Functional Groups: Definition

Functional Groups
Definition: A functional group is an atom or group of atoms in a molecule that gives the molecule its
characteristics chemical properties.
 Several transformation of organic molecules are carried out. In most cases the change will occur at
one spot in the original molecule. That spot is called a functional group.
 The functional group is an action group of the molecule. The hydrocarbon portion remains inert.
 Example: Single bond, double bond, triple bond, -OH, -Cl, -Br, NH2 groups etc.
Importance: The concept of functional group is important to organic chemistry for three reason:
1) Functional group serve as basis for nomenclature of organic compound.
2) Functional group serve to classify organic compounds into families.
3) All compounds having same functional group count in a same family.
4) A functional group is a site of chemical reactivity in a molecule.
Following is the list of some functional groups;
1) Alkanes:
The ‘default’ in organic chemistry (essentially, the lack of any functional groups) is given the
term alkane, characterized by single bonds between carbon and carbon, or between carbon and
hydrogen.
 Example: Methane, CH4, is the natural gas you may burn in your furnace. Octane, C8H18, is a
component of gasoline.

2) Alkenes and Alkynes:

Alkenes (sometimes called olefins) have carbon-carbon double bonds, and alkynes have carbon-
carbon triple bonds.
 Example:
 Ethene is the simplest example of alkene.
 Ethyne is the simplest example of alkyne functional group.
3) Aromatics:
The aromatic group is exemplified by benzene (which used to be a commonly used solvent on the
organic lab, but which was shown to be carcinogenic).
 Example: naphthalene, a compound with a distinctive ‘mothball’ smell. Aromatic groups are planar
(flat) ring structures, and are widespread in nature.

4) Alkyl Halides:
When the carbon of an alkane is bonded to one or more halogens, the group is referred to as an alkyl
halide or haloalkane.
 Example: Chloroform, Chlorodifluoromethane, Bromoethane etc are simple alkyl halide often used
in organic synthesis. Alkyl halides groups are quite rare in biomolecules.

5) Alcohols, Phenols, and Thiols:

In the alcohol functional group, a carbon is single-bonded to an OH group (the OH group, when it is
part of a larger molecule, is referred to as a hydroxyl group). Except for methanol, all alcohols can be
classified as primary, secondary, or tertiary. In a primary alcohol, the carbon bonded to the OH group
is also bonded to only one other carbon. In a secondary alcohol and tertiary alcohol, the carbon is
bonded to two or three other carbons, respectively.
 Phenol: When the hydroxyl group is directly attached to an aromatic ring, the resulting group is
called a phenol.
 Thiol: The sulfur analog of an alcohol is called a thiol (from the Greek thio, for sulfur).
Note that the definition of a phenol states that the hydroxyl oxygen must be directly attached to
one of the carbons of the aromatic ring. The compound below, therefore, is not a phenol – it is a
primary alcohol.

The distinction is important, because as we will see later, there is a significant difference in the
reactivity of alcohols and phenols
6) Ethers and Sulfides:

In an ether functional group, an oxygen is bonded to two carbons.
 Sulfide: The sulfur analog of an ether is called a thioether or sulfide.

 Example: Below is the structure of diethyl ether.

7) Amines
Amines are characterized by nitrogen atoms with single bonds to hydrogen and carbon. Just as there
are primary, secondary, and tertiary alcohols, there are primary, secondary, and tertiary amines.
Ammonia is a special case with no carbon atoms .

8) Aldehydes and Ketones
There are a number of functional groups that contain a carbon-oxygen double bond, which is
commonly referred to as a carbonyl.
Ketones and aldehydes are two closely related carbonyl-based functional groups that react in
very similar ways.
 Ketone: In a ketone, the carbon atom of a carbonyl is bonded to two other carbons.
 Aldehyde: In an aldehyde, the carbonyl carbon is bonded on one side to a hydrogen, and on
the other side to a carbon. The exception to this definition is formaldehyde, in which the
carbonyl carbon has bonds to two hydrogens.
 Example: Examples of ketone is (acetone) and aldehyde is acetaldehyde.
9) Carboxylic Acids and Their Derivatives

When a carbonyl carbon is bonded on one side to a carbon (or hydrogen) and on the other side to an
oxygen, nitrogen, or sulfur, the functional group is considered to be one of the ‘carboxylic acid
derivatives’, a designation that describes a set of related functional groups. The main member of this
family is the carboxylic acid functional group, in which the carbonyl is bonded to a hydroxyl group.
The carboxylate ion form has donated the H+ to the solution. Other derivatives are carboxylic
esters (usually just called ‘esters’), thioesters, amides, acyl phosphates, acid chlorides, and acid
anhydrides.
10) Nitriles:
Finally, a nitrile group is characterized by a carbon-nitrogen triple bond as shown in the structure of
acetonitrile.
 Example: acetonitrile

Functional Groups: Definition

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Functional Groups

2) Alkenes and Alkynes:

5) Alcohols, Phenols, and Thiols:

6) Ethers and Sulfides:

 Sulfide: The sulfur analog of an ether is called a thioether or sulfide.

9) Carboxylic Acids and Their Derivatives

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