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Pearson Edexcel
International GCSE

Chemistry
Unit: 4CH0
Paper: 2C

Wednesday 17 January 2018 – Afternoon Paper Reference

Time: 1 hour 4CH0/2C

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• centre
Fill in the boxes at the top of this page with your name,
number and candidate number.
• Answer all questions.
• Answer the questions in the spaces provided
– there may be more space than you need.
• Show all the steps in any calculations and state the units.
• Some questions must be answered with a cross in a box
your mind about an answer, put a line through the box
. If you change
and then mark
your new answer with a cross .

Information
• The total mark for this paper is 60.
• The marks for each question are shown in brackets
– use this as a guide as to how much time to spend on each question.

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P53146A
©2018 Pearson Education Ltd.

1/1/1/1/1/
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2
 Answer ALL questions.

1 These pieces of apparatus are used in chemistry experiments.

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P Q R S

(a) Name these pieces of apparatus.

(4)
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P . . . . . . . . ................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .............. ............................................................................................................................. . . . . . . . . . . . . . . . . . . . . .

Q . . . . . . . ................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............... ............................................................................................................................. . . . . . . . . . . . . . . . . . . . .

R . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............... ............................................................................................................................. . . . . . . . . . . . . . . . . . . . . .

S . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............... ............................................................................................................................. . . . . . . . . . . . . . . . . . . . . .

(b) Apparatus P contains dilute hydrochloric acid.

Litmus indicator is added to this acid.
What is the final colour of the litmus?
(1)
A blue B green C orange D red
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(c) Apparatus R contains potassium hydroxide solution.

Litmus indicator is added to this alkaline solution.

What is the final colour of the litmus?

(1)
A blue B green C orange D red

(Total for Question 1 = 6 marks)

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2 The diagram shows an atom of lithium with atomic number 3 and mass number of 6.

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F

(a) Name the particle labelled E.

(1)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

(b) Name the part of the atom labelled F.

(1)

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(c) Name the two types of particle found in part F.

(2)

1 . . . . . . . . ................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .............. .............................................................................................................................. . . . . . . . . . . . . . . . . . . . .

2 . . . . . . . . ................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .............. .............................................................................................................................. . . . . . . . . . . . . . . . . . . . .

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4
*P53146A0416*
 (d) Another type of lithium atom has atomic number 3 and mass number 7.
(i) State the name given to atoms with the same atomic number but different
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mass numbers.
(1)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

(ii) Draw a diagram to show the arrangement of electrons in an atom of lithium

with atomic number 3 and mass number 7.
(1)
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(e) A sample of lithium contains 92.5% of atoms with mass number 7 and 7.5% of atoms
with mass number 6.
Calculate the relative atomic mass of lithium.
(2)
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relative atomic mass = ................................. . . . . . . . . . . . . . . . . . . . . . .

(Total for Question 2 = 8 marks)

*P53146A0516*
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3 A student is provided with a solution of dilute sulfuric acid and a solution of sodium hydroxide.

The student does a titration using 25.0 cm3 of the sodium hydroxide solution.

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She adds the acid from a burette.

(a) Which type of reaction occurs between dilute sulfuric acid and sodium hydroxide?
(1)

A displacement
B neutralisation
C precipitation
D redox

(b) The diagram shows the student’s burette readings for the titration.

1 26

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2 27

before after

(i) Use the readings to complete the table, giving all values to the nearest 0.05 cm3.
(3)

burette reading after adding acid

burette reading before adding acid DO NOT WRITE IN THIS AREA

volume in cm3 of acid added

6
*P53146A0616*
 (ii) Explain why the student needs to repeat the titration in order to obtain a
reliable value for the volume of acid required to react exactly with 25.0 cm3 of
sodium hydroxide solution.
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(2)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

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. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........... ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........... ............................................................................................................................... .. . . . . . . . . . . . . . . . . . . . .

(Total for Question 3 = 6 marks)

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*P53146A0716*
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4 (a) This is the displayed formula of an organic compound, X.

H H H

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H C C C O H

H H H

(i) Give the molecular formula of compound X.

(1)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

(ii) A student describes compound X as a saturated hydrocarbon.

Explain whether the student is correct.
(3)

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. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........... ............................................................................................................................... .. . . . . . . . . . . . . . . . . . . . .

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(b) Compound X and ethanol are members of the homologous series of alcohols.
One property of members of a homologous series is that they have similar
chemical reactions.
Give one other property of members of a homologous series.
(1)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

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8
*P53146A0816*
 (c) This apparatus is used for a dehydration reaction using compound X.
This reaction is similar to the dehydration reaction of ethanol.
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mineral wool soaked

in compound X aluminium oxide gas Y

heat water

The reaction produces gas Y and one other product.

(i) State the purpose of the aluminium oxide.
(1)
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. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

(ii) State a property of gas Y that allows it to be collected over water.

(1)

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(iii) Give a reason why the first sample of gas Y collected is not pure.
(1)

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(iv) Complete the equation for the dehydration reaction showing the displayed formula
of gas Y and the molecular formula of the other product.
(2)

H H H
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H C C C O H o +

H H H

(v) Give the name of gas Y.

(1)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

(Total for Question 4 = 11 marks)

*P53146A0916*
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5 Chromium is a shiny metal that has many uses.
Most chromium is extracted from the ore chromite, FeCr2O4

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(a) Complete the table by giving the names of the elements in FeCr2O4
(1)

Chemical symbol Name of element

Fe

Cr

(b) In the extraction process, chromite is converted into chromium(III) oxide, Cr2O3
Chromium is made by this reaction

chromium oxide + aluminium o chromium + aluminium oxide

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(i) Write a chemical equation for this reaction.
(2)

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(ii) Explain what the reaction shows about the reactivity of chromium compared
to the reactivity of aluminium.
(2)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

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(iii) Explain why the reaction between chromium oxide and aluminium is described
as a redox reaction.
(2)

. . . . . . . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ ............................................................................................................................... . . . . . . . . . . . . . . . . . . . . . .

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*P53146A01016*
 (c) Chromium metal reacts with dilute hydrochloric acid to form hydrogen gas.
This apparatus is used to investigate the reaction.
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pieces of excess
chromium hydrochloric acid

The equation for the reaction is

Cr(s) + 2HCl(aq) o CrCl 2(aq) + H2(g)

A student adds 0.13 g of a sample of chromium metal to excess dilute hydrochloric acid.
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(i) Calculate the maximum volume of hydrogen gas that the student could produce
in this experiment at room temperature and pressure (rtp).
[molar volume of a gas is 24 dm3 at rtp]
(3)

maximum volume = .............................................. . . . . . . . . . dm3

(ii) The student does the experiment at rtp and finds that the volume collected is
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less than the calculated maximum.

Give two possible reasons for this.
(2)

1 . . . . . . . . ................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .............. .............................................................................................................................. . . . . . . . . . . . . . . . . . . . .

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2 . . . . . . . . ................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .............. .............................................................................................................................. . . . . . . . . . . . . . . . . . . . .

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(Total for Question 5 = 12 marks)

*P53146A01116*
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6 Lithium fluoride, LiF, and magnesium oxide, MgO, are ionic compounds.
(a) (i) Calculate the relative formula mass (Mr ) of MgO.

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(1)

Mr = ................................. . . . . . . . . . . . . . . . . . . . . . .

(ii) Give the formulae of the two ions in LiF.

(1)

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(b) Explain why

• ionic compounds have high melting points

• the melting point of magnesium oxide is much higher than the melting point
of lithium fluoride
(4)

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 (c) Explain why ionic compounds do not conduct electricity when solid, but do conduct
electricity when molten or in aqueous solution.
(2)
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(Total for Question 6 = 8 marks)

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7 The diagram shows the electrolysis of concentrated sodium chloride solution in a diaphragm cell.

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chlorine gas + – hydrogen gas

concentrated sodium
chloride solution
negative electrode

positive electrode impure sodium

hydroxide solution
diaphragm

(a) (i) The ionic half-equation for the reaction at the positive electrode is

2Cl– o Cl 2 + 2e–

Use this equation to explain why oxidation occurs at the positive electrode.
(2)

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(ii) At the negative electrode, water molecules gain electrons to form hydroxide ions
and hydrogen gas.
Complete the ionic half-equation for this reaction.
(2)

2H2O + .............................................................. o .............................................................. + ............................................................. . DO NOT WRITE IN THIS AREA

(b) Chlorine reacts with sodium hydroxide to produce a mixture of water, sodium chloride

and sodium chlorate(I), NaOCl.
Write a chemical equation for this reaction.
(1)

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 (c) Chlorine is used in the manufacture of the addition polymer poly(chloroethene).
(i) Explain how an addition polymer is formed from its monomers.
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(2)

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(ii) Complete this equation by drawing the displayed formula of poly(chloroethene).

(2)

H Cl
n C C
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H H

(Total for Question 7 = 9 marks)

TOTAL FOR PAPER = 60 MARKS

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BLANK PAGE

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Every effort has been made to contact copyright holders to obtain their permission for the use of copyright material.
Pearson Education Ltd. will, if notified, be happy to rectify any errors or omissions and include any such rectifications in
future editions.

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