SAFETY DATA SHEET

According to JIS Z 7253:2012

Revision Date 04-Apr-2018
Version 5

Section 1: PRODUCT AND COMPANY IDENTIFICATION

Product name 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic Acid)Diammonium

Salt
Product code 018-10311
CAS No 30931-67-0
Formula C18H16N4O6S4·(NH4)2

Manufacturer FUJIFILM Wako Pure Chemical Corporation

1-2 Doshomachi 3-Chome
Chuo-ku, Osaka 540-8605, Japan
Phone: +81-6-6203-3741
Fax: +81-6-6203-5964
Supplier FUJIFILM Wako Pure Chemical Corporation
1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan
Phone: +81-6-6203-3741
Fax: +81-6-6203-2029
Emergency telephone number +81-6-6203-3741 / +81-3-3270-8571
Recommended uses and For research purposes
restrictions on use
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Section 2: HAZARDS IDENTIFICATION

GHS classification
Classification of the substance or mixture
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A

Pictograms

Signal word Warning

Hazard statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation

Precautionary statements-(Prevention)
•Washf ace,handsandanyex posedskinthor
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yaft
erhandl
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ng
•Wearpr ot
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eyeprot
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Precautionary statements-(Response)

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•I FINEYES:Ri nsecaut i
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Precautionary statements-(Storage)
•Notappl icable
Precautionary statements-(Disposal)
•Notappl icable

Others
Other hazards Not available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Single Substance or Mixture Substance

Formula C18H16N4O6S4·(NH4)2

Chemical Name Weight-% Molecular weight ENCS ISHL No. CAS No.
2,2'-Azinobis(3-ethylbenz =<100 548.68 N/A N/A 30931-67-0
othiazoline-6-sulfonic
Acid) Diammonium Salt

：
Impurities and/or Additives： Not applicable

Section 4: FIRST AID MEASURES

Inhalation
Remove to fresh air. If symptoms persist, call a physician.
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. Immediate medical attention is required.
Ingestion
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately.
Do not induce vomiting without medical advice.
Protection of first-aiders
Use personal protective equipment as required.

Section 5: FIRE FIGHTING MEASURES

Suitable extinguishing media

Water spray (fog), Carbon dioxide (CO2), Foam, Extinguishing powder, Sand
Unsuitable extinguishing media
No information available
Special extinguishing method
No information available
Specific hazards arising from the chemical product
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Protection of fire-fighters

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Use personal protective equipment as required. Firefighters should wear self-contained breathing apparatus and full firefighting
turnout gear.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

For indoor, provide adequate ventilation process until the end of working. Deny unnecessary entry other than the people
involved by, for example, using a rope. While working, wear appropriate protective equipments to avoid adhering it on skin, or
inhaling the gas. Work from windward, and retract the people downwind.
Environmental precautions
To be careful not discharged to the environment without being properly handled waste water contaminated.
Methods and materials for contaminent and methods and materials for cleaning up
Sweep up and gather scattered particles, and collect it in an empty airtight container.
Recoverly, neutralization
No information available
Secondary disaster prevention measures
Clean contaminated objects and areas thoroughly observing environmental regulations.

Section 7: HANDLING AND STORAGE

Handling
Technical measures
Avoid contact with strong oxidizing agents. Use with local exhaust ventilation.
Precautions
Do not rough handling containers, such as upsetting, falling, giving a shock, and dragging. Prevent leakage, overflow, and
scattering. Not to generate steam and dust in vain. Seal the container after use. After handling, wash hands and face, and then
gargle. In places other than those specified, should not be smoking or eating and drinking. Should not be brought contaminated
protective equipment and gloves to rest stops. Deny unnecessary entry of non-emergency personnel to the handling area.
Safety handling precautions
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Storage
Safe storage conditions
Storage conditions Keep container protect from light tightly closed. Store in a cool (2-10 °C) place.
Safe packaging material Glass
Incompatible substances Strong oxidizing agents

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering controls
In case of indoor workplace, seal the source or use a local exhaust system. Provide the safety shower facility, and hand- and
eye-wash facility. And display their position clearly.

Exposure limits This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.

Personal protective equipment

Respiratory protection Dust mask
Hand protection Protection gloves
Eye protection protective eyeglasses or chemical safety goggles
Skinandbody　pr otection Long-sleeved work clothes
General hygiene considerations
Handle in accordance with good industrial hygiene and safety practice.

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Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Form
Color White - pale yellow or pale green
Appearance powder or mass
Odor No data available
pH 5.0 - 6.0
Melting point/freezing point No data available
Boiling point, initial boiling point and boiling range No data available
Flash point No data available
Evaporation rate: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or
explosive limits
Upper： ： No data available
Lower： ： No data available
Vapour pressure No data available
Vapour density No data available
Specific Gravity / Relative density No data available
Solubilities water : freely soluble . Ethanol : slightly soluble . acetone : very
slightly soluble.
n-Octanol/water partition coefficient:(log Pow) No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Viscosity (coefficient of viscosity) No data available
Dynamic viscosity No data available

Section 10: STABILITY AND REACTIVITY

Stability

Stability May be altered by light.

Reactivity No data available
Hazardous reactions
None under normal processing
Conditions to avoid
Extremes of temperature and direct sunlight
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Carbon monooxide (CO), Carbon dioxide (CO2), Nitrogen oxides (NOx), Sulfur oxides (SOx)

Section 11: TOXICOLOGICAL INFORMATION

Acute toxicity No data available

Skin irritation/corrosion No data available

Serious eye damage/ irritation No data available
Respiratory or skin sensitization No data available
Reproductive cell mutagenicity No data available
Carcinogenicity No data available

Reproductive toxicity No data available

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STOT-single exposure No data available

STOT-repeated exposure No data available
Aspiration hazard No data available

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity No information available

Other data No data available

Persistence and degradability No information available

Bioaccumulative potential No information available
Mobility in soil No information available
Hazard to the ozone layer No information available

Section 13: DISPOSAL CONSIDERATIONS

Waste from residues
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated container and contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.

Section 14: TRANSPORT INFORMATION

ADR/RID Not regulated
UN number -
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Marine pollutant Not applicable

IMDG Not regulated

UN number -
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Marine pollutant (Sea) Not applicable
Transport in bulk according to No information available
Annex II of MARPOL 73/78 and
the IBC Code
IATA Not regulated
UN number -
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Environmentally Hazardous Not applicable
Substance

Section 15: REGULATORY INFORMATION

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International Inventories
EINECS/ELINCS Listed
TSCA -

Japanese regulations
Fire Service Act Not applicable
Poisonous and Deleterious Not applicable
Substances Control Law
Industrial Safety and Health Act Not applicable
Regulations for the carriage and Not applicable
storage of dangerous goods in
ship
Civil Aeronautics Law Not applicable
Pollutant Release and Transfer Not applicable
Register Law
Water Pollution Control Act Harmful Substances (Law Art.2, Enforcement Order Art.2, Ordinace Designating
Wastewater Standards Art.1)
Export Trade Control Order Not applicable

Section 16: OTHER INFORMATION

Key literature references and NITE: National Institute of Technology and Evaluation (JAPAN)
sources for data etc. http://www.safe.nite.go.jp/japan/db.html
IATA dangerous Goods Regulations
RTECS:Registry of Toxic Effects of Chemical Substances
Japan Industrial Safety and Health Association GHS Model SDS
Dictionary of Synthetic Oraganic Chemistry , SSOCJ, Koudansha Scientific Co.Ltd.
Chemical Dictionary, Kyouritsu Publishing Co., Ltd.
etc

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
GHS Classification is acoording to JIS Z7252(2014). *JIS: Japanese Industrial Standards

Product information You might get a product which indicates a former company name, during the period of
transition.
End of Safety Data Sheet

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