SAFETY DATA SHEET

Introductory Information
Product Name: Calcium Nitrate Liquid
Page 1 of 5
Date of issue/ Date of revision: 20/06/2020

SECTION 1: IDENTIFICATION OF THE SUBSTANCE AND OF THE SUPPLIER

1.1 Product Identifier

Product Form : Transparent clear liquid
Product Name : Calcium Nitrate
Trade Name : CalNite 55
CAS No. : 10124-37-5
Common Name/Synonym : Nitrocalcite
Formula : Ca(NO3)2
1.2 Intended Use of the Product
Used as coagulant of natural and synthetic rubber lattices.
1.3. Details of the Responsible Party
Manufacturer
Name and address : CCM Chemicals Sdn Bhd (159498-A)
16th & 17th Floor, Menara NAZA TTDI
No 11, Jalan Judo 13/45, Section 13
40100 Shah Alam, Selangor Malaysia.
Telephone No. : 03-5561 6888
Fax No. : 03-5516 6898
1.4. Emergency Telephone Number
Emergency Number : 1-800-88-8565 (Toll free)
SECTION 2: HAZARD IDENTIFICATION

2.1. Classification of the Substance or Mixture

GHS Classification :Acute Oral Toxicity (Category 4)
Skin Corrosion/Irritation (Category 3)
Eye Irritation (Category 2A)
2.2. Label Elements
Hazard Pictograms/Symbols :

GHS07

Signal Word : Warning

Hazard Statements : H302 - Harmful if swallowed
H316 - Causes mild skin irritation
H319 - Causes serious eye irritation

Precautionary Statements
Prevention :P264 - Wash hands thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P280 - Wear protective gloves/protective clothing/eye protection/face
protection.

Rev. 2 Prepared by: CCM Chemicals Sdn Bhd

 SAFETY DATA SHEET
Introductory Information
Product Name: Calcium Nitrate Liquid
Page 2 of 5
Date of issue/ Date of revision: 20/06/2020

Response :P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician

if you feel unwell.
P330 - Rinse mouth.
P332 + P313 - If skin irritation occurs: Get medical advice/attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
Storage : No storage statements
Disposal : P501- Dispose of contents/container to comply with appropriate federal,
state and local regulations.
2.3. Other Hazards
Classification not possible.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENT

Chemical Common CAS No % (w/w) Exposure Limit, Hazard

Identity Name ppm Codes
Calcium Nitrocalcite 10124-37-5 54%-56% TLV H302, H316,
Nitrate (Not Classified) H319

SECTION 4: FIRST AID MEASURES

4.1. Description of First Aid Measures

If inhaled: Remove to fresh air. If nitrous fumes have been inhaled, rest the patient in fresh air and
keep warm. Administer oxygen if necessary.
In case of eye contact: Promptly wash eyes with lots of water while lifting the eye lids. Continue to
rise for water at least 15 minutes and get medical attention.
In case of skin contact: Remove affected person from source of contamination. Promptly remove
clothing if soaked through and flush skin with water.
If ingested: Do not feed anything through mouth while victim still unconscious. If swallowed: do
NOT induce vomiting. Promptly let affected drink lots of water to dilute the swallowed chemical.
4.2 Most Important Symptoms and Effect Both Acute and Delayed
Inhalation: Cough. Sore throat.
Eye contact: Redness.
Skin contact: Not applicable
Ingestion: Abdominal pain. Blue lips, fingernails and skin. Confusion. Convulsions. Dizziness.
Headache. Nausea. Unconsciousness.
5.1 Indication of Any Immediate Medical Attention and Special Treatment Needed
If concerned or irritation persists, get medical attention/advice immediately.

SECTION 5: FIRE FIGHTING MEASURES

5.1. Extinguishing Media

Flammability of the product: Not combustible but enhances combustion of other substances. In case
of fire in the surroundings, use appropriate extinguishing media.
Suitable extinguishing media: Water spray
5.2 Specific Hazards Arising from the Chemical
Severe explosion hazard when vapours are exposed to flames. Gives off irritating or toxic fumes (or
gases) in a fire. May decompose very toxic gases/vapour/fumes of nitrous gases (Nox) oxides of
nitrogen.
5.3 Special Protective Equipment and Precautions for Fire Fighters

Rev. 2 Prepared by: CCM Chemicals Sdn Bhd

 SAFETY DATA SHEET
Introductory Information
Product Name: Calcium Nitrate Liquid
Page 3 of 5
Date of issue/ Date of revision: 20/06/2020

Fire fighters should use water to keep fire exposed containers cool and disperse vapour. Move
container from fire area if it can be done without risk. Self-contained breathing apparatus should be
used for firefighting.
SECTION 6: ACCIDENTAL RELEASE MEASURE

6.1. Personal Precautions, Protective Equipment and Emergency Procedures

Personal precautions for spills or leaks: Small quantities should be washed away with large
quantities of water. Do not use fire extinguisher. Large quantities should be absorbed in sand or
similar absorbent materials for safe disposal. Personnel should use rubber gloves and wear goggles for
eye protection.
6.2. Environmental Precautions
Classification not possible.
6.3. Methods and Material for Containment and Cleaning
Disposed according to local waste disposal act for chemical substances.
SECTION 7: HANDLING AND STORAGE

7.1 Precautions for Safe Handling

Wash hand thoroughly after handling, before eating or smoking. Contaminated clothing to be placed
in closed container until disposal or decontamination.
7.2 Conditions for Safe Storage, Including Any Incompatibilities
Storage conditions: Keep away from flammable and combustion materials. Keep in cool and closed
containers.
Incompatible materials: Combustible substances, reducing agents, heat sources and naked flames.
SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION

8.1. Control Parameters

Permissible exposure limit: Not classified.
Occupational exposure limit (TLV): Classification not possible.
8.2 Appropriate Engineering Controls
Exposure should be kept as low as is reasonably practicable.
8.3 Individual Protection Measures
Respiration protection: Respiratory protection may be required when combustion occur.
Eyes protection: Wear chemical safety goggles where eye exposure is reasonably probable.
Hand protection: Wear suitable impervious protective gloves.
Ventilation: Provide adequate general and exhaust ventilation
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on Basic Physical and Chemical Properties

Appearance :Liquid, Colourless

Odour :Odourless
Odour threshold :Not classified
pH-value (30°C) :7.0-8.5
Boiling point :120oC
Flash point :Not applicable
Evaporation rate :Not applicable
Flammability (solid,gas) :Not applicable
Upper/lower flammability or :Not applicable
explosive limits
Vapour pressure (mmHg) deg°C :Classification not possible

Rev. 2 Prepared by: CCM Chemicals Sdn Bhd

 SAFETY DATA SHEET
Introductory Information
Product Name: Calcium Nitrate Liquid
Page 4 of 5
Date of issue/ Date of revision: 20/06/2020

Vapour density :Classification not possible

Relative density (Water =1) :1.50-1.55
Water Solubility :Soluble in water, alcohol
Partition coefficient, n-octanol/water :Not applicable
Auto-ignition Temperature :Not applicable
Decomposition temperature :Not applicable
Viscosity :Not applicable
SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
Calcium nitrate is a strong oxidant. It reacts with combustible and reducing materials. Present risk of
fire and explosion on contact with combustible substances.
10.2 Chemical Stability
Normally stable.
10.3 Possibility of Hazardous Reactions
Risk of fire and explosion on contact with combustible substances.
10.4 Conditions to Avoid
Heat, flame.
10.5 Incompatible Materials
Sulphuric Acid, strong reducing agents, flammable/combustion material.
10.6. Hazardous Decomposition Products
May decompose very toxic gases/vapour/fumes of nitrous gases (Nox) oxides of nitrogen in a fire.
SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on the Likely Routes of Exposure (Inhalation, Ingestion, Skin, and Eye
Contact)
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.
11.2 Symptoms Related to the Physical, Chemical and Toxicological Characteristics
Inhalation: A nuisance-causing concentration of airborne particles can be reached quickly when
dispersed.
Ingestion: Swallowing may cause nausea, vomiting, stomach distress.
Skin Contact: May cause slight irritation
Eye Contact: May cause moderate irritation
Carcinogenicity: This substance has no evidence of carcinogenic properties.
11.3 Delayed, Immediate, and Chronic Effects from Short and Long Term Exposure
Effects of short-term exposure: May cause mechanical irritation to the eyes and respiratory tract.
Ingestion could cause effects on the blood. This may result in formation of methaemoglobin. The
effects may be delayed. Medical observation is indicated.
Effects of long-term exposure: Classification not possible.
Acute and chronic health hazard: Anaemia, methaemoglobin formation, nephritis.
11.4 Numerical Measures of Toxicity
Oral: Rat LD50 = 302 mg/kg
Other data: Classification not possible
SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity : Avoid contaminating waterways

Persistence and degradability : Classification not possible
Bioaccumulative potential : Classification not possible
Mobility in soil : Classification not possible
Aquatic toxicity : Fish LC50 = 2400 mg/L (96 hours)
Other adverse effects : Avoid release to the environment

Rev. 2 Prepared by: CCM Chemicals Sdn Bhd

 SAFETY DATA SHEET
Introductory Information
Product Name: Calcium Nitrate Liquid
Page 5 of 5
Date of issue/ Date of revision: 20/06/2020

SECTION 13: DISPOSAL INFORMATION

Safe handling: Wash hand thoroughly after handling. Contaminated clothing to be placed in closed
container until disposal or decontamination.
Disposal methods: Contact supplier or a licensed contractor for detail recommendations. Follow
applicable federal, state, and local regulations.
SECTION 14: TRANSPORTATION INFORMATION

UN number : 1454
UN proper shipping name : CALCIUM NITRATE
Transport hazard class(es) : Not classified
Packing group, if applicable
Environmental hazards : Classification not possible
Transport in bulk (according to Annex II of : Not applicable
MARPOL 73/78 and the IBC code)
Special precautions : Classification not possible
SECTION 15: REGULATORY INFORMATION

This Safety Data Sheet complies with the Malaysian Occupational Safety and Health (Classification,
Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013.
SECTION 16: OTHER INFORMATION

This data sheet is informative only. Such information is, to the best of our knowledge and belief,
accurate and reliable as of the date indicated.
However, so representation, warranty or guarantee is made to its accuracy, reliability or completeness.
It is user’s responsibility to satisfy himself as to the suitability of such information for his own
particular use.

Prepared by : CCM Chemicals Sdn Bhd (159498-A)

16th & 17th Floor, Menara NAZA TTDI,
No 11, Jalan Judo 13/45, Section 13
40100 Shah Alam, Malaysia
Tel: 03-5561 6888
Fax: 03-5516 6898
Prepared on : January 2015
Revision date : June 2020
Reference : INCHEM, ICOP, Sax's Dangerous Properties of Industrial Materials, 9th ed
Abbreviation : N/A (Not Applicable)
File name : Calcium Nitrate (Eng GHS).doc

Rev. 2 Prepared by: CCM Chemicals Sdn Bhd