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    Avio ICP-OES Product Line

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    NguyễnHoàngDanh
    The document discusses PerkinElmer's history in ICP-OES instrumentation from 1979 to present, focusing on their recent Avio 200 and Avio 500 product lines which feature flat plate induction technology for lower argon consumption, a vertical torch for easy maintenance, and software like Universal Data Acquisition for enhanced flexibility. Key benefits of the Avio series include improved plasma robustness, lower detection limits, and faster analysis times enabled by innovations like SmartRinse for efficient sample washout.

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    Avio ICP-OES Product Line

    Uploaded by

    NguyễnHoàngDanh
    56 views41 pages
    The document discusses PerkinElmer's history in ICP-OES instrumentation from 1979 to present, focusing on their recent Avio 200 and Avio 500 product lines which feature flat plate induction technology for lower argon consumption, a vertical torch for easy maintenance, and software like Universal Data Acquisition for enhanced flexibility. Key benefits of the Avio series include improved plasma robustness, lower detection limits, and faster analysis times enabled by innovations like SmartRinse for efficient sample washout.

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    The document discusses PerkinElmer's history in ICP-OES instrumentation from 1979 to present, focusing on their recent Avio 200 and Avio 500 product lines which feature flat plate induction technology for lower argon consumption, a vertical torch for easy maintenance, and software like Universal Data Acquisition for enhanced flexibility. Key benefits of the Avio series include improved plasma robustness, lower detection limits, and faster analysis times enabled by innovations like SmartRinse for efficient sample washout.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    56 views41 pages

    Avio ICP-OES Product Line

    Uploaded by

    NguyễnHoàngDanh
    The document discusses PerkinElmer's history in ICP-OES instrumentation from 1979 to present, focusing on their recent Avio 200 and Avio 500 product lines which feature flat plate induction technology for lower argon consumption, a vertical torch for easy maintenance, and software like Universal Data Acquisition for enhanced flexibility. Key benefits of the Avio series include improved plasma robustness, lower detection limits, and faster analysis times enabled by innovations like SmartRinse for efficient sample washout.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 41

    Avio ICP-OES product line

    Helmut Ernstberger
    13.6.2019, Budapest Seminar
    PerkinElmer long history in ICP-OES

    1979 – PerkinElmer Introduces the ICP 5000

    1984 – PerkinElmer Plasma II Introduced

    1987 – PerkinElmer introduces the Plasma40

    1993 – PerkinElmer introduces Optima 3000

    1995 – Optima 3000DV Introduced

    2001 – Optima 4300 and Optima 2000

    2005 – Optima 5300 and Optima 2100

    2007 –Optima 7300 and Optima 7000

    2011 –Optima 8x00 Family

    2016 –Avio 200 2017 –Avio 500


    PerkinElmer Continues to Lead the Market for ICP-OES

    ICP-OES Vendor Share 2017


    PerkinElmer

    13% Competitor 1
    2%
    26% Competitor 2
    4%
    Competitor 3
    5% PerkinElmer Competitor 4
    6% Competitor 5

    16% Competitor 6
    7%
    Competitor 7
    7%
    14% Competitor 8

    Others

    Source: SDI Global Assessment Report 2018


    New AVIO series
    • Avio 200, launched • Avio 500, launched
    July 2016 July 2017

    Scanning array ICP-OES Simultaneous ICP-OES


    What do Avio 200 and 500 have in common?

    • Flat Plate technology for low argon consumption


    • 40 MHz RF generator for robustness and stability
    • PlasmaShear
    • Vertical torch
    • Easty to use torch mount
    • Dual View
    • Viewing height selectable element by element
    • PlasmaCam
    • Interference correction capabilities IEC, MSF
    • Syngistix Software
    • RoHS compliant
    • 4-channel, 12-roller peristaltic pump
    • Compact size
    Argon saving: Flat Plate Technology

    Patented Flat Induction


    Plates operate at 40 –
    60% of the Argon flow
    of helical designs

    • Avio and Optima platforms are the only ICP-OES systems capable of
    running a stable plasma at 8 L/min plasma gas
    • Same robust plasma conditions for all samples
    • Full power range allows the analysis of all sample types
    • No helical load coil needed: eliminates maintenance, consumables
    cost, downtime and leakage risk
    Load coil vs Flat plate – Performance evaluation

    • Side by side comparison


    ◦ Optima 8300 vs Optima 4300 DV
    ◦ Difference: RF generator / Flat Plate
    ◦ Same sample introduction system: GemCone / Cyclonic

    • Matrix Robustness according to Mermet’s criteria for Mg


    ◦ Mg II (280.270 nm) / Mg I (285.213 nm) > 8 for robust plasma
    ◦ Vary Neb flow and plasma power
    Plasma parameters Load Coil Flat Plate
    Plasma Power [W] varied varied
    Plasma gas flow [L/min] 15 8
    Aux. gas flow [L/min] 0.2 0.2
    Neb. gas flow [L/min] varied varied
    • High Matrix Samples
    ◦ Digested coal fly ash: NIST 1633c
    ◦ Mg in digest = 10 mg/L
    Load coil vs Flat plate - Plasma robustness

    robust

    robust

    Better efficiency of energy transfer for Flat Plate


    Load coil vs Flat plate - Sensitivity

    Higher sensitivity for Flat Plate


    Load coil vs Flat plate – Method detection limits

    • MDLs determined according to EPA 200.7


    • Axial view
    • Matrix: Aqua regia, 1:5 diluted
    Wavelength Flat Plate MDL Improvement factor
    Element [nm] [µg/L] over load coil
    As 188.979 8.2 1.5
    Co 228.616 1.6 19
    Cr 267.716 1.5 23
    Cu 324.752 2.7 10
    Mn 257.610 2.7 7
    Ni 231.604 0.6 23
    Pb 220.353 2.1 9
    Zn 213.857 0.5 44

    Flat Plate detection limits on average 17 times lower


    Source: University of Jyväskylä, with permission
    Saving Argon: PlasmaShear

    PlasmaShear exclusive to
    PerkinElmer
    • Improved performance
    • Efficient removal of the tail plume
    without the need of argon
    • Eliminates self-absorption
    • Extended linear range
    • Matrix independent
    • Increase accuracy
    • Reduces maintenance time
    Vertical Torch Configuration

    New Vertical Torch Configuration


    • Easy-to-use torch mount with fewer parts
    ◦ No tools required
    ◦ One-handed removal
    ◦ Quick-change components
    • Easy and cost-effective maintenance
    ◦ Removable injector independent of torch
    • Lockable depth position for repeatable torch
    insertion
    • Adjustable, even while the ICP is running, to
    ensure optimum results
    • Solid design
    • Accommodates a vast array of sample introduction accessories that make
    running sample analysis simple, regardless of sample matrix
    Dual View: the Best of Both Worlds –
    No Compromise

    Designers of the first Dual View ICP-OES (Optima 3000 in 1995)

    • Provides analysis of both low-level and high-level elements in one method


    • Sub-ppb to % level concentration range for all elements across UV and Vis
    • Fully-selectable radial viewing height and axial sampling depth
    • Delivers flexibility for different sensitivities; i.e. Na and K
    • Allows regulatory methods to be run at
    prescribed wavelength
    • Removes EIE interferences
    • 1500W in both axial and radial modes This saves you
    time and money.
    Lower Cost and Time Savings
    PlasmaCam Viewing Camera

    • Real-time plasma viewing


    • Verify sample introduction
    components during analysis
    • Simplifies method development
    • Perform remote diagnostics
    • Ensures maximum up time

    Industry’s first integrated color camera for continuous plasma


    viewing during analysis
    Adjustable viewing height can eliminate EIE Effects
    Avio 500 ICP-OES Features

    • Simultaneous instrument
    • High performance optical system
    • Universal Data Acquisition
    • Argon Quick Change
    • SmartRinse
    Analysis Speed: Optics & Detector

    • Unique optical system & detector allow simultaneous reading


    of both the visible and UV regions of the spectrum
    • Requires thermally stable optical bench
    Avio 500 Performance: Unsurpassed stability
    Precision over 9 hours of continuous analysis

    Meinhard Type K1 and standard baffled cyclonic spray chamber

    9-hour stability run results in <1% RSD


    Universal Data Acquisition - UDA

    • UDA gathers data for all 6300+ wavelengths available on both


    detectors for each sample
    • Simple click to turn on
    • Uses approx 80kB
    • No time penalty
    • Live concentration results on screen for every element

    Benefits
    • No need to re-analyse samples for additional elements/ to
    confirm results
    • Saves analyses time (and money) during method development,
    all of this can be done offline (not using gas, sample.)
    UDA for Quantitative Analysis Scenario…
    Enter calibration concentrations and reprocess data
    Quantitation with UDA standard sets

    • UDA Standard set


    ◦ Covers a wide element range (69 elements)
    ◦ Include UDA standards in run
    • ALL wavelengths info is collected with UDA
    • Retrospective quant analysis
    ◦ Calibrate any UDA element not part in your original standards mix
    ◦ Assign internal standard
    ◦ Reprocess with UDA solution as standard
    ◦ Quantitative analysis result – however only 1 concentration level

    Answer questions about your samples which are asked


    in hindsight!
    Argon Quick-Change

    • A mode in the software that allows Ar tanks to be changed


    without powering off the Avio 500
    • Instrument goes into Stand-by Mode
    • The user has 30 minutes to change the Ar tank
    • After the tank is changed, start up time is 15 minutes
    ◦ Time required to purge the detector
    Analysis Speed

    • Sample: 1 ppm mixed element standard


    • Number of wavelengths: 20
    ◦ Elements: Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na,
    Ni, Pb, Se, Sr, V, Zn
    - Some elements with low sensitivity (i.e. As, Se, Pb, etc.)
    - Some elements with high sensitivity (i.e. Mg, Na, Sr, etc.)
    • Default Read Time Range: 1 - 5 seconds
    ◦ Software automatically selects best integration time within the range
    based on a pre-shot
    ◦ Time selected per wavelength
    ◦ Integration Time based on signal intensity
    • Views: axial & radial

    • Analysis Time: 30 seconds


    Analysis Speed: Sample Washout

    • Sample washout can be the longest time going from sample-


    to-sample

    • A variety of sample introduction components are available to


    minimize washout
    ◦ ESI FAST
    ◦ Cetac ASXpress
    ◦ Glass Expansion Niagara

    • A variety of rinse options are available in Syngistix


    Sample Washout: SmartRinse

    • User-defined concentrations for each element in the method


    • When the concentrations are below the user-defined
    thresholds, rinsing is complete
    Sample Washout: Upper Limits-1

    • User-defined upper-limit concentrations for each element to


    determine if washing is required
    Sample Washout: Upper Limits-2

    • User-defined upper-limit concentrations for each element to


    determine if extra washing is required
    Full Range of Intelligent Autosamplers and Diluters
    prep3
    • Automatic calibration from stock standard solution(s)
    • Automatic sample dilution
    • Automatic over-range dilution
    • Automatic internal standard out-of-range dilution
    • Analyze samples from undiluted to up to 25x diluted
    • Fully supported by PerkinElmer Syngistix software

    https://www.youtube.com/watch?v=yvWIy-fDyuA
    AVIO 200 ICP-OES
    Avio 200…

    • Scanning Array Spectrometer


    • Does not require to be thermostated
    • Designed to turn off when not in use
    • OFF is OFF
    • Optical system with very high light
    throughput allows short read times
    • Fastest start up from cold (10 min)
    • DWS for best stability
    • Smallest ICP on the market at
    65x76x81cm
    Fastest Start up
    • 10 minutes from cold
    ◦ No gas
    ◦ No electricity
    • How? DWS – Dynamic Wavelength Stabilisation
    ◦ Use of the Neon reference source corrects for any peak shift due to
    temperature and purge (or lack of)

    Benefits
    • Excellent stability despite changing laboratory environment
    • Best precision and accuracy
    Dynamic Wavelength Stabilisation (DWS)
    • All wavelengths are automatically
    referenced to Neon to eliminate
    wavelength drift Detector Echelle grating

    • done in real time for every


    replicate of every measurement
    • Temperature fluctuations allowed Intermediate slit

    Prism spectrum

    Optical fiber

    trum
    Neon source

    Prism
    With and Without DWS

    With: 20 hour run over Without: 20 hour


    a temperature range of run over a temperature
    10-35 °C range of 10-35 °C
    Avio 200 Speed – 6 wavelengths, radial
    Sample to sample times with autosampler without FAST valve
    Read time 0.5-2s Read time 0.2-0.2s
    Flush and read delay (typical) 40-50 s 40-50 s
    Analytical time 72 s 48
    Washout (typical) 20 s 20 s
    Sample to sample time 137 113

    Sample to sample times with autosampler with FAST valve


    Read time 0.5-2s Read time 0.2-0.2s
    Flush and read delay (typical) 10-15 s 10-15 s
    Analytical time 72 s 48
    Washout (typical) 10-15 s 10-15 s
    Sample to sample time 97 73

    Analytical time is average for solutions with range 0 – 100 ppm analyte
    Attenuation mode

    • Ability to extend the dynamic range is valuable for the analysis of high
    concentration samples.

    • Attenuation Mode provides a simple way to dramatically extend the


    dynamic range (ca. 50x)

    • Eliminate the need for additional sample prep or repeat analyses.

    • Avoids the efforts involved with validating alternate wavelengths.

    • Freely selectable, element by element.

    • Allows measurement of both high & low concentration elements in the


    same method, using a mix of attenuated and unattenuated modes.
    Attenuation mode

    • Comparison of detector saturation limits for Attenuated and Normal modes


    Axially and Radially

    1000

    100
    Axial
    Radial
    Att Axial
    10
    Att Radial

    1
    Al Ca Fe K Mg Na

    Attenuation Mode allows concentrations greater than


    1000 mg/L to be measured without dilution
    The Avio Series

    • When to choose an Avio 500?


    ◦ Simultaneous instrument
    ◦ High sample throughput regardless of number of
    wavelengths
    ◦ Instrument used continuously or in planned intervals -
    Continuously ON
    ◦ Backup quantitation with UDA

    • When to choose an Avio 200?


    ◦ Scanning array instrument
    ◦ High sample throughput for < 10 wavelengths
    ◦ medium sample throughput for > 10 wavelengths
    ◦ Instrument used intermittently or ad hoc – OFF is OFF, short
    startup
    ◦ versatility
    Thank you for your attention!
    Helmut Ernstberger
    Product Specialist Inorganic EMEA EMT and Spain
    [email protected]

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