Merck Catalog For Analytical Lab
Merck Catalog For Analytical Lab
Merck Catalog For Analytical Lab
YOUR LAB
EMSURE® | EMPARTA® | EMPLURA®
Inorganics & Solvents for classical analysis
2
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Looking for the
right reagent for
Your applIcatIon?
Just choose your grade
Life science is a vast field. It can mean anything from complex analysis to routine lab work
or production. Each poses unique demands, requires distinct solutions, and is governed by
different regulations. When looking for products, you have to consider your application, your
target and, of course, your budget.
To simplify your search, our extensive portfolio of Inorganics and Solvents is divided into three
grades: EMSURE®, EMPARTA® and EMPLURA®. Each quality grade is offered in a variety of
volumes, packaging materials, and with different documentation packages. Now, you won’t
have to search for the right solution for your application. All you have to do is choose.
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Contents
CoA’s
MSDS 99.0 –
ACS < 10
BSE / TSE 99.5 %
certificates
CoA’s
– 99 % 4–5
MSDS
6
Inorganics & Solvents
EMSURE®
Acids EMPARTA®
Page 72
EMPLURA®
EMSURE®
EMSURE®
EMSURE®
Salts EMPLURA®
Page 90
EMSURE®
Solvents EMPARTA®
Page 106
EMPLURA®
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Compliance
and Documentation
Whether you manufacture products nationally or internationally, you
need to comply with a host of regulations. It can be challenging to
maintain an overview of requirements – especially when they change.
This is where a capable partner can help.
Our Inorganics and Solvents are produced and tested according to mul-
tiple international guidelines. This means they can be used worldwide
for almost all applications. It also allows our global customers to work
with the same standard operating procedures (SOPs), and export to
countries with different regulations.
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Regulatory environment
Our analytical reagents are available in different grades, which are specified in accordance
with various international regulations.
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Compliance and
Documentation
We offer a choice of product grades to suit the regulatory environment you work in.
EMPARTA® products are specified according to ACS. EMSURE® product specifications not
only fulfill ACS, Reag. Ph Eur, and ISO guidelines – but exceed them. That’s because we
are regularly adding new parameters required by our customers. This is essential as it
enables the use of new, more sensitive technologies.
EMSURE® Quality
Documentation
BASIC
10
Additional parameters
for EMSURE®
Additional parameters
25
for ISO 6353
Additional parameters
for Reag. Ph Eur
20
15
ACS
10
EMSURE®
5
0
Sodium chloride for analysis Brand A Brand B Brand C
EMSURE® ACS, ISO, Reag. Ph Eur
(Cat. No. 106404)
CoA’s
EMPLURA®
MSDS
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Pharmaceutical
AnalYsis
With suitable, specified reagents
We supply several hundred Inorganics and Solvents for pharmaceutical analysis – the most
extensive range offered by any manufacturer. Comprising solvents, acids, salts, caustics, bas-
es, indicators and special reagents, our pharmacopoeia portfolio ensures that you work with
the most suitable products for your particular needs and that they meet all quality guidelines.
For pharmaceutical analysis, you have the choice of two grades: EMSURE® or EMPARTA®.
While both grades comply with ACS standards, EMSURE® products also fulfill the Reagents
requirements of the European Pharmacopoeia.
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Regulations
Specification
Reag. Ph Eur = Reagents section of the European Pharmacopoeia
ACS = American Chemical Society
USP = United States Pharmacopoeia (refers to ACS for reagents)
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Specifications
and PuritY
Our promise of exceptional quality
Our reagents and chemicals are renowned for their outstanding quality. We achieve and main-
tain this reputation through three important measures: validation, accreditation, and compli-
ance with regulations. Every step in our supply chain is subject to the most stringent controls
and fully documented to give you complete confidence in your analysis.
Purity
Decades of experience with highly pure chemicals combined with state-of-the-art production
and filling plants ensure that what you order is what you receive. We only use high-quality
raw materials and manufacture under strictly controlled conditions using our advanced
methodology. This results in outstanding chemical purity and extremely low limiting values,
which makes our products the ideal choice for reliable qualitative
and quantitative analyses.
Quality control
All our Inorganics and Solvents are tested and certified in our own state-of-the-art laborato-
ries under the guidance of highly qualified specialists. We have quality control labs at every
production site, which work closely together to ensure comparable test procedures and
results. During testing, we always adhere to international standards and legal requirements,
and integrate the latest developments in technology and methods.
So you can trust on our analytical competence. EMPARTA® and EMPLURA® grade products are
tested at one of our own labs close to its production site. EMSURE® grade products are quality
controlled at our Merck KGaA, Darmstadt, Germany site.
Consistency
Due to their outstanding batch-to-batch consistency, each time you use our products, you can
expect the same excellent quality. This not only ensures reproducible results, but also avoids
the costs and complications of repeat analyses.
The graphs on the right demonstrate the superior batch-to-batch consistency of some of our
products.
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Acetone for analysis EMSURE® ACS, ISO, Reag. Ph Eur
100.0 %
99.9 %
99.8 %
99.7 %
99.6 %
99.5 %
99.4 %
99.3 %
99.2 %
99.1 %
99.0 %
K44105228 K44065228 K44014928 K43990428 K43953828 K43912828 K43884128 K43824328 K43800428 K43733628
Assay specification
Assay effective values
Hydrochloric acid fuming 37 % for analysis EMSURE® ACS, ISO, Reag. Ph Eur
39.0 %
38.0 %
37.0 %
36.0 %
35.0 %
34.0 %
K44070471 K44056371 K44043371 K44012671 K44015471 K43975371 K43940571 K43922171 K43893371 K43804771
50.00 ppb
15.63 ppb
3.13 ppb
0.63 ppb
0.13 ppb
0.03 ppb
0.01 ppb
0.00 ppb
K44070471 K44056371 K44043371 K44012671 K44015471 K43975371 K43940571 K43922171 K43893371 K43804771
Fe specification Cu specification
Fe effective values Cu effective values
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Specifications and Purity
Our promise of exceptional quality
Unrivalled specifications
Our reagents and solvents often offer additional specifications beyond those required by
international guidelines, such as ISO, ACS and Reag. Ph Eur. Many are measured for up to
70 parameters! Furthermore, thanks to our proven Quality Management System, we are
able to continuously improve our specifications.
Application-optimized
The differences in our quality grades are clearly shown in their individual specifications.
Regardless of the grade you choose, you will always receive a product of excellent quality
that’s perfectly suited to your application.
Dedicated service
For us, quality encompasses more than product purity and consistency. It also means service
that exceeds expectations. Whether you require regulatory support, application advice, or a
specific product, our experienced team is always at hand to work closely with you and deliver
swift, innovative solutions.
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SAFETY AND PACKAGING
Protecting people, products and the planet
Besides offering premium chemicals and reagents, we have invested decades into developing
the most advanced packaging concepts in the field of chemistry. Our innovative packaging and
withdrawal systems are precisely tailored to the contents, and based on sustainable principles.
So they not only protect your personnel and products, but also the environment.
Robust, PE-coated
Safebreak bottles for acids
• Safe handling of acids
• Meet all safety requirements
• All advantages of glass bottles
• Easy, eco-friendly disposal
(with glass)
Environmentally friendly,
returnable stainless steel
drums for solvents
• Safe, easy and convenient handling
of solvents
• Ecological, returnable container
• Cost effective solution
• Suitable withdrawal systems available
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Development and testing
Our internal packaging department is exclusively responsible for testing,
developing and approving packaging materials. Our package testing facility is
accredited by the German Federal Institute for Materials Research and Test-
ing (BAM – Bundesanstalt für Materialforschung und -prüfung), the authority
responsible for the packaging of dangerous goods.
Packaging advantages
• Packaging is always compatible with the product
• Safe and convenient handling, storage and transportation
• Optimal protection of chemicals and reagents from
contamination
• Application-oriented packaging
• Wide choice of packaging materials and sizes
For more details about our packaging, please see ‟Packaging and Safe Handling”
on page 42
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EMSURE ®
20
Highest convenience Obtain more accurate Fulfill regulatory
and safety and reliable results requirements
Page 26 Page 24 Page 27
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EMSURE®
Premium Grade Inorganics and Solvents
All EMSURE® products are made from high-quality raw materials in our
state-of-the-art production facilities, then tested for up to 70 parameters at
our stringent quality control labs in Darmstadt, Germany. This results in
outstanding chemical purity and extremely low limiting values.
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Acetic acid (glacial) 100 % anhydrous for Acetic acid (glacial)
analysis EMSURE® Premium Grade Inorgan- 100% anhydrous for analysis
ics and Solvents, ACS, ISO, Reag. Ph Eur EMSURE®
Water ≤ 0.2 %
Zr (Zirconium) ≤ 0.050 ppm
Zn (Zinc) ≤ 0.030 ppm
V (Vanadium) ≤ 0.010 ppm
Tl (Thallium) ≤ 0.020 ppm
Ti (Titanium) ≤ 0.050 ppm
Sr (Strontium) ≤ 0.010 ppm
Sn (Tin) ≤ 0.050 ppm
Pt (Platinum) ≤ 0.100 ppm
Phosphate (PO4) ≤ 0.4 ppm
Ni (Nickel) ≤ 0.020 ppm
Na (Sodium) ≤ 0.200 ppm
Mo (Molybdenum) ≤ 0.010 ppm
Mn (Manganese) ≤ 0.010 ppm
Mg (Magnesium) ≤ 0.050 ppm
Li (Lithium) ≤ 0.010 ppm
K (Potassium) ≤ 0.100 ppm
In (Indium) ≤ 0.050 ppm
Hg (Mercury) ≤ 0.005 ppm
Ge (Germanium) ≤ 0.020 ppm
Ga (Gallium) ≤ 0.050 ppm
Cr (Chromium) ≤ 0.020 ppm
Co (Cobalt) ≤ 0.010 ppm
Cd (Cadmium) ≤ 0.020 ppm
Ca (Calcium) ≤ 0.100 ppm
Bi (Bismuth) ≤ 0.050 ppm
Be (Beryllium) ≤ 0.005 ppm
Ba (Barium) ≤ 0.010 ppm
B (Boron) ≤ 0.100 ppm
Additional parameters for EMSURE® products
Au (Gold) ≤ 0.010 ppm
As (Arsenic) ≤ 0.010 ppm
Al (Aluminium) ≤ 0.020 ppm
Ag (Silver) ≤ 0.005 ppm
Acetaldehyde ≤ 2 ppm
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EMSURE®
Premium Grade Inorganics and Solvents
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Chloroform for analysis EMSURE® ACS, ISO, Reag. Ph Eur
200 ppm
150 ppm
100 ppm
50 ppm
0 ppm
K44097933 K44067833 K44029133 K43960433 K43817633 K43775133 K43732433 K43622833 K43369833 K43353133 K43243633 I623733
100.0 %
99.9 %
99.8 %
99.7 %
99.6 %
99.5 %
99.4 %
99.3 %
99.2 %
99.1 %
99.0 %
K44009804 K43975604 K43957204 K43941004 K43925404 K43896604 K43860404 K43831304 K43744604 K43737504
1000 ppb
100 ppb
10 ppb
B0867719 B0866819 B0865619 B0864719 B0859819 B0859019 B0858019
Fe specification Cu specification
Fe effective values Cu effective values
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EMSURE®
Premium Grade Inorganics and Solvents
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Regulatory compliance – Specified beyond standards
EMSURE® product specifications not only fulfill ACS, Reag. Ph Eur
and ISO guidelines – but surpass them. That’s because we are regu-
larly adding new parameters required by our customers. As a result,
EMSURE® products can be used around the world for almost all
applications, including pharmacopoeia analysis. Due to their exten-
sive specifications, EMSURE® products are also suitable for use with
the latest technologies, such as detecting concentrations of metals
via atomic absorption spectroscopy (AAS).
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EMSURE®
Premium Grade Inorganics and Solvents
Comprehensive documentation –
All the documents you need – whenever you need them
We provide extensive documentation for EMSURE® products to further
support your work. All standard documents are available 24/7 on
www.merckmillipore.com. Simply search for documents using the product
number, CAS number or keywords.
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www.merckmillipore.com/EMPOWER 29
EMSURE®
Premium Grade Inorganics and Solvents
Learn more about your advantages, and obtain your copy of EMSURE®
Quality Documentation on:
www.merckmillipore.com/emsure/documentation
EMSURE® Quality
Documentation
Advanced
EMSURE® Quality
Documentation
BASIC
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Quality Documentation Basic
Available free of charge, the ‟Basic” version provides all standard registration and product-
specific characteristics in a clear and concise format. Simply download the package from the
our website, and obtain essential, up-to-date information about the reagents you use.
Package includes:
• Synonyms / nomenclature
• Chemical formula
• Material Safety Data Sheet
• ISO certificates of Merck KGaA, Darmstadt, Germany production sites
• REACH registration statements
• Chemical inventories statement
• Product specifications
• Country of origin
• Risk statements e.g. BSE / TSE information
The documentation is available as a PDF file, which can be saved directly in your lab sys-
tem. The complete package can be ordered and it includes free updates for 5 years. Simply
sign the confidentiality agreement, download the document, and enjoy unlimited access to
the most current information.
Package includes:
• All documents of the ‟Basic” package
• Production flow charts
• Test monographs
• RoHS certificate
• Batch analysis comparison
• Additional test certificates e.g. allergens, aflatoxins, residual solvents
• GMO information
• Non-nano particle information
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EMPARTA ®
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Standard quality Compliant with Convenient
for routine applications ACS lab-sized packaging
Page 35 Page 34 Page 35
EMPARTA
EMPARTA®®
Standard Grade Products
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EMPARTA ®
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Standard quality for routine lab applications
EMPARTA® products offer just the parameters you really
need – including all those required by the ACS. Hence, they
are the perfect choice for reliable quality control and routine
analytical applications in less regulated industries.
Reliable results
EMPARTA® Inorganics and Solvents feature a high analytical
purity of 99.0 – 99.5 %. Thanks to our sophisticated pro-
duction chain, particulate impurities and cross-contamina-
tion from other products are completely ruled out.
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EMPLURA ®
36
Economical Adequate specifications Suitable for numerous
solution with most common parameters basic applications
Page 38 Page 38 Page 38
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EMPLURA ®
Economical solution
Why pay for high purity when your application only requires basic quality?
EMPLURA® products Inorganics and Solvents are your economical answer.
It gives you reliable results at a reasonable price.
Adequate specifications
EMPLURA® products are mainly tested for preparative lab applications and
standard production processes. Hence, we only monitor the basic param-
eters that are important in these applications, such as purity, identity, den-
sity, evaporation residue and water content. In most cases, the purity ex-
ceeds 98 %.
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Principles of green chemistry
• Prevent waste
• Use renewable raw materials
• Minimize energy and resource requirements of
chemical processes
• Create safer, less toxic chemicals
• Develop less hazardous synthetic methods
• Design chemicals that do not persist in air and water
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EMPLURA ®
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Cyclopentyl methyl ether (CPME) Ethyl lactate
Cyclopentyl methyl ether is a greener sub- Ethyl lactate is a safer and more sustainable
stitute for tetrahydrofuran, tert-butyl methyl alternative to ethyl acetate and acetone. It
ether, 1,4 dioxane and other ether solvents. is an ester of natural L-lactic acid, which is
produced by fermentation of sugar.
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Packaging and
Safe Handling
Perfected to protect
For us, packaging is not just an empty vessel for products. It is a fundamental aspect of
safety, sustainability and reliability. Hence, we pay as much attention to the quality of our
outer materials as to their inner contents. This commitment has led to an exceptional range
of packaging options that ensure safe transport, storage and handling, while minimizing
environmental impact.
For
more information
about PE canisters &
Fassetts® see page 61
42
For more information
about stainless steel
drums see page 63
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Packaging and Safe Handling
Perfected to protect
Your advantages
• Application-oriented packaging materials and volumes
• Convenient, safe and contamination-free handling
• Maximum safety through an extensive portfolio of accessories
• Ecological and economical use of returnable containers where suitable
• Individual user installation or other customized solutions possible
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Product label
First published in the UN’s ‟Purple Book” in December 2003, the Globally Harmonized
System (GHS) describes standardized classification and labeling criteria for chemicals,
including hazard symbols and safety data sheets. Since its introduction, the GHS has been
progressively adopted in different countries. June 1, 2015 was a significant implementation
deadline in both the EU and the US. Since all our Inorganics and Solvents carry GHS labels,
our customers can work safely and in compliance with these regulations.
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Packaging overview
From bottles to tanks
500 ml 1l 2.5 l 4l
1l 2.5 l 5l
46
5l
10 l 25 l 190 l
47
Packaging overview
From bottles to tanks
10 l 25 l 180 / 190 l
25 l 200 l 1,000 l
48
500 g 1 kg 2.5 kg 5 kg
12 kg 25 kg / 50 kg
49
Quantity Guide
Safety comes in many sizes
Our extensive variety of packaging types and sizes is unrivaled in the industry. With volumes
from 0.05 l to 20,000 l, and materials from glass and HDPE to metal and stainless steel, we
can easily cater to your individual requirements. The guide below will help you select the size
and material that best suits your application. Whichever you choose, extraordinary safety
comes standard.
one-way one-way
packaging packaging
Bottles
50
Tank trucks
returnable
packaging
190 l – 20,000 l
> 1,000 l
51
Amber glass bottles
for acids, bases and solvents
Specially formed,
sharp thread lip
for safe drip free pouring
52
HDPE bottles for liquids
for acids, bases and solvents
Specially formed,
sharp thread lip
for safe drip free pouring Integrated handle
for best pouring properties
(for 2.5 l and 5 l)
Specially treated high
quality HDPE
with extreme durability, inertness For certain chemicals,
and shock resistance for highest bottles are colored to
safety and product quality protect against UV
53
Safety accessories for bottles
To further protect you during daily lab work, we offer several safety
accessories specially designed for Merck KGaA, Darmstadt, Germany bottles.
S40 thread
S28 thread
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Label set acc. to GHS, DIN EN ISO and GLP (1.00801.0001)
• Comprehensive label compliant with GHS, DIN EN ISO and GLP standards
• Complete safety information at a glance with adhesive pictograms and signal words
• Non-permanent adhesive for easy, residue-free removal
• Robust plastic label, resistant to chemicals
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Specials for acids
Problem solved
Fortunately, we have developed an effective solution: the Safebreak bottle. This computer-
designed glass bottle is coated with polyethylene (PE), and can withstand considerable impact
force. But should the bottle break, all liquid acid (!) and glass splinters are reliably contained
within the PE coating, thereby protecting users from cuts or exposure to harmful chemicals.
56
HDPE dosage bottle for hydrofluoric acid
Hydrofluoric acid is extremely dangerous. Even small quantities can cause
severe injuries and poisoning. To avoid such hazards, we supply hydrofluoric
acid in a special 500 ml dosage bottle. It is equipped with a pouring aid that
allows safe, drop-by-drop withdrawal of the acid, and the last drop stays
reliably in the bottle. Furthermore, our exclusive S40 screw cap ensures that
the bottle is completely airtight, thereby preventing exposure to the acid or
its vapors.
This innovative cap has a valve that allows excess gas to be released,
hence preventing the build-up of pressure. It is also absolutely leak-proof
– even if the bottle is tipped. Furthermore, the PTFE membrane incorpo-
rated in the SafetyCap allows neither gas nor liquid to enter the bottle,
thus protecting the contents from contamination. For additional safety, all
bottles with such reagents are packed in PE bags.
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HDPE bottles
for solids
Wide opening
for easy withdrawal
Specially treated,
high-quality HDPE
with extreme durability, inert-
ness and shock resistance
ensures maximum safety and
maintains product quality
Unique, clear and
complete labeling
with product specifications
and all relevant hazard
declarations
Square base
allows optimum use of storage
space in the laboratory and
during transportation
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Corrugated board box
with PE inliner
PE inliner
is produced in clean room
conditions to protect contents
Robust construction
for convenient and secure
packing
Technical data
Material: Corrugated cardboard, PE bag
Available packaging size: 25 kg and 50 kg (volume dependent on bulk density of the product)
Volume Height Width Depth
26 l 310 mm 370 mm 275 mm
36 l 420 mm 370 mm 275 mm
40 l 330 mm 379 mm 379 mm
44 l 500 mm 370 mm 275 mm
50 l 413 mm 374 mm 374 mm
57 l 640 mm 370 mm 275 mm
60 l 488 mm 374 mm 374 mm
80 l 648 mm 369 mm 369 mm
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Aluminum bottle
for solvents
Pack size: 5 l
60
PE canisters & Fassetts®
for acids and bases
Fassett®
specially designed
for chemicals which
Safe and easy usage build pressure
due to convenient
handles on top
Standard opening
to ensure maximum
compatibility
High quality PE
for maximum safety and
product quality
Blue canisters
available for light-sensitive
Withdrawal systems for acids and bases see page 66 chemicals
61
Steel drums and combi drums
for solvents and acids
one-way
packaging
Bottom reservoir
for optimal emptying
Withdrawal systems for acids see page 67; for solvents see page 68
Technical data
Parameter 10 l 25 l 25 l with PE 180 / 190 l 180 / 190 l with PE
Height 34 cm 52 cm 52 cm 88 cm 88.5 cm
Diameter 24.5 cm 29 cm 29 cm 59.5 cm 58.8 cm
Volume 13.5 l 28 l 28 l 216.5 l 203 l
Filling quantity 10 l 25 l 25 l 180 / 190 l 180 / 190 l
Weight (empty) 1.8 kg 3.6 kg 3.4 kg 22 kg 22 kg
Number per pallet 13 11 11 2 2
Openings 2" decentrally 2" centrally and S56 x 4 (PP) 2" centrally and 3/4" decentrally 2 x S56x4 (PP)
located 3/4" decentrally located located (steel, galvanized)
Material steel steel steel with PE steel steel with PE
62
Stainless steel drums
for solvents
Printed / engraved
UN-code
includes important safety
information and provides
Safe and easy handling packaging certificates
due to 2 large handles
Unique, clear and
complete labeling
High quality stainless steel
with product specifications
with extreme durability, inertness
and all relevant hazard
and shock resistance for highest
declarations
safety and product quality
returnable
packaging
Bottom reservoir
for optimal emptying
Technical data
Parameter 10 l 25 l 190 l
Height 35 cm 52 cm 88 cm
Diameter 24 cm 29 cm 59.5 cm
Volume 12 l 28 l 215 l
Filling quantity 10 l 25 l 190 l
Weight (empty) 1.9 kg 3.8 kg 18 kg
Number per pallet 15 11 2
Openings 2" decentrally located 2" decentrally located 2" decentrally located
3 / 4" decentrally located
Material stainless steel stainless steel stainless steel
63
Important information for safety
and returnable system
If flammable liquids (e.g. solvents) are to be used, the container (10 l or more) must be properly
earthed according to valid safety regulations to avoid the risk of explosion and fire. Appropriate
measures must be taken to discharge static electricity.
• General warnings and safety instructions must be observed.
• All components (e.g. container and withdrawal system) must be grounded separately in accordance
with the applicable safety regulations.
• Grounding clamps must have metallic contact with both the container and the withdrawal system,
and a safe ground connection.
• The grounding of the container and the grounding of the withdrawal system must be installed before
opening the container.
• The user must always wear conductive personal protective equipment, especially shoes and gloves,
to avoid electrostatic charges.
• The floor has to be conductive.
• Sampling vessels made of insulating material with a volume greater than 1 liter should not be used.
• Before using organic solvents, the user must ensure that there are no additional ignition hazards
caused by process-specific parameters, such as increased ignitability of the substances due to
changed environmental conditions or when sampling in combination with highly charge-generating
processes.
These measures reduce the risk of electrostatic separation of charges, and significantly increase safety
when handling solvents.
HE
YG
A
OX
FUEL
Heavy and light gases, hydrocarbon liquids and vapours, vapours of chemicals / lubricants / solvents,
frac oils, flammable materials
64
The returnable system and process
CUSTOMER
CONSUMPTION
Easy detection
Symbols for easy detection which
TRANSPORT
packaging material can be returned:
TRANSPORT
tainless steel drums are part of a
S
returnable
packaging
returnable process (in Europe) –
FILLING optional returnable packaging.
In Europe Merck KGaA, Darmstadt, Germany stainless steel drums are part of a returnable process. Their use means
that the user no longer has to cope with the topics of complete emptying, rinsing, disposing of the rinsing liquid and
even disposing of the packaging itself in the proper manner.
After consumption of the solvents on user site the empty drums are returned to us, unrinsed and with their
original labels still attached. On their return, we will ensure that they are properly cleaned, checked and refilled.
Clear advantages for a time saving and cost effective way of daily solvent handling.
Our withdrawal systems have been developed and optimized for the use with containers and solvents from us.
We therefore disclaims any warranty or liability for the operability of its withdrawal systems in connection with
containers or solvents from other manufacturers.
We reserve the right to refrain from the delivery of withdrawal systems if the respective order does not indicate
that each withdrawal system will be used in combination with appropriate solvents and containers from us.
We inform and advise our customers to the best of our knowledge and ability but without any engagement or
liability on our part. Our customers must obey all existing laws and regulations. This also applies in respect of
any protected rights of third parties. Our information and advice does not eliminate the need for our customers
to check, on their own responsibility, that our products are suitable for the purpose envisaged.
65
Manual withdrawal systems NEW
for acids & bases
The need for greater volumes of acids or bases may require a switch from bottles to larger
containers, which increases the risk of spills and accidents. The best way to protect yourself
from unintended contact with harmful and often corrosive liquids is through the use of
suitable withdrawal systems. Our unique solutions allow you to safely and easily dispense
harmful chemicals from large containers into other, typically smaller, reaction vessels,
thereby minimizing risks.
• Unique concept allows safe and easy withdrawal of chemicals, preventing accidental
contact with contents and vapors
• Flexible, lightweight withdrawal systems with integrated outlet valve and individual
pressurizing options
• Integrated check valve protects the pump ball from chemical vapors
• Integrated venting system avoids vacuum development
• No operating supplies required: manual pressure buildup by hand or foot pump ball
• Lower costs through use of larger volumes of 10 l or more
Pump ball
Outlet valve Squeeze to pressurize
Rotate to dispense
Cutlet valve
Open
Closed
Integrated check
valve
Protects pump ball from
chemical vapors
Dispense head (PE) for acids and bases, Dispense head (PE) for acids and bases,
1.67500.0001 1.67500.0001
manual pressure build-up manual pressure build-up
Hand pump ball for withdrawal systems 9.67114.0000 Hand pump ball for withdrawal systems 9.67114.0000
Dip tube (PE) for acids and bases Dip tube (PE) for acids and bases in
1.67526.0001 1.67525.0001
in 25 l fassetts 25 l canisters
66
Manual withdrawal system especially for Nitric acid and Sulfuric acid (PVDF)
• Made of specially tested high purity polyvinylidene fluoride (PVDF)
• Developed specifically for use with aggressive acids, e.g. HNO3 and H2SO4
Safe withdrawal in
8 simple steps
Dispense head (PVDF) for Nitric acid and Dispense head (PVDF) for Nitric acid and
1.67501.0001 1.67501.0001
Sulfuric acid, manual pressure build-up Sulfuric acid, manual pressure build-up
Hand pump ball for withdrawal systems 9.67114.0000 Foot pump ball for dispense heads 1.67502.0001
Dip tube (PVDF) for Nitric acid and Sulfuric Dip tube (PVDF) for Nitric acid in 180 l
1.67527.0001 1.67585.0001
acid in 25 l combi containers combi containers
67
Withdrawal Systems
for solvent drums
Position Z:
line closed
Horizontal line:
outlet closed
Vertical line:
outlet open
Horizontal line:
outlet closed
System at a glance
Necessary completive 9.67100.1026 Dip tube for 25 l composite drum
Order number 1.01114.0001
products (steel/PE)
Suitability 10 l and 25 l metal and stainless steel drums
Recommended safety Antistatic set (3 cables) 1.07070.0001
Operation mode Manual pressure build-up by pump ball products Drum opening key 1.08803.0001
Withdrawal system body with 2" clamp, Dip tube for 10 l drums 9.67100.1012
Set
Hand pump ball with rapid action connector, Spare parts Dip tube for 25 l drums 9.67100.1028
components
10 l dip tube, 25 l dip tube Hand pump ball 9.67114.0000
68
Pressurizing with inert gas [only for stainless steel drums]
• Safe, easy and convenient solvent handling
• Usage of tested high quality materials to ensure a reliable, contamination free and safe
handling of our solvents
• Construction of a central supply system, direct connection to instruments or individual
installations as options
Self closing tear off connections 9.67100.9051
for quick connection and disconnection Spiral gas
9.67100.9002 feeding tube
Threaded adapter with
vertical connections
9.67106.0001
Stainless steel clamp
9.67100.9090
Filling nozzle with stainless
steel coated PTFE-tube
System at a glance
Order number 1.06710.0001 Dip tube for 10 l stainless steel drums 9.67100.1010
10 l, 25 l and 190 l Necessary Dip tube for 25 l stainless steel drums 9.67100.1025
Suitability
stainless steel drums completive Dip tube for 190 l stainless steel drums 9.67100.1190
products Stainless steel clamp for filling nozzle 9.67106.0001
Pressurizing with inert gas attachment to drums
Operation mode
(house gas / gas bottle)
Recommended Antistatic set (3 cables) 1.07070.0001
Filling nozzle with stainless safety products Drum opening key 1.08803.0001
steel coated, flexible PTFE- 9.67100.9090 Filling nozzle with stainless steel coated, 9.67100.9090
Set tube (80 cm) flexible PTFE-tube (80 cm)
components Gas feeding tube 9.67100.9051 Spare parts Gas feeding tube 9.67100.9051
Threaded adapter with 9.67100.9002 Threaded adapter with horizontal connections 9.67100.9003
vertical connections Threaded adapter with vertical connections 9.67100.9002
69
Withdrawal Systems
for solvent drums
Threaded connection
Stop cock at
product outlet
Quick connection to
foot pump tube
System at a glance
Reducer (PE) from S56 x 4 to
Order number 1.19171.0001 Necessary completive products 9.67202.0000
2" thread (for combi drum)
180 l / 190 l / 200 l metal and stainless
Suitability Recommended safety Antistatic set (3 cables) 1.07070.0001
steel drums
products Drum opening key 1.08803.0001
Operation mode Manual pressure build-up by foot pump ball
Withdrawal system body with 2" thread
Foot pump ball with flexible tube and rapid
Set components Spare parts –
action connector
Adjustable dip tube
70
Ordering information
Inorganics & Solvents
EMSURE®
Acids EMPARTA®
Page 72
EMPLURA®
EMSURE®
EMSURE®
EMSURE®
Salts EMPLURA®
Page 90
EMSURE®
Solvents EMPARTA®
Page 106
EMPLURA®
71
Acids
72
EMSURE® | EMPARTA® | EMPLURA® acids offer the highest possible quality,
greatest safety and optimized packaging – for a multitude of analytical
applications. Every product undergoes strict quality checks using the
most sensitive instruments and methods.
www.merckmillipore.com/EMPOWER 73
Ordering information
Acids
Acids A-B
Product CAS No. Chemical formula Content Packaging Ord. No.
A Acetic acid 30 % for analysis EMSURE® Reag. Ph Eur 500 ml Glass bottle 1.59166.0500
25 l PE canister 1.00062.9025
25 l PE canister 1.00063.9026
Acetic acid (glacial) 100 % for analysis 2.5 l HDPE bottle 1.01830.2500
64-19-7 CH3COOH
EMPARTA® ACS NEW
25 l PE canister 1.01830.9025
12 kg PE bucket 1.00165.9012
Acids
ACS, ISO, Reag. Ph Eur
12 kg PE bucket 1.00244.9012
20 l Carboy 1.00304.9020
25 l PE canister 1.00316.9025
25 l PE canister 1.00319.9025
www.merckmillipore.com/EMPOWER 75
Ordering information
Acids
Acids H-N
Product CAS No. Chemical formula Content Packaging Ord. No.
Nitric acid 69 % for analysis EMSURE® ACS, NEW 1 l Safebreak bottle 1.01799.1010
Acids
Reag. Ph Eur 2.5 l Glass bottle 1.01799.2500
Oxalic acid dihydrate for analysis EMSURE® ACS, 500 g HDPE bottle 1.00495.0500
6153-56-6 (COOH)2 * 2 H2O
ISO, Reag. Ph Eur 1 kg HDPE bottle 1.00495.1000
Oxalic acid dihydrate EMPLURA® 6153-56-6 (COOH)2 * 2 H2O 5 kg HDPE bottle 1.00492.5000
www.merckmillipore.com/EMPOWER 77
Ordering information
Acids
Acids S-T
Product CAS No. Chemical formula Content Packaging Ord. No.
Sulfuric acid 95 – 97 % for analysis EMSURE® ISO 7664-93-9 H2SO4 2.5 l Glass bottle 1.00731.2500
2.5 l Safebreak bottle 1.00731.2510
2.5 l HDPE bottle 1.00731.2511
25 l PE canister 1.00731.9025
L(+)-Tartaric acid for analysis EMSURE® ACS, HOOCCH(OH)CH(OH) 1 kg HDPE bottle 1.00804.1000
87-69-4
ISO, Reag. Ph Eur COOH 5 kg HDPE bottle 1.00804.5000
50 kg Fibre carton 1.00804.9050
Acids
Trichloroacetic acid for analysis EMSURE® ACS,
76-03-9 CCl3COOH 250 g Glass bottle 1.00807.0250
Reag. Ph Eur
1 kg Glass bottle 1.00807.1000
80
EMSURE® | EMPLURA® Our high-quality caustic alkalis and bases are pro-
duced using specially selected raw materials. The range includes sodium and
potassium hydroxide pellets and corresponding solutions, as well as ammo-
nia solutions in various concentrations and grades. Simply choose the right
product for your application.
www.merckmillipore.com/EMPOWER 81
Ordering information
Caustics and bases
Caustics and bases A-S
Product CAS No. Chemical formula Content Packaging Ord. No.
25 l PE canister 1.05432.9025
EMSURE® EMPLURA®
82
Caustics and bases S-Z
Product CAS No. Chemical formula Content Packaging Ord. No.
84
EMSURE® | EMPLURA® metal salts, metals and noble metals are renowned
for their high quality and purity. We offer a diverse range of products suitable
for a multitude of applications in R&D, production and quality control.
www.merckmillipore.com/EMPOWER 85
Ordering information
Metals and metal oxides
Metals and metal oxides A-L
Product CAS No. Chemical formula Content Packaging Ord. No.
Aluminium (foil) for analysis 0.3 mm thickness, 250 g Fibre case 1.01057.0250
7429-90-5 Al
30 mm width EMSURE® 1 kg Plastic bag 1.01057.1000
C Cadmium coarse powder, for analysis and for 250 g Metal can 1.02001.0250
filling reductors particle size about 0.3 -1.6 mm 7440-43-9 Cd
EMSURE® 1 kg Metal can 1.02001.1000
Cadmium granular, for analysis particle size
7440-43-9 Cd 250 g Metal can 1.02004.0250
about 3 – 6 mm EMSURE®
25 g Glass bottle 1.02038.0025
Cesium chloride for analysis EMSURE® 7647-17-8 CsCl
100 g HDPE bottle 1.02038.0100
Copper fine powder particle size < 63 MYm 250 g HDPE bottle 1.02703.0250
7440-50-8 Cu
(> 230 mesh ASTM) EMSURE® 1 kg HDPE bottle 1.02703.1000
Copper foil about 0.1 mm thickness for analysis
7440-50-8 Cu 250 g Fibre case 1.02700.0250
EMSURE®
Copper(II) oxide granular for analysis EMSURE® 1317-38-0 CuO 500 g HDPE bottle 1.02768.0500
I Iron for analysis reduced, particle size 10 µm 100 g HDPE bottle 1.03819.0100
7439-89-6 Fe
EMSURE® 500 g HDPE bottle 1.03819.0500
EMSURE® EMPLURA®
86
Metals and metal oxides L-U
Product CAS No. Chemical formula Content Packaging Ord. No.
50 kg PE drum 1.05658.9050
Lithium hydroxide 98 % + for analysis EMSURE® 1310-65-2 LiOH 100 g HDPE bottle 1.05691.0100
Magnesium oxide for analysis 1309-48-4 MgO 100 g HDPE bottle 1.05866.0100
(max. 0.001 % SO4) EMSURE® ACS
500 g HDPE bottle 1.05866.0500
Magnesium oxide for analysis EMSURE® 1309-48-4 MgO 100 g HDPE bottle 1.05865.0100
Molybdenum(VI) oxide for analysis EMSURE® 1313-27-5 MoO3 100 g HDPE bottle 1.00403.0100
P Palladium powdered 99+ for analysis EMSURE® 7440-05-3 Pd 1 g Glass bottle 1.19225.0001
Platinum black 98+ for analysis EMSURE® 7440-06-4 Pt 5 g Glass bottle 1.19233.0005
Ruthenium(III) chloride hydrate for analysis 14898-67-0 RuCl3 * x H2O 5 g Glass bottle 1.19247.0005
EMSURE®
25 g Glass bottle 1.19247.0025
S Selenium black 99+ for analysis EMSURE® 7782-49-2 Se 50 g HDPE bottle 1.07714.0050
Silver oxide 99+ for analysis EMSURE® 20667-12-3 Ag2O 25 g HDPE bottle 1.19208.0025
T Tin fine powder EMPLURA® (particle size < 71 µm) 7440-31-5 Sn 250 g HDPE bottle 1.07807.0250
Tin foil about 0.04 mm thick 7440-31-5 Sn 200 strips Plastic box 1.07826.0001
Tin granulated for analysis (particle size about 7440-31-5 Sn 250 g HDPE bottle 1.07806.0250
4 mm) EMSURE® Reag. Ph Eur
1 kg HDPE bottle 1.07806.1000
www.merckmillipore.com/EMPOWER 87
Ordering information
Metals and metal oxides
Metals and metal oxides V-Z
Product CAS No. Chemical formula Content Packaging Ord. No.
V 250 g HDPE bottle 1.00824.0250
Vanadium(V) oxide EMPLURA® 1314-62-1 V2O5
1 kg HDPE bottle 1.00824.1000
Y Yttrium oxide 99+ for analysis EMSURE® 1314-36-9 Y2O3 25 g HDPE bottle 1.12412.0025
Z 1 kg HDPE bottle 1.08774.1000
Zinc dust particle size < 63 µm EMPLURA® 7440-66-6 Zn
50 kg Steel drum 1.08774.9050
Zinc coarse powder for analysis suitable for filling 250 g Metal can 1.08756.0250
of reductors, particle size about 0.3 – 1.5 mm 7440-66-6 Zn
(14 – 50 mesh ASTM) EMSURE® Reag. Ph Eur 1 kg Metal can 1.08756.1000
Zinc granular for analysis, particle size 500 g HDPE bottle 1.08780.0500
7440-66-6 Zn
about 3 – 8 mm EMSURE® ISO 1 kg HDPE bottle 1.08780.1000
Zinc powder for analysis particle size < 45 MYm 500 g Metal can 1.08789.0500
7440-66-6 Zn
EMSURE® 1 kg Metal can 1.08789.1000
Zinc oxide for analysis EMSURE® ACS, Reag. Ph Eur 1314-13-2 ZnO 1 kg HDPE bottle 1.08849.1000
EMSURE® EMPLURA®
88
Metals and metal oxides
For more details about our packaging, please see
‟Packaging and Safe Handling” on page 42
www.merckmillipore.com/EMPOWER 89
Salts
90
EMSURE® | EMPLURA® Salts. We offer an extensive range of inorganic salts
for qualitative and quantitative analysis. Each product is manufactured under
strictly controlled conditions at our facilities in Darmstadt, Germany, to
ensure outstanding analytical purity.
www.merckmillipore.com/EMPOWER 91
Ordering information
Salts
Salts A
Product CAS No. Chemical formula Content Packaging Ord. No.
Ammonium carbamate for analysis EMSURE® 1111-78-0 H2NCOONH4 500 g HDPE bottle 1.01134.0500
Ammonium fluoride for analysis EMSURE® ACS 12125-01-8 NH4F 1 kg HDPE bottle 1.01164.1000
EMSURE® EMPLURA®
92
Salts A–B
Product CAS No. Chemical formula Content Packaging Ord. No.
A 500 g HDPE bottle 1.01154.0500
di-Ammonium hydrogen citrate for analysis
3012-65-5 C6H8O7 * 2 NH3 2.5 kg HDPE bottle 1.01154.2500
EMSURE® ACS, Reag. Ph Eur
25 kg Fibre carton 1.01154.9025
Salts
Ammonium iron(II) sulfate hexahydrate for
7783-85-9 (NH4)2Fe(SO4)2 * 6 H2O
analysis EMSURE® ISO 5 kg HDPE bottle 1.03792.5000
Ammonium nitrate for analysis EMSURE® ACS 6484-52-2 NH4NO3 1 kg HDPE bottle 1.01188.1000
12 kg PE bucket 1.01201.9012
25 kg PE bucket 1.01200.9025
www.merckmillipore.com/EMPOWER 93
Ordering information
Salts
Salts B-C
Product CAS No. Chemical formula Content Packaging Ord. No.
Barium chloride dihydrate EMPLURA® 10326-27-9 BaCl2 * 2 H2O 1 kg HDPE bottle 1.01717.1000
Barium hydroxide octahydrate for analysis
12230-71-6 Ba(OH)2 * 8 H2O 500 g HDPE bottle 1.01737.0500
EMSURE® ACS, ISO, Reag. Ph Eur
Barium hydroxide octahydrate EMPLURA ®
12230-71-6 Ba(OH)2 * 8 H2O 1 kg HDPE bottle 1.01735.1000
C Cadmium acetate dihydrate for analysis EMSURE® 5743-04-4 (CH3COO)2Cd * 2 H2O 500 g HDPE bottle 1.02003.0500
EMSURE® EMPLURA®
94
Salts C-I
Product CAS No. Chemical formula Content Packaging Ord. No.
Chromium(III) potassium sulfate dodecahydrate
C 7788-99-0 KCr(SO4)2 * 12 H2O 250 g HDPE bottle 1.01036.0250
for analysis EMSURE® ACS, Reag. Ph Eur
Cobalt(II) acetate tetrahydrate for analysis
6147-53-1 (CH3COO)2Co * 4 H2O 100 g HDPE bottle 1.02529.0100
EMSURE® ACS
Salts
Copper(II) acetate monohydrate cryst. 500 g HDPE bottle 1.02710.0500
6046-93-1 (CH3COO)2Cu * H2O
EMPLURA® 50 kg Fibre carton 1.02710.9050
www.merckmillipore.com/EMPOWER 95
Ordering information
Salts
Salts I-M
Product CAS No. Chemical formula Content Packaging Ord. No.
25 kg PE drum 1.03965.9025
L Lead(II) acetate trihydrate for analysis EMSURE® 250 g HDPE bottle 1.07375.0250
6080-56-4 (CH3COO)2Pb * 3 H2O
ACS, Reag. Ph Eur 1 kg HDPE bottle 1.07375.1000
Lead(II) hydroxide acetate anhydrous for the (CH3COO)2Pb * 1 kg HDPE bottle 1.07414.1000
51404-69-4
analysis of sugar acc. to Horne EMSURE® Pb(OH)2 30 kg Fibre carton 1.07414.9030
Lead(II) nitrate for analysis EMSURE® ACS, 100 g HDPE bottle 1.07398.0100
10099-74-8 Pb(NO3)2
Reag. Ph Eur 1 kg HDPE bottle 1.07398.1000
Magnesium hydroxide carbonate for analysis ~ 4 MgCO3 * Mg(OH) 250 g HDPE bottle 1.05827.0250
12125-28-9
EMSURE® * 5 H2O 25 kg Fibre carton 1.05827.9025
EMSURE® EMPLURA®
96
Salts M–N
Product CAS No. Chemical formula Content Packaging Ord. No.
Mercury for analysis and for polarography 250 g HDPE bottle 1.04403.0250
7439-97-6 Hg
EMSURE® 1 kg HDPE bottle 1.04403.1000
Salts
Mercury(II) acetate for analysis EMSURE ACS,
® 50 g HDPE bottle 1.04410.0050
1600-27-7 Hg(CH3COO)2
Reag. Ph Eur 250 g HDPE bottle 1.04410.0250
www.merckmillipore.com/EMPOWER 97
Ordering information
Salts
Salts N-P
Product CAS No. Chemical formula Content Packaging Ord. No.
Potassium chloride for analysis (≤ 0.005 % Br) 500 g HDPE bottle 1.04933.0500
7447-40-7 KCl
EMSURE® ACS, ISO, Reag. Ph Eur 25 kg Fibre carton 1.04933.9025
Potassium chloride for analysis EMSURE® 7447-40-7 KCl 1 kg HDPE bottle 1.04936.1000
EMSURE® EMPLURA®
98
Salts P
Product CAS No. Chemical formula Content Packaging Ord. No.
Potassium disulfite for analysis EMSURE® 16731-55-8 K2S2O5 1 kg HDPE bottle 1.05057.1000
Salts
100 g HDPE bottle 1.04984.0100
Potassium hexacyanoferrate(II) trihydrate for analysis
14459-95-1 K4[Fe(CN)6] * 3 H2O 500 g HDPE bottle 1.04984.0500
EMSURE® ACS, ISO, Reag. Ph Eur
50 kg Fibre carton 1.04984.9050
Potassium hydrogen carbonate for analysis EMSURE® 500 g HDPE bottle 1.04854.0500
298-14-6 KHCO3
ACS 25 kg Fibre carton 1.04854.9025
Potassium hydrogen diiodate for analysis EMSURE® 13455-24-8 KH(IO3)2 50 g Glass bottle 1.04867.0050
www.merckmillipore.com/EMPOWER 99
Ordering information
Salts
Salts P
Product CAS No. Chemical formula Content Packaging Ord. No.
Potassium sulfide small lumps for analysis 250 g HDPE bottle 1.05134.0250
39365-88-3
EMSURE® 1 kg HDPE bottle 1.05134.1000
EMSURE® EMPLURA®
100
Salts S
Product CAS No. Chemical formula Content Packaging Ord. No.
Silver nitrate for analysis EMSURE® ACS, ISO, 100 g HDPE bottle 1.01512.0100
7761-88-8 AgNO3
Reag. Ph Eur 250 g HDPE bottle 1.01512.0250
Salts
50 kg Fibre carton 1.06267.9050
www.merckmillipore.com/EMPOWER 101
Ordering information
Salts
Salts S
Product CAS No. Chemical formula Content Packaging Ord. No.
Sodium formate for analysis EMSURE® ACS, 500 g HDPE bottle 1.06443.0500
141-53-7 HCOONa
Reag. Ph Eur 50 kg Fibre carton 1.06443.9050
25 kg PE drum 1.06329.9025
EMSURE® EMPLURA®
102
Salts S
Product CAS No. Chemical formula Content Packaging Ord. No.
Salts
Sodium hypochlorite solution (6 – 14 % active 2.5 l HDPE bottle 1.05614.2500
chlorine) EMPLURA® 25 l PE canister 1.05614.9025
100 g Glass bottle 1.06525.0100
Sodium iodate for analysis EMSURE® 7681-55-2 NaIO3
1 kg Glass bottle 1.06525.1000
www.merckmillipore.com/EMPOWER 103
Ordering information
Salts
Salts S
Product CAS No. Chemical formula Content Packaging Ord. No.
Sodium polyphosphate EMPLURA® (Graham’s salt) 10361-03-2 (NaPO3)n / n = ~ 25 5 kg HDPE bottle 1.06529.5000
Sodium salicylate for analysis EMSURE® 54-21-7 HOC6H4COONa 1 kg HDPE bottle 1.06601.1000
EMSURE® EMPLURA®
104
Salts S-Z
Product CAS No. Chemical formula Content Packaging Ord. No.
Salts
25 kg Fibre carton 1.07815.9025
Tin(II) chloride dihydrate for analysis EMSURE® 250 g Glass bottle 1.07814.0250
10025-69-1 SnCl2 * 2 H2O
ACS, ISO, Reag. Ph Eur 2.5 kg Glass bottle 1.07814.2500
Z Zinc acetate dihydrate for analysis EMSURE® 250 g HDPE bottle 1.08802.0250
5970-45-6 (CH3COO)2Zn * 2 H2O
ACS 1 kg HDPE bottle 1.08802.1000
Zinc iodide for analysis EMSURE® 10139-47-6 ZnI2 100 g Glass bottle 1.08828.0100
Zinc nitrate tetrahydrate for analysis EMSURE® 19154-63-3 Zn(NO3)2 * 4 H2O 1 kg HDPE bottle 1.08833.1000
106
EMSURE® | EMPARTA® | EMPLURA® Solvents. Distinguished by exceptional
quality and reliability, our solvents undergo strict controls and continuous
development to meet growing regulations. As your reliable, one-stop
supplier, we offer a complete solution, including solvents, documentation,
secure packaging and withdrawal systems.
www.merckmillipore.com/EMPOWER 107
Ordering information
Solvents
Solvents A–B
Product CAS No. Purity (GC) Evap. residue Water Content Packaging Ord. No.
Acetonitrile EMPLURA ®
75-05-8 ≥ 99.0 % ≤ 0.005 % ≤ 0.5 % 4 l Glass bottle 1.15500.4000
1-Butanol EMPLURA ®
71-36-3 ≥ 99.0 % ≤ 0.004 % ≤ 0.2 % 2.5 l HDPE bottle 8.22262.2500
Solvents
25 l Stainless steel drum 1.01974.6025
1 l Glass bottle 1.01849.1000
2.5 l Glass bottle 1.01849.2500
tert-Butyl methyl ether for analysis EMSURE® 1634-
≥ 99.5 % ≤ 0.001 % ≤ 0.03 % 4 l Glass bottle 1.01849.4000
ACS 04-4
5 l HDPE bottle 1.01849.5011
190 l Metal drum 1.01849.9190
2.5 l Glass bottle 1.01843.2500
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Ordering information
Solvents
Solvents C-D
Product CAS No. Purity (GC) Evap. residue Water Content Packaging Ord. No.
Cyclohexanone EMPLURA ®
108-94-1 ≥ 99.0 % ≤ 0.2 % 10 l Stainless steel drum 1.02888.6010
Dichloromethane EMPLURA® 75-09-2 ≥ 99.0 % ≤ 0.002 % ≤ 0.1 % 2.5 l Glass bottle 8.22271.2500
Diethanolamine for analysis EMSURE® 111-42-2 ≥ 99.5 % ≤ 0.25 % 1 l HDPE bottle 1.16205.1000
Solvents
N,N-Dimethylformamide EMPARTA ®
68-12-2 ≥ 99.5 % ≤ 0.001 % ≤ 0.1 % 2.5 l HDPE bottle 1.03034.2511
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Ordering information
Solvents
Solvents E
Product CAS No. Purity (GC) Evap. residue Water Content Packaging Ord. No.
Ethyl acetate for analysis EMPARTA® ACS 141-78-6 ≥ 99.5 % ≤ 0.003 % ≤ 0.2 % 4 l Glass bottle 1.07048.4000
25 l PE canister 1.09621.9028
Ethylene glycol EMPLURA® 107-21-1 ≥ 99.0 % ≤ 0.3 % 2.5 l HDPE bottle 1.00949.2500
25 l PE canister 1.00949.9028
Ethyl methyl ketone for analysis EMSURE® 2.5 l Glass bottle 1.09708.2500
78-93-3 ≥ 99.5 % ≤ 0.001 % ≤ 0.05 %
Solvents
ACS, Reag. Ph Eur 4 l Glass bottle 1.09708.4000
Formamide EMPLURA ®
75-12-7 ≥ 99.0 % ≤ 0.3 % 2.5 l HDPE bottle 1.04008.2500
25 l PE canister 1.04008.9025
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Ordering information
Solvents
Solvents H–I
Product CAS No. Purity (GC) Evap. residue Water Content Packaging Ord. No.
Isobutanol (Isobutyl alcohol) EMPLURA® 78-83-1 ≥ 98.5 % ≤ 0.05 % 25 l Stainless steel drum 1.00985.6025
Isobutyl methyl ketone EMPLURA® 108-10-1 ≥ 99.0 % 10 l Stainless steel drum 8.20820.6010
Solvents
1 l Glass bottle 1.04333.1000
Isohexane for analysis EMSURE® 92112-69-1 ≥ 95.0 % ≤ 10 mg/l ≤ 0.01 %
2.5 l Glass bottle 1.04333.2500
www.merckmillipore.com/EMPOWER 115
Ordering information
Solvents
Solvents M-P
Product CAS No. Purity (GC) Evap. residue Water Content Packaging Ord. No.
Methyl benzoate EMPLURA® 93-58-3 ≥ 99.0 % ≤ 0.1 % 2.5 l Glass bottle 1.06059.2500
25 l PE canister 8.06072.9025
n-Pentane for analysis EMSURE® 109-66-0 ≥ 99.0 % ≤ 0.001 % ≤ 0.01 % 2.5 l Glass bottle 1.07177.2500
Petroleum for analysis EMSURE® 64742-48-9 ≤ 0.01 % 2.5 l Glass bottle 1.09718.2500
Solvents
5 l Aluminum bottle 1.01769.5000
2-Propanol for analysis EMPARTA® ACS 67-63-0 ≥ 99.5 % ≤ 0.001 % ≤ 0.2 % 4 l Glass bottle 1.07022.4000
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Ordering information
Solvents
Solvents P-T
Product CAS No. Purity (GC) Evap. residue Water Content Packaging Ord. No.
Tetrahydrofuran EMPLURA ®
109-99-9 ≥ 99.0 % ≤ 0.1 % 25 l Stainless steel drum 1.08114.6025
Toluene for analysis EMPARTA® ACS 108-88-3 ≥ 99.5 % ≤ 0.001 % ≤ 0.03 % 2.5 l HDPE bottle 1.07019.2511
Toluene EMPLURA ®
108-88-3 ≥ 99.0 % 10 l Metal drum 1.08323.9011
1,1,2-Trichlorotrifluoroethane
76-13-1 ≥ 99.8 % ≤ 0.0005 % ≤ 0.005 % 2.5 l Glass bottle 1.08440.2500
for analysis EMSURE® Reag. Ph Eur
5 l PE canister 8.22341.5000
Triethanolamine EMPLURA® 102-71-6 ≤ 0.3 %
25 l PE canister 8.22341.9026
W 4 l Titripac 1.16754.4000
Solvents
Water for analysis EMSURE ®
7732-18-5 ≥ 99.0 % ≤ 1 mg/l ≤ 0.01 % 5 l HDPE bottle 1.16754.5000
10 l Titripac 1.16754.9010
p-Xylene for analysis EMSURE® ISO 106-42-3 ≥ 99.0 % ≤ 0.001 % ≤ 0.01 % 2.5 l Glass bottle 1.08684.2500
NEW Xylene (isomeric mixture) for analysis 2.5 l Glass bottle 1.08297.2500
1330-20-7 ≥ 98.5 % ≤ 0.002 % ≤ 0.03 %
EMSURE® ACS, ISO, Reag. Ph Eur 4 l Glass bottle 1.08297.4000
NEW Xylenes (isomeric mixture) for analysis 2.5 l Glass bottle 1.08633.2500
1330-20-7 ≥ 98.5 % ≤ 0.002 % ≤ 0.05 %
EMPARTA® ACS 4 l Glass bottle 1.08633.4000
Learn more
The following pages present a selection of our general application chemicals. For further products
and information, please visit www.merckmillipore.com/safety-products, or download our
Inorganic Reagents catalog on www.merckmillipore.com/inorganic-reagents-catalog.
120
For more information about cleaning
applications see page 122
121
Cleaning Applications
Extran® cleaning agents for reliable,
residue-free cleaning
For over 30 years, Extran® cleaning agents have enabled precise scientific
working procedures in labs and production facilities around the world. Thanks
to their thorough, residue-free cleaning, Extran® products ensure that every-
thing that comes into contact with chemicals or biological substances is free of
impurities – before and after use. Despite their exceptional cleaning strength,
Extran® products contain biodegradable ingredients that are free of toxins, so
they are gentle on the environment and on the health of laboratory staff.
Safer
Extran® cleaning agents not only supports your work, but also protects your health.
Our cleaning agents contain no chlorine or other toxic ingredients, and avoid all
scents and dyestuffs. Extran® products are also free of silicones, oxidants, and NTA
(nitrilotriacetic acid).
Greener
Extran® cleaning agents are produced from biodegradable active ingredients under strictly
controlled conditions, and fulfill the highest standards in environmental protection. In al-
most all cases, Extran® cleaning agents avoid the use of the toxic cleaning agent chromo-
sulfuric acid, which is still common on the market.
Simpler
For added certainty, we provide a practical and easy-to-use application aid to prove the
absence of nonionic surfactant residues by means of a photometric test. This helps you
prepare your cleaning validation, thus saving you time and costs.
Learn more
The following pages present a selection of Extran® cleaning agents. For further products and
information, please visit www.merckmillipore.com/extran, or download our Inorganic
Reagents catalog on www.merckmillipore.com/inorganic-reagents-catalog.
122
Your advantages
• Reliable, residue-free all-purpose cleaner
• Free from NTA thus safer for lab staff
• Free from scents and dyestuffs
• Free from chlorine or other toxic ingredients
• All active ingredients are biodegradable
• Validation support to prove the absence of surfactants
123
Cleaning Applications
Extran® cleaning agents for manual washing
Manual washing
Extran® MA cleaning agents for manual washing are universally applicable concentrates for the pro-
duction of water baths. Simply immerse equipment in the diluted solution for reliable, residue-free
cleaning.
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Dosing aid
For dependable and economical cleaning, the detergent must be dosed precisely: too little
cleans insufficiently, too much leaves residues. To ensure accurate dosing and safe handling
during manual cleaning, we offer 1 l bottles with reusable dosing aids. They can also be
ordered separately if required.
Extran MA 01 alkaline
®
1 l HDPE bottle 1.07555.1000
10 l PE canister 1.07555.9010
25 l PE canister 1.07555.9025
Extran MA 02 neutral
®
2.5 l HDPE bottle 1.07553.2500
10 l PE canister 1.07553.9010
25 l PE canister 1.07553.9025
10 l PE canister 1.40000.9010
25 l PE canister 1.40000.9025
Accessories Ord. No.
125
Cleaning Applications
Extran® cleaning agents for automated cleaning
Automated cleaning
Extran® AP automated cleaning agents were created and tested in cooperation with leading ap-
pliance manufacturers especially for use in laboratory washing machines. The products ensure
effective cleaning, while significantly limiting foam formation and minimizing residues.
Extran AP 12 alkaline
®
2 kg HDPE bottle 1.07563.2000
10 kg PE bucket 1.07563.9010
25 kg PE drum 1.07563.9025
10 l PE canister 1.40006.9010
25 l PE canister 1.40006.9025
Extran® AP 21 liquid, acidic with phosphoric acid Content Packaging Ord. No.
10 l PE canister 1.07559.9010
25 l PE canister 1.07559.9025
Extran® AP 22 liquid, acidic with citric acid Content Packaging Ord. No.
10 l PE canister 1.07561.9010
25 l PE canister 1.07561.9025
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Universal adapter
Larger volumes of detergent, such as 10 and 25 l cans, are typically used for
cleaning equipment. The cans should be connected tightly to washing machines
to prevent spraying and potential health risks. Since various types of machines
are used around the world with different connection systems, we have designed
a universal adapter that fits them all. It enables secure connection between
different machines and detergent cans to avoid spills, protect personnel and
prevent external contamination.
Your advantages
• Safety: Secure connection between cans and washing machines
prevents spills and protects users
• Reliability: External (airborne) contamination is avoided, thus analytical
results are unaffected
127
Absorbents for spilled liquids
Chemizorb® absorbents for safe and
swift absorption
Accidents happen in every lab. With Chemizorb® absorbents, you can remove aggressive or
unpleasant spilled liquids quickly and safely. Chemizorb® absorbents consist of porous mineral
or synthetic copolymers that are chemically inert, and are capable of taking up 100 to 400 per-
cent of their own weight in liquid material.
Learn more
For further products and information, please visit www.merckmillipore.com/chemizorb,
or download our Inorganic Reagents catalog on
www.merckmillipore.com/inorganic-reagents-catalog.
128
The »all-rounders«
Chemizorb® powder and granule absorbents are insoluble in water and in
all other media that are liquid at room temperature. These ‟all-rounders”
are suitable for removing nearly all kinds of aqueous spills, such as acids,
alkalis and solvents.
20 kg PE drum 1.01568.9021
The »specialists«
We offer specific absorbents for alkalis, acids, and hydrofluoric acid. Each contains special carrier
materials and water-soluble neutralizers, as well as pH indicators that help you visually monitor the
neutralization of the spilled chemicals. Please note that the reaction may generate heat and gas.
Chemizorb® OH- Content Packaging Ord. No.
Chemizorb® H+ absorbent and neutralizer for spilled 500 g HDPE bottle 1.02491.0500
acids, with indicator 2.5 kg Bucket, plastic 1.02491.2500
1 set consisting of: 500 g of reagent 1, 100 ml of reagent 2, one small tub, one large disposal can, protective gloves, …
Chemizorb® Hg reagents refill pack for Ord. No. 1.12576.0001 1 set PE can 1.01569.0001
129
Drying Agents
Safe, environmentally friendly desiccants
Our drying agents are not only effective and easy to use, but also support sus
tainability and safety in the lab. For example, we offer silica gels with or without
orange or brown indicators as an alternative to silica gel with blue indicator, which
is known to be toxic and carcinogenic due to the presence of cobalt chloride.
Your advantages
• Reliability: Thorough drying minimizes the effects of moisture on
products to maintain their original condition
• Convenience: Ease of use saves time and increases lab productivity
• Cost efficiency: Effective drying increases the longevity of your
products and avoids costly damages
130
Safety information
The use of drying agents carries potential risks. These are listed below for your safety.
• Acidic and basic drying agents can be corrosive
• Magnesium perchlorate can be explosive
• Sodium and potassium can be explosive when in contact with certain organic substances,
water or chlorinated hydrocarbons
• Drying agents that develop hydrogen during the drying process must be used in a well-ventilated
fume chamber
Learn more
The following pages present a selection of the most important drying agents.
For further products, information and advice, please visit
www.merckmillipore.com/safety-products, or download our
Inorganic Reagents catalog on
www.merckmillipore.com/inorganic-reagents-catalog.
131
Drying Agents
Safe, environmentally friendly desiccants
Desiccant sachet 3 g silica gel with humidity indicator 100 units Metal can 1.03803.0001
(orange gel) sachet: 4 x 7 cm 1000 units Fibre carton 1.03803.0002
Desiccant sachets
132
Molecular
sieves
Molecular sieve 0.4 nm rods ~ 1.6 mm (1/16") 1318-02-1 1 kg HDPE bottle 1.05743.1000
1) M
olecular sieves with 0.3 nm bead form (105704) and with indicator brown gel (105734) are suitable for use in
Karl Fischer titrators.
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Absorption and Filtration
Dependable, flexible and ecological
Absorption, adsorption, filtration and clarification are among the most important
applications in laboratories. Our product portfolio includes a wide variety of
reagents and materials for these purposes, such as activated charcoal, graphite,
molecular sieves and sea sand.
Your advantages
• Reliability: Premium reagents and materials ensure highly reliable take
up and purification of a wide range of substances
• Convenience: Comprehensive portfolio allows easy ordering – from
one trusted supplier
• Cost efficiency: A variety of pack sizes available to suit individual needs
134
Nature in the lab
Many of the absorption and adsorption reagents and filter materials we offer for use in laborato-
ries are produced from natural resources that are not harmful to the environment. One example
is our activated charcoal, which is gained from pinewood or mineral coal. It is used in numerous
applications, such as for adsorption, de-colorization and purification of gases and liquids, or as
a carrier for catalysts. Another product that promotes sustainability is calcium oxide, which is
extracted from natural marble, and used as a CO2 absorbent among other applications.
Learn more
The following pages present a selection of the most important absorption,
adsorption and filtration products. For further solutions, information and
advice, please visit
www.merckmillipore.com/absorption-filtration, or download our
Inorganic Reagents catalog on
www.merckmillipore.com/inorganic-reagents-catalog.
135
Absorption and Filtration
Dependable, flexible and ecological
Calcium oxide from marble small lumps ~ 3 – 20 mm 1305-78-8 1 kg HDPE bottle 1.02109.1000
Charcoal activated granular about 1.5 mm extra pure 7440-44-0 1 kg Plastic bag 1.02514.1000
Charcoal
136
Glass wool
Sea sand purified by acid and calcined for 7631-86-9 1 kg HDPE bottle 1.07712.1000
analysis 5 kg HDPE bottle 1.07712.5000
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Merck KGaA
Frankfurter Strasse 250
64293 Darmstadt, Germany
www.merckmillipore.com/empower
www.SigmaAldrich.com/empower
Merck, the vibrant M, Chemizorb, EMPARTA, EMPLURA, EMSURE, Extran, Perhydrol, SICAPENT are trademarks of Merck KGaA, Darmstadt, Germany or its affiliates. All other
trademarks are the property of their respective owners. Detailed information on trademarks is available via publicly accessible resources.
Copyright © 2017 Merck KGaA, Darmstadt, Germany and/or its affiliates. All Rights Reserved.
We provide information and advice to our customers on application technologies and regulatory matters to the best of our knowledge and ability,
but without obligation or liability. Existing laws and regulations are to be observed in all cases by our customers. This also applies in respect to any
rights of third parties. Our information and advice do not relieve our customers of their own responsibility for checking the suitability of our products
for the envisaged purpose.
PB8647EN00 11/2017