Mod 1 Smart Mat Lec 2

Module 1: Overview of Smart Materials
Bishakh Bhattacharya & Nachiketa Tiwari

Department of Mechanical Engineering
Indian Institute of Technology, Kanpur
Lecture #2: Introduction to
Piezoelectric Materials
History of Piezoelectricty
Piezoelectric Materials
How to prepare a
Pi
Piezoceramic i Actuator?
A t t ?
Constitutive
Co st tut e Relationship
e at o s p
Piezoceramic Polymers &
Composites
Bimorphs
p & Piezostacks
History of Piezoelectricity
• Piezoelectricity ii.e.
e Electricity from
Pressure was discovered by Pierre and
Jacque Curie
C in 1880
• Contemporary: Contact Electricity – Static
Electricity generated from Friction
• Pyroelectricity:
P l t i it ElElectricity
t i it generated
t d ffrom
crystals while heating
Who’s
Who s who in Piezoelectricity?
Pierre Curie (1859-1906),

Nobel Prize in Physics, 1903
Direct Piezoelectric Effect
Gabriel Lippmann (1845-1921),

Nobel Prize in Physics, 1908
Reverse Piezoelectric Effect

Piezoelectricity – Time Line
• The effect observed by Pierre and Jacque Curie
is called as Direct Piezoelectric Effect (Hankel
1881)
• The
Th didirectt effect
ff t was found
f d in
i Zinc
Zi Blende,
Bl d
Boracite, Tourmaline, Quartz, Cane Sugar and
R h ll S
Rochelle Salt
lt
• The reverse effect was theoretically predicted by
Lippman (1881) and experimentally confirmed
by Voight in 1894
• First application – Langvein (1917) in Sonar
Transducer ((composite
p made of steel p plate &
quartz) – later Ceramic Phonograph, Ceramic
Electret Microphone
Piezoelectricity in Perovskites
(1949-60)
Perovskite: A Ternary (3 Component structure)
Example: BaTiO3 a common piezoelectric material
Tetragonal Symmetry with

Dipole moment below
C i T
Curie Temperature
Similar material: PZT family,

family LiNb family,
family PbNb family
family, YMn family
family,
(NH4)Cd family (1970--)
Polarization of Piezoelectric
Material
How to prepare a Piezoceramic
Actuator?
• St
Startt with
ith fine
fi powders
d off componentt metal
t l
oxides (PZT or Barium Titanate family) e.g.. for
PZT you need PbO,PbO ZrO2 and TiO2 powders
• Mix them in fixed proportions
• Use
U an organic i bi
binder
d
• Form into specific shapes
• Heat for a specific time and specified
temperature 650-800oC
• Cool – apply electrode (sputtering)
• Polarize the sensor/actuator using a DC electric
field
4 steps
p for Powder Processing
g
Constitutive Equation of
Piezoelectricity
X
D  dX   E Direct Effect
E Converse
x  S X  dE Effect
X-stress
X stress, x
x-strain
strain, D
D-electric
electric displacement/flux
density, S-compliance, E-Electric field intensity
 permittivity d
-permittivity, d-piezoelectric
piezoelectric constant
Superscripts denote the measurement of
permittivity
itti it att constant
t t stress
t and
d compliance
li att
constant electric field intensity
Response
p of a Piezo-fibre
Electromechanical Coupling Coefficient
• Due to nonlinearity the equations

p
represented in Variational form:
D  dX   x
E
x  S E
X  dE
• Electromechanical coupling Coefficient:

k 2
W 2
12 / W 1W 2
W12 – Piezoelectric Energy Density

Density, W1
Mechanical and W2 Electrical energy
density
Commercial Piezoelectric Material Property Set
Prp unit BaTiO3 PZT-A PZT-B Pb Nb2O6 LiNbO3 Pb Ti O3
 Mg/m3 57
5.7 79
7.9 77
7.7 59
5.9 46
4.6 71
7.1
k31 .21 .33 .39 .04 .02 .05
k33 .49 .68 .72 .38 .17 .35
d31 pCN-1 79 119 234 11 .85 7.4
S m2/N 8.6 12.2 14.5 29 5.8 11

A few observations
• PZT family has highest piezoelectric
p g
coupling
• Curie Point PZT family 220-315oC, same
for Li family 600 1200oC
600-1200
• Instead of polycrystalline
Piezoceramics a single cut PMN could
give k33 = 0.92 and d33 = 2070 pC/N
Piezoelectric Polymer
y
• PVF2 (Poly Vinylidene Fluoride) a semi-

y
crystalline p
polymer
y consist of long-chain
g
molecules with the repeat unit of CF2CH2
• Form I PVDF (all trans) shows all chain
oriented parallel to the axis of the unit cell
and the dipoles pointing in the same direction
• d31 4.2
4.2-19
19 pC/N (for PZT ~ 234)
• k31 3-14.7%
• E – 1.6 – 3.8 GPa
Piezoelectric Composite
• Composite made of a polymer and PZT
y
• Polymer phase
p – lower density,
y ppermittivity
y and
increase elastic compliance
(5 10 m) in Polyurethane
• Smaller PZT particles (5-10
(PU) matrix
• Larger 120m particles in a silicone rubber
matrix
• Skinner et al: Smaller particles generate series
connectivity, while larger parallel
Piezoelectric Composites
• For series connection, even very low volume
f ti off polymer
fraction l (1%) drastically
d ti ll reduces
d ‘d’
however ‘g’ remains unaffected
• For parallel connection ‘d’ remains unchanged,
‘g’ increases
• Replamineform process to enhance
interconnectivity
IInspiration
i ti from
f Coral
C l
structure:
Narrow pore-size
p
distribution, complete
pore interconnectivity
Applications: Bimorph
D31 Actuator
D31 Sensor
Piezostack
D33 Actuator
D33 Se
Sensor
so
Operating Point
END OF LECTURE 2

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Module 1: Overview of Smart Materials

Bishakh Bhattacharya & Nachiketa Tiwari

Pierre Curie (1859-1906),

Direct Piezoelectric Effect

Gabriel Lippmann (1845-1921),

Reverse Piezoelectric Effect

Tetragonal Symmetry with

Similar material: PZT family,

• Due to nonlinearity the equations

• Electromechanical coupling Coefficient:

W12 – Piezoelectric Energy Density

Prp unit BaTiO3 PZT-A PZT-B Pb Nb2O6 LiNbO3 Pb Ti O3

k31 .21 .33 .39 .04 .02 .05

k33 .49 .68 .72 .38 .17 .35

d31 pCN-1 79 119 234 11 .85 7.4

S m2/N 8.6 12.2 14.5 29 5.8 11

• PVF2 (Poly Vinylidene Fluoride) a semi-

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