Gen Chem
Gen Chem
Gen Chem
FEBRUARY 2020
www.asc.org/chemmatters
1
Teacher’s Guide
Chernobyl’s Legacy
February 2020
Table of Contents
Anticipation Guide 3
Activate students’ prior knowledge and engage them before they read the article.
Graphic Organizer 6
This helps students locate and analyze information from the article. Students should use their own words and
not copy entire sentences from the article. Encourage the use of bullet points.
Answers 7
Access the answers to reading comprehension questions and a rubric to assess the graphic organizer.
Additional Resources 10
Here you will find additional labs, simulations, lessons, and project ideas that you can use with your students
alongside this article.
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Chernobyl’s Legacy, February 2020
Directions: Before reading the article, in the first column, write “A” or “D,” indicating your Agreement or
Disagreement with each statement. Complete the activity in the box.
As you read, compare your opinions with information from the article. In the space under each statement, cite
information from the article that supports or refutes your original ideas.
Me Text Statement
1. Most of the people who left Chernobyl after the nuclear plant explosion have returned.
3. Temperatures inside the reactor during the explosion were as hot as parts of the Sun’s
atmosphere.
4. The fuel in the reactor included U-238 from enriched uranium dioxide.
7. When one mole of U-235 undergoes fission, the energy released can power about 400
average U.S. homes for a year.
8. Nuclear reactors must have control rods to keep a chain reaction from occurring.
10. The radioactive iodine released during the explosion still poses a health threat to people
in Northern Europe.
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Chernobyl’s Legacy, February 2020
Student Reading
Comprehension Questions Name: ______________________________
5. Nuclear reactions involve the nucleus of an atom. Which two subatomic particles are found in the nucleus of
an atom?
7. List the three radioisotopes that can result from the decay of U-235 in order of their half-lives.
9. If you start with a 30 g sample of I-131, how many grams of I-131 would there be after 16 days?
10. Explain how half a pound of U-235 can generate enough energy to power 400 average U.S. homes for a year.
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Chernobyl’s Legacy, February 2020
1. In 1979, the U.S. experienced a nuclear accident at Three Mile Island. Do some research and compare and
contrast the two events.
2. Th-232 undergoes decay by emitting the following particles: alpha, beta, beta, alpha, alpha, alpha, alpha,
beta, beta, alpha. What is the resulting isotope? Write out the entire decay series.
3. Do some research to conclude why alpha radiation is dangerous when ingested, beta particles cause
damage to skin, and gamma radiation damages human cells.
4. Develop a list of at least three drawbacks and three benefits for using nuclear power as an energy source.
Examine your list and explain whether or not we should continue to use nuclear power. Read the Open for
Discussion article in this issue to help you decide.
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Chernobyl’s Legacy, February 2020
Directions: As you read, complete the graphic organizer below to describe what happened during and after the
explosion of the nuclear power plant at Chernobyl.
When did it
happen?
Where did it
happen?
What happened?
What
radioisotopes
were produced?
What kind of
radiation was
emitted?
Summary: In the space below, or on the back of this paper, write three new things you learned about nuclear
power plants and/or nuclear radiation.
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Chernobyl’s Legacy, February 2020
5. Nuclear reactions involve the nucleus of an atom. Which two subatomic particles are found in the nucleus
of an atom?
Protons and neutrons are found in the nucleus of an atom.
s.
7. List the three radioisotopes that can result from the decay of U235 in order of their half-lives.
Iodine -131 half-life of eight days, strontium – 90 half-life of 29 years, cesium-137 half-life of 30 years
9. If you start with a 30 g sample of I-131, how many grams of I-131 would there be after 16 days?
There would be 7.5 grams of I-131.
10. Explain how half a pound of U-235 can generate enough energy to power 400 average U.S. homes for a
year.
When one atom of uranium goes through fission, the reaction releases a small amount of energy. When the
reaction is repeated on the mole scale though, the self-sustaining reaction becomes significantly larger,
producing exponentially more energy.
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Chernobyl’s Legacy, February 2020
1. In 1979, the U.S. experienced a nuclear accident at Three Mile Island. Do some research and compare and
contrast the two events.
Three Mile Island information can be found here: https://www.thebalance.com/three-mile-island-nuclear-
accident-facts-impact-today-3306337
From the article: At 4 a.m. on March 28, a cooling circuit malfunctioned, allowing the primary coolant to
overheat. The reactor shut down immediately, and the release valve opened for 10 seconds, which
allowed enough coolant to escape to reduce pressure and heat. But the valve got stuck in the open
position, and as a result, all the coolant was released. Unfortunately, there wasn't an instrument that
could have alerted engineers that this had happened.
New coolant rushed into the tank, but the engineers now thought that there was too much, so they
reduced the flow. The remaining coolant turned to steam. The fuel rods overheated, melting the
protective coating, which released radioactive material into the coolant. When the steam was released,
the radioactive contaminant was released into the surrounding area. Fortunately, the amount released
was not enough to harm local food supplies, animals, or people.
Chernobyl scenario: Operator errors and design flaws in the reactor. A power surge caused the temperature
and pressure of the reactor to rise dramatically creating a meltdown and explosion. Additionally, there were
only eight control rods in the reactor when there should have been at least 15.
2. Th-232 undergoes decay by emitting the following particles: alpha, beta, beta, alpha, alpha, alpha, alpha,
beta, beta, alpha. What is the resulting isotope? Write out the entire decay series.
Pb-208
90Th 2α +
232 4 228
88Ra
88Ra -1β +
228 0 228
89Ac
228
89Ac 0
-1 β + 228 Th
90
90Th 2α +
228 4 224
88Ra
88Ra 2α +
224 4 220
86Rn
220
86Rn 4
2α + 216
84Po
84Po 2α +
216 4 212
82Pb
82Pb -1β +
212 0 212
83Bi
83Bi -1β +
212 0 212
84Po
84Po 2α +
212 4 208
82Pb
3. Do some research to conclude why alpha radiation is dangerous when ingested, beta particles cause
damage to skin, and gamma radiation damages human cells.
Alpha particles are two protons and two neutrons, so they are too large to penetrate human skin. If alpha
particles are ingested through food or breathing contaminated air, the large particles can wreak havoc on
the human body inside.
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Chernobyl’s Legacy, February 2020
Beta particles are an electron expelled from a nucleus, so they are small high-energy particles that can
penetrate pores in the skin.
Gamma rays are the most dangerous because it is pure energy, not matter. These rays can pass through
human cells and cause damage.
4. Develop a list of at least three drawbacks and three benefits for using nuclear power as an energy source.
Examine your list and explain whether or not we should continue to use nuclear power. Read the Open for
Discussion article in this issue to help you decide.
Benefits: Source of low carbon energy, considered safe, produces a large amount of energy, low fuel costs
Drawbacks: Long-term waste disposal can be expensive, potential for nuclear accidents, initial building of
nuclear reactor can be expensive
0 Not acceptable So incomplete that no judgment can be made about student understanding
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Chernobyl’s Legacy, February 2020
Additional Resources
Half-Life: In this lab, students visualize the random nature of atomic decay (or first order chemical reactions). It
helps them answer the inevitable question of what happens when a decaying material reaches a single particle
of the species. https://teachchemistry.org/classroom-resources/half-life
Using Dice to Explore Radioactive Decay: In this activity, students will use dice to simulate the radioactive
“decay” of samples of two different elements with two different half-lives.
https://teachchemistry.org/classroom-resources/using-dice-to-explore-radioactive-decay
Simulations
Half-Life Investigation: This simulation provides students with an opportunity to explore the decay of two
unstable atom samples. https://teachchemistry.org/classroom-resources/half-life-investigation-simulation
Nuclear Energy Power Plants: In this activity, students will write a persuasive essay in which they state an
opinion about whether the number of nuclear plants should be increased or decreased.
https://teachchemistry.org/classroom-resources/nuclear-energy-power-plants
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Chernobyl’s Legacy, February 2020
HS-PS1-8
Develop models to illustrate the changes in the composition of the nucleus of the atom and the energy
released during the processes of fission, fusion, and radioactive decay.
HS-ETS1-3
Evaluate a solution to a complex real-world problem based on prioritized criteria and tradeoffs that
account for a range of constraints, including cost, safety, reliability, and aesthetics, as well as possible
social, cultural, and environmental impacts.
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Chernobyl’s Legacy, February 2020
Teaching Strategies
Consider the following tips and strategies for incorporating this article into your classroom:
Alternative to the Anticipation Guide provided: Before reading, ask students if they have heard about
Chernobyl. If students have never heard of the nuclear accident at Chernobyl, tell them there was a
serious accident at the nuclear power plant in Chernobyl and ask them what questions they have about
the accident or its aftermath. As they read the article, students should look for answers to their
questions.
Encourage students to watch the video (What Exactly Happened at Chernobyl? bit.ly/ACSReactions-
Chernobyl) after they read the article. The video summarizes much of the information in the article and
presents some animation to help students understand what happened.
After students read “Chernobyl’s Legacy,” ask them to read “Open for Discussion: Can Nuclear Power
Save the Planet” on page 4 of this issue of ChemMatters. Then ask students to list (or debate) the pros
and cons of nuclear power.
Have students do the Radioactivity Puzzle on the next page.
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Chernobyl’s Legacy, February 2020
Radioactivity Puzzle
Sources of ionizing radiation
A lot of radioactive elements are either mined in a quarry (like uranium) or made in a lab (like americium). But
there are a lot of things in your everyday life that are sources of ionizing radiation. Unscramble the words and
phrases below to find some of them.
1) UNS
2) PASS
3) CHEWSAT
4) ANABANS
5) BEANSTEMS
6) ARLBIZ STUN
7) COTTONPURSE
8) KOMES DECOTTERS
9) AMBERSINUS
10) PROWE LTSNAP
11) PACES ORBSEP
12) KALE CITEDNOTE
13) ARCENC MATTRENTE
14) CLAIMED ADIOSSIGN
15) NUTRIMENTS INITIALZOSTER
16) ODOF INCANTATIONMODE
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Chernobyl’s Legacy, February 2020
Answers
Sources of ionizing radiation
A lot of radioactive elements are either mined in a quarry (like uranium) or made in a lab (like
americium). But there are a lot of things in your everyday life that are sources of ionizing radiation.
Unscramble the words and phrases below to find some of them.
1) Sun
Fusion reactions in the sun’s core emit powerful gamma () radiation that travels to the Earth. This
radiation is responsible for generating a steady supply of radioactive 14C on the Earth’s surface. Since the
sun’s rays cannot reach under the crust, scientists can measure the amount 14C in buried objects to
determine their age in a process called carbon dating.
2) Spas
Radon occurs naturally as a result of the radioactive decay of uranium in the soil. Because it is the
densest gas known, it tends to accumulate in underground spaces, such as mines and basements. In the
1950s, a number of abandoned gold and uranium mines were converted into health spas that
supposedly treat a variety of ailments via exposure to the radon in the mines. Despite the well-known
dangers of radon, some of these spas continue to do business today.
3) Watches
The original glow-in-the-dark watches were painted with radium and a “phosphor” (phosphorescent
compound) to achieve their luminescent effect. As the dangers of radium became known, the paints
were replaced with tritium- and promethium-based paints. While they are also radioactive, they emit
very low-energy beta () radiation, which is easily contained in the small quantities of a watch.
4) Bananas
About 0.01% of all potassium is the radioactive 40K, which means that any high-potassium food, such as
bananas, contains the radioactive isotope. However, your body only absorbs as much potassium as it
needs and flushes the rest away. Even if you eat a truckload of bananas, your radiation exposure is
about the same as eating one or two..
5) Basements
As mentioned above, radon occurs naturally in the soil, and it’s density means that it accumulates in
enclosed, underground spaces. Inhaling it puts the alpha ()-emitter in your lungs, where is the leading
cause of lung cancer after smoking. Because it is also odorless, colorless, and tasteless, the EPA
recommends testing your basement regularly for radon.
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Chernobyl’s Legacy, February 2020
6) Brazil nuts
Brazil nut trees have deep roots that absorb naturally-occurring radium from the soil. The radium
accumulates in the nuts. Brazil nuts are also high in potassium, making them one of the most radioactive
foods available. Fortunately, the radioactivity of Brazil nuts is closely monitored to ensure the ones you
buy in the store are safe.
7) Countertops
Stone countertops, like granite and marble, may contain veins of radioactive uranium and thorium,
which release radon in their decay products. While the composition of natural stone varies, the amount
of radiation exposure from any given countertop is too small to measure by the average consumer.
8) Smoke detectors
Smoke detectors contain a small amount of 241Am, which emits a steady stream of particles. When the
stream is disrupted by the presence of smoke, an alarm is triggered. The plastic casing of the detector is
more than enough to protect you from the radiation—just keep it intact!
9) Submarines
Some US Navy submarines, and a few surface ships, rely on on-board nuclear reactors for power. These
vessels can then run for 25 years or more without refueling, even at high speeds. In contrast, diesel- and
battery-powered ships must refuel every few days or even hours. Due the expense of building and
maintaining nuclear vessels, only about 140 exist today.
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Chernobyl’s Legacy, February 2020
12) Leak detection
Gas & oil pipelines, metal welding, boilers, and vehicle parts are often inspected for cracks or leaks using
192
Ir or 60Co. These isotopes emit rays that can be used like X-rays. Because radioactive decay is
spontaneous, the detectors don’t need batteries to function; they are also small and can find leaks in
tight corners.
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Is Iron the Most Important Element? February 2020
Teacher’s Guide
Is Iron the Most Important Element?
February 2020
Table of Contents
Anticipation Guide 18
Activate students’ prior knowledge and engage them before they read the article.
Graphic Organizer 21
This helps students locate and analyze information from the article. Students should use their own words and
not copy entire sentences from the article. Encourage the use of bullet points.
Answers 22
Access the answers to reading comprehension questions and a rubric to assess the graphic organizer.
Additional Resources 25
Here you will find additional labs, simulations, lessons, and project ideas that you can use with your students
alongside this article.
17
Is Iron the Most Important Element? February 2020
Directions: Before reading the article, in the first column, write “A” or “D,” indicating your Agreement or
Disagreement with each statement. Complete the activity in the box.
As you read, compare your opinions with information from the article. In the space under each statement, cite
information from the article that supports or refutes your original ideas.
Me Text Statement
1. Earth would be lifeless without iron.
3. As a star’s core starts producing iron, the star begins to collapse, eventually forming a
supernova that releases iron into space.
4. Seismic waves were used to confirm the hypothesis that most of Earth’s core is made of iron.
10. Only animals need iron to survive; plants and bacteria do not need iron.
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Is Iron the Most Important Element? February 2020
Student Reading
Comprehension Questions Name: ______________________________
3. What was the procedure that determined that Earth’s core was made of iron?
4. Give examples of how iron is needed for plants and animals to live.
5. There are two ways to get the required iron to live. What are those two ways?
6. List the effects of having too much and too little iron in our bodies.
7. Describe an ionic bond. What would be some properties in ionic bonds that are different from metallic
bonds?
8. Describe the process of converting iron oxides to pure iron. How could this process be detrimental to the
environment?
9. There is very little pure iron in Earth’s crust. How is iron typically found? What does that tell you about the
reactivity of iron, compared to other metals that are typically found in pure form? (Hint: look up the activity
series of metals.)
10. Sketch particle diagrams of pure iron, and of iron/carbon (steel) alloy. Use these diagrams to show how the
alloy is stronger than pure iron.
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Is Iron the Most Important Element? February 2020
1. The core of the planet is over 10,000 oF. Research the ways people are using this heat as an alternative
energy source (called geothermal energy).
2. Research and describe how seismic waves are detected and measured. How do these waves travel through
the planet?
3. Research and report any alternative methods to produce steel that reduces the CO2 production, or how steel
producers try to limit the amount of CO2 produced.
4. Research and list what metals are found in the human body. What are the primary uses/functions of these
metals?
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Is Iron the Most Important Element? February 2020
Directions: As you read, complete the graphic organizer below to describe the importance of iron.
How is iron
formed?
Where is iron
found on Earth?
What ores
contain iron?
How is iron
obtained from
ores?
What
compounds in
living things
contain iron?
What can
happen if you do
not eat enough
iron?
Summary: On the back of this paper, write a tweet (280 characters or less) describing the importance of iron.
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Is Iron the Most Important Element? February 2020
3. What was the procedure that determined that Earth’s core was made of iron?
Scientists measured the seismic waves, created by earthquakes, and how they travelled through Earth.
4. Give examples of how iron is needed for plants and animals to live.
For plants, enzymes that contain iron are needed to help them produce chlorophyll. For humans, iron is
needed in the blood cells as hemoglobin. This chemical helps transport oxygen throughout the body, and
transports carbon dioxide out of the body to the lungs.
5. There are two ways to get the required iron to live. What are those two ways?
Two forms of needed iron are heme and non-heme. The heme is found in meat, poultry and fish. The non-
heme is found in dark green leafy vegetables, as well as cereals, lentils, beans and rice.
6. List the effects of having too much and too little iron in our bodies.
Too much iron in the body will lead to iron poisoning, and hemochromatosis (causing fatigue and joint pain
and other symptoms. Too little iron causes anemia, which results in fatigue and shortness of breath.
7. Describe an ionic bond. What would be some properties in ionic bonds that are different from metallic
bonds?
Ionic bonds occur when electrons are transferred from metal atoms to nonmetal atoms, creating positive and
negative attractions, which form ordered crystal structures. One difference from metallic bonds is that ionic
bonds cannot conduct electricity or heat, because there are no free flowing electrons. The ionic bonds also
create a structure that cannot be malleable or ductile, because the ions remain in a fixed position.
8. Describe the process of converting iron oxides to pure iron. How could this process be detrimental to the
environment?
Coke (impure carbon) is reacted with oxygen to make carbon dioxide.
C + O2 CO2
The resulting carbon dioxide reacts with more coke to make carbon monoxide.
C + CO2 2CO
The carbon monoxide reacts with the iron ore to make pure iron and carbon dioxide
Fe2O3 + 3CO 2Fe + 3CO2
This process is not environmentally friendly because CO2 (a greenhouse gas) is produced. Also, there may be
some excess CO remaining (a poisonous gas). Also, some of the impurities of the coke could be hazardous to
the environment.
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Is Iron the Most Important Element? February 2020
9. There is very little pure iron in the earth’s crust. How is iron typically found? What does that tell you
about the reactivity of iron, compared to other metals that are typically found in pure form? (Hint: look
up the activity series of metals.)
Iron is typically found as iron oxide. Very little pure iron is found in nature. Iron is not very stable reactivity-
wise, compared to other metals. It is easy for oxygen to react with it. (Iron is oxidized).
10. Sketch particle diagrams of pure iron, and of iron/carbon (steel) alloy. Use these diagrams to show how
the alloy is stronger than pure iron.
Carbon atoms fill in the gaps between iron atoms (the interstices), which gives the alloy stronger structure.
2. Research and describe how seismic waves are detected and measured. How do these waves travel
through the planet?
Get started with this article about seismic waves: www.sciencelearn.org.nz/resources/340-seismic-waves
3. Research and report any alternative methods to produce steel that reduces the CO2 production, or how
steel producers try to limit the amount of CO2 produced.
Get started with this C&EN article about this: https://cen.acs.org/environment/greenhouse-gases/Steel-
plant-waste-mop-CO2/97/web/2019/08
4. Research and list what metals are found in the human body. What are the primary uses/functions of these
metals?
You can point students here to get started: https://askabiologist.asu.edu/content/atoms-life
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Is Iron the Most Important Element? February 2020
0 Not acceptable So incomplete that no judgment can be made about student understanding
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Is Iron the Most Important Element? February 2020
Additional Resources
Iron Nail Redox: In this lab, students perform a simple redox reaction using an iron nail and copper(II) chloride
solution. They will consider both quantitative and qualitative data collected during the reaction in order to
attempt to explain what happened. https://teachchemistry.org/classroom-resources/inquiry-redox-investigation
Separating Mixtures: In this lab, students devise their own method to separate a mixture of sand, salt, poppy
seeds, and iron filings. https://teachchemistry.org/classroom-resources/separation-of-a-mixture
Mineral Investigation: In this lab, students will put their problem solving skills to work as a team to determine
how many specific samples of ore can be made from a lode equivalent to the size of their classroom.
https://teachchemistry.org/classroom-resources/mineral-investigation
Other Resources
A clearer look at how iron reacts in the environment: https://www.anl.gov/article/a-clearer-look-at-how-iron-
reacts-in-the-environment
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Is Iron the Most Important Element? February 2020
HS-PS1-3.
Plan and conduct an investigation to gather evidence to compare the structure of substances at the bulk
scale to infer the strength of electrical forces between particles.
HS-ESS1-3.
Communicate scientific ideas about the way stars, over their life cycle, produce elements.
Teaching Strategies
Consider the following tips and strategies for incorporating this article into your classroom:
Alternative to the Anticipation Guide: Before reading, ask students why iron is important to life on Earth.
After reading, ask students what they found most interesting or surprising from reading the article.
After reading, ask students to identify occurrences of iron in their day-to-day lives. Classify each
occurrence of iron as an element or an ion.
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Is Iron the Most Important Element? February 2020
Teacher’s Guide
Chemistry Takes to the Skies
February 2020
Table of Contents
Anticipation Guide 28
Activate students’ prior knowledge and engage them before they read the article.
Graphic Organizer 31
This helps students locate and analyze information from the article. Students should use their own words and
not copy entire sentences from the article. Encourage the use of bullet points.
Answers 32
Access the answers to reading comprehension questions and a rubric to assess the graphic organizer.
Additional Resources 35
Here you will find additional labs, simulations, lessons, and project ideas that you can use with your students
alongside this article.
27
Chemistry Takes to the Skies, February 2020
Directions: Before reading the article, in the first column, write “A” or “D,” indicating your Agreement or
Disagreement with each statement. Complete the activity in the box.
As you read, compare your opinions with information from the article. In the space under each statement, cite
information from the article that supports or refutes your original ideas.
Me Text Statement
11. World War I pilots used skywriting to communicate with one another.
13. The gaseous products expelled from the exhaust pipe of a jet are white.
17. Words written with skywriting remain legible for 3-4 hours.
18. When the letters from skywriting dissipate, the particles evaporate.
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Chemistry Takes to the Skies, February 2020
Student Reading
Comprehension Questions Name: ______________________________
1. Classify each of the following as either chemical or physical processes. For each, explain your answer.
a. Combustion
b. Fractional distillation
3. If there are seven carbons in an alkane, then what is its molecular formula? Write the balanced chemical
equation for the combustion of this seven-carbon compound.
5. When we see a contrail in the sky, it is not the water vapor from the combustion reaction that we see.
Explain what happens to allow us to see this contrail.
6. Would you expect a contrail to last longer on a humid day or a dry day (assuming the same temperature)?
Explain.
7. An aerosol is one subcategory of a colloid. Colloids have particles of one substance with a size between 1
and 1000 nm dispersed in another substance. Each part of this mixture can be of any phase and the phase
combination is what classifies them into their subcategories. Use the table and the figure on page 14 to
answer the questions below:
a. How many nanometers are in a micrometer?
b. How many nanometers are in a kilometer?
c. How many nanometers are in a millimeter?
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Chemistry Takes to the Skies, February 2020
8. Why don’t skywriters simply rely on contrails to do their writing, rather than adding in other substances?
9. Why do contrails and the smoke from skywriting dissipate fairly quickly, even on a day without any wind?
1. Which would make more water when combusted in oxygen, 1 mole of C10H22 or 1 mole of C15H32? Explain,
but do not use calculations.
2. To what total volume will the water vapor from the combustion of 1.00 liter of kerosene spread when
released in the atmosphere at 30,000 feet, where the temperature is -47.8oC and the pressure is 0.298 atm?
The density of kerosene is 0.800 g/cm3.
3. Adiabatic processes are those during which no heat is exchanged between the system and the surroundings.
This term is often used as an approximation for processes that are very fast and have no heat exchange
while the process is occurring, even if heat is eventually exchanged. Fans of Superman often attempt to
describe the science of his superpowers. Use the idea of adiabatics to explain how Superman can freeze
things with his breath.
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Chemistry Takes to the Skies, February 2020
Directions: As you read, complete the graphic organizer below to compare contrails and skywriting.
Contrails Skywriting
How produced
(chemical
equation)
Composition
of vapor
Atmospheric
conditions
needed
Height of
plane
Appearance
Summary: In the space below, or on the back of this paper, write a short email to a friend explaining the
difference between contrails and skywriting.
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Chemistry Takes to the Skies, February 2020
1. Classify each of the following as either chemical or physical processes. For each, explain your answer.
a. Combustion
Chemical process. The bonds in the original compounds are broken and new bonds are formed.
b. Fractional Distillation
Physical process. This works on evaporation and condensation, both of which are physical processes.
No bonds are broken or formed.
3. If there are seven carbons in an alkane, then what is its molecular formula? Write the balanced chemical
equation for the combustion of this seven-carbon compound.
C7H16
C7H16 + 11 O2 7 CO2 + 8 H2O
5. When we see a contrail in the sky, it is not the water vapor from the combustion reaction that we see.
Explain what happens to allow us to see this contrail.
The water vapor from combustion spreads into the atmosphere and condenses into liquid, then freezes into
solid around small particles in the atmosphere, where water vapor from the atmosphere also crystallizes. It is
the frozen water around the particles that we see as the contrail.
6. Would you expect a contrail to last longer on a humid day or a dry day (assuming the same temperature)?
Explain.
It should last longer on a humid day because there are more water molecules in the atmosphere to crystallize
onto the particles, making them last longer before dissipating.
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Chemistry Takes to the Skies, February 2020
7. An aerosol is one subcategory of a colloid. Colloids have particles of one substance with a size between 1
and 1000 nm dispersed in another substance. Each part of this mixture can be of any phase and the phase
combination is what classifies them into their subcategories. Use the table and the figure on page 14 to
answer the questions below:
a. How many nanometers are in a micrometer?
1000 micrometers = 1 nm
b. How many nanometers are in a kilometer?
1012 nanometers = 1 km
c. How many nanometers are in a millimeter?
1,000,000 nm = 1 mm
8. Why don’t skywriters simply rely on contrails to do their writing, rather than adding in other substances?
They fly at 10,000 feet, rather than 30,000 feet, so the air isn’t cold enough to crystallize enough water to
make it very visible.
9. Why do contrails and the smoke from skywriting dissipate fairly quickly, even on a day without any wind?
All molecules are in motion all the time. Over time, the air molecules and the molecules in the contrail or
smoke will run into each other and eventually mix and spread.
2. To what total volume will the water vapor from the combustion of 1.00 liter of kerosene spread when
released in the atmosphere at 30,000 feet, where the temperature is -47.8oC and the pressure is 0.298
atm? The density of kerosene is 0.800 g/cm3.
1000𝑚𝐿 0.800𝑔 1𝑚𝑜𝑙 𝐿 ∙ 𝑎𝑡𝑚⁄
𝑛𝑅𝑇 [(1.00𝐿 × 1𝐿 × 𝑚𝐿 )(170.34𝑔)] × 0.0821 𝑚𝑜𝑙 ∙ 𝐾 × 225.4𝐾
𝑉= = = 292𝐿
𝑃 0.298𝑎𝑡𝑚
3. Adiabatic processes are those during which no heat is exchanged between the system and the
surroundings. This term is often used as an approximation for processes that are very fast and have no
heat exchange while the process is occurring, even if heat is eventually exchanged. Fans of Superman
often attempt to describe the science of his superpowers. Use the idea of adiabatics to explain how
Superman can freeze things with his breath.
Student answers will vary.
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Chemistry Takes to the Skies, February 2020
0 Not acceptable So incomplete that no judgment can be made about student understanding
34
Chemistry Takes to the Skies, February 2020
Additional Resources
Labs and demos
Whoosh bottle: In this demonstration, you will show students how hydrocarbons combust and that the products
are no longer combustible. Do not let students do this experiment, it must be done as a demo.
https://www.flinnsci.com/api/library/Download/bf2f0d16dd86411ea26eb0cb687dc593
What Type of Mixture is Paint: In this lesson students will use simple laboratory tests to characterize differences
between solutions, colloids, and suspensions. They will then apply those tests to paints to classify them as
specific types of mixtures. https://teachchemistry.org/classroom-resources/what-type-of-mixture-is-paint
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Chemistry Takes to the Skies, February 2020
HS-PS2-6.
Communicate scientific and technical information about why the molecular-level structure is important
in the functioning of designed materials.
HS-ETS1-3
Evaluate a solution to a complex real-world problem based on prioritized criteria and tradeoffs that
account for a range of constraints, including cost, safety, reliability, and aesthetics, as well as possible
social, cultural, and environmental impacts.
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Chemistry Takes to the Skies, February 2020
Teaching Strategies
Consider the following tips and strategies for incorporating this article into your classroom:
Alternative to the Anticipation Guide: Before reading, ask students if they have seen contrails,
where they have seen them, and what they think they are made of. Also ask them if they have
seen skywriting, and what questions they have about skywriting. As they read, students
should record information they find interesting and look for answers to their questions.
Show (or ask students to watch) the three-minute video clip referenced in the article to learn
more about contrails.
This lesson could be a phenomenon-based lesson, with skywriting or contrails being the
phenomenon to investigate through combustion reactions.
Ask students what they found most interesting from reading article.
Using phase diagrams, pressure and temperature are easy to find at various altitudes. This can
be used to interact with a phase diagram to learn all of its parts and to explain why the water
condenses and then crystallizes in the upper atmosphere to make a contrail.
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Crystal Caves, February 2020
Teacher’s Guide
Crystal Caves
February 2020
Table of Contents
Anticipation Guide 39
Activate students’ prior knowledge and engage them before they read the article.
Graphic Organizer 42
This helps students locate and analyze information from the article. Students should use their own words and
not copy entire sentences from the article. Encourage the use of bullet points.
Answers 43
Access the answers to reading comprehension questions and a rubric to assess the graphic organizer.
Additional Resources 46
Here you will find additional labs, simulations, lessons, and project ideas that you can use with your students
alongside this article.
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Crystal Caves, February 2020
Directions: Before reading the article, in the first column, write “A” or “D,” indicating your Agreement or
Disagreement with each statement. Complete the activity in the box.
As you read, compare your opinions with information from the article. In the space under each statement, cite
information from the article that supports or refutes your original ideas.
Me Text Statement
1. Huge gypsum crystals were discovered in a cave under a mountain rich in lead, zinc, and
silver ore.
2. The cave where the crystals were found is cold and dry.
7. The age of the crystals in the cave was determined by carbon dating.
8. The Cave of Crystals (with larger crystals) is found at a shallower depth than the Cave of
Swords (with smaller crystals).
10. In order to preserve the gigantic crystals, the crystals must be removed from the cave.
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Crystal Caves, February 2020
Student Reading
Comprehension Questions Name: ______________________________
2. Compare and contrast the following: unsaturated solution, saturated solution, and supersaturated solution.
4. What environmental conditions caused the crystals to grow to their tremendous size?
5. What are the potential benefits of conducting research on the conditions in the cave and on mineral
deposits?
6. Explain how a chemist could create a supersaturated solution in a laboratory. What equipment would be
needed?
7. Rock candy is an example of a product created from a supersaturated solution. Research and explain the
process of making rock candy.
8. Explain, using your knowledge of chemical principles, why generally solubility increases with increasing
temperature.
9. Mineral deposits form in many different colors. What causes the color differences between various
minerals?
10. Compare and contrast the formation of the minerals in the article to how diamonds are formed.
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Crystal Caves, February 2020
Suppose the Mexican government wanted to make “Crystal Cave” a tourist destination to increase tourism
revenue. You have been put in charge of the team who is tasked with making Crystal Cave a safe, accessible,
place for tourists to visit and enjoy the beauty of the caves. Devise a detailed plan explaining how you would
alter a dangerous cave into a civilian-friendly display for all to enjoy.
Things to consider: How would you access the cave? How would you control the climate in the cave and not
interrupt the crystal formation? How would civilians navigate the cave? How would your ensure the structural
integrity of the cave?
41
Crystal Caves, February 2020
Directions: As you read, complete the graphic organizer below to compare the Cave of Crystals and Cave of
Swords described in the article.
Cave of Crystals Cave of Swords
Size of crystals
Type of crystals
Depth of cave
Location of cave
Summary: On the back of this sheet, write a one-sentence summary (18 words or less) describing what you
learned about crystal growth.
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Crystal Caves, February 2020
2. Compare and contrast the following: unsaturated solution, saturated solution, and supersaturated
solution.
Unsaturated Solution: A solution in which more solute can be added and dissolved in the solvent.
Saturated Solution: A solution in which no more solute can be dissolved in the solvent.
Supersaturated Solution: An unstable solution which contains more dissolved solute than the predicted
amount in a saturated solution.
4. What environmental conditions caused the crystals to grow to their tremendous size?
Warm water, mineral rich water, nucleation sites, and a perfect cooling rate. If the water would have could
too fast, the minerals would have been smaller as in the “Cave of Swords”
5. What are the potential benefits of conducting research on the conditions in the cave and on mineral
deposits?
The mineral research could help mining companies prevent mineral deposits on their machinery and
equipment, thus prolonging the life of the equipment and saving the company money.
6. Explain how a chemist could create a supersaturated solution in a laboratory. What equipment would be
needed?
One would need a solute (example sodium acetate), a solvent (example water), a beaker or flask, and a hot
plate. The student/teacher would make a saturated solution of sodium acetate and water with excess
sodium acetate remaining in solution (undissolved) at room temperature. The solution should be slowly
heated while stirring until all the solute dissolves. Once all the solute is completely dissolved the solution
should be cooled slowly. A simple agitation of or the solution or the addition of one granule of the solute
would be enough to cause the supersaturated solute to come out of solution and crystalize
7. Rock candy is an example of a product created from a supersaturated solution. Research and explain the
process of making rock candy.
1) Put water in a pot and bring to boil on a stove or hotplate
2) Slowly add sugar until no more sugar will dissolve
3) Let solution cool to room temperature.
4) Pour solution through a strainer to remove undissolved sugar.
5) Add food coloring or flavoring
6) Pour solution in a jar or cup
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Crystal Caves, February 2020
7) Tie a clean string around a pencil, wooden dowel, or similar object that will allow the string to hang in the
solution
8) Let the string soak in the solution for about a week, undisturbed.
9) Take the string out and enjoy the candy.
8. Explain, using your knowledge of chemical principles, why generally solubility increases with increasing
temperature.
Answers may vary. Simply stated, a higher temperatures molecules have increased kinetic energy and are
vibrating and moving faster. This increased kinetic energy, or vibration, allow solvent molecules to more
effectively break down solute molecules causing them to dissolve or dissociate.
9. Mineral deposits form in many different colors. What causes the color differences between various
minerals?
Color differences in minerals are caused by of the wavelengths of visible light that are absorbed and emitted
from the different minerals. Depending on the composition of the mineral, and which elements (different
arrangement of electrons) they contain and what patterns they form, difference light waves will be absorbed
and emitted causing different colors.
10. Compare and contrast the formation of the minerals in the article to how diamonds are formed.
Mineral deposits in Crystal Cave required mineral rich water, cavernous areas, high temperatures, and slow
cooling.
Diamonds need incredible pressure and temperature deep in the earth’s mantle.
44
Crystal Caves, February 2020
Suppose the Mexican government wanted to make “Crystal Cave” a tourist destination to increase tourism
revenue. You have been put in charge of the team who is tasked with making Crystal Cave a safe, accessible,
places for tourists to visit and enjoy the beauty of the caves. Devise a detailed plan explaining how you would
alter a dangerous cave into a civilian friendly display for all to enjoy.
Things to consider: How would you access the cave? How would you control the climate in the cave and not
interrupt the crystal formation? How would civilians navigate the cave? How would your ensure the structural
integrity of the cave?
Answers will vary. Some things to consider are ease of access to the mine, how the tourist will get down to the
cave, temperature control and comfort in the cave without damaging the crystals, safe navigation of the cave,
structural integrity of the cave, preserving the cave with the increased traffic.
0 Not acceptable So incomplete that no judgment can be made about student understanding
45
Crystal Caves, February 2020
Additional Resources
Supersaturated Solution Lab: Lab in which students create their own supersaturated solution.
https://teachchemistry.org/classroom-resources/winter-crystals
Chemistree: In this lab, students will prepare a solution to observe a physical change.
https://teachchemistry.org/classroom-resources/chemistree
Crystallization of Sugar: In this demonstration, students will observe how to make rock candy in order to
understand how sugar crystals form. They will be able to explain what a supersaturated solution is and how it is
relevant to sugar crystallization. https://teachchemistry.org/classroom-resources/crystallization-of-sugar
Saturated Solutions: An Engagement Activity: In this demonstration, students will observe salt dissolving in
water and participate in a think-pair-share activity using teacher-led questions. It is intended to be an
introduction to solutions, particularly saturation. https://teachchemistry.org/classroom-resources/saturated-
solutions-an-engagement-activity
Particle Modeling of Hand Warmers: In this lesson, students will create a particulate model of matter that
explains energy changes and transfer during a physical process, such as the crystallization of a solid from a
supersaturated solution. https://teachchemistry.org/classroom-resources/particle-modeling-of-hand-warmers
Other Resources
Mineral Chemistry Webinar: A webinar on minerals and chemistry to reinforce or expand on information in the
article. https://teachchemistry.org/professional-development/webinars/the-rocky-road-to-chemistry
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Crystal Caves, February 2020
HS-PS1-5.
Apply scientific principles and evidence to provide an explanation about the effects of changing the
temperature or concentration of the reacting particles on the rate at which a reaction occurs.
HS-ESS2-5.
Plan and conduct an investigation of the properties of water and its effects on Earth materials and
surface processes.
Teaching Strategies
Consider the following tips and strategies for incorporating this article into your classroom:
Alternative to Anticipation Guide: Before reading, ask students if they have ever grown crystals (like rock
candy) and how crystals form. As they read, students can find information to confirm or refute their
original ideas.
After they read, ask students what conditions promoted the growth of the giant gypsum crystals.
47
ChemMatters Magazine, February 2020
Christine Suh (Managing Editor), Emily Abbott (Administrative Editor), and Lis Gallegos (Production
Editor) coordinated the production and development of the Teacher’s Guides.
E-mail: [email protected]
48