Trend Graph of Waste Water Control For Amonia Total (NH3-N) Period: 2014 - 2015

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Waste Water Control

Amonia (NH3-N) Sulfide (H2S)


(Unit : mg/L) (Unit : mg/L) Date of
Sampling Received
Year Date Remark
threshold threshold Result
Result Result
value (max) value (max)
Sampling location
6-Feb 36.85 20.0 1.660 0.05 - Other OOC : COD
7-Mar 90.39 20.0 11.204 0.05 - Other OOC : BOD, Zat Padat Tersuspensi
4-Apr 61.13 20.0 10.190 0.05 - Other OOC : COD
8-May 41.68 20.0 0.103 0.05 - Other OOC : Minyak & Lemak, Zat Padat Tersuspensi
6-Jun 52.55 20.0 4.374 0.05 - Other OOC : Minyak & Lemak, BOD, Zat Padat Tersuspensi, COD
2014 4-Jul 62.34 20.0 0.022 0.05 -
8-Aug 53.85 20.0 0.040 0.05 -
4-Sep 81.78 20.0 2.641 0.05 - Other OOC : Minyak & Lemak
14-Oct 0.34 20.0 0.002 0.05 -
6-Nov 44.88 20.0 0.002 0.05 -
5-Dec 31.71 20.0 0.417 0.05 27-Jan
9-Jan 50.76 20.0 3.211 0.05 11-Mar
11-Feb 39.20 20.0 0.002 0.05 15-Apr
6-Mar 44.79 20.0 0.033 0.05 5-May
13-Apr 53.00 20.0 0.002 0.05 8-Jun
11-May 15.00 20.0 0.002 0.05 12-Oct Other OOC : None
2015
10-Jun 1.00 20.0 0.004 0.05 14-Sep Other OOC : Minyak & Lemak
6-Jul 90.00 20.0 0.300 0.05 14-Sep Other OOC : Minyak & Lemak, COD
12-Aug 119.00 20.0 0.300 0.05 8-Oct Other OOC : BOD, Minyak & Lemak, Zat Padat Tersuspensi, COD
7-Sep 30.00 20.0 0.002 0.05 28-Oct Other OOC : Minyak & Lemak, Zat Padat Tersuspensi
9-Oct 65.00 20.0 0.100 0.05 4-Dec Other OOC : Minyak & Lemak, COD
Note. OOC = Out of Control
Concentration (mg/L)

Record of Septic Tank Drainage


29-Oct-15
Trend Graph of Waste Water Control for Amonia Total (NH3-N)
Period : 2014 - 2015
140.00

120.00

100.00

80.00

60.00 Amonia (NH3-N)


(Unit : mg/L)
40.00 threshold value
(max)
20.00

0.00
42041

42070

42098

42161

201442189

42224

42251

42291

42314

42343

42013

42046

42069

42107

42135

42165

42191

42228

42254

42286
42132

2015

Sampling Date

Summary:
1. Based on the record, Amonia is always upper than threshold value since the beginning (Feb 2014) except for October 2014, May & Jun 2015.
2. For Sulfide, the condition is fluctuation.

Action Plan for Investigation


1. Check all the used material wich has content of Amonia & Sulfide. (Status : Done)
2. Check the commonality (production condition, etc.) at the sampling date with pollutant concetration less than threshold limit.
3. Take additional sample to verify at the different sampling location.
4. Consult to sample office for the other potential source.
Waste Water Control

Amonia (NH3-N) Sulfide (H2S)


(Unit : mg/L) (Unit : mg/L) Date of
Sampling
Year Received
Date
threshold threshold Result
Result Result
value (max) value (max)

6-Feb 36.85 20.0 1.660 0.05 -


7-Mar 90.39 20.0 11.204 0.05 -
4-Apr 61.13 20.0 10.190 0.05 -
8-May 41.68 20.0 0.103 0.05 -
6-Jun 52.55 20.0 4.374 0.05 -
2014 4-Jul 62.34 20.0 0.022 0.05 -
8-Aug 53.85 20.0 0.040 0.05 -
4-Sep 81.78 20.0 2.641 0.05 -
14-Oct 0.34 20.0 0.002 0.05 -
6-Nov 44.88 20.0 0.002 0.05 -
5-Dec 31.71 20.0 0.417 0.05 27-Jan
9-Jan 50.76 20.0 3.211 0.05 11-Mar
11-Feb 39.20 20.0 0.002 0.05 15-Apr
2015
6-Mar 44.79 20.0 0.033 0.05 5-May
13-Apr 53.00 20.0 0.002 0.05 8-Jun
Concentration (mg/L)

Trend Graph of Waste Water Control for Amonia Tota


Period : 2014 - 2015
100.00
90.00
80.00
70.00
60.00
50.00
40.00
30.00
20.00
10.00
0.00
42041 42070 42098 42132 42161 42189 42224 42251 42291 42314 42343 42013 42
2014

Sampling Date

Summary:
1. Based on the record, Amonia is always upper than threshold value since the beginning (Feb 2014) except for Octobe
2. For Sulfide, the condition is fluctuation.
Action Plan for Investigation
1. Check all the used material wich has content of Amonia & Sulfide. (Status : Done)
2. Check the commonality (production condition, etc.) at the sampling date with pollutant concetration less than thresh
3. Take additional sample to verify at the different sampling location.
4. Consult to sample office for the other potential source.
Remark

Other OOC : COD


Other OOC : BOD, Zat Padat Tersuspensi
Other OOC : COD
Other OOC : Minyak & Lemak, Zat Padat Tersuspensi
Other OOC : Minyak & Lemak, BOD, Zat Padat Tersuspensi, COD

Other OOC : Minyak & Lemak

Note. OOC = Out of Control

Control for Amonia Total (NH3-N)

Amonia (NH3-N)
(Unit : mg/L)
threshold value (max)

42291 42314 42343 42013 42046 42069 42107


2015

te

eginning (Feb 2014) except for October 2014.


pollutant concetration less than threshold limit.
List of material NH3-N H2S
No Name Amonia content Sulfide content Related Grease or function
1 SR 130 0 0.9 (% weight, sulphur) One Luber
2 Raffene 750L 0 0
3 Minarex A 0 0
4 Minarex H 0 0
5 500 SN 0 0
6 150 BS 0 0
7 PFA 0 0
8 12-HAS 0 0
9 Dailube S-320 0 9 (% mass, sulphur ) Citrax
10 Calcium Hydroxide 0 0
11 Zinc Oxide 0 0
12 Glycerine 0 sulphate 20 ppm Citrax
13 Flowtac 2000 0 0
14 Automate Blue 8AHF 0 0
15 Latex Pekat 0.65% 0 Cobra
16 Vanlube SL 4% (Nitrogen) 0 One Luber
17 Asphalt 0 0
18 Silicon oil 0 0
19 Blue dye 0 0
20 lithium hydroxide (LiOH) 0 0.05 (weight %, sulphate) One Luber
21 Yellow dye 0 0
22 Kurita T-7680 0 0 cooling water
23 Kurita NT-63 0 0 cooling water
24 Kurita F-5100 0 0 cooling water
25 Solar 0 0 clean up strainer
26 Aceton 0 0 Laboratory
27 N-Hexane 0 0 Laboratory
28 Ethanol 0 0 Laboratory

Summary :
Based on the above data, Amonia is probably generated from Latex and Vanlube. Meanwhile Sulfide is generated from SR 130, Dailube, LiOH.
Possible cause of problem source
No Content Photograph Plan of Action

Condensation of exhaust gas


during grease manufacturing
process: a. Take sample of water at
a. accumulated on the roof --> the drain gutter.
1 drop to the drain gutter during b. Take sample of
raining. condensed exhaust gas at
b. accumulated at temporary the temporary waste tank.
waste tank --> drop to the drain
gutter during transfer to drum.

Dispose of remained sample


Take sample of water waste
grease at laboratory during
2 at the laboratory wash
cleaning the lab. Tools at the
basin.
wash basin.

Dropping of human urine from Take sample of water drain


the toilet ( Male employee from toilet at the connection
uritory is sometime overflow area to drain gutter.
3
caused by champor blocked the (Cancelled due to drain line
drain line) ---> clean by flowing has properly can be used
water to the drain gutter. after action taken).

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