Canadian Environmental Quality Guidelines (2003)
Canadian Environmental Quality Guidelines (2003)
Canadian Environmental Quality Guidelines (2003)
December 2003
Azinphos-methyl 20
Barium 1000 750 500 2000 2000
Bendiocarb 40
Benz (a)anthracene [See Polycyclic aromatic hydrocarbons
(PAHs)]
Benzene 5 370 110 0.05 0.5 5 5
Continued.
Canadian Environmental Quality Guidelines SUMMARY
TABLE
Carbofuran 90 1.8 45
Carbon monoxide 1 h: 15 000–35 000
8 h: 6000–20 000
1 a: no EQG j
Carbon tetrachloride [See Halogenated methanes,
Tetrachloromethane]
Cerium–141 100 Bq·L-1 k
Cerium–144 20 Bq·L-1 k
Cesium–134 7 Bq·L-1 k
Cesium–137 10 Bq·L-1 k
Chemical characteristics Narrative
Chloramines [See Reactive chlorine species]
Chlordane No EQG j No EQG j 4.50 8.87 2.26 4.79
2
Canadian Environmental Quality Guidelines SUMMARY
TABLE
Chlorinated ethanes
1,1-Dichloroethane 0.1y 5y 50y 50y
1,2-Dichloroethane 5 (IMAC) 100 5ff 0.1y 5y 50y 50y
1,1,1-Trichloroethane 0.1y 5y 50y 50y
1,1,2-Trichloroethane 0.1y 5y 50y 50y
1,1,2,2-Tetrachlorethane 0.1y 5y 50y 50y
Chlorinated ethenes
Monochloroethene (Vinyl chloride) 2
1,1-Dichloroethene (Dichloroethylene) 14 0.1y 5y 50y 50y
1,2-Dichloroethene 0.1y
5 y
50y
50y
ff
1,1,2-Trichloroethene (Trichloroethylene, TCE) 50 21 50 0.1 3 31 31
1,1,2,2-Tetrachloroethene (Tetrachloroethylene, PCE) 30 111 0.1 0.2 0.5 0.6
3
Canadian Environmental Quality Guidelines SUMMARY
TABLE
Coliphages Narrative
Colour 15 TCUm Narrative Narrative Narrative
Conductivity 2y [dS/m] 2y [dS/m] 4y [dS/m] 4y [dS/m]
ff
Copper 1000 2–4 200–1000 500–5000 35 700 197 000 18 700 108 000 63 63 91 91
Cyanazine 10 (IMAC) 2.0 0.5 10
Diazinon 20
Dibenz (a,h)anthracene [See Polycyclic
aromatic hydrocarbons (PAHs)]
Dibromochloromethane [See Halogenated methanes]
Di-n-butyl phthalate [See Phthalate esters]
4
Canadian Environmental Quality Guidelines SUMMARY
Dichloroethane [See Chlorinated ethanes] TABLE
Continued.
5
Chapter 1 Chapter 2 Chapter 3 Chapter 4 Chapter 5 Chapter 6 Chapter 7 Chapter 8
Water:
Recreation and Tissue Residue
Air Water: Community aesthetics Water: Aquatic life Water: Agriculture Sediment Soil
Parameter Freshwater Marine Irrigation Livestock Freshwater Marine
-1
1 h, 8 h or 24
-3
h, 1 aa MAC, IMAC
-1
b
AO c-1 -1 -1 -1 -
ISQG-1d PELe-1 ISQG-1d PELe-1 Agri.f-1 Res./Park
-1
g
Comm.-1h Industrial
-1
i
(µg·kg
(µg·m ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L (µg·kg ) (µg·kg ) (µg·kg ) (µg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) diet ww)
1
Dichloroethene [See Chlorinated ethenes] )
Dichloroethylene [See Chlorinated ethenes,
1,1-Dichloroethene]
Dichloromethane [See Halogenated methanes]
Dichlorophenols [See Chlorinated phenols]
2,4-Dichlorophenoxyacetic acid (2,4-D) [See also Phenoxy 100 (IMAC) See also Phenoxy See also Phenoxy
herbicides] herbicides o herbicides o
Enterococci Narrative
Escherichia coli [See Coliforms, fecal]
Ethylbenzene 2.4 90 25 2.4 0.1 1.2 20 20
Ethylene glycol [See Glycols]
Fecal coliforms [See Coliforms, fecal]
5
Chapter 1 Chapter 2 Chapter 3 Chapter 4 Chapter 5 Chapter 6 Chapter 7 Chapter 8
Water:
Recreation and Tissue Residue
Air Water: Community aesthetics Water: Aquatic life Water: Agriculture Sediment Soil
Parameter Freshwater Marine Irrigation Livestock Freshwater Marine
a b c d e d -1
1 h, 8 h or 24
-3
h, 1 a MAC, IMAC
-1
AO -1 ISQG-1 PEL -1 ISQG-1 PELe -1 Agri.-1f Res./Park
-1
g
Comm.-1h Industrial
-1
i
(µg·kg
-1 -1 -1 -1
(µg·m ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·kg ) (µg·kg ) (µg·kg ) (µg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) diet ww)
Glycols
Ethylene glycol 192 000 960 960 960 960
Diethylene gly col
Propylene glycol 500 000
Glyphosate 280 (IMAC) 65 280ff
Methoxychlor 900
Methyl bromide [See Halogenated methanes,
Monobromomethane]
Methyl chloride [See Halogenated methanes,
Monochloromethane]
2-Methyl-4-chloro phenoxy acetic acid [See MCPA]
Methylene chloride [See Halogenated methanes,
Dichloromethane]
Organotins
Tributyltin 0.008 0.001 250ff
Tricyclohexyltin 250ff
Triphenyltin 0.022 820ff
Oxygen, dissolved 5500–9500 >8000
Ozone 1 h: 100–300
24 h: 30–50
1 a: 30
PAHs [See Polycyclic aromatic hydrocarbons (PAHs)]
Paraquat (as dichloride) 10 (IMAC)
Parathion 50
Particulate matter <2.5 µm (PM <2.5) 1 h: no EQG j
24 h: 15
1 a: no EQG j
Particulate matter <10 µm (PM <10) 1 h: no EQG j
24 h: 25
1 a: no EQG j
8
Chapter 1 Chapter 2 Chapter 3 Chapter 4 Chapter 5 Chapter 6 Chapter 7 Chapter 8
Water:
Recreation and Tissue Residue
Air Water: Community aesthetics Water: Aquatic life Water: Agriculture Sediment Soil
Parameter Freshwater Marine Irrigation Livestock Freshwater Marine
a b c d e d -1
1 h, 8 h or 24
-3
h, 1 a MAC, IMAC
-1
AO -1 ISQG-1 PEL -1 ISQG-1 PELe -1 Agri.-1f Res./Park
-1
g
Comm.-1h Industrial
-1
i
(µg·kg
-1 -1 -1 -1
(µg·m ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·kg ) (µg·kg ) (µg·kg ) (µg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) diet ww)
Phthalic acid esters (each) 30y
Phthalate esters
Di-n-butyl phthalate 19
Di(2-ethylhexyl) phthalate 16
Di-n-octyl phthalate
Polychlorinated dibenzo-p-dioxins/dibenz o furans No EQGj No EQGj 0.85 ng 21.5 ng 0.85 ng 21.5 ng 4 ng 4 ng TEQ.kg- 4 ng TEQ.kg- 4 ng mammalian:
-1
(PCDD/Fs) TEQ.kg-1 TEQ.kg-1 TEQ.kg-1 TEQ.kg-1 TEQ.kg -1 1 1
TEQ.kg-1 0.71 ng TEQ·kg
s,t
dws,w dws,w dws,w dws,w diet ww
avian: 4.75 ng
-1
TEQ·kg diet
s,u
ww
Polycyclic aromatic hydrocarbons (PAHs)
Acenaphthene 5.8 6.71 88.9 6.71 88.9
Acenaphthylene 5.87 128 5.87 128
Acridine 4.4
Anthracene 0.012 46.9 245 46.9 245
Benzo(a)anthracene 0.018 31.7 385 74.8 693 0.1y 1y 10y 10 y
Benzo(a)pyrene 0.01 0.015 31.9 782 88.8 763 0.1 0.7 0.7 0.7
Benzo(b)fluoranthene 0.1y 1y 10y 10y
Benzo(k)fluoranthene 0.1y 1y 10y 10y
Chrysene 57.1 862 108 846
Dibenz (a,h)anthracene 6.22 135 6.22 135 0.1y 1y 10y 10y
Fluoranthene 0.04 111 2355 113 1494
Fluorene 3.0 21.2 144 21.2 144
Indeno(1,2,3-c,d)pyrene 0.1y 1y 10y 10y
2-Methylnaphthalene 20.2 201 20.2 201
Naphthalene 1.1 1.4 34.6 391 34.6 391 0.1 0.6 22 22
Phenanthrene 0.4 41.9 515 86.7 544 0.1y 5y 50y 50y
Pyrene 0.025 53.0 875 153 1398 0.1y 10y 100y 100y
Quinoline 3.4 0.1y
Continued.
9
Pyrene [See Polycyclic aromatic hydrocarbons (PAHs)]
Continued.
1
0
Chapter 1 Chapter 2 Chapter 3 Chapter 4 Chapter 5 Chapter 6 Chapter 7 Chapter 8
Water:
Recreation and Tissue Residue
Air Water: Community aesthetics Water: Aquatic life Water: Agriculture Sediment Soil
Parameter Freshwater Marine Irrigation Livestock Freshwater Marine
-1
1 h, 8 h or 24
-3
h, 1 aa MAC, IMAC
-1
b
AO c-1 -1 -1 -1 -
ISQG-1d PELe-1 ISQG-1d PELe-1 Agri.f-1 Res./Park
-1
g
Comm.-1h Industrial
-1
i
(µg·kg
(µg·m ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L ) (µg·L (µg·kg ) (µg·kg ) (µg·kg ) (µg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) (mg·kg ) diet ww)
1
Quinoline [See Polycyclic aromatic hydrocarbons (PAHs)] )
Radium–224 2 Bq·L-1 k
Radium–226 0.6 Bq·L-1 k
Radium–228 0.5 Bq·L-1 k
Reactive chlorine species (Hypochlorous acid and 0.5 0.5
monochloramine)
Chloramines 3000
10
Chapter 1 Chapter 2 Chapter 3 Chapter 4 Chapter 5 Chapter 6 Chapter 7 Chapter 8
Water:
Recreation and Tissue Residue
Air Water: Community aesthetics Water: Aquatic life Water: Agriculture Sediment Soil
Parameter Freshwater Marine Irrigation Livestock Freshwater Marine
1 h, 8 h or 24 h, 1 aa MAC, IMAC b AOc
ISQG d
PELe
ISQG d
PELe Agri.f Res./Park g Comm.h Industrial i -1
-3 (µg·kg
(µg·m ) -1
(µg·L ) (µg·L )
-1
(µg·L )
-1
(µg·L )
-1
(µg·L )
-1
(µg·L
- -1
(µg·kg )
-1
(µg·kg )
-1
(µg·kg )
-1
(µg·kg )
-1
(mg·kg )
-1 -1
(mg·kg ) (mg·kg )
-1
(mg·kg ) diet ww)
1
)
Thallium 0.8 1 1 1 1
Thiophene 0.1y
Thorium–228 2 Bq·L-1 k
Thorium–230 0.4 Bq·L-1 k
Thorium–232 0.1 Bq·L-1 k
Thorium–234 20 Bq·L-1 k
Zinc–65 40 Bq·L-1 k
Zirconium–95 100 Bq·L-1 k
a
y
1 h, 8 h or 24 h, 1 a: 1-hour, 8 -hour, or 24 -hour, and 1-year averaging times. For hydrogen fluoride, a 7 -day averaging time was used instead of annual averaging. This interim remediation criterion (CCME1991) was put in place prior to development of the soil protocol (CCME1996). The criterion should be used until
b
MAC: Maximum acceptable concentration. IMAC: Interim maximum acceptable concentration. The guideline listed is the MAC unless otherwise noted in superseded by a full guideline. For more information consult Chapter 7:Soil, especially Table 1 “Canadian Soil Quality Guidelines” and Table 2 “Historical record of
c
parentheses. interim remediation criteria for soil and soil quality guidelines”.
z
AO: Aesthet ic objective. Hot water soluble boron.
d
aa
ISQG: Interim sediment quality guideline. Guidelines are for each chemical and include:
e
PEL: Probable effect level. 2,4 -dimethylphenol
f
Agri.: Agricultural land uses. 2,4 -dinitrophenol
g 2-methyl 4,6-dinitrophenol
Res./Park: Residential/Parkland uses. nitrophenol (2-,4-)
h
Comm.: Commercial land uses. cresol
iIndustrial: Industrial land uses. bb
Aliphatic chlorinated hydrocarbons include:
j
No EQG: No environmental quality guideline is recommended; see environmental quality guidelines for other media where chloroform
appropriate. dichloroethane (1,1 - 1,2-), dichloroethene (1,1 - 1,2-)
k
Bq·L-1: Becquerels per litre. dichloromethane
l
The tissue residue guideline is for total DDT, which is equal to DDD + DDE + DDT. 1,2 -dichloropropane, 1,2-dichloropropene (cis and trans)
m 1,1,2,2 -tetrachloroethane, carbon tetrachloride
TCU: True colour units.
n trichloroethane (1,1,1 - 1,1,2-)
No units for cc
Expressed on a TEQ basis using NP TEFs, see nonylphenol factsheet in Table 2.
pH. dd
o -1 Provisional; use of equillibrium partitionin g approach.
The aquatic life guideline of 4.0 µg·L for phenoxy herbicides is based on data for ester formulations of 2,4 -dicholorophenoxyacetic ee
Expressed on a TEQ basis using NP TEFs; assumes 1% TOC.
p
acid.
ff
NTU: Nephelometric turbidity units. No fact sheet created. For more information on this guideline, please refer to Canadian Water Quality Guidelines (CCREM 1987), available electronically on
q
A health-based guideline for aluminium in drinking water has not been established. However, water treatment plants using aluminium -based coagulants the accompanying CEQG CD.
should gg
May not protect fully high trophic level fish, and may not prevent accumulation of methylmercury in aquatic life, therefore, may not protect wildlife that consume
optimize their operations to reduce residual aluminium levels in treated water to the lowest extent possible as a precautionary measure. Operational guidance values of
-1 -1 aquatic life; see factsheet for details. Consult also the appropriate Canadian Tissue Residue Guideline for the Protection of Wildlife Consumers of Aquatic Biota.
less than 100 g·L total aluminium for conventional treatment plants and less than 200 g·L total aluminium for other types of treatment systems are hh
recommended. Any attempt to minimize aluminium residuals must not compromise the effectiveness of disinfection processes or interfere with the removal of For protection from direct toxic effects; the guidelines do not consider indirect effects due to eutrophication.
disinfection by -product precursors.
r
Guideline modified / released: April 1999
s
Guideline modified / released: March 2001
t
Values are expressed as toxic equivalency (TEQ) units, based on WHO 1998 TEF v alues for
mammals.
u
Values are expressed as toxic equivalency (TEQ) units, based on WHO 1998 TEF values for
birds.
v -1
Sediment quality guideline for Aroclor 1254: Provisional; 1% TOC; adoption of severe effect level of 34 g·g TOC from Ontario (Persaud et al.
1993).
w
Values are expressed as toxic equivalency (TEQ) units, based on WHO 1998 TEF values for fish.
x
Sediment quality guideline for Toxaphene: Provisional; 1% TOC; adoption of the chronic sediment quality criterion of 0.01 g·g-1 TOC of the New York
State
Department of Environmental Conservation (NYSDEC 1994).