ME 6163: Combustion Engineering: (Moran Ex. 13.2)

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ME 6163: Combustion Engineering

Term Paper 01 Submission Date: TBA

1. Methane, CH4 , is burned with dry air. The molar analysis of the products on a dry
basis is CO2 , 9.7%; CO, 0.5%; O2 , 2.95%; and N2 , 86.85%. Determine (a) the air-fuel
ratio on both a molar and a mass basis, (b) the percent theoretical air, (c) the dew
point temperature of the products, if the products are cooled at 1 atm. [Moran Ex.
13.2]

2. A natural gas has the following molar analysis: CH4 , 80.62%; C2 H6 , 5.41%; C3 H8 , 1.87%;
C4 H10 , 1.60%; N2 , 10.50%. The gas is burned with dry air, giving products having a molar
analysis on a dry basis: CO2 , 7.8%; CO, 0.2%; O2 , 7%; N2 , 85%. (a) Determine the air-fuel
ratio on a molar basis. (b) Determine the air-fuel ratio on a mass basis. (c) Determine the
percent of theoretical air. [Moran Ex. 13.3]

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3. One kilomole of carbon monoxide, CO, reacts with 2 kmol of oxygen, O2 , to form an equilibrium
mixture of CO2 , CO, and O2 at (a) 1500 K, 1 atm, (b) 3000 K, 10 atm. Determine the
equilibrium composition in terms of mole fractions. [Moran Ex. 14.2]

4. Carbon dioxide at 25o C, 1 atm enters a reactor operating at steady state and dissociates, giving
an equilibrium mixture of CO2 , CO, and O2 that exits at 3200 K, 1 atm, Determine the heat
transfer, in kJ per kmol of CO2 entering. [Moran Ex. 14.5]

5. Liquid Butane (C4 H10 ) is sprayed into a combustion chamber. In addition, 400% theoretical
air is supplied at an inlet temperature of 600 K. Gaseous products of combustion leave the
chamber at 1100 K. If complete combustion is assumed, determine the heat transfer in kJ/kmol
of fuel. [Wark Ex. 13.8]

6. Liquid Butane (C4 H10 ) at 25o C an 400% theoretical air at 298 K react in a steady-flow process.
Determine adiabatic flame temperature assuming complete combustion. [Wark Ex. 13.9]

7. Charcoal (wood char) is an easily made, high energy fuel that is lightweight and easy to trans-
port. Assume that charcoal is composed of only C and consider the reaction of carbon with
stoichiometric air to produce CO2 , CO, and O2 at 2200 K and 2 atm. What is the volume
fraction of CO when the products are in equilibrium at 2200 K due to the dissociation of CO2 ?
[Borman Ex. 3.10]

8. Bituminous coal is burned to completion with 50% excess air. Find (a) the fuel-air ratio, (b) the
volumetric analysis of the dry products. (c) the adiabatic flame temperature of this bituminous
coal. The as-received ultimate analysis of the coal is 70% carbon, 5% hydrogen, 15% oxygen,
5% moisture, and 5% ash on a weight basis. [Borman, Ex. 3.4 & 3.13]

9. Ultimate analysis of coal is given as: sulphur, 1.1; hydrogen, 4.4; carbon, 66.0; nitrogen 1.5;
oxygen, 7.9; ash, 5.6; water, 13.5, in percent by mass. (a) Determine the reaction equation and
air-fuel ratio used for complete combustion with 20% excess air. (b) If the products are cooled
to 500 K, determine the heat transfer. (c) Estimate HHV and LHV of the coal sample. [Wark
Ex. 13.14]

10. One mole of CO and 1 mole of H2 O are heated to 2500 K and 1 atm. Determine the equilibrium
composition, if it is assumed that only CO, CO2 , H2 , H2 O & O2 are present. [Wark Ex. 14.10]

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