III.

BUTYL
HALOBUTYL
184
THE RUBBER FORMULARY

BROMOBUTYL HIGH TEMPERATURE HOSE

Exxon

Bromobutyl 2244 100

N-330 45
Sunpar 2280 5
Stearic Acid 1
Zinc Oxide 5
MBTS 2
TMTDS 1
MS @ 132°C, 3 Pt. Rise 6.1
ML (1+8) @ 100°C 79.2
Rheometer, 160°C, 3° Arc
MH, In-Lb 42.4
ML, In-Lb 18.7
T90, Min. 5.65
Ts2, Min. 2.02
Physical Properties, Cured 20’ @ 160°C
Elongation, % 698
Hardness, Shore A 61
Tensile Strength, MPa 17.27
100% Modulus, MPa 1.26
300% Modulus, MPa 6.29
Aged Physical Properties, 70 Hrs. @ 125°C
Elongation Retained, % 78.5
Hardness Change, Point 3
Tensile Retained, % 91.4
Aged Physical Properties, 70 Hrs. @ 150°C
Elongation Retained, % 63.6
Hardness Change, Point 3
Tensile Retained, % 53.5
Tear Strength, Die C @ 125°C 27.82
Tear Strength, Die C @ 25°C 48.5
Compression Set, 72 Hrs. @ 70°C 22.7
 185
BUTYL, HALOBUTYL

CHLOROBUTYL STEAM HOSE COMPOUND – TUBE

Exxon

Chlorobutyl 1066 100

Hi-Sil 233 60
N-550 20
Paraffinic Oil 10
Stearic Acid 1
Paracin 1 4
Phenolic Resin Tackifier 3
Antioxidant 2246 1
Diethylene Glycol 2
Magnesium Oxide 2
Zinc Oxide 3
TMTDS 2
MBTS 1
ML (1+8) @ 100°C 75
MS @ 132°C, Min. to 3 pt. Rise 23
Physical Properties, Cured 60’ @ 153°C
300% Modulus, MPa 8.0
Tensile Strength, MPa 11.2
Elongation, % 430
Aged Physical Properties, 14 Days @ 149°C
100% Modulus, MPa --
Tensile Strength, MPa 3.3
Elongation, % 90
186
THE RUBBER FORMULARY

STEAM HOSE TUBE

R.T. Vanderbilt

Exxon Chlorobutyl 1066 100.0

Hi-Sil 233 60.0
Flexon 765 10.0
Stearic Acid 1.0
SP-1045 3.0
VANOX MBPC 1.0
Diethylene Glycol 2.0
Magnesium Oxide 0.25
Litharge 10.0
END-75 1.0
Total 188.25
Density, Mg/m3 1.16
Properties, Cured 60 Minutes at 153°C(307°F)
100% Modulus, MPa (psi) 3.9(560)
Tensile Strength, MPa (psi) 13.5(1960)
Elongation, % 720
Hardness, Shore A 62
Mooney at 100°C(212°F)
Plasticity, ML (1+8) 66
Compression Set After 22 Hours at 70°C(158°F)
Set, % 30
 187
BUTYL, HALOBUTYL

DUROMETER 65 COMPOUND FOR STEAM HOSE

PPG

CIIR 1240 100.0

Hi-Sil 233 60.0
Paraffinic Oil 15.0
Stearic Acid 2.0
DEG 3.0
Zinc Oxide 5.0
Magnesia 2.0
ETU (75%) 2.7
Total 187.7
Cure Rate @ 160°C 60’
Mooney Scorch @ 121°C, T5 9’
T35 >30’
Viscosity, ML100 114
Stress-Strain Properties (Cure: 60’/160°C)
Original Aged 3 d @ 121°C
Hardness 65 75
M300 560(3.9)
TB 2140(14.7) 1770(12.2)
EB 660 240
MG Trouser Tear @ 23°C 95(16.6)
@ 100°C 50(8.7)
Compression Set, 3 days @ 100°C 52
DeMattia Flex @ 23°C, KC to 0.6” 15
Yerzley Resilience 50
Water Immersion @ 100°C Volume % Hardness
1 Day 10.3 74
7 Days 9.0 71
14 Days 8.6 73
188
THE RUBBER FORMULARY

HEAT-RESISTANT CONVEYOR BELT

R.T. Vanderbilt

Exxon Bromobutyl 2244 100.0

FEF (N-550) 45.0
Maglite D 1.0
Carbowax 3350 1.5
Stearic Acid 1.0
VANOX MTI 1.0
Zinc Oxide 3.0
VAROX DCP-40C 2.0
VANAX MBM 1.0
Cured 35>PR at 160°C
Original/Aged 7 Days at 150°C
Hardness, Shore A 59/64
Tensile Strength, MPa 11.2/9.1
Elongation, % 250/200
 189
BUTYL, HALOBUTYL

CHLOROBUTYL COVER COMPOUND FOR CONVEYOR BELT

Exxon

Chlorobutyl 1066 100

N-330 25
N-110 25
Paraffinic Oil 5
Stearic Acid 1
Phenolic Resin Tackifier 3
Antioxidant 2246 1
Magnesium Oxide 1
Zinc Oxide 5
TMTDS 1
MBTS 2
ML (1+8) @ 100°C 75
MS @ 126°C, Min. to 5 pt. Rise 23
Physical Properties, Cured 40’ @ 153°C
Hardness, Shore A 69
300% Modulus, MPa 8.3
Tensile Strength, MPa 19.1
Elongation, % 580
Aged Physical Properties, 16 Hrs. @ 194°C
Hardness, Shore A 80
100% Modulus, MPa 3.5
Tensile Strength, MPa 4.5
Elongation, % 175
190
THE RUBBER FORMULARY

BROMOBUTYL CONVEYOR BELT COVER

Exxon

Bromobutyl 2222 100

N-550 45
Naphthenic Oil 5
Stearic Acid 1
Carbowax 3350 1.5
Magnesium Oxide 1
MBI 1
DiCup 40C 2
HVA-2 1
Rheometer, 171°C, 3° Arc, 30’
ML, dN-m 23
MH, dN-m 85
Ts2, minutes 1
Tc90, minutes 8
Physical Properties, Cured 12’ @ 180°C
Hardness, Shore A 56
100% Modulus, MPa 2.7
Tensile Strength, MPa 9.2
Elongation, % 900
Aged Physical Properties, 14 Days @ 150°C
Hardness, Shore A 51
100% Modulus, MPa 2.4
Tensile Strength, MPa 6.7
Elongation, % 270
Compression Set, 72 Hrs. @ 125°C, % 35
 191
BUTYL, HALOBUTYL

TIRE WHITE SIDEWALL COMPOUND

Uniroyal
1 2

Naugawhite Antioxidant ---- 1.5
Natural Rubber 35.0 35.0
Chlorobutyl Rubber 50.0 50.0
Royalene 505 15.0 15.0
Titanium Dioxide 40.0 40.0
Hydrated Aluminum Silicate 20.0 10.0
Zinc Oxide 15.0 15.0
Stearic Acid 1.0 1.0
Sunproof Improved Wax 3.0 3.0
Tackifying Resins 3.0 3.0
Ultramarine Blue 0.2 0.2
Vultac 5 1.0 1.0
Delac NS 1.5 1.5
Insoluble Sulfur, 80% Oiled 1.5 1.5
Mooney Viscosity
ML (1+4) @ 100°C 32 31
Mooney Scorch, MS @ 132°°C
3 pt. Rise, minutes 12.6 13.1
Physical Properties at Room Temperature
Press Cured 30 minutes @ 160°°C
Tensile Strength, MPa 17.4 16.8
Elongation, % 630 610
300% Modulus, MPa 5.8 6.1
Hardness, Shore A 51 52
Oven Aging, 1 Month @ 70°°C, % Retention
Tensile Strength, MPa 12.1 14.7
Tensile Strength, % Retained 70 88
Elongation, % 570 580
Elongation, % Retained 90 95
300% Modulus, MPa 8.1 7.4
300% Modulus, % Retained 140 121
Hardness, Shore A 57 55
DeMattia Flexing
KC to failure 4524 4994
Outdoor Dynamic Flexing
KC to failure 7155 33030
192
THE RUBBER FORMULARY

TIRE INNERLINER COMPOUND

Uniroyal
1 2

Naugard Q ---- 1.5
Zinc Oxide 1.5 1.0
Sulfur 1.0 1.5
Chlorobutyl 1066 60.0 60.0
Natural Rubber 20.0 20.0
SBR 8401 27.5 27.5
N-660 Black 60.0 60.0
Paraffinic Oil 10.0 10.0
Stearic Acid 1.0 1.0
Hydrocarbon Resin 2.0 2.0
Naugex MBTS 1.0 1.0
Mooney Viscosity ML (1+4) @ 100°C 49 51
Mooney Scorch, MS @ 132°°C
3 pt. Rise, minutes 16.3 15.9
Physical Properties at Room Temperature
Press Cured 15 minutes @ 165°°C
Tensile, MPa 14.0 13.8
Elongation, % 650 670
300% Modulus, MPa 5.4 4.9
Hardness, Shore A 55 53
Tear, Die C, kN/m 28.0 29.5
Oven Aging, 2 Weeks @ 70°°C
Tensile Strength 10.1 12.2
Tensile Strength, % Retention 72 88
Elongation, % 410 500
Elongation, % Retention 63 74
300% Modulus, MPa 7.9 7.1
300% Modulus, % Retention 146 144
Hardness, Shore A 62 59
Hardness, points change +7 +6
Tear, Die C, kN/m 20 22
Tear, Die C, % Retention 71 74
Flex Fatigue to Failure
Kilocycles 1408 2107
DeMattia Flex, Kilocycles 6800 7100
 193
BUTYL, HALOBUTYL

CHLOROBUTYL INNERLINER COMPOUND

Exxon

Chlorobutyl 1065 100

N-660 60
Naphthenic Oil 8
Stearic Acid 2
Phenolic Resin Tackifier 4
Struktol 40 MS 7
Magnesium Oxide 0.15
Zinc Oxide 3
Sulfur 0.5
MBTS 1.5
ML (1+4) @ 100°C 43
MS @ 135°C, Min. to 3 pt. Rise 12
Physical Properties, Cured 25’ @ 160°C
Hardness, Shore A 55
300% Modulus, MPa 3.2
Tensile Strength, MPa 8.1
Elongation, % 860
Tear Strength, kN/m @ 100°C 27
Aged Physical Properties, 3 Days @ 125°C
Hardness, Shore A 74
100% Modulus, MPa 8.3
Tensile Strength, MPa 8.3
Elongation, % 330
194
THE RUBBER FORMULARY

BROMOBUTYL INNERLINER COMPOUND

Exxon

Bromobutyl 2222 100

N-660 60
Naphthenic Oil 8
Stearic Acid 1
Phenolic Resin Tackifier 4
Struktol 40 MS 7
Magnesium Oxide 0.15
Zinc Oxide 3
Sulfur 0.5
MBTS 1.5
ML (1+4) @ 100°C 70
MS @ 135°C, Min. to 3 pt. Rise 14
Rheometer, 160°C, 3° Arc
MH-ML, lb-in 21
Ts2, minutes 4
Tc90, minutes 18
Physical Properties, Cured 25’ @ 160°C
Hardness, Shore A 56
300% Modulus, MPa 2.7
Tensile Strength, MPa 9.2
Elongation, % 900
Tear Strength, kN/m @ 100°C 27
 195
BUTYL, HALOBUTYL

INNERLINERS
R.T. Vanderbilt
1 2 3
Chlorobutyl 1065 100.0 80.0 ---
Chlorobutyl 1066 --- --- 60.0
Natural Rubber --- 20.0 25.0
Plioflex 1778 --- --- 20.6
N-660 GPF Black 60.0 55.0 ---
N-330 HAF Black --- --- 40.0
Whiting (OMYA) --- --- 40.0
Phenol-Formaldehyde Resin 4.0 8.0 4.0
Struktol 40 MS 7.0 10.0 ---
Naphthenic Oil 8.0 --- 10.0
Stearic Acid 2.0 2.0 1.0
Magnesium Oxide 0.15 --- 0.5
Zinc Oxide 3.0 3.0 3.0
Sulfur 0.5 0.5 ---
ALTAX 1.5 1.5 1.0
Vultac 5 --- --- 1.3
METHYL TUADS --- --- 0.25
Mooney Viscosity at 100°C, ML
1+4 Minute Reading 43 52 54
Mooney Scorch, MS
Minutes to 3 Pt. Rise, 135°C 12 12 ---
Minutes to 5 Pt. Rise, 121°C --- --- 15
Original/After Aging 3 Days at 125°C in Air
Cure Time, Minutes at 160°C 25 25 20
Shore A Hardness 55/74 63/76 55
300% Modulus, MPa 3.2/8.3 3.6/6.8 5.2
Tensile Strength, MPa 8.1/8.6 10.8/8.7 11.1
Elongation, % 860/330 850/510 520
Tear Strength, kN/m at 100°C 27 25 28
Air Permeability, 66°C
Q x 103 3.0 6.0 8.2
General Purpose Rubber Carcass Adhesion, 100°C
kN/m 4.4 1* 15.0 S/1* ---
*S denotes stock tearing; 1 denotes interfacial separation
Monsanto Fatigue-to-Failure
Extension, % 140 140 100
Kilocycle to Failure 415 434 236
196
THE RUBBER FORMULARY

INNERLINER
R.T. Vanderbilt

Exxon Bromobutyl 2255 100.0

Carbon Black GPF (N-660) 50.0
Flexon 876 8.0
Stearic Acid 2.0
Maglite D 0.5
Mineral Rubber 7.0
Sulfur 0.5
ALTAX 1.5
Mooney Viscosity at 100°C
1+8 Min. Reading 65
Mooney Scorch at 135°C
Min. to 5 Pt. Rise 22
Rheometer at 150°C
ML/MH, lb/in 18/44
tc90, Min. 37
Monsanto Tel-Tak, kPa (30 s, 16 oz.)
• To Self 240
• To 100% NR Carcass 125
• To 50/50 NR/SBR Carcass 80
• To 25/75 NR/BR Chafer 85
Green Strength, MPa x 10-2 27
Decay Time to 50% of Initial Stress, s 32
Press Cured Tc90 Minute at 150°C
Initial/After Aging 3 Days at 125°C in Air
Hardness, Shore A 44/48
100% Modulus, MPa 1.1/1.5
300% Modulus, MPa 3.7/4.8
Tensile Strength, MPa 11.8/10.4
Elongation at Break, % 756/687
Tear Strength, kN/m 40/36
Monsanto Fatigue-to-Failure
K cycles, 140% Extension
Mean 40
Range 25-55
 197
BUTYL, HALOBUTYL

INNERLINER
Continued

Static Peel Adhesion to 100% NR Carcass, kN/m 35*

* = Separation with stock tearing
Permeability to Air at 65°C
cm3.cm.cm-2.s-1.atm-1.10-8 3.0
Water Vapor Permeability at 65°C
g.cm.cm-2.h-1.atm-1.10-6 2.5
198
THE RUBBER FORMULARY

CHLOROBUTYL EXHAUST HANGER COMPOUND

Exxon

Chlorobutyl 1068 100

N-330 40
Paraffinic Oil 15
Stearic Acid 1
Zinc Oxide 5
TMTDS 1
MBTS 2
ML (1+8) @ 100°C 53
MS @ 127°C, Min. to 3 pt. Rise 10
Rheometer, 171°C, 3° Arc, 30’
ML, lb-in 11.2
MH, lb-in 34.0
Ts2 minutes 1.6
Tc90, minutes 4.3
Physical Properties, Cured 60’ @ 153°C
Hardness, Shore A 51
100% Modulus, MPa 1.0
300% Modulus, MPa 4.7
Tensile Strength, MPa 13.1
Elongation, % 620
Tear Strength, Die C, kN/m 40
Aged Physical Properties, 70 Hours @ 125°C
Hardness Change, Points 9
Tensile Change, % -13
Elongation Change, % -34
 199
BUTYL, HALOBUTYL

DUROMETER 45 COMPOUND FOR SQUASH BALLS

PPG

Bromobutyl X2 75.0
SMR 25.0
Hi-Sil 233 20.0
Hi-Sil EP 20.0
Barytes 40.0
Naphthenic Oil 10.0
ODPA 1.0
Stearic Acid 2.0
Diethylene Glycol 2.0
Zinc Oxide 10.0
Sulfur 0.6
CBS 1.5
TMTD 1.0
Total 208.1
Cure Rate, 90% ODR
At 150°C 17
At 166°C 9
Mooney Scorch at 121°C, T5 11
Viscosity, ML100 54
Stress-Strain Properties (Cure: 10’/166°C)
Original Aged 3 d @ 150°C
Hardness 45 70
M300 130(0.9)
TB 1460(10) 430(2.9)
EB 840 350
Trouser Tear, Grooved; lbs./in. 95(17)
Goodyear Rebound, % 38.4
PICO Abrasion Index 32 (Chunking)
Compression Set, 70 hr. @ 100°C 39
200
THE RUBBER FORMULARY

CHLORINATED BUTYL PHARMACEUTICAL CLOSURE

Engelhard

Chlorobutyl HT 10-66 100.00

Maglite D 2.00
Satintone W 120.00
Paraffin Wax 2.00
Paricin 1 2.50
Zinc Oxide 5.00
NA-22 1.50

Specific Gravity 1.42

Processibility Properites
Mooney Scorch @ 270°C(MS), t3, mins. 26
Mooney Viscosity, ML (1+8), 212°F, units 69
Physical Properties,
Press Cure: 60 secs @ 420°°F
Hardness 61
300% Modulus, psi 325
Tensile Strength, psi 900
Ultimate Elongation, % 640
 201
BUTYL, HALOBUTYL

BROMOBUTYL PHARMACEUTICAL CLOSURE

Exxon

Bromobutyl 2244 100

Whitex 60
Stearic Acid 1
AC-617A 3
Wax 2
White Oil 5
Diak No. 1 1
ML (1+8) @ 100°C 53
MS @ 132°C, Min. to 3 pt. Rise 4.6
Physical Properties, Cured 10’ @ 171°C
Hardness, Shore A 45
100% Modulus, MPa 0.7
300% Modulus, MPa 1.2
Tensile Strength, MPa 6.0
Elongation, % 640
Tear, Die C @ 25°C 15
@ 160°C 5.5
Compression Set, 22 Hrs. @ 70°C, % 16
202
THE RUBBER FORMULARY

DUROMETER 55 COMPOUND FOR GENERAL MRG

PPG

Butyl 365 100.0

Hi-Sil 233 40.0
Naphthenic Oil 5.0
KP 140 3.0
Stearic Acid 1.0
Zinc Oxide 5.0
PEG 4000 3.0
Sulfur As noted
TMETD 2.0
DPTH 1.0
Sulfur 1.7 0.5
Cure Rate @ 160°C, 90% ODR 20 13
Mooney Scorch @ 121°C, T5` 19 19
Viscosity, ML 100 77 80
Garvey Extrusion @ 121°C
Rate, Ft./Min. 5 5
Swell, % 35 35
Edge & Surface 10A 10A
Stress-Strain Properties
Cure @ 160°C 30’ 20’
Hardness 57 56
M300 190(1.3) 130(0.9)
Tensile 2020(14) 1950(13)
Elongation 750 850
Aged 3 Days @ 121°C
Hardness 60 62
M300 370(2.5) 240(1.6)
Tensile 1600(11) 1300(9.0)
Elongation 750 860
Trouser Tear, Grooved, lbs./in.
At 20°C 60(11) 80(14)
At 100°C 22(3.8) 40(7.0)
PICO Abrasdion 39 44
Compression Set, 70 h @ 100°C 65 53
 203
BUTYL, HALOBUTYL

DUROMETER 55 COMPOUND FOR GENERAL MRG

Continued

DeMattia Flex @ 20°C

KC to 0.6” cut growth 9 60
Water Immersion @ 100°C
1 Day 5.8 6.2
3 Days 8.2 8.7
7 Days 7.9 10.9
204
THE RUBBER FORMULARY

LOW RESILIENCE COMPOUND

R.T. Vanderbilt

Exxon Butyl 268 100.0

THERMAX N-990 Carbon Black 15.0
HAF (N-330) Carbon Black 30.0
Flexon 845 Naphthenic Oil 10.0
Zinc Oxide 5.0
Sulfur 1.0
ETHYL CADMATE 2.0
ALTAX 0.5
Total 183.5
Properties, Cured 30 minutes at 160°C
Hardness, Shore A 48
Tensile, MPa (psi) 15(2200)
Elongation, % 640
Density, Mg/m3 1.11
Resilience at 20°C, % 11
Resilience at 100°C ∼55
 205
BUTYL, HALOBUTYL

HIGH HARDNESS COMPOUND

R.T. Vanderbilt

Exxon Chlorobutyl 1066 100.0

Magnesium Oxide 1.0
Stearic Acid 1.0
VANOX MBPC 1.0
VANWAX H 2.0
FEF (N-550) Carbon Black 15.0
HAF (N-350) Carbon Black 35.0
CRF (N-326) Carbon Black 40.0
VANWAX H Special 10.0
Zinc Oxide 5.0
ALTAX 2.0
SP-1055 Resin 4.0
Total 216.0
Properties, Cured 30 minutes at 160°C
Hardness, Shore A 82
Tensile, MPa (psi) 12(1700)
Elongation, % 240
Density, Mg/m3 1.17
206
THE RUBBER FORMULARY

Notes: