MATERIAL SAFETY DATA SHEET Page: 1

Klean-Strip Aircraft Remover

Flammability Instability
HEALTH * 2
FLAMMABILITY 1
1 Printed: 01/22/2013
Revision: 01/22/2013
PHYSICAL 0 Health
2 0 Supercedes Revision: 08/21/2012
PPE X Special Hazard

1. PRODUCT AND COMPANY IDENTIFICATION

Product Code: 3404.14
Product Name: Klean-Strip Aircraft Remover
Manufacturer Information
Company Name: W. M. Barr
2105 Channel Avenue
Memphis, TN 38113
Phone Number: (901)775-0100
Emergency Contact: 3E 24 Hour Emergency Contact (800)451-8346
Information: W.M. Barr Customer Service (800)398-3892
Web site address: www.wmbarr.com
Preparer Name: W.M. Barr EHS Dept (901)775-0100
Synonyms
GAR343, QAR343
Revision Date: 01/22/2013

2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components (Chemical Name) CAS # Concentration OSHA TWA ACGIH TWA Other Limits
1. Dichloromethane {Methylene chloride; R-30; 75-09-2 60.0 -100.0 % 25 ppm 50 ppm No data.
Freon 30}
2. Methanol {Methyl alcohol; Carbinol; Wood 67-56-1 5.0 -10.0 % 200 ppm 200 ppm No data.
alcohol}
3. Tall oil 8002-26-4 1.0 -5.0 % No data. No data. No data.
4. Ammonium hydroxide {Ammonia aqua; 1336-21-6 1.0 -5.0 % No data. No data. No data.
Ammonium liquor}
5. Xylene (mixed isomers) {Benzene, dimethyl-} 1330-20-7 1.0 -5.0 % 100 ppm 100 ppm No data.
Hazardous Components (Chemical Name) RTECS # OSHA STEL OSHA CEIL ACGIH STEL ACGIH CEIL
1. Dichloromethane {Methylene chloride; R-30; PA8050000 125 ppm (15 min) No data. No data. No data.
Freon 30}
2. Methanol {Methyl alcohol; Carbinol; Wood PC1400000 No data. No data. 250 ppm No data.
alcohol}
3. Tall oil WW2860000 No data. No data. No data. No data.
4. Ammonium hydroxide {Ammonia aqua; BQ9625000 No data. No data. No data. No data.
Ammonium liquor}
5. Xylene (mixed isomers) {Benzene, dimethyl-} ZE2100000 No data. No data. 150 ppm No data.

3. HAZARDS IDENTIFICATION
Emergency Overview
Danger! Poison. May be fatal or cause blindness if swallowed. Vapor harmful. Eye and skin irritant.
Potential Health Effects (Acute and Chronic)
Inhalation Acute Exposure Effects:
Vapor harmful. May cause dizziness; headache; watering of eyes; injuries to mucous membranes; irritation of the
throat and respiratory tract; nausea; numbness in fingers, arms and legs; bronchospasm; hot flashes; tissue
damage; spotted vision; dilation of pupils; increase of carboxyhemoglobin levels, which can cause stress to the
cardiovascular system; arm, leg, and chest pains; depression of the central nervous system; bronchitis; pulmonary
edema; chemical pneumonitis; difficulty breathing; vomiting; visual disturbances; giddiness; intoxication;
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sleepiness; cough and dyspnea; cold, clammy, extremities, and diarrhea. Severe overexposure may cause
irregular or rapid heartbeat; convulsions; unconsciousness; and death. Elevated carboxyhemoglobin levels can be
additive to the increase caused by smoking and other carbon monoxide sources.

Skin Contact Acute Exposure Effects

This product is a skin irritant. May be absorbed through the skin. May cause irritation; burns; blisters; tissue
destruction; drying and defatting of skin; and dermatitis. May cause symptoms listed under inhalation. Vapors
and mist can irritate moist skin.

Eye Contact Acute Exposure Effects

This material is an eye irritant. May cause irritation and pain; conjunctivitis of eyes; corneal ulcerations of the
eye; burns; and blindness. Vapors and mist can irritate eyes.

Ingestion Acute Exposure Effects

Poison. Cannot be made non-poisonous. May be fatal or cause blindness. May cause irritation to mouth, throat
and stomach; headache; nausea; dizziness; stupor; liver, kidney and heart damage; depression of the central
nervous system; narcosis; burning of esophagus, stomach, mouth and throat; vomiting; gastrointestinal irritation;
diarrhea; abdominal pain; collapse; and death. May be corrosive to mouth and throat. May produce symptoms
listed under inhalation. Liquid aspirated into lungs may cause chemical pneumonitis and systemic effects.

Chronic Exposure Effects

Reports have associated repeated and prolonged overexposure to solvents with neurological and other
physiological damage. Prolonged or repeated contact may cause dermatitis. Prolonged skin contact may result in
absorption of a harmful amount of this material. May cause headache; conjunctivitis; gastric disturbances; skin
irritation; permanent central nervous system changes; decreased response to visual and auditory stimulation;
visual impairment or blindness; hallucinations; changes in blood; blood disorders; kidney, liver or pancreatic
damage; insomnia; giddiness; and death. May cause additional symptoms listed under inhalation.
Signs and Symptoms Of Exposure
See Potential Health Effects.
Medical Conditions Generally Aggravated By Exposure
Diseases of the blood; skin; eyes; liver; kidneys; lungs; cardiovascular; pulmonary; and respiratory systems;
alcoholism; and rhythm disorders of the heart.
OSHA Regulatory Status:
This material is classified as hazardous under OSHA regulations.
4. FIRST AID MEASURES
Emergency and First Aid Procedures
Skin:
Immediately begin washing the skin thoroughly with large amounts of water and mild soap, if available, while
removing contaminated clothing. Seek medical attention if irritation persists.

Eyes:
Immediately begin to flush eyes with water, remove any contact lens. Continue to flush the eyes for at least 15
minutes, then seek immediate medical attention.

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention.

Ingestion:
If swallowed, do NOT induce vomiting. Seek immediate medical attention. Call a physician, hospital emergency
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room, or poison control center immediately. Never give anything by mouth to an unconscious person.
Note to Physician
Poison. This product contains methylene chloride and methanol.

This product contains methanol which can cause intoxication and central nervous system depression. Methanol is
metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual
disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be delayed
from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to
prevent methanol metabolism. Ethanol administration is indicated in symptomatic patients or at blood methanol
concentrations above 20 ug/dl. Methanol is effectively removed by hemodialysis. Adrenalin should never be
given to a person overexposed to methylene chloride.

Methylene Chloride is an aspiration hazard. Risk of aspiration must be weighed against possible toxicity of the
material when determining whether to induce emesis or to perform gastric lavage. This material sensitizes the
heart to the effects of sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate
cardiac arrhythmias in individuals exposed to this material. This material is metabolized to carbon monoxide.
Consequently, elevations in carboxyhemoglobin as high as 50% have been reported, and levels may continue to
rise for several hours after exposure has ceased. Data in experimental animals suggest there is a narrow margin
between concentrations causing anesthesia and death.
5. FIRE FIGHTING MEASURES
Flash Pt: No data.
Explosive Limits: LEL: No data. UEL: No data.
Autoignition Pt: No data available.
Fire Fighting Instructions
Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined
areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay
away from heads of containers that have been exposed to intense heat or flame.

Contact of liquid or vapor with flame or hot surfaces will produce toxic gases and a corrosive residue that will
cause deterioration of metal.
Flammable Properties and Hazards
Flashpoint: NO FLASH TO BOILING
Hazardous Combustion Products
carbon monoxide, carbon dioxide, phosgene, chlorine.
Extinguishing Media
Use carbon dioxide, dry powder or foam.
Unsuitable Extinguishing Media
No data available.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Released Or Spilled
Clean-up
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate
closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area.

Small Spills
Take up liquid with sand, earth or other noncombustible absorbent material and place in a plastic container where
applicable.

Large Spills
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Dike far ahead of spill for later disposal.

Waste Disposal
Dispose in accordance with applicable local, state and federal regulations.

7. HANDLING AND STORAGE

Precautions To Be Taken in Handling
Read carefully all cautions and directions on product label before use. Since empty container retains residue,
follow all label warnings even after container is empty. Dispose of empty container according to all regulations.
Do not reuse this container.

Wear protective clothing and take precautions to prevent all skin and eye contact.

Precautions To Be Taken in Storing

Store in a cool, dry place. Exposure to high temperatures or prolonged exposure to sun may cause can to leak or
swell. Once opened, remover should be used within six months or discarded to avoid can deterioration. Do not
store near flames or at elevated temperatures.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Equipment (Specify Type)
For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered
air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air
control is not feasible, use properly maintained and properly fitted NIOSH approved self-contained breathing
apparatus for chlorinated solvent vapors. A dust mask does not provide protection against vapors.
Eye Protection
Safety glasses, chemical goggles, or face shields are recommended to safeguard against potential eye contact,
irritation, or injury. Chemical goggles or face shields are recommended when splashing or spraying of chemical
is possible. A faceshield provides more protection to help reduce chemical contact to the face and eyes.
Protective Gloves
Wear gloves with as much resistance to the chemical ingredients as possible. Laminate film gloves offer the best
protection. Other glove materials will be degraded by methylene chloride, but may provide protection for some
amount of time, based on the type of glove and the conditions of use. Consult your glove supplier for additional
information. Gloves contaminated with product should be discarded and not reused.
Other Protective Clothing
Various application mehods can dictate use of additional protective safety equipment, such as impermeable
aprons, etc., to minimize exposure. A source of clean water should be available in the work area for flushing eyes
and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse,
thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any
clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes.
Engineering Controls (Ventilation etc.)
Use only with adequate ventilation to prevent build up of vapors. Open all windows and doors. Use only with a
cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight
dizziness, headache, nausea, or eye-watering, STOP ventilation is inadequate. Leave area immediately.
Work/Hygienic/Maintenance Practices
A source of clean water should be available in the work area for flushing of the eyes and skin.

Wash hands thoroughly after use.

Do not eat, drink, or smoke in the work area.

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Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use.

Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical States: [ ] Gas [ X ] Liquid [ ] Solid
Melting Point: No data.
Boiling Point: ~ 110 F
Autoignition Pt: No data.
Flash Pt: No data.
Specific Gravity (Water = 1): 1.1683 - 1.1985
Vapor Pressure (vs. Air or mm Hg): 350 MM HG at 20 C
Vapor Density (vs. Air = 1): >1
Evaporation Rate: >1
Solubility in Water: Partial
Percent Volatile: 95 % by weight.
VOC / Volume: 12 % WT
pH: 10 - 12
Appearance and Odor
No data available.
10. STABILITY AND REACTIVITY
Stability: Unstable [ ] Stable [ X ]
Conditions To Avoid - Instability
No data available.
Incompatibility - Materials To Avoid
Incompatible with strong oxidizing agents; strong caustics; strong alkalis; oxygen; nitorgen peroxide; chemically
active metals such as aluminum and magnesium; sodium; potassium; and nitric acid.
Hazardous Decomposition Or Byproducts
Thermal decomposition may produce hydrogen chloride; chlorine gas; small quantities of phosgene; carbon
monoxide; carbon dioxide; formaldehyde; and unidentified organic compounds in black smoke.
Hazardous Polymerization: Will occur [ ] Will not occur [ X ]
Conditions To Avoid - Hazardous Polymerization
Will not occur.
11. TOXICOLOGICAL INFORMATION
Toxicological Information
Methylene Chloride:
ACUTE TOXICITY:
LC50 Rat inhalation 52 mg/L 4 hrs
LD50 Rat oral 985-1600 mg/kg
SKIN CORROSION / IRRITATION:
810 mg/24 hr skin rabbit - severe
100 mg/24 hr skin rabbit - moderate
SERIOUS EYE DAMAGE / IRRITATION:
162 mg eyes rabbit - moderate
10 mg eyes rabbit - mild
500 mg/24 hr eyes rabbit - mild
RESPIRATORY OR SKIN SENSITIZATION: Not a respiratory or skin sensitizer.
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ASPIRATION HAZARD: Mehtylene chloride does present an aspiration hazard.
MUTAGENIC DATA: Positive results have been observed in the Ames test. In mammalian systems, responses
have generally been negative.
IMMUNOTOXICITY: A study found there was no evidence of harm to the immune system of laboratory
animals or reduced ability to combat disease.
NEUROTOXICITY: Tests in rats indicate no significant neurotoxic effects after exposure to concentrations up to
2,000 ppm for 90 days. No neurotoxic effects have been observed in humans at typical occupational exposure
levels.
DEVELOPMENTAL/REPRODUCTIVE: No significant developmental effects were observed in female rats and
mice exposed to 1,250 ppm during gestation. A similar result was observed in rats exposed to 4,500 ppm before
and during gestation. A two-generation inhalation study showed no adverse reproductive effects in rats exposed
to as much as 1,500 ppm for 14 weeks.
CARCINOGEN STATUS: Methylene chloride is carcinogenic in experimental animals at a relatively high dose,
by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) that are not considered relevant
to worker exposure. Available epidemiological studies do not confirm an increased risk of cancer in humans.
Available evidence suggests that this material is not likely to cause cancer in humans except under uncommon or
unlikely routes or levels of exposure.
__________________________________

Methanol:
ACUTE TOXICITY:
LD50 Rat oral 5628 mg/kg
LC50 Rat inhalation 64000 ppm/4 hr
LC50 Rat inhalation 87.5 mg/L/6 hr
LD50 Mouse oral 7300 mg/kg
SKIN CORROSION / IRRITATION: LD50 Rabbit dermal 15,800 mg/kg bw
SERIOUS EYE DAMAGE / IRRITATION: Methanol is a mild to moderate eye irritant.
RESPIRATORY OR SKIN SENSITIZATION: Not a respiratory or skin sensitizer.
ASPIRATION HAZARD: Methanol presents an aspiration hazard.
MUTAGENIC DATA: No data.
IMMUNOTOXICITY: No data.
NEUROTOXICITY: Overexposure to methanol has been suggested as causing central nervous system damage in
laboratory animals.
DEVELOPMENTAL/REPRODUCTIVE: The inhalation of methanol by pregnant rodents throughout the period
of embryogenesis induces a wide range of concentration-dependent teratogenic and embryolethal effects.
Methanol has caused birth defects in laboratory animals, but only when inhaled at extremely high vapor
concentrations. The relevance of this finding to humans is uncertain.
CARCINOGEN STATUS: There is no evidence from animal studies to suggest methanol is a carcinogen.
_______________________________________

Ammonium Hydroxide:
LD50 Rat oral 350 mg/kg
_______________________________________

Xylene:
LD50 Rat oral 4.3 g/kg
LD50 Rat oral 10 mL/kg /Xylene/
LD50 Mouse oral 1590 mg/kg /Xylene/
LC50 Rat inhalation 6,350 ppm/4 hr
LCLo Rat inhalation 8,000 ppm/4 hr

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LC50 Rat inhalation 6,350 ppm/4 hr
LC50 Mouse inhalation 3,907 ppm/6 hr
LD50 Rat oral 4.3 g/kg and 10 ml/kg /Xylene/
LD50 Mouse oral 1590 mg/kg /Xylene/
LC50 Rat oral 29,000 mg/cu m (6670 ppm) /Xylene/
LD50 Rat oral range from 3523 mg/kg to 8600 mg/kg. /Mixed Xylenes/ LD50 Mouse (B6C3F1) oral 5251 mg/kg
(female) and 5627 mg/kg (male). /Mixed Xylenes/
LD50 Rabbit dermal > 5 ml/kg (43 g/kg). /Mixed Xylenes

Chronic Toxicological Effects

No data available.
Carcinogenicity/Other Information
IARC 2B - Possibly Carcinogenic to Humans
IARC 3: Not Classifiable as to Carcinogenicity in Humans.
ACGIH A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
ACGIH A4 - Not Classifiable as a Human Carcinogen.
Hazardous Components (Chemical Name) CAS # NTP IARC ACGIH OSHA
1. Dichloromethane {Methylene chloride; R-30; 75-09-2 Possible 2B A3 Yes
Freon 30}
2. Methanol {Methyl alcohol; Carbinol; Wood 67-56-1 n.a. n.a. n.a. n.a.
alcohol}
3. Tall oil 8002-26-4 n.a. n.a. n.a. n.a.
4. Ammonium hydroxide {Ammonia aqua; 1336-21-6 n.a. n.a. n.a. n.a.
Ammonium liquor}
5. Xylene (mixed isomers) {Benzene, dimethyl-} 1330-20-7 n.a. 3 A4 n.a.

12. ECOLOGICAL INFORMATION

General Ecological Information
No data available.
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method
Dispose in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
LAND TRANSPORT (US DOT)
DOT Proper Shipping Name UN1760, Corrosive Liquid, N.O.S. 8, PGI (Ammonium Hydroxide, Methylene
Chloride)
DOT Hazard Class: 8
DOT Hazard Label: CORROSIVE
UN/NA Number: 1760
Packing Group: I
Additional Transport Information
For D.O.T. information, contact W.M. Barr Technical Services at 1-800-398-3892.

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15. REGULATORY INFORMATION

US EPA SARA Title III
Hazardous Components (Chemical Name) CAS # Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110
1. Dichloromethane {Methylene chloride; R-30; 75-09-2 No Yes 1000 LB Yes Yes
Freon 30}
2. Methanol {Methyl alcohol; Carbinol; Wood 67-56-1 No Yes 5000 LB Yes No
alcohol}
3. Tall oil 8002-26-4 No No No No
4. Ammonium hydroxide {Ammonia aqua; 1336-21-6 No Yes 1000 LB No No
Ammonium liquor}
5. Xylene (mixed isomers) {Benzene, dimethyl-} 1330-20-7 No Yes 100 LB Yes Yes
Other US EPA or State Lists
Hazardous Components (Chemical Name) CAS # CAA HAP,ODC CWA NPDES TSCA CA PROP.65
1. Dichloromethane {Methylene chloride; R-30; 75-09-2 HAP Yes Inventory, 4 Test, Yes
Freon 30} 8A CAIR
2. Methanol {Methyl alcohol; Carbinol; Wood 67-56-1 HAP No Inventory Yes
alcohol}
3. Tall oil 8002-26-4 No No Inventory No
4. Ammonium hydroxide {Ammonia aqua; 1336-21-6 No No Inventory No
Ammonium liquor}
5. Xylene (mixed isomers) {Benzene, dimethyl-} 1330-20-7 HAP Yes Inventory No
SARA (Superfund Amendments and
Reauthorization Act of 1986) Lists:
Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000
LB TPQ if not volatile.
Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. **
indicates statutory RQ.
Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a
chemical category.
Sec.110: EPA SARA 110 Superfund Site Priority Contaminant List
TSCA (Toxic Substances Control
Act) Lists:
Inventory: Chemical Listed in the TSCA Inventory.
5A(2): Chemical Subject to Significant New Rules (SNURS)
6A: Commercial Chemical Control Rules
8A: Toxic Substances Subject To Information Rules on Production
8A CAIR: Comprehensive Assessment Information Rules - (CAIR)
8A PAIR: Preliminary Assessment Information Rules - (PAIR)
8C: Records of Allegations of Significant Adverse Reactions
8D: Health and Safety Data Reporting Rules
8D TERM: Health and Safety Data Reporting Rule Terminations
12(b): Notice of Export
Other Important Lists:
CWA NPDES: EPA Clean Water Act NPDES Permit Chemical
CAA HAP: EPA Clean Air Act Hazardous Air Pollutant
CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC)

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CA PROP 65: California Proposition 65
International Regulatory Lists:
EPA Hazard Categories:
This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated:
[X] Yes [ ] No Acute (immediate) Health Hazard
[X] Yes [ ] No Chronic (delayed) Health Hazard
[ ] Yes [X] No Fire Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
[ ] Yes [X] No Reactive Hazard
Regulatory Information Statement
All components of this material are listed on the TSCA Inventory or are exempt.
16. OTHER INFORMATION
Company Policy or Disclaimer
The information contained herein is presented in good faith and believed to be accurate as of the effective date
shown above. This information is furnished without warranty of any kind. Employers should use this information
only as a supplement to other information gathered by them and must make independent determination of
suitability and completeness of information from all sources to assure proper use of these materials and the safety
and health of employees. Any use of this data and information must be determined by the user to be in
accordance with applicable federal, state and local laws and regulations.
N.A.=Not available, N.P.=Not applicable, N.D.=Not determined, N.E.=Not established, N.R.=Not required

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