Transmutation

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Nuclear Transmutation

Nuclear transmutation is artificial method of transforming one element/isotope into


another element/isotope, without which the field of radiochemistry is limited to only
natural radioactivity. Stable atoms can be transformed into radioactive atoms by
bombardment with high speed particles. In the early experimental studies, high-speed
alpha particles from 214Bi (known as radium C) were used.

In 1919, Lord Rutherford and his collaborators in the Cavendish Laboratory at


Cambridge carried out the first nuclear reaction between alpha particles and nitrogen that
is given by

14
7 N + 24 He ⎯⎯
→ 178 O + 11H

In this reaction, a nitrogen nucleus reacted with a high speed helium nucleus to form two
new nuclei a 17O and a proton. This reaction demonstrated the possibility of converting
one element into another – a long cherished dream of alchemists. The natural radioactive
decay and nuclear transmutation both produce new atoms but with one difference; the
latter involves bombarding the nuclei in question with a high-speed particle.

The above reaction can be abbreviated as 147 N (α , p ) 178 O . The reacting nucleus is written
first and then the parenthesis followed by the resulting nucleus. The parenthesis contains
the reacting particle and the ejecting particle, with the reacting particle first written
followed by the comma and then the ejecting particle.

Example

Write balanced nuclear reactions for

(a) 106
46 Pd (α , p ) 109
47 Ag

(b) 56
26 Fe( d , α ) 25
54
Mn

Answer

(a) The abbreviation tells us that when a palladium-106 is bombarded with an alpha
particle, it produces a silver-109 nucleus with ejection of a proton. Therefore, the nuclear
equation for this reaction is

106
46 Pd + 24 He ⎯⎯
→ 109
47 Ag + 1 p
1

Check: the sum of atomic numbers and mass numbers are the same on both sides of the
equation, as they should be.

1
(b) In this example, the bombarding particle is d (deuterium, 21H), which is an isotope of
hydrogen with charge 1 and mass 2. The ejecting particle is alpha (42 α) with charge 2
and mass 4. Hence, the balanced equation for this nuclear reaction is

56
26 Fe + 12 H ⎯⎯
→ 25
54
Mn + 24α

Check: the sum of atomic numbers and mass numbers are the same on both sides of the
equation, as they should be.

There is, however, one requirement in this technique. The bombarding particle must
possess high kinetic energy (high velocity), otherwise it will not split the target nucleus.
The particles are accelerated in a device known as particle accelerator. There are two
kinds of particle accelerators; (a) cyclotron, and (b) linear accelerator. You may refer to
any general chemistry textbook for further information on particle accelerators.

The Nobel Prize in Chemistry 1908


"for his investigations into the disintegration of the elements, and the chemistry of
radioactive substances"

Ernest Rutherford

Taken from http://nobelprize.org/nobel_prizes/chemistry/laureates/1908/.

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