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    Diffusivity Formula Chart (Infographic)

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    Safayet Aziz
    Diffusivity can occur through several mechanisms depending on the material properties and conditions. Pore diffusivity in random porous materials can involve both Knudsen and molecular diffusion. Gas mass diffusivity is described by various equations depending on whether the gas is pure or a mixture, polar or non-polar, and operating temperature and pressure. Liquid mass diffusivity of non-electrolytes is typically modeled using the Stokes-Einstein or Wilke-Chang equations, while electrolyte diffusion is estimated using the Nernst equation.

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    Diffusivity Formula Chart (Infographic)

    Uploaded by

    Safayet Aziz
    41 views3 pages
    Diffusivity can occur through several mechanisms depending on the material properties and conditions. Pore diffusivity in random porous materials can involve both Knudsen and molecular diffusion. Gas mass diffusivity is described by various equations depending on whether the gas is pure or a mixture, polar or non-polar, and operating temperature and pressure. Liquid mass diffusivity of non-electrolytes is typically modeled using the Stokes-Einstein or Wilke-Chang equations, while electrolyte diffusion is estimated using the Nernst equation.

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    Diffusivity formula chart (Infographic)

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    Diffusivity can occur through several mechanisms depending on the material properties and conditions. Pore diffusivity in random porous materials can involve both Knudsen and molecular diffusion. Gas mass diffusivity is described by various equations depending on whether the gas is pure or a mixture, polar or non-polar, and operating temperature and pressure. Liquid mass diffusivity of non-electrolytes is typically modeled using the Stokes-Einstein or Wilke-Chang equations, while electrolyte diffusion is estimated using the Nernst equation.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    41 views3 pages

    Diffusivity Formula Chart (Infographic)

    Uploaded by

    Safayet Aziz
    Diffusivity can occur through several mechanisms depending on the material properties and conditions. Pore diffusivity in random porous materials can involve both Knudsen and molecular diffusion. Gas mass diffusivity is described by various equations depending on whether the gas is pure or a mixture, polar or non-polar, and operating temperature and pressure. Liquid mass diffusivity of non-electrolytes is typically modeled using the Stokes-Einstein or Wilke-Chang equations, while electrolyte diffusion is estimated using the Nernst equation.

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    © All Rights Reserved
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    of 3

    Diffusivity

    Pore Diffusivity

    Knudsen + Molecuar diffusion Randon porus material


    Pure gas Molecular Pure gas Knudsen
    diffusion diffusion

    Cylindrical Pores NOon-Cylindrical Pores


    Cylindrical Pores Cylindrical Pores
    ( If ƛ < pore diameter) ( If ƛ > pore diameter)

    Hirschfelder Knudsen
    ’s equation Number

    With
    If Kn > 1
    Gas Mass Diffusivity

    BInary, Non Polar & Binary and Polar


    Non Reacting

    With Lennard-Jones With no reliable Diffusivity at any Temperature With modified 'Ω'
    parameters 'σ' and 'Ω' 'σ' and 'ɛ' and Pressure below 25atm suggested by Brokaw

    Hirschfelder Fuller Hirschfelder


    ’s equation correlation ’s equation

    Where

    Where
    Polar or Non Polar
    Multicomponent

    Diffusivity at any Temperature For Gas Mixtures


    and Pressure below 25atm

    With
    Liquid Mass Diffusivity

    Non Electrolytes ( Molecules ) Electrolytes ( Ions )

    Solute diffusion of Estimating of DAB in other


    For larger Non Electrolyte solute System having infinite dilution For infinite dilution of
    Electrolytes in dilute temperature is by
    molecules diffusing in a of Non Electrolyte solute Non Electrolytes in water,
    solution extrapolation
    smaller size solvent molecules molecules Wilke-Chang equation is
    simplified to Nernst equation
    Stokes-Einstein Wilke-Chang
    equation Hayduk-Laudie’s

    If no ΦB data then Scheibel’s


    equation is applied

    Where K:

    Except:
    1. For Benzene as a solvent, if Va<2Vb,use K=18.9*10^-8
    2. For other organic solvents, if Va<2.5Vb, use K=1.75*10^-8

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