Tugas 2 - Matematika Teknik Kimia 2
Tugas 2 - Matematika Teknik Kimia 2
Tugas 2 - Matematika Teknik Kimia 2
Soal No.1
F1 CA F2 CBo
T0
Cp T0 Cp
A B
Electric heater is
used to supply CA
V
energy at W watt = F
W Joule/s
CA Cc
Cp CB CD
Reacting system T Cp
A+B C+D
Reaction of A to form B at an optimum temperature according to second order
reaction :
−r A = k. CA . CB (mol A/L/min)
Heat of reaction is HR (Cal/mol), which is positive in value?
Penyelesaian :
1. Neraca Massa Total
R input−R output=R accumulation
dM d ( ρV )
F 1 ρ+ F 2 ρ−F ρ= =
dt dt
dρ dV
ρ ( F 1+ F 2−F )=V +ρ
dt dt
dV
=F1 + F 2−F
dt
Neraca Energi
R input−R output−R reaksi+ R add=R accumulation
d ( Q s) d ( ρ V C P T )
F 1 ρ C PA T o + F 2 ρ C PB T o −F ρ C p T −k C A C B V ∆ H R +W = =
dt dt
dT dV d CP d
ρ T o ( F 1 C PA + F 2 C PB ) −F ρ C P T −k C A C B V ∆ H R +14,4=ρV C P + ρ CPT +ρ V T +V C P T
dt dt dt d
dT
ρ T o ( F 1 C PA + F 2 C PB ) −F ρ C P T −k C A C B V ∆ H R +14,4=ρV C P + ρ C P T ( F1 + F 2−F )
dt
dT ρ T o ( F 1 C PA + F 2 C PB ) −F ρ C P T −k C A C B V ∆ H R +14,4−ρC P T ( F 1 + F2 −F )
=
dt ρV C P
dT ρ T o ( F 1 C PA + F 2 C PB ) −F ρ C P T −k C A C B V ∆ H R−ρ C P T ( F 1+ F 2 ) +14,4
=
dt ρ V CP
Soal No.2
A solution containing A
and B (initial volume is
Vo, density is o) is
heated in a still flask
equipped with heating
coil (electric heater is
used as heat source). At
one time, the solution
starts to boil and the
vapor is condensed in a
condenser employing
cooling water. Find the
composition of the
condensate and
remaining solution in the
flask. Write mass
balance and energy
balance for this system
Electric heater is used
to supply energy at W
watt = W Joule/s
Penyelesaian
2. Senyawa A dan B, t = 0 → ρo , V o ,T o , C P
a. Sebelum mendidih (To → Tboiling)
Neraca Massa Total
R input−R output=R accumulation
dM d ( ρV )
0−0= =
dt dt
dV
=0
dt
Neraca Energi
R input−R output + R heater=R acc
d ( Q s ) d ( ρV C P T )
0−0+W = =
dt dt
dT dV d CP dρ
W =ρ C P V +ρ CP T + ρV T +V C P T
dt dt dt dt
dT W
=
dt ρ C P V
t=0 T = To
t = tb T = Tboiling
b. Setelah mendidih
Pada saat mendidih berlaku kesetimbangan uap ↔ air
Equilibrium efisien :
y i=hi x i
y i=α i x i
1+ ( α i−1 ) x i
Neraca Energi
R input−R Out put + R add−R reaction=R accumulation
dT dV
0−D ( ρ y A λ A + ρ y B λ B ) +W −C W =ρ C P V −ρ C P T
dt dt
dT
−D(ρ y A λ A + ρ y B λ B)+W −C W =ρ C P V −D ρC P T
dt
dT
ρ CP V =−D ρ ( y A λ A + y B λB −C P T ) +W −C W
dt
dT −D ( y A λ A + y B λ B−C P T ) +W CW
=
dt CP V