metal coin of mass 5 g and radius 1 cm is fixed to a thin stick AB of negligible mass as
shown in the figure. The system is initially at rest. The constant torque, that will make the
system rotate about AB at 25 rotations per second is 5 s is close to

(A) 2.0  10–5 Nm (B) 4.0  10–6 Nm

(C) 1.6  10–5 Nm (D) 7.9  10–6 Nm

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21. The figure represents a voltage regulator circuit using a Zener diode. The breakdown
voltage of the Zener diode is 6 V and the load resistance is RL= 4k. The series
resistance of the circuit is Ri = 1k. If the battery voltage V8 varies from 8 V to 16 V,
what are the minimum and maximum values of the current through Zener diode?

(A) 0.5 mA; 0.6 mA (B) 1 mA; 8.5 mA

(C) 1.5 mA; 8.5 mA (D) 0.5 mA; 8.5 mA

22. A simple pendulum of length L is placed

between the plates of a parallel plate capacitor
having electric field E, as shown in figure. Its
bob has mass m and charge q. the time period
of the pendulum is given by

L L
(A) 2 (B) 2
 qE 
2  qE 
g2    g  
 m
m
L L
(C) 2 (D) 2
 qE  q2E 2
g   g2 
 m  m2

23. In free space, a particle A of charge 1 C is held fixed at a point P. Another particle B of
the same charge and mass 4 g is kept at a distance of 1 mm from P. If B is released,
then its velocity at a distance of 9 mm from P is
 1 
 Take  9  109 Nm2C2 
 4o 
(A) 1.5  102 m/s (B) 2.0  103 m/s
(C) 1.0 m/s (D) 3.0  104 m/s

24. A 2 mW laser operates at a wavelength of 500 nm. The number of photons that will be
emitted per second is
[Given Planck’s constant h = 6.6  10–34 Js, speed of light c = 3.0  108 m/s]
(A) 1  1016 (B) 1.5  1016
16
(C) 2  10 (D) 5  1015

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25. A coil of self inductance 10 mH and resistance 0.1  is connected through a switch to a
battery of internal resistance 0.9 . After the switch is closed the time taken for the
current to attain 80% of the saturation values is: [take ln 5 = 1.6]
(A) 0.016 s (B) 0.324 s
(C) 0.002 s (D) 0.103 s

26. A submarine experiences a pressure of 5.05  106 Pa at a depth of d1 in a sea. When it

goes further to a depth of d2, it experiences a pressure of 8.08  106 Pa. Then d2 – d1 is
approximately (density of water = 103 kg/m3 and acceleration due to gravity = 10 ms–2)
(A) 400 m (B) 500 m
(C) 600 m (D) 300 m

27. A cubical block of side 0.5 m floats on water with 30% of its volume under water. What is
the maximum weight that can be put on the block without fully submerging it under
water?
[Take density of water = 103 kg/m3]
(A) 46.3 kg (B) 65.4 kg
(C) 30.1 kg (D) 87.5 kg

28. In a Young’s double slit experiment the ratio of the slit’s width is 4 : 1. The ratio of the
intensity of maxima to minima, close to central fringe on the screen will be
4
(A)  
3  1 : 16 (B) 25 : 9
(C) 9 : 1 (D) 4:1

29. A source of sound S is moving with the velocity of 50 m/s towards a stationary observer.
The observer measures the frequency of the sound as 1000 Hz. What will be the
apparent frequency of the source when it is moving away from the observer after
crossing him?
(Take velocity of sound in air is 350 m/s)
(A) 1143 Hz (B) 857 Hz
(C) 750 Hz (D) 807 Hz

30. A square loop is carrying a steady current I and the magnitude of its magnetic dipole
moment is m. If this square loop is changed to a circular loop and it carries the same
current, the magnitude of the magnetic dipole moment of circular loop will be
m 3m
(A) (B)
 
4m 2m
(C) (D)
 

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PART –B (CHEMISTRY)
31. The difference between H and U (H - U), when the combustion of one mole of
heptane(I) is carried out a temperature T is equal to
(A) -4 RT (B) -3 RT
(C) 3 RT (D) 4 RT

32. The major product obtained in the given reaction is

(A) (B)

(C) (D)

33. The ratio of the shortest wavelength of two spectral series of hydrogen spectrum is
found to be about 9. The spectral series are:
(A) Lyman and Paschen (B) Brackett and Pfund
(C) Paschen and Pfund (D) Balmer and Brackett

34. The correct order of the first ionization enthalpies is

(A) Mn < Ti < Zn < Ni (B) Zn < Ni < Mn < Ti
(C) Ti < Mn < Zn < Ni (D) Ti < Mn < Ni < Zn

35. The correct statements among (a) to (b) are:

(a) saline hydrides produce H2 gas when reacted with H2O.
(b) reaction of LiAH4 with BF3 leads to B2H6.
(c) PH3 and CH4 are electron - rich and electron-precise hydrides, respectively.
(d) HF and CH4 are called as molecular hydrides.
(A) (c) and (d) only (B) (a), (b) and (c) only
(C) (a), (b), (c) and (d) (D) (a), (c) and (d) only

36. Air pollution that occurs in sunlight is:

(A) oxidising smog (B) acid rain
(C) reducing smog (D) fog

37. For the re action of H2 w i t h I2, the rate constant is 2.5  10-4 dm3 mol–1 s–1 at 327°C and
1.0 dm3 mol–1 s–1 at 527°C. The activation energy for the reaction, in kJ mol–1 is:
(R = 8.314 J K–1 mol–1)
(A) 72 (B) 166
(C) 150 (D) 59

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38. In chromatography, which of the following statements is INCORRECT for Rf?

(A) Rf value depends on the type of chromatography.
(B) The value of Rf can not be more than one.
(C) Higher Rf value means higher adsorption.
(D) Rf value is dependent on the mobile phase.

39. A hydrated solid X on heating initially gives a monohydrated compound Y. Y upon

heating above 373K leads to an anhydrous white powder Z. X and Z,
respectively, are:
(A) Washing soda and soda ash. (B) Washing soda and dead burnt
plaster.
(C) Baking soda and dead burnt plaster. (D) Baking soda and soda ash.

40. The INCORRECT statement is:

(A) the spin-only magnetic moments of [Fe(H2O)6]2+ and [Cr(H2O)6]2+ are nearly
similar.
(B) the spin-only magnetic moment of [Ni(NH3)4(H2O)2]2+ is 2.83 BM.
(C) the gemstone, ruby, has Cr3+ ions occupying the octahedral sites of beryl.
(D) the color of [CoCl(NH3)5]2+ is violet as it absorbs the yellow light.

41. Which of these factors does not govern the stability of a conformation in acyclic
compounds?
(A) Torsional strain (B) Angle strain
(C) Steric interactions (D) Electrostatic forces of interaction

42. The correct statement is:

(A) zincite is a carbonate ore
(B) aniline is a froth stabilizer
(C) zone refining process is used for the refining of titanium
(D) sodium cyanide cannot be used in the metallurgy of silver

43. For the reaction,

2 SO2  g   O2  g   2 SO3  g 
H = –57.2 kJ mol–1 and
KC = 1.7 1016
Which of the following statement is INCORRECT?
(A) The equilibrium constant is large suggestive of reaction going to completion and so
no catalyst is required.
(B) The equilibrium will shift in forward direction as the pressure increase.
(C) The equilibrium constant decreases as the temperature increases.
(D) The addition of inert gas at constant volume will not affect the equilibrium constant.

44. The increasing order of nucleophilicity of the following nucleophiles is :

(a) CH3CO2 (b) H2O

(c) CH3SO3 (d) OH
(A) (b) < (c) < (a) < (d) (B) (a) < (d) < (c) < (b)
(C) (d) < (a) < (c) < (b) (D) (b) < (c) < (d) < (a)

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45. The correct match between Item-I and Item-II is:

(A) (a)  (III), (b)(I), (c)(II), (d)(IV)

(B) (a)(IV), (b)(II), (c)(I), (d)(III)
(C) (a)(II), (b)(IV), (c)(I), (d)(III)
(D) (a)(III), (b)(I), (c)(IV), (d)(II)

46. The major product 'Y' in the following reaction is:-

Ph CH3
NaOCl i  SOCl
  X 
 ii  Aniline  Y
2

O
(A) (B)

(C) (D)

47. Points I, II and III in the following plot respectively correspond to

(Vmp : most probable velocity)

(A) Vmp of N2 (300K); Vmp of H2(300K); V mp of O2(400K)

(B) Vmp of H2 (300K); Vmp of N2(300K); Vmp of O2(400K)
(C) Vmp of O2 (400K); Vmp of N2(300K); Vmp of H2(300K)
(D) Vmp of N2 (300K); Vmp of O2(400K); Vmp of H2(300K)

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48. The highest possible oxidation states of uranium and plutonium, respectively, are
(A) 6 and 4 (B) 7 and 6
(C) 4 and 6 (D) 6 and 7

49. Compound A (C9H10O) shows positive iodoform test. Oxidation of A with KMnO4/KOH
gives acid B(C8H6O4). Anhydride of B is used for the preparation of phenolphthalein.
Compound A is:-

50. The noble gas that does NOT occur in the atmosphere is:
(A) He (B) Ra
(C) Ne (D) Kr

51. The pH of a 0.02 M NH4Cl solution will be

[given Kb (NH4OH) = 10–5 and log 2 = 0.301]
(A) 2.65 (B) 5.35
(C) 4.35 (D) 4.65

52. The crystal field stabilization energy (CFSE) of [Fe(H 2 O) 6 ]Cl 2 and K 2 [NiCl 4 ],
respectively, are :-
(A) –0.4o and –0.8t (B) –0.4o and –1.2t
(C) –2.4o and –1.2t (D) –0.6o and –0.8t

53. The correct option among the following is:

(A) Colloidal particles in lyophobic sols can be precipitated by electrophoresis.
(B) Brownian motion in colloidal solution is faster the viscosity of the solution is very high.
(C) Colloidal medicines are more effective because they have small surface area.
(D) Addition of alum to water makes it unfit for drinking.

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54. Which one of the following graphs between molar conductivity (m) versus C is
correct?
(A) (B)

(C) (D)

55. 1 g of non-volatile non-electrolyte solute is dissolved in 100g of two different solvents

A and B whose ebullioscopic constants are in the ratio of 1 : 5. The ratio of the elevation
Tb  A 
in their boiling points, is :
Tb B 
(A) 5 : 1 (B) 10 : 1
(C) 1 : 5 (D) 1 : 0.2

56. Which of the following is NOT a correct method of the preparation of benzylamine from
cyanobenzene?
(A) (i) HCl/H2O (ii) NaBH4
(B) (i) LiAIH4 (ii) H3O+
(C) (i) SnCl2 + HCl(gas) (ii) NaBH4
(D) H2/Ni

57. The number of pentagons in C60 and trigons (triangles) in white phosphorus,
respectively, are:
(A) 12 and 3 (B) 20 and 4
(C) 12 and 4 (D) 20 and 3

58. The minimum amount of O2(g) consumed per gram of reactant is for the reaction :
(Given atomic mass : Fe = 56, O = 16, Mg = 24, P = 31, C = 12, H = 1)
(A) C3H8(g) + 5O2(g)  3 CO2(g) + 4 H2O(l)
(B) P4(s) + 5O2(g)  P4O10(s)
(C) 4Fe(s) + 3O2(g)  2 Fe2O3(s)
(D) 2 Mg(s) + O2(g)  2 MgO(s)

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59. Number of stereo centers present in linear and cyclic structures of glucose are
respectively
(A) 4 & 5 (B) 5 & 5
(C) 4 & 4 (D) 5 & 4

60. The major product 'Y' in the following reaction is:

(A) (B)

(C) (D)

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PART–C (MATHEMATICS)
x 2  ax  b
61. If lim  3 , then a + b is equal to
x 1 x 1
(A) 5 (B) 1
(C) -4 (D) -7
62. The sum of the real roots of the equation
x 6 1
2 3x x  3  0 is equal to
3 2x x2
(A) -4 (B) 0
(C) 6 (D) 1

3
63. Lines are drawn parallel to the line 4x – 3y + 2 = 0 at a distance from the origin. Then
5
which one of the following points lies on any of these lines?
 1 2  1 1
(A)   ,  (B)  , 
 4 3  4 3
 1 1  1 2
(C)  ,   (D)   ,  
 4 3   4 3

x
64. If the tangent to the curve y  2
x 3
 
, x  R, x   3 at a point (, )  (0, 0) on it is

parallel to the line 2x + 6y – 11 = 0 then

(A) |2 + 6| = 11 (B) |2 + 6| = 19
(C) |6 + 2| = 19 (D) |6 + 2| = 9

65. The distance of the point having position vector ˆi  2ˆj  6kˆ from the straight line
passing through the point (2, 3, -4) and parallel to the vector 6iˆ  3ˆj  4kˆ is
(A) 7 (B) 4 3
(C) 2 13 (D) 6

66. If the line ax + y = c, touches both the curves x2 + y2 = 1 and y 2  4 2 x , then |c| is
equal to
1
(A) (B) 2
2
1
(C) (D) 2
2

67. Let f(x) = loge(sinx), (0 < x < ) and g(x) = sin–1(e–x), (x  0). If  is a positive real number
such that a = (fog)’() and b = (fog)(), then
(A) a2 + b – a = 22 (B) a2 – b – a = 0
(C) a2 – b – a = 1 (D) a2 + b + a = 0

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68. If 5x + 9 = 0 is the directrix of the hyperbola 16x2 – 9y2 = 144, then its corresponding
focus is
5 
(A) (5, 0) (B)  ,0 
3 
 5 
(C) (-5, 0) (D)   ,0 
 3 

y y
69. If cos–1x – cos–1 2   , where -1  x  1, – 2  y  2, x  2 , then for all x, y, 4x2 – 4xy
cos  + y2 is equal to
(A) 4 sin2 - 2x2y2 (B) 4 cos2 + 2x2y2
(C) 2 sin2 (D) 4 sin2

70. The locus of the centres of the circles, which touch the circle, x2 + y2 = 1 externally, also
touch the y-axis and lie in the first quadrant is
(A) x  1  2y, y  0 (B) y  1  4x, x  0
(C) x  1  4y, y  0 (D) y  1  2x, x  0

71. Let a1, a2, a3, …… be and A.P with a6 = 2. Then the common difference of this A.P.,
which maximizes the product a1a4a5 is
3 8
(A) (B)
2 5
2 6
(C) (D)
3 5

72. The smallest natural number n, such that the coefficient of x in the expansion of
n
 2 1  n
 x  3  is C23 is
 x 
(A) 38 (B) 58
(C) 23 (D) 35

73. Suppose that 20 pillars of the same height have been erected along the boundary of a
circular stadium. If the top of each pillar has been connected by beams with the top of all
its non-adjacent pillars, then the total number of beams is
(A) 210 (B) 180
(C) 170 (D) 190

74. A spherical iron ball of radius 10 cm is coated with a layer of ice of uniform thickness that
melts at a rate of 50 cm3/min. When the thickness of the ice is 5 cm, then the rate at
which the thickness (in cm/min) of ice decreases is
1 5
(A) (B)
36 6
1 1
(C) (D)
9 18

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75. If both the means and the standard deviation of 50 observations x1, x2, ………, x50 are
equal to 16, then the mean of (x1 - 4)2, (x2 - 4)2, …., (x50 - 4)2 is
(A) 400 (B) 380
(C) 525 (D) 480
76. The number of real roots of the equation
5 + |2x - 1| = 2 x(2 x - 2) is
(A) 4 (B) 3
(C) 2 (D) 1
77. The tangent and normal to the ellipse 3x2 + 5y2 = 32 at the point P(2, 2) meet the x-axis
at Q and R, respectively. Then the area(in sq. units) of the triangle PQR is
34 68
(A) (B)
15 15
14 16
(C) (D)
3 3
x 1 y 1 z
78. A perpendicular is drawn from a point on the line   to the plane x + y + z
2 1 1
= 3 such that the foot of the perpendicular Q also lies on the plane x – y + z = 3. Then
the co-ordinates of Q are
(A) (2, 0, 1) (B) (-1, 0, 4)
(C) (1, 0, 2) (D) (4, 0, -1)
 /3
79. The integral  sec 2/3 x cos ec 4/3 x dx is equal to
/ 6
(A) 35/6 – 32/3 (B) 35/3 – 31/3
(C) 37/6 – 35/6 (D) 34/3 – 31/3
80. The angles A, B and C of a triangle ABC are in A.P and a : b = 1 : 3 . If c = 4 cm, then
the area (in sq. cm) of this triangle is
4
(A) 2 3 (B)
3
2
(C) 4 3 (D)
3
1
81. Let a, b and c be in G.P with common ratio r, where a  0 and 0 < r  . If 3a, 7b and
2
15c are the first three terms of an A.P., then the 4th term of this A.P is
2 7
(A) a (B) a
3 3
(C) 5a (D) a
82. Let y = y(x) be the solution of the differential equation
dy   
 y tan x  2x  x 2 tan x, x    ,  , such that y(0) = 1. Then
dx  2 2
        
(A) y '    y '   2 (B) y '    y '  2
4  4  4  4 
         2
(C) y    y     2 (D) y    y     2
4  4 4  4 2

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1 2
83. If the plane 2x – y + 2z + 3 = 0 has the distances and units from the planes 4x – 2y
3 3
+ 4z +  = 0 and 2x – y + 2z +  = 0, respectively, then the maximum value of +  us
equal to
(A) 15 (B) 13
(C) 5 (D) 9
84. The area(in sq. units) of the region bounded by the curves y = 2x and y = |x +1| in the
first quadrant is
3 3
(A) (B) loge 2 
2 2
3 1 1
(C)  (D)
2 loge 2 2

85. Let  be a real number for which the system of linear equations
x+y+z=6
4x + y - z =  - 2
3x + 2y – 4z = -5
Has indefinitely many solutions. Then  is a root of the quadratic equation
(A) 2 -  – 6 = 0 (B) 2 - 3 – 4 = 0
2
(C)  + 3 – 4 = 0 (D) 2 +  – 6 = 0

86. The sum

3 3 3 3 3 3 3 3 3
1 2 1 2 3 1  2  3  .....  15 1
1   ......   1  2  3  ......  15  is equal to
1 2 1 2  3 1  2  3  .....  15 2
(A) 620 (B) 1860
(C) 1240 (D) 660
87. Minimum number of times a fair coin must be tossed so that the probability of getting at
least one head is more than 99% is
(A) 8 (B) 6
(C) 7 (D) 5

88. The negation of the Boolean expression ~ s(~rs) is equivalent to

(A) sr (B) ~s ~r
(C) r (D) s  r
5  x2 2
89. If x e dx  g  x  e x  c , where c is a constant of integration, then g(-1) is equal to
(A) -1 (B) 1
5 1
(C)  (D) 
2 2

90. If z and w are two complex numbers such that |zw| = 1 and arg(z) – arg(w) = , then
2
1  i
(A) zw  i (B) zw 
2
1 i
(C) zw  (D) zw  i
2

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HINTS AND SOLUTIONS

PART A – PHYSICS
1. n = 1 mole
 1  V  2 
P = Po 1   o   ; PV = nRT = RT
 2  V  
RT
P
V
RT  V2 
 Po 1  o 2 
V  2V 
Po V
 V 2  Po  Vo2 
T 1  2
=  V  
R  2V  R  2V 2 
P  V2  1 1  
T  o (2Vo  Vo )  o   
R  2  2Vo Vo  
Po Vo2 
= V
 o  
R 2 
P  V2  1 1  
T  o (2Vo  Vo )  o   
R  2  2Vo Vo  
Po  Vo2 (1  2) 
=  Vo  
R  2  2Vo 
P  V  3 Po Vo
= o  Vo  o  =
R  4 4 R

 7M  2
  (ZR) 7M  4R 2 7MR2
8
2. I1     
2 28 4
2 2 2
2 MR 2M R MR
I2     
5 82 58 4 80
2
I1 7MR  80
  140
I2 4MR 2

3. By looking into graph.

4. =1M
A = 10–6 M2 Ys = 120 × 109
F
Stress = Ys = 120 × 109 F
A 9
YB = 60 × 10
Stress
Stress =
Y

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F
 
AY
1F  2F
 1   2    0.2  10 3
AY1 AY2
F 0.2  10 3

A  

Y1 Y2
0.2  10 3 0.2  10 3  109  120
= 
1 1 1 2
9

120  10 60  109
0.2  10 6  120
=  8  106
3

5. Q = CVT
Q = CPT
C  2 7
Q = P Q   1   Q  Q
CV  5 5

1
6. 2.5 × 10–2 × 0.2 =
2

 20  10 3  V 2  12 
5 × 10–3 = 10 × 10–3 (1 –V2)
1 1 1
1 – V2 = ; V2 = ; V= = 0.7
2 2 2

400
7.  379  106
 2
d
4
4  400  106
d2  = 0.336 × 10–6 × 4
  379
d  2 0.336  10 3 M  1.16 mm

2 u sin 
8. T
g cos 
1
R  ucos  T  g sin  T 2
2
ucos  2u sin  gsin  4u2 sin2 
= 
gcos  2 g2 cos2 
u2 sin2  u2 sin 
=  1  cos 2
g cos  g cos2 
1
4
2 u2 sin   3 
=  2 1  
3 g cos   2 
10 
2

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4 8  3 
=  1  
10 3 30  2 
4 8 8 3  8 8( 3  1)
=    = 20 cm
5 3 30 30 30

9. i = 10 A
=1m
N i
o = 4 × 10–7
A2 C
o i
B= 3
4 3 
2
 i 3 4  10 7  10  3
= o  = 20 3  107
2 2  1
= 3 T

1
10. 2
 e t  5 t
e
1
t
2

11. MA = 1 kg, MB = 3 kg
 AB  0.2
B = 0.2 A

Fmax = (MA + MB) × 0.2 × 10 + (MA + MB) × 0.2 × B F

10
= 4 × 2 + 4 × 2 = 16

12. X = 5YZ2
X
Y= 2
= M–3 L–2 T8A4
5Z

hc  1
13.  13.6 eV(g) 1  
  16  h=4
1240 eV 15
  9  13.6 eV
 16
1240  16 h=1
 = 10.8 nm
15  9  13.6

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b m
14. f
c
C c
b

V
a b
mV 2 GMm
15.  2
r r
GM
V
r
VT GM T
n 
2r r 2r
 GM  T 6.67  1011  8  1022 T
=  3 
   
 r  2 (202  104 )3 2

24  3600 6.67  8  1011 24  3600 24  3600

= 3 12
 =  11
2  3.14 (202)  10 2  3.14  1242.8 78.51

W
16. I  25  25  10 4 W / m2
cm2
P = 25 × 25 ; W = 625 W
hc dn
P
 dt
h dn P 625
F  
 dt C 3  108
625  40  60
Momentum = = 5 × 10–3 Ns
3  108

17. v  2iˆ  6  ˆj
At t = 2

v  2iˆ  12ˆj
 
P  mv  4i  24 ˆj
At t = 2

r  4iˆ  12ˆj
ˆi ˆj kˆ
  
L  r  P  4 12 0
4 24 0
= 4( 24)  4  12 kˆ
=  –96  48  kˆ
= ( ) 48 kˆ

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18. 10 4  1  (1)2  2  10  0.15  A

10 4
A = 5 × 10–5
2

b
 dx
19. R
a 4 x 2
  1 1
= 
4   a b 

20. m = 5 × 10–3 kg, r = 10–2 m

 = 25 × 2 rad/5
= 50  rad/sec

 t
I
I 5mr 2 
  
t 4 t
5  5  10  10 4  50 
3
=
45
25
=  106 = 2 × 10–5
4

21. Vbreakdwon = 6V, RL = 4k, Ri = 1 k Ri

6 ii
iL =  103  1.5  10 3 = 1.5 mA i
4
ii = 2 × 10–3 RL
i = i1 – iL = 0.5 mA – minimum current VB
iL

ii = 10 × 10–3 = 10 mA
imax = 8.5 mA

L
22. T  2 + –
q2E 2
2 + –
g  2 –
M +  –
+ E –
–
+ –
+ –
–
+ –
+ –
m –
+ q qE –
+ –
+ –
–
+ Mg –

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23. qA = 1 c ; qB = 1 c, mB = 4 × 10–9 kg, rAB = 10–3 m

1  1 1 
MB V 2  k qA qB  3  
2 10 9  10 3 
1 8
4  109 V 2  9  109  10 6  10 6   103
2 9
8
V 2   109  4  109
2

hc dn
24. 2  103 
 dt
dn 2  103 

dt hc
2  10 3  500  10 9
=
6.6  10 34  3  108
1000
=  1014 = 5 × 1015
6.6  3

25. L = 10 × 10–3 H, r1 = 0.1  L = 10

–2
r1 = 0.1

i =  1  e  t/2 
isaturation = 
80% isaturation = 0.8 

0.8  =  1  e  t/2 
 t/2
0.8 = 1  e ; e  t/2  0.2
et/L = 5
t = L ln 5 = 10 × 10–3 × 1.6 = 16 × 10–3  r2 = 0.9 

26. P1 = 5.05 × 106 ; P2 = 8.08 × 106

P2 – P1 = g(d2 – d1)
3.03  106
d2  d1  = 3.03 × 102 = 303
103  10

27. 0.3 3  = 3  ××

kg
 = 300
m3 0.3 3
m + 3 = 3

M = 3(w – ) = (5)3 {1000 – 300} = 700 × (5)3

= 87.5 kg

IMax 9
28. 
IMin 1

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V
29. fa  fo = 1000 Hz
V  Vs

s V = 50 m/s

V
fa  fo
V  Vs
fa V  Vs 350  50 300 3
   
fa V  Vs 350  50 400 4
3
fa   1000 = 750 Hz
4

30. m = I2 2r = 4

I4 2 2
m = r
 
m 4 4 2 42
 r 2  =
m  2 
4
m  m


PART B – CHEMISTRY
31.

32.

1  1 1
 RH  2  2  Z2
2  n1 n2 
33.
1 1 1
 RH  1  1  Z2
1  n1 n2 
As for shortest wavelength both n1 and n12 are 
1 9 n11
  
 2 1 n12
Now if n11 = 3 and n1 is 1 it will justify the statement hence Lyman and Paschen is
correct.

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34. As Zn is fully filled and left to right in group IP increases.

35.

36. Fact based

37.

38. Rf value can’t measure the extent of adsorption.

39.

40. In gemstone, ruby has Cr3+ ion occupying the octahedral sites of aluminium oxide
(Al2O3) normally occupied by Al3+ion.

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41. Angle strain govern stability in cyclic compound.

42. Fact based.

43. In option (B)- ng is –ve therefore increase in pressure will bring reaction in forward
direction.
In option (C)- as the reaction is exothermic therefore increase in temperature will
decrease the equilibrium constant.
In option (D)- Equilibrium constant changes only with temperature. Hence, option (B), (C)
and (D) are correct therefore option (1) is incorrect choice.

44.

45 (a) High density (III) Ziegler-Natta Catalyst

(b) polythene
Polyacrylonitrile (I) Peroxide catalys t
(c) Novolac (IV) Acid or base catalyst
(d) Nylon 6 (II) Condensation at high temperature & pressure

46.

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47.

48. The highest oxidation state of U and Pu is 6+ and 7+ respectively.

49.

50. Fact based.

51.

52. CFSE = [-0.4n t2g + 0.6 n eg] o

53. In electrophoresis precipitation occurs at the electrode which is oppositely charged

therefore (A) is correct.

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54. Both NaCl and KCl are strong electrolytes and as Na+(aq.) has less conductance than
K+ (aq.) due to more hydration therefore the graph of option (B) is correct.

55.

56. Benzylamine will not give cyanobenzene with HCl/H2O & NaBH4.

57. Refer structure of C60 & P4

P

P P

58. 4 mol of Fe require 3  32 gram

1 3  32 1
mol of Fe require    0.428 g
56 4 56

59.

60.

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PART C – MATHEMATICS
2
x  ax  b
61. lim 5
x 1 x 1
1 a  b  0 ……..(i)
2a5 . ……..(ii)
 a  b  7

62. By expansion, we get

5x 3  30x  30  5x  0
 5x3  35x  30  0
 x3  7x  6  0 , All roots area real
So, sum of roots = 0

63. Required line is 4x  3y    0 Y

 3

5 5
   3
So, required equation of line is
(–2, 0)
4x  3y  3  0 and 4x  3y  3  0 X
 1 2
(1) 4     3    3  0
 4 3
4x – 3y + 2 = 0

dy  2  3
64.  2
dx  ,  
2  3 
Given that :
 2  3 1
2

 2
 3  3

   0,  3   0
1
 .   0 
2
6  2  19

  P (–1, 2, 6)
AP.n
65. AD    61
n

 PD  AP 2  AD 2  110  61  7

A (2, 3, –4) D

n  6iˆ  3 ˆj  4kˆ

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2
66. Tangent to y 2  4 2 x is y  mx  it is also tangent to x 2  y 2  1
m
2 /m
  1  m  1
1  m2
 Tangent will be y  x  2 or y   x  2 compare with y  ax  C
 a  1 and C   2
67. fog  x     x    fg        b
 fg  x  '  1   fg    '  1  a
x2 y2
68.  1
9 16
16 5
a  3, b  4 and e  1  
9 3
corresponding focus will be (–ae, 0) i.e.  5, 0  .

y
69. cos1 x  cos1 
2
 y
cos  cos1 x  cos1   cos 
 2
y y2
 x  1  x2 1   cos 
2 4
2
 xy  2  y2 
  cos  
 2 
 1  
x  1 4 


y2
x2   xy cos   1  cos2   sin2 
4

70. h2  k 2  h  1
 x 2  y 2  x 2  1  2x
 y 2  1  2x
 y  1  2x; x  0

71. Let a is first term and d is common difference then, a  5d  2 (given) ……(1)
f  d    2  5d 2  2d 2  d

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2 8
f ' x  0  d  ,
3 5
8
f "  d   0 at d 
5
8
d
5

n
72. Tr 1   nCr x 2n 2r . x 3r
r 0

2n  5r  1  2n  5r  1 for r  15, n  38 smallest value of n is 38.

73. Total cases = number of diagonals in 20 sided polygon.

 20C2  20  170

4
74. V
3
 3
 10  h   103 
dV 2 dh
 4 10  h 
dt dt
2 dh
50  4 10  5 
dt
dh 1 cm
 
dt 18 min e

75. Mean     x i
 16
50
2

Standard deviation    
 i 2
     16
50
2

  256   2 
x i

50
 New mean
2 2


x i  4

x i  16  50  8 x i
50 50
  256   2  16  8  16  400

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76. Let 2x  t
5  t  1  t 2  2t

 t  1  t 2  2t  5 
gt f t
From the graph
So, number of real root is 1.

77. 3x 2  5y 2  32
dy 3

dx  2,2 5
3 16
Tangent : y  2    x  2   Q  , 0 
5  3 
5  4 
Normal : y  2   x  2   R  , 0 
3  5 
1 68
Area is   QR   2  QR 
2 15

78. Let point P on the line is  2  1,    1,   foot of perpendicular Q is given by

x  2  1 y    1 z     2  3 
  
1 1 1 3
 Q lies on x  y  z  3 and x  y  z  3
 x  z  3 and y  0
2  3
y  0   1 0
3
 Q is (2, 0, 1)
1
79. I  dx
cos x sin1/3 x.sin x
2/3

tan2/3 x
 .sec 2 x.dx
tan2 x
sec 2 x
 4/3
tan x
.dx 
tan x  t, sec 2 x dx  dt 
dt t 1/3
 
tan4/3 1/ 3
 3 t 1/3  
1/3
 1  3 tan  x 
 /3  
3  1 1/3

I
 tan x 
1/3
 3  1/3
  3 
 /6

   3 

 37/6  3 5/6

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
80. B  , by sine Rule
3
1
sin A 
2
 A  30o ,a  2, b  2 3, c  4
1
   2 3  2  2 3 sq.cm
2

81. b  ar
c  ar 2
3a,7b and 15c are in A.P.
 14b  3a  15c
 14  ar   3a  15 ar 2
 14r  3  15r 2
 15r 2  14r  3  0   3r  1 5r  3   0
1 3
r ,
3 5
1  1
Only acceptable value is r  , because r   0, 
3  2
7 2
 c .d  7b  3a  7ar  3a  a  3a   a
3 3
2 15 2
 4th term  15c  a  a aa
3 9 3

dy
82.  y  tan x   2x  x 2 tan x
dx
I.F.  e 
 tan x dx
 eln.sec x  sec x
 
 y.sec x   2x  x 2 tan x sec x.dx
2
  2x sec x dx   x  sec x .tan x  dx
y sec x  x 2 sec x  
 y  x 2   cos x
y 0   0    1   1
2
y  x  cos x
   2 1
y   
 4  16 2
2
   1
y   
 4  16 2
y '  x   2x  sin x
  1
y '   
4 2 2

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    1
y '  2 
 4  2
    
y '   y'    2
4  4 

83. 4x  2y  4z  6  0
6 6 1
 
16  4  16 6 3
6 2
  8, 4
3 2

4  4 1 3
3  2
  5, 1
 Maximum value of       13 .

84. Required Area

1

   x  1  2  dx
x

0
1
 x2 2x 
 x 
 2 ln 2 0
1 2   1 
   1   0  0  
2 ln 2   ln 2 
3 1
 
2 ln 2

85. D0
1 1 1
4   0 3
3 2 4

13  23  .....n3 1 15.16
15
86. Sum    .
n 1 1  2  .....  n 2 2
 
15 n n  1
  60
n 1 2
15 n  n  1  n  2   n  1 
  60
n 1 6
15.16.17
  60  620
6

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n
 1 99
87. 1   
2 100
n
 1 1
  
 2  100
n7

88. ~  ~ s   ~ s  
s  r  ~ s 
 s  r    s ~ s 
 s  r   
s  r 
89. Let x 2  t 2xdx  dt
1 2 t 1  2 t
  t .e dt   t .e   2t.e  t , dt 
2 2
1
  
  t 2 .e  t  t.e t   1.e t .dt
2

t 2e t  t2 
  te  t  e  t     t  1 e  t
2  2 
 x4  2
   x 2  1 e  x  C
 2 
for k  0
1 5
g  1  1  1   
2 2

 
i   1
90. z . w 1 z  re  2
and w  ei
r
   
 i    i  
z. w  e  2
.ei  e  2
 i
   
i    i 
z.w  e  2
.e  i  e  2   i

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